Depending on the thermal environment and the final temperature, pyrolysis will yield mainly biochar at low temperatures, less than 450 ⁰C, when the heating rate is quite slow, and mainly gases at high temperatures, greater than 800 ⁰C, with rapid heating rates. At an intermediate temperature and under relatively high heating rates, the main product is bio-oil.

Pyrolysis can be performed at relatively small scale and at remote locations which enhance energy density of the biomass resource and reduce transport and handling costs.  Pyrolysis offers a flexible and attractive way of converting solid biomass into an easily stored and transported liquid, which can be successfully used for the production of heat, power and chemicals.

A wide range of biomass feedstocks can be used in pyrolysis processes. The pyrolysis process is very dependent on the moisture content of the feedstock, which should be around 10%. At higher moisture contents, high levels of water are produced and at lower levels there is a risk that the process only produces dust instead of oil. High-moisture waste streams, such as sludge and meat processing wastes, require drying before subjecting to pyrolysis.

The efficiency and nature of the pyrolysis process is dependent on the particle size of feedstocks. Most of the pyrolysis technologies can only process small particles to a maximum of 2 mm keeping in view the need for rapid heat transfer through the particle. The demand for small particle size means that the feedstock has to be size-reduced before being used for pyrolysis.

Pyrolysis processes can be categorized as slow pyrolysis or fast pyrolysis. Fast pyrolysis is currently the most widely used pyrolysis system. Slow pyrolysis takes several hours to complete and results in biochar as the main product. On the other hand, fast pyrolysis yields 60% bio-oil and takes seconds for complete pyrolysis. In addition, it gives 20% biochar and 20% syngas.

Bio-oil is a dark brown liquid and has a similar composition to biomass. It has a much higher density than woody materials which reduces storage and transport costs. Bio-oil is not suitable for direct use in standard internal combustion engines. Alternatively, the oil can be upgraded to either a special engine fuel or through gasification processes to a syngas and then bio-diesel. Bio-oil is particularly attractive for co-firing because it can be more readily handled and burned than solid fuel and is cheaper to transport and store.

Bio-oil can offer major advantages over solid biomass and gasification due to the ease of handling, storage and combustion in an existing power station when special start-up procedures are not necessary. In addition, bio-oil is also a vital source for a wide range of organic compounds and speciality chemicals.

]]> http://www.bioenergyconsult.com/biomass-pyrolysis-process/feed/ 0 http://www.bioenergyconsult.com/biomass-handling-equipments/ http://www.bioenergyconsult.com/biomass-handling-equipments/#comments Sun, 19 Feb 2012 13:47:15 +0000 Salman Zafar http://www.bioenergyconsult.com/?p=856 Read more... → ]]>

The physical handling of biomass fuels during collection or at a processing plant can be challenging to conveying equipment designers, particularly for solid biomass. Biomass fuels tend to vary with density, moisture content and particle size (some even being stringy in nature) and can also be corrosive. Therefore biomass fuel handling equipment is often a difficult part of a plant to adequately design, maintain and operate.

The design and equipment choice for the fuel handling system, including preparation and refinement systems is carried out in accordance with the plant configuration. This is of special importance when the biomass is not homogeneous and contains impurities, typically for forest and agro residues. Some of the common problems encountered have been the unpopular design and undersized fuel handling, preparation and feeding systems. The fuel handling core systems and equipment are dependent on both the raw fuel type and condition as well as on the conversion/combustion technology employed. The core equipments in a biomass power plant include the following:

1. Fuel reception
2. Fuel weighing systems
3. Receiving bunkers
4. Bunker discharge systems (stoker, screw, grab bucket)
5. Fuel preparation
6. Fuel drying systems
7. Crushers
8. Chippers
9. Screening systems
10. Shredding systems
11. Grinding systems (for pulverised fuel burners)
12. Safety systems (explosion relieve, emergency discharge, fire detections and protection)
13. Fuel transport and feeding
14. Push floors
15. Belt feeders
16. Conveyers, Elevators
17. Tube feeders
18. Fuel hoppers and silos (refined fuel)
19. Hopper, bunker and silo discharge
20. Feeding stokers
21. Feeding screws
22. Rotary valves

To enable any available biomass resource to be matched with the end use energy carrier required (heat, electricity or transport fuels) the correct selection of conversion technologies is required. Since the forms in which biomass can be used for energy are diverse, optimal resources, technologies and entire systems will be shaped by local conditions, both physical and socio-economic in nature. Since the majority of people in developing countries will continue using biomass as their primary energy source well into the next century, it is of critical importance that biomass-based energy truly can be modernized to yield multiple socioeconomic and environmental benefits.

• Primary residues – paddy straw, sugarcane top, maize stalks, coconut empty bunches and frond, palm oil frond and bunches;
• Secondary residues – paddy husk, bagasse, maize cob, coconut shell, coconut husk, coir dust, saw dust, palm oil shell, fiber and empty bunches, wastewater, black liquor.

Agricultural residues are highly important sources of biomass fuels for both the domestic and industrial sectors. Availability of primary residues for energy application is usually low since collection is difficult and they have other uses as fertilizer, animal feed etc. However secondary residues are usually available in relatively large quantities at the processing site and may be used as captive energy source for the same processing plant involving minimal transportation and handling cost.

Crop residues encompasses all agricultural wastes such as straw, stem, stalk, leaves, husk, shell, peel, pulp, stubble, etc. which come from cereals (rice, wheat, maize or corn, sorghum, barley, millet), cotton, groundnut, jute, legumes (tomato, bean, soy) coffee, cacao, tea, fruits (banana, mango, coco, cashew) and palm oil.

Rice produces both straw and rice husks at the processing plant which can be conveniently and easily converted into energy. Significant quantities of biomass remain in the fields in the form of cob when maize is harvested which can be converted into energy. Sugar cane harvesting leads to harvest residues in the fields while processing produces fibrous bagasse, both of which are good sources of energy. Harvesting and processing of coconuts produces quantities of shell and fibre that can be utilised. Peanuts leave shells. All these materials can be converted into energy.

In anaerobic digestion, organic material is converted to biogas by a series of bacteria groups into methane and carbon dioxide. The majority of commercially operating digesters are plug flow and complete-mix reactors operating at mesophilic temperatures. The type of digester used varies with the consistency and solids content of the feedstock, with capital investment factors and with the primary purpose of digestion.

Biogas contain significant amount of hydrogen sulfide (H₂S) gas which needs to be stripped off due to its highly corrosive nature. The removal of H₂S takes place in a biological desulphurization unit in which a limited quantity of air is added to biogas in the presence of specialized aerobic bacteria which oxidizes H₂S into elemental sulfur.

Gas is dried and vented into a CHP unit to a generator to produce electricity and heat. The size of the CHP system depends on the amount of biogas produced daily. The digested substrate is passed through screw presses for dewatering and then subjected to solar drying and conditioning to give high-quality organic fertilizer. The press water is treated in an effluent treatment plant based on activated sludge process which consists of an aeration tank and a secondary clarifier. The treated wastewater is recycled to meet in-house plant requirements. A chemical laboratory is necessary to continuously monitor important environmental parameters such as BOD, COD, VFA, pH, ammonia, C:N ratio at different locations for efficient and proper functioning of the process.

The continuous monitoring of the biogas plant is achieved by using a remote control system such as Supervisory Control and Data Acquisition (SCADA) system. This remote system facilitates immediate feedback and adjustment, which can result in energy savings.

Vietnam is one of the few countries having a low level of energy consumption in the developing world with an estimated amount of 210 kg of oil equivalent per capita/year. Over half of the Vietnamese population does not have access to electricity. The development of power sources is limited mainly to large central power plants using hydropower and traditional fossil fuels. Vietnam is facing the difficult challenge of maintaining this growth in a sustainable manner, with no or minimal adverse impacts on society and the environment.

Biomass energy potential is estimated at 1,430 MW by 2002, and could supply 9,020 GWh of electricity annually. The possible major biomass sources likely to be exploited in the near future for power production are paddy straw, rice husk and bagasse. Their estimated potential is 730 MW, and could provide 4500 GWh of electricity yearly. Rice husk and bagasse are the biomass resources with the greatest economic potential, estimated at 50 MW and 150 MW respectively (ENERTEAM, 2003). Biomass fuels sources that can also be developed include forest wood, rubber wood, logging residues, saw mill residues, sugar cane residues, bagasse, coffee husk and coconut residues. Currently biomass is generally treated as a non-commercial energy source, and collected and used locally.

The biogas potential in the country is large due to livestock population of more than 30 million, mostly pigs, cattle, and water buffalo. Although most livestock dung already is used in feeding fish and fertilizing fields and gardens, there is potential for higher-value utilization through biogas production. It is estimated that more than 25,000 household biogas digesters with 1 to 50 m³, have been installed in rural areas. The Dutch-funded Biogas Program operated by SNV Vietnam constructed some 18,000 biogas facilities in 12 provinces between 2003 and 2005, with a second phase (2007-2010) target of 150,000 biogas tanks in both rural and semi-urban settings.

]]> http://www.bioenergyconsult.com/biomass-energy-vietnam/feed/ 1 http://www.bioenergyconsult.com/major-obstacles-in-indias-biodiesel-program/ http://www.bioenergyconsult.com/major-obstacles-in-indias-biodiesel-program/#comments Mon, 30 Jan 2012 06:49:19 +0000 Salman Zafar http://bioenergyconsult.wordpress.com/?p=621 Read more... → ]]> The unavailability of sufficient feedstock and lack of R&D to evolve high-yielding drought tolerant Jatropha seeds have been major stumbling blocks. In addition, smaller land holdings, ownership issues with government or community-owned wastelands, lackluster progress by state governments and negligible commercial production of biodiesel have hampered the efforts and investments made by both private and public sector companies.

Another major obstacle in implementing the biodiesel programme has been the difficulty in initiating large-scale cultivation of Jatropha. The Jatropha production program was started without any planned varietal improvement program, and use of low-yielding cultivars made things difficult for smallholders. The higher gestation period of biodiesel crops (3–5 years for Jatropha and 6–8 years for Pongamia) results in a longer payback period and creates additional problems for farmers where state support is not readily available. The Jatropha seed distribution channels are currently underdeveloped as sufficient numbers of processing industries are not operating. There are no specific markets for Jatropha seed supply and hence the middlemen play a major role in taking the seeds to the processing centres and this inflates the marketing margin.

 Biodiesel distribution channels are virtually non-existent as most of the biofuel produced is used either by the producing companies for self-use or by certain transport companies on a trial basis. Further, the cost of biodiesel depends substantially on the cost of seeds and the economy of scale at which the processing plant is operating. The lack of assured supplies of feedstock supply has hampered efforts by the private sector to set up biodiesel plants in India. As of now, only two firms, Naturol Bioenergy Limited and Southern Online Biotechnologies, have embarked on commercial-scale biodiesel projects, both in the southern state of Andhra Pradesh. In the absence of seed collection and oil extraction infrastructure, it becomes difficult to persuade entrepreneurs to install trans-esterification plants.

Thailand’s annual energy consumption has risen sharply during the past decade and will continue its upward trend in the years to come. While energy demand has risen sharply, domestic sources of supply are limited, thus forcing a significant reliance on imports. To face this increasing demand, Thailand needs to produce more energy from its own renewable resources, particularly biomass wastes derived from agro-industry, such as bagasse, rice husk, wood chips, livestock and municipal wastes.

In 2005, total installed power capacity in Thailand was 26,430 MW. Renewable energy accounted for about 2 percent of the total installed capacity. In 2007, Thailand had about 777 MW of electricity from renewable energy that was sold to the grid. Several studies have projected that biomass wastes can cover up to 15 % of the energy demand in Thailand (Thailand-Danish Country Programme for Environmental Assistance 1998-2001, Ministry of Environment and Energy, 2000). These estimations are primarily made from biomass waste from the extraction part of agricultural activities, and for large scale agricultural processing of crops etc. – as for instance saw and palm oil mills – and do not include biomass wastes from SMEs in Thailand. Thus, the energy potential of biomass waste can be much larger if these resources are included. The major biomass resources in Thailand include the following:

• Woody biomass residues from forest plantations
• Agricultural residues (rice husk, bagasse, corn cobs, etc.)
• Wood residues from wood and furniture industries    (bark, sawdust, etc.)
• Biomass for ethanol production (cassava, sugar cane, etc.)
• Biomass for biodiesel production (palm oil, jatropha oil, etc.)
• Industrial wastewater from agro-industry
• Livestock manure
• Municipal solid wastes and sewage

Thailand’s vast biomass potential has been partially exploited through the use of traditional as well as more advanced conversion technologies for biogas, power generation, and biofuels. Rice, sugar, palm oil, and wood-related industries are the major potential biomass energy sources. The country has a fairly large biomass resource base of about 60 million tons generated each year that could be utilized for energy purposes, such as rice, sugarcane, rubber sheets, palm oil and cassava. Biomass has been a primary source of energy for many years, used for domestic heating and industrial cogeneration. For example, paddy husks are burned to produce steam for turbine operation in rice mills; bagasse and palm residues are used to produce steam and electricity for on-site manufacturing process; and rubber wood chips are burned to produce hot air for rubber wood seasoning.

In addition to biomass residues, wastewater containing organic matters from livestock farms and industries has increasingly been used as a potential source of biomass energy. Thailand’s primary biogas sources are pig farms and residues from food processing. The production potential of biogas from industrial wastewater from palm oil industries, tapioca starch industries, food processing industries, and slaughter industries is also significant. The energy-recovery and environmental benefits that the KWTE waste to energy project has already delivered is attracting keen interest from a wide range of food processing industries around the world.

The main problem with anaerobic digestion of crop residues is that most of the agricultural residues are lignocellulosic with low nitrogen content. To improve the digestibility of crop residues, pre-treatment methods like size reduction, electron irradiation, heat treatment, enzymatic action etc are necessary. For optimizing the C/N ratio of agricultural residues, co-digestion with sewage sludge, animal manure or poultry litter is recommended.

Several organic wastes from plants and animals have been exploited for biogas production as reported in the literature. Plant materials include agricultural crops such as sugar cane, cassava, corn etc, agricultural residues like rice straw, cassava rhizome, corn cobs etc, wood and wood residues (saw dust, pulp wastes, and paper mill. Others include molasses and bagasse from sugar refineries, waste streams such as rice husk from rice mills and residues from palm oil extraction and municipal solid wastes, etc. However, plant materials such as crop residues are more difficult to digest than animal wastes (manures) because of difficulty in achieving hydrolysis of cellulosic and lignocellulosic constituents.

Crop residues can be digested either alone or in co-digestion with other materials, employing either wet or dry processes. In the agricultural sector one possible solution to processing crop biomass is co-digestion together with animal manures, the largest agricultural waste stream. In addition to the production of renewable energy, controlled anaerobic digestion of animal manures reduces emissions of greenhouse gases, nitrogen and odour from manure management, and intensifies the recycling of nutrients within agriculture.

In co-digestion of plant material and manures, manures provide buffering capacity and a wide range of nutrients, while the addition of plant material with high carbon content balances the carbon to nitrogen (C/N) ratio of the feedstock, thereby decreasing the risk of ammonia inhibition. The gas production per digester volume can be increased by operating the digesters at a higher solids concentration. Batch high solids reactors, characterized by lower investment costs than those of continuously fed processes, but with comparable operational costs, are currently applied in the agricultural sector to a limited extent.

A biorefinery is a facility that integrates biomass conversion processes and equipment to produce fuels, power, and value-added chemicals from biomass. The biorefinery concept is analogous to today’s petroleum refinery, which produces multiple fuels and products from petroleum.By producing several products, a biorefinery takes advantage of the various components in biomass and their intermediates, therefore maximizing the value derived from the biomass feedstock. A biorefinery could, for example, produce one or several low-volume, but high-value, chemical products and a low-value, but high-volume liquid transportation fuel such as biodiesel or bioethanol. At the same time, it can generate electricity and process heat, through CHP technology, for its own use and perhaps enough for sale of electricity to the local utility. The high value products increase profitability, the high-volume fuel helps meet energy needs, and the power production helps to lower energy costs and reduce GHG emissions from traditional power plant facilities.

There are several platforms which can be employed in biorefineries with the major ones being the sugar platform and the thermochemical platform (also known as syngas platform). Sugar platform biorefineries breaks down biomass into different types of component sugars for fermentation or other biological processing into various fuels and chemicals. On the other hand, thermochemical biorefineries transform biomass into synthesis gas (hydrogen and carbon monoxide) or pyrolysis oil.

The thermochemical biomass conversion process is complex, and uses components, configurations, and operating conditions that are more typical of petroleum refining. Biomass is converted into syngas, and syngas is converted into an ethanol-rich mixture. However, syngas created from biomass contains contaminants such as tar and sulphur that interfere with the conversion of the syngas into products. These contaminants can be removed by tar-reforming catalysts and catalytic reforming processes. This not only cleans the syngas, it also creates more of it, improving process economics and ultimately cutting the cost of the resulting ethanol.

The typical composition of raw biogas does not meet the minimum CNG fuel specifications. In particular, the CO₂ and sulfur content in raw biogas is too high for it to be used as vehicle fuel without additional processing. Biogas that has been upgraded to biomethane by removing the H₂S, moisture, and CO₂ can be used as a vehicular fuel. Biomethane is less corrosive than biogas, apart from being more valuable as a fuel.

Since production of such fuel typically exceeds immediate on-site demand, the biomethane must be stored for future use, usually either as compressed biomethane (CBM) or liquefied biomethane (LBM). Biomethane can be liquefied, creating a product known as liquefied biomethane (LBM). Two of the main advantages of LBM are that it can be transported relatively easily and it can be dispensed to either LNG vehicles or CNG vehicles. Liquid biomethane is transported in the same manner as LNG, that is, via insulated tanker trucks designed for transportation of cryogenic liquids.

Biomethane can be stored as CBM to save space. The gas is stored in steel cylinders such as those typically used for storage of other commercial gases. Storage facilities must be adequately fitted with safety devices such as rupture disks and pressure relief valves. The cost of compressing gas to high pressures between 2,000 and 5,000 psi is much greater than the cost of compressing gas for medium-pressure storage. Because of these high costs, the biogas is typically upgraded to biomethane prior to compression.