Tag Archives: biogas

Biogas Enrichment Methods

  By Salman Zafar | May 19, 2012 - 9:15 am | Anaerobic Digestion, biogas
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Enrichment of biogas is primarily achieved by carbon dioxide removal which then enhances the energy value of the gas to give longer, driving distances with a fixed gas storage volume. Removal of carbon dioxide also provides a consistent gas quality with respect to energy value. The latter is regarded to be of great importance from the vehicle manufacturers in order to reach low emissions of nitrogen oxide. At present four different methods are used commercially for removal of carbon dioxide from biogas either to reach vehicle fuel standard or to reach natural gas quality for injection to the natural gas grid. These methods are:

  • Water absorption
  • Polyethylene glycol absorption
  • Carbon molecular sieves
  • Membrane separation

 Water scrubbing

Water scrubbing is used to remove carbon dioxide but also hydrogen sulphide from biogas since these gases is more soluble in water than methane. The absorption process is purely physical. Usually the biogas is pressurized and fed to the bottom of a packed column where water is fed on the top and so the absorption process is operated counter-currently.

Polyethylene glycol scrubbing

Polyethylene glycol scrubbing is a physical absorption process. Selexol is one of the trade names used for a solvent. In this solvent, like in water, both carbon dioxide and hydrogen sulphide are more soluble than methane. The big difference between water and Selexol is that carbon dioxide and hydrogen sulphide are more soluble in Selexol which results in a lower solvent demand and reduced pumping. In addition, water and halogenated hydrocarbons (contaminants in biogas from landfills) are removed when scrubbing biogas with Selexol.

Carbon molecular sieves

Molecular sieves are excellent products to separate specifically a number of different gaseous compounds in biogas. Thereby the molecules are usually loosely adsorbed in the cavities of the carbon sieve but not irreversibly bound. The selectivity of adsorption is achieved by different mesh sizes and/or application of different gas pressures. When the pressure is released the compounds extracted from the biogas are desorbed. The process is therefore often called “pressure swing adsorption” (PSA). To enrich methane from biogas the molecular sieve is applied which is produced from coke rich in pores in the micrometer range. The pores are then further reduced by cracking of the hydrocarbons. In order to reduce the energy consumption for gas compression, a series of vessels are linked together. The gas pressure released from one vessel is subsequently used by the others. Usually four vessels in a row are used filled with molecular sieve which removes at the same time CO2 and water vapour.

Membranes

There are two basic systems of gas purification with membranes: a high pressure gas separation with gas phases on both sides of the membrane, and a low-pressure gas liquid absorption separation where a liquid absorbs the molecules diffusing through the membrane.

  • High pressure gas separation

Pressurized gas (36 bar) is first cleaned over for example an activated carbon bed to remove (halogenated) hydrocarbons and hydrogen sulphide from the raw gas as well as oil vapour from the compressors. The carbon bed is followed by a particle filter and a heater. The raw gas is upgraded in 3 stages to a clean gas with 96 % methane or more. The waste gas from the first two stages is recycled and the methane can be recovered. The waste gas from stage 3 (and in part of stage 2) is flared or used in a steam boiler as it still contains 10 to 20 % methane.

  • Gas-liquid absorption membranes

Gas-liquid absorption using membranes is a separation technique which was developed for biogas upgrading in the recent past. The essential element is a micro-porous hydrophobic membrane separating the gaseous from the liquid phase. The molecules from the gas stream, flowing in one direction, which are able to diffuse through the membrane will be absorbed on the other side by the liquid flowing in counter current. The absorption membranes work at approx. atmospheric pressure (1 bar) which allows low-cost construction. The removal of gaseous components is very efficient. At a temperature of 25 to 35°C the H2S concentration in the raw gas of 2 % is reduced to less than 250 ppm.

Anaerobic Digestion of Cow Manure

  By Salman Zafar | May 18, 2012 - 10:45 pm | Anaerobic Digestion, biogas
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Cow manure is a valuable source of nutrients and renewable energy. However, most of the manure is collected in lagoons or left to decompose in the open which pose a significant environmental hazard. The air pollutants emitted from manure include methane, nitrous oxide, ammonia, hydrogen sulfide, volatile organic compounds and particulate matter, which can cause serious environmental concerns and health problems. In the past, livestock waste was recovered and sold as a fertilizer or simply spread onto agricultural land. The introduction of tighter environmental controls on odour and water pollution means that some form of waste management is necessary, which provides further incentives for biomass-to-energy conversion.

Anaerobic digestion is a unique treatment solution for animal wastes as it can  deliver  positive  benefits  related  to  multiple  issues,  including  renewable  energy,  water pollution, and air emissions. Anaerobic digestion of animal manure is gaining popularity as a means to protect the environment and to recycle materials efficiently into the farming systems. Waste-to-Energy (WTE) plants, based on anaerobic digestion of cow manure, are highly efficient in harnessing the untapped renewable energy potential of organic waste by converting the biodegradable fraction of the waste into high calorific gases.

The establishment of anaerobic digestion systems for livestock manure stabilization and energy production has accelerated substantially in the past several years. There are thousands of digesters operating at commercial livestock facilities in Europe, United States,  Asia and elsewhere. which are generating clean energy and fuel. Many of the projects that generate electricity also capture waste heat for various in-house requirements.

Important Factors

The main factors that influence biogas production from livestock manure are pH and temperature of the feedstock. It is well established that a biogas plant works optimally at neutral pH level and mesophilic temperature of around 35o C. Carbon-nitrogen ratio of the feed material is also an important factor and should be in the range of 20:1 to 30:1. Animal manure has a carbon – nitrogen ratio of 25:1 and is considered ideal for maximum gas production. Solid concentration in the feed material is also crucial to ensure sufficient gas production, as well as easy mixing and handling. Hydraulic retention time (HRT) is the most important factor in determining the volume of the digester which in turn determines the cost of the plant; the larger the retention period, higher the construction cost.

Process Description

The fresh animal manure is stored in a collection tank before its processing to the homogenization tank which is equipped with a mixer to facilitate homogenization of the waste stream. The uniformly mixed waste is passed through a macerator to obtain uniform particle size of 5-10 mm and pumped into suitable-capacity anaerobic digesters where stabilization of organic waste takes place.

In anaerobic digestion, organic material is converted to biogas by a series of bacteria groups into methane and carbon dioxide. The majority of commercially operating digesters are plug flow and complete-mix reactors operating at mesophilic temperatures. The type of digester used varies with the consistency and solids content of the feedstock, with capital investment factors and with the primary purpose of digestion.

Biogas contain significant amount of hydrogen sulfide (H2S) gas which needs to be stripped off due to its highly corrosive nature. The removal of H2S takes place in a biological desulphurization unit in which a limited quantity of air is added to biogas in the presence of specialized aerobic bacteria which oxidizes H2S into elemental sulfur. Biogas can be used as domestic cooking, industrial heating, combined heat and power (CHP) generation as well as a vehicle fuel. The digested substrate is passed through screw presses for dewatering and then subjected to solar drying and conditioning to give high-quality organic fertilizer.

Hydrogen Sulphide Removal from Biogas

  By Salman Zafar | May 5, 2012 - 6:24 am | biogas, Biomass Energy
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Depending on the use of the biogas, most trace components must be removed from the biogas. Water vapour can be particularly hazardous because it is highly corrosive when combined with acidic components such as hydrogen sulfide and to a lesser extent, carbon dioxide. The major contaminant in biogas is H2S. This component is both poisonous and corrosive, and causes significant damage to piping, equipment and instrumentation.

The concentration of various components of biogas has an impact on its ultimate end use. While boilers can withstand concentrations of H2S up to 1000 ppm, and relatively low pressures, internal combustion engines operate best when H2S is maintained below 100 ppm.

Most commonly used methods for hydrogen sulphide removal are internal to the digestion process:

  • air/oxygen dosing to digester biogas and
  • iron chloride dosing to digester slurry.

Biological desulphurization

Desulphurization of biogas can be performed by micro-organisms. Most of the sulphide oxidising micro-organisms belong to the family of Thiobacillus. For the microbiological oxidation of sulphide it is essential to add stoichiometric amounts of oxygen to the biogas. Depending on the concentration of hydrogen sulphide this corresponds to 2 to 6 % air in biogas.

The simplest method of desulphurization is the addition of oxygen or air directly into the digester or in a storage tank serving at the same time as gas holder. Thiobacilli are ubiquitous and thus systems do not require inoculation. They grow on the surface of the digestate, which offers the necessary micro-aerophilic surface and at the same time the necessary nutrients. They form yellow clusters of sulphur. Depending on the temperature, the reaction time, the amount and place of the air added the hydrogen sulphide concentration can be reduced by 95 % to less than 50 ppm.

Measures of safety have to be taken to avoid overdosing of air in case of pump failures. Biogas in air is explosive in the range of 6 to 12 %, depending on the methane content). In steel digesters without rust protection there is a small risk of corrosion at the gas/liquid interface.

Iron chloride dosing to digester slurry

Iron chloride can be fed directly to the digester slurry or to the feed substrate in a pre-storage tank. Iron chloride then reacts with produced hydrogen sulphide and form iron sulphide salt (particles). This method is extremely effective in reducing high hydrogen sulphide levels but less effective in attaining a low and stable level of hydrogen sulphide in the range of vehicle fuel demands. In this respect the method with iron chloride dosing to digester slurry can only be regarded as a partial removal process in order to avoid corrosion in the rest of the upgrading process equipment. The method need to be complemented with a final removal down to about 10 ppm.

The investment cost for such a removal process is limited since the only investment needed is a storage tank for iron chloride solution and a dosing pump. On the other hand the operational cost will be high due to the prime cost for iron chloride.

An Introduction to BioMethane

  By Salman Zafar | May 1, 2012 - 5:19 am | Anaerobic Digestion, biogas
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The typical composition of raw biogas does not meet the minimum CNG fuel specifications. In particular, the CO2 and sulfur content in raw biogas is too high for it to be used as vehicle fuel without additional processing. Biogas that has been upgraded to biomethane by removing the H2S, moisture, and CO2 can be used as a vehicular fuel. Biomethane is less corrosive than biogas, apart from being more valuable as a fuel.

Since production of such fuel typically exceeds immediate on-site demand, the biomethane must be stored for future use, usually either as compressed biomethane (CBM) or liquefied biomethane (LBM). Biomethane can be liquefied, creating a product known as liquefied biomethane (LBM). Two of the main advantages of LBM are that it can be transported relatively easily and it can be dispensed to either LNG vehicles or CNG vehicles. Liquid biomethane is transported in the same manner as LNG, that is, via insulated tanker trucks designed for transportation of cryogenic liquids.

Biomethane can be stored as CBM to save space. The gas is stored in steel cylinders such as those typically used for storage of other commercial gases. Storage facilities must be adequately fitted with safety devices such as rupture disks and pressure relief valves. The cost of compressing gas to high pressures between 2,000 and 5,000 psi is much greater than the cost of compressing gas for medium-pressure storage. Because of these high costs, the biogas is typically upgraded to biomethane prior to compression.

Biomethane is more flexible in its application than any other renewable source of energy. Its ability to be injected directly into the existing natural gas grid allows for energy-efficient and cost-effective transport. This allows gas grid operators to enable consumers to make an easy transition to a renewable source of gas. The diverse, flexible spectrum of applications in the areas of electricity generation, heat provision, and mobility creates a broad base of potential customers. Biomethane can be used to generate electricity and heating from within smaller decentralized, or large centrally-located combined heat and power plants. It can be used by heating systems with a highly efficient fuel value, and employed as a regenerative power source in gas-powered vehicles. The utilization of biomethane as a source of energy is a crucial step toward a sustainable energy supply.

Feedstocks for Anaerobic Digestion Plants

  By Salman Zafar | April 24, 2012 - 10:57 am | Anaerobic Digestion, biogas, Biomass Energy
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A wide range of feedstock is available for anaerobic digesters. In addition to MSW, large quantity of waste, in both solid and liquid forms, is generated by the industrial sector like breweries, sugar mills, distilleries, food-processing industries, tanneries, and paper and pulp industries. Poultry waste has the highest per ton energy potential of electricity per ton but livestock have the greatest potential for energy generation in the agricultural sector.

Agricultural Feedstock

  • Animal manure
  • Energy crops
  • Algal biomass
  • Crop residues

Community-Based Feedstock

  • Organic fraction of MSW (OFMSW)
  • MSW
  • Sewage sludge
  • Grass clippings/garden waste
  • Food remains
  • Institutional wastes etc.

 Industrial Feedstock

  • Food/beverage processing
  • Dairy
  • Starch industry
  • Sugar industry
  • Pharmaceutical industry
  • Cosmetic industry
  • Biochemical industry
  • Pulp and paper
  • Slaughterhouse/rendering plant etc.

Anaerobic digestion is particularly suited to wet organic material and is commonly used for effluent and sewage treatment. Almost any organic material can be processed with anaerobic digestion. This includes biodegradable waste materials such as waste paper, grass clippings, leftover food, sewage and animal waste. The exception to this is woody wastes that are largely unaffected by digestion as most anaerobic microorganisms are unable to degrade lignin.

Anaerobic digesters can also be fed with specially grown energy crops such as silage for dedicated biogas production. A wide range of crops, especially C-4 plants, demonstrate good biogas potentials. Corn is one of the most popular co-substrate in Germany while Sudan grass is grown as an energy crop for co-digestion in Austria. Crops like maize, sunflower, grass, beets etc., are finding increasing use in agricultural digesters as co-substrates as well as single substrate.

A wide range of organic substances are anaerobically easily degradable without major pretreatment. Among these are leachates, slops, sludges, oils, fats or whey. Some wastes can form inhibiting metabolites (e.g.NH3) during anaerobic digestion which require higher dilutions with substrates like manure or sewage sludge. A number of other waste materials often require pre-treatment steps (e.g. source separated municipal organic waste, food residuals, expired food, market wastes and crop residues).

Overview of Biomass Conversion Technologies

  By Salman Zafar | April 15, 2012 - 2:58 am | Biomass Energy, Cogeneration, Thermochemical
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A wide range of technologies are available for realizing the energy potential of biomass wastes, ranging from very simple systems for disposing of dry waste to more complex technologies capable of dealing with large amounts of industrial waste. Conversion routes for wastes are generally thermo-chemical or bio-chemical, but may also include chemical and physical.

Thermal Technologies

The three principal methods of thermo-chemical conversion corresponding to each of these energy carriers are combustion in excess air, gasification in reduced air, and pyrolysis in the absence of air. Direct combustion is the best established and most commonly used technology for converting wastes to heat. During combustion, biomass is burnt in excess air to produce heat. The first stage of combustion involves the evolution of combustible vapours from wastes, which burn as flames. Steam is expanded through a conventional turbo-alternator to produce electricity. The residual material, in the form of charcoal, is burnt in a forced air supply to give more heat.

Co-firing or co-combustion of biomass wastes with coal and other fossil fuels can provide a short-term, low-risk, low-cost option for producing renewable energy while simultaneously reducing the use of fossil fuels. Co-firing involves utilizing existing power generating plants that are fired with fossil fuel (generally coal), and displacing a small proportion of the fossil fuel with renewable biomass fuels. Co-firing has the major advantage of avoiding the construction of new, dedicated, waste-to-energy power plant. An existing power station is modified to accept the waste resource and utilize it to produce a minor proportion of its electricity.

Gasification systems operate by heating biomass wastes in an environment where the solid waste breaks down to form a flammable gas. The gasification of biomass takes place in a restricted supply of air or oxygen at temperatures up to 1200–1300°C. The gas produced—synthesis gas, or syngas—can be cleaned, filtered, and then burned in a gas turbine in simple or combined-cycle mode, comparable to LFG or biogas produced from an anaerobic digester. The final fuel gas consists principally of carbon monoxide, hydrogen and methane with small amounts of higher hydrocarbons. This fuel gas may be burnt to generate heat; alternatively it may be processed and then used as fuel for gas-fired engines or gas turbines to drive generators. In smaller systems, the syngas can be fired in reciprocating engines, micro-turbines, Stirling engines, or fuel cells.

Pyrolysis is thermal decomposition occurring in the absence of oxygen. During the pyrolysis process, biomass waste is heated either in the absence of air (i.e. indirectly), or by the partial combustion of some of the waste in a restricted air or oxygen supply. This results in the thermal decomposition of the waste to form a combination of a solid char, gas, and liquid bio-oil, which can be used as a liquid fuel or upgraded and further processed to value-added products.

Biochemical Technologies

Biochemical processes, like anaerobic digestion, can also produce clean energy in the form of biogas which can be converted to power and heat using a gas engine. Anaerobic digestion is a series of chemical reactions during which organic material is decomposed through the metabolic pathways of naturally occurring microorganisms in an oxygen depleted environment. In addition, wastes can also yield liquid fuels, such as cellulosic ethanol and biodiesel, which can be used to replace petroleum-based fuels.

Anaerobic digestion is the natural biological process which stabilizes organic waste in the absence of air and transforms it into biogas and biofertilizer. Almost any organic material can be processed with anaerobic digestion. This includes biodegradable waste materials such as municipal solid waste, animal manure, poultry litter, food wastes, sewage and industrial wastes. An anaerobic digestion plant produces two outputs, biogas and digestate, both can be further processed or utilized to produce secondary outputs. Biogas can be used for producing electricity and heat, as a natural gas substitute and also a transportation fuel. Digestate can be further processed to produce liquor and a fibrous material. The fiber, which can be processed into compost, is a bulky material with low levels of nutrients and can be used as a soil conditioner or a low level fertilizer.

A variety of fuels can be produced from biomass wastes including liquid fuels, such as ethanol, methanol, biodiesel, Fischer-Tropsch diesel, and gaseous fuels, such as hydrogen and methane. The resource base for biofuel production is composed of a wide variety of forestry and agricultural resources, industrial processing residues, and municipal solid and urban wood residues. The largest potential feedstock for ethanol is lignocellulosic biomass wastes, which includes materials such as agricultural residues (corn stover, crop straws and bagasse), herbaceous crops (alfalfa, switchgrass), short rotation woody crops, forestry residues, waste paper and other wastes (municipal and industrial). The three major steps involved in cellulosic ethanol production are pretreatment, enzymatic hydrolysis, and fermentation. Biomass is pretreated to improve the accessibility of enzymes. After pretreatment, biomass undergoes enzymatic hydrolysis for conversion of polysaccharides into monomer sugars, such as glucose and xylose. Subsequently, sugars are fermented to ethanol by the use of different microorganisms. Bioethanol production from these feedstocks could be an attractive alternative for disposal of these residues. Importantly, lignocellulosic feedstocks do not interfere with food security.

Biogas Strorage Systems

  By Salman Zafar | April 11, 2012 - 2:28 am | Anaerobic Digestion, biogas, Biomass Energy, Waste-to-energy
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Selection of an appropriate biogas storage system makes a significant contribution to the efficiency and safety of a biogas plant. There are two basic reasons for storing biogas: storage for later on-site usage and storage before and/or after transportation to off-site distribution points or systems. A biogas storage system also compensates fluctuations in the production and consumption of biogas as well as temperature-related changes in volume.

There are two broad categories of biogas storage systems: Internal Biogas Storage Tanks are integrated into the anaerobic digester while External Biogas Holders are separated from the digester forming autonomous components of a biogas plant. The simplest and least expensive storage systems for on-site applications and intermediate storage of biogas are low-pressure systems. The energy, safety, and scrubbing requirements of medium- and high-pressure storage systems make them costly and high-maintenance options for non-commercial use. Such extra costs can be best justified for biomethane or bio-CNG, which has a higher heat content and is therefore a more valuable fuel than biogas.

Low-Pressure Storage of Biogas

Floating gas holders on the digester form a low-pressure storage option for biogas systems. These systems typically operate at pressures below 2 psi. Floating gas holders can be made of steel, fiberglass, or a flexible fabric. A separate tank may be used with a floating gas holder for the storage of the digestate and also storage of the raw biogas. A major advantage of a digester with an integral gas storage component is the reduced capital cost of the system.

The least expensive and most trouble-free gas holder is the flexible inflatable fabric top, as it does not react with the H2S in the biogas and is integral to the digester. These types of covers are often used with plug-flow and complete-mix digesters. Flexible membrane materials commonly used for these gas holders include high-density polyethylene (HDPE), low-density polyethylene (LDPE), linear low density polyethylene (LLDPE), and chlorosulfonated polyethylene covered polyester. Thicknesses for cover materials typically vary from 0.5 to 2.5 millimeters.

Medium-Pressure Storage of Cleaned Biogas

Biogas can also be stored at medium pressure between 2 and 200 psi. To prevent corrosion of the tank components and to ensure safe operation, the biogas must first be cleaned by removing H2S. Next, the cleaned biogas must be slightly compressed prior to storage in tanks.

High-Pressure Storage of Compressed Biomethane

The typical composition of raw biogas does not meet the minimum CNG fuel specifications. In particular, the CO2 and sulfur content in raw biogas is too high for it to be used as vehicle fuel without additional processing. Biogas that has been upgraded to biomethane by removing the H2S, moisture, and CO2 can be used as a vehicular fuel. Biomethane is less corrosive than biogas, apart from being more valuable as a fuel. Since production of such fuel typically exceeds immediate on-site demand, the biomethane must be stored for future use, usually either as compressed biomethane (CBM) or liquefied biomethane (LBM).

Two of the main advantages of LBM are that it can be transported relatively easily and it can be dispensed to either LNG vehicles or CNG vehicles. Liquid biomethane is transported in the same manner as LNG, that is, via insulated tanker trucks designed for transportation of cryogenic liquids.

Biomethane can be stored as CBM to save space. The gas is stored in steel cylinders such as those typically used for storage of other commercial gases. Storage facilities must be adequately fitted with safety devices such as rupture disks and pressure relief valves. The cost of compressing gas to high pressures between 2,000 and 5,000 psi is much greater than the cost of compressing gas for medium-pressure storage. Because of these high costs, the biogas is typically upgraded to biomethane prior to compression.

Bioenergy Perspectives for Southeast Asia

  By Salman Zafar | April 8, 2012 - 10:38 am | Biofuels, biogas, Biomass Energy, Clean Energy, Southeast Asia
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Southeast Asia, with its abundant biomass resources, holds a strategic position in the global biomass energy atlas. There is immense potential of biopower in Southeast Asian countries due to plentiful supply of diverse forms of wastes such as agricultural residues, woody biomass, animal wastes, municipal solid waste, etc. The rapid economic growth and industrialization in the region has accelerated the drive to implement the latest waste-to-energy technologies to tap the unharnessed potential of biomass resources.

The Southeast Asian region is a big producer of wood and agricultural products which, when processed in industries, produces large amounts of biomass residues. According to conservative estimates, the amount of biomass residues generated from sugar, rice and palm oil mills is more than 200-230 million tons per year which corresponds to cogeneration potential of 16-19 GW.

Rice mills in the region produce 38 million tonnes of rice husk as solid residue which is a good fuel for producing heat and power. Sugar industry is an integral part of the industrial scenario in Southeast Asia accounting for 7% of sugar production worldwide. Sugar mills in Thailand, Indonesia, Philippines and Vietnam generate 34 million tonnes of bagasse every year.  Malaysia, Indonesia and Thailand account for 90% of global palm oil production leading to the generation of 27 million tonnes of waste per annum in the form of empty fruit bunches (EFBs), fibers and shells, as well as liquid effluent.

Woody biomass is a good energy resource due to presence of large number of forests in Southeast Asia. Apart from natural forests, non-industrial plantations of different types (e.g. coconut, rubber and oil palm plantations, fruit orchards, and trees in homesteads and gardens) have gained recognition as important sources of biomass. In addition, the presence of a large number of wood processing industries also generates significant quantity of wood wastes. The annual production of wood wastes in the region is estimated to be more than 30 million m3.

The prospects of biogas power generation are also high in the region thanks to presence of well-established food-processing and dairy industries. Another important biomass resource is contributed by municipal solid wastes in heavily populated urban areas.  In addition, there are increasing efforts both commercially and promoted by governments to develop biomass energy systems for efficient biofuel production, e.g. bio-diesel from palm oil.

Biomass resources, particularly residues from forests, wood processing, agricultural crops and agro-processing, are under-utilised in Southeast Asian countries. There is an urgent need to utilize biomass wastes for commercial electricity and heat production to cater to the needs of the industries as well as urban and rural communities.

Southeast Asian countries are yet to make optimum use of the additional power generation potential from biomass waste resources which could help them to partially overcome the long-term problem of energy supply. Technologies for biomass utilization which are at present widely used in Southeast counties need to be improved towards best practice by making use of the latest trends in the waste-to-energy sector.

Properties and Uses of POME

  By Salman Zafar | April 5, 2012 - 1:29 am | Anaerobic Digestion, biogas, Biomass Energy, Energy-from-Waste, Industrial Waste Management, Southeast Asia, Waste-to-energy
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Palm Oil processing gives rise to highly polluting waste-water, known as Palm Oil Mill Effluent (POME), which is often discarded in disposal ponds, resulting in the leaching of contaminants that pollute the groundwater and soil, and in the release of methane gas into the atmosphere. POME is an oily wastewater generated by palm oil processing mills and consists of various suspended components. This liquid waste combined with the wastes from steriliser condensate and cooling water is called palm oil mill effluent (POME).

On average, for each ton of FFB (fresh fruit bunches) processed, a standard palm oil mill generate about 1 tonne of liquid waste with biochemical oxygen demand (BOD) 27 kg, chemical oxygen demand (COD) 62 kg, suspended solids (SS) 35 kg and oil and grease 6 kg. POME has a very high Biochemical Oxygen Demand (BOD) and Chemical Oxygen Demand (COD), which is 100 times more than the municipal sewage.

POME is a non-toxic waste, as no chemical is added during the oil extraction process, but will pose environmental issues due to large oxygen depleting capability in aquatic system due to organic and nutrient contents. The high organic matter is due to the presence of different sugars such as arabinose, xylose, glucose, galactose and manose. The suspended solids in the POME are mainly oil-bearing cellulosic materials from the fruits. Since the POME is non-toxic as no chemical is added in the oil extraction process, it is a good source of nutrients for microorganisms.

Currently, recovery of renewable organic-based product is a new approach in managing POME. The technology is aimed to recover by-products such as volatile fatty acid, biogas and poly-hydroxyalkanoates to promote sustainability of the palm oil industry. In addition, it is envisaged that POME can be sustainably reused as a fermentation substrate in production of various metabolites through biotechnological advances. In addition, POME consists of high organic acids and is suitable to be used as a carbon source.

Anaerobic digestion is widely adopted in the industry as a primary treatment for POME. Biogas is produced in the process in the amount of 20 m3 per ton FFB. This effluent could be used for biogas production through anaerobic digestion. At many Palm-oil mills this process is already in place to meet water quality standards for industrial effluent. The gas, however, is flared off. Palm Oil mills, being one of the largest industries in Malaysia and Indonesia, effluents from these mills can be anaerobically converted into biogas which in turn can be used to generate power through gas turbines or gas-fired engines. According to World Oil Data (World Oil, 2006), potential POME produced from all Palm Oil Mills in Indonesia was 34 million m3in 2005. This is equivalent to total COD loading of about 1.7 million tons resulting in 350,000 tons of methane.

Ultrasonic Pretreatment in Anaerobic Digestion of Sewage

  By Salman Zafar | April 4, 2012 - 11:44 am | Anaerobic Digestion, biogas, Biomass Energy, Solid Waste Management, Waste-to-energy
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Anaerobic digestion (AD) process comprises of four major steps – hydrolysis, acidogenesis, acetogenesis and methanogenesis. The biological hydrolysis is the rate limiting step and pretreatment of sludge by chemical, mechanical or thermal disintegration can improve the anaerobic digestion process. Ultrasonic disintegration is a method for breakup of microbial cells to extract intracellular material.

Ultrasound activated sludge disintegration could positively affect sludge anaerobic digestion. Due to sludge disintegration, organic compounds are transferred from the sludge solids into the aqueous phase resulting in an enhanced biodegradability. Therefore disintegration of sewage sludge is a promising method to enhance anaerobic digestion rates and lead to reduce the volume of sludge digesters.

The addition of disintegrated surplus activated sludge and/or foam to the process of sludge anaerobic digestion can lead to markedly better effects of sludge handling at wastewater treatment plants. In the case of disintegrated activated sludge and/or foam addition to the process of anaerobic digestion it is possible to achieve an even twice a higher production of biogas. Here are few examples:

STP Bad Bramstedt, Germany (4.49 MGD)

  • First fundamental study on pilot scale by Technical University of Hamburg-Harburg, 3 years, 1997 – 1999
  • reduction in digestion time from 20 to 4 days without losses in degradation efficiency
  • increase in biogas production by a factor of 4
  • reduction of digested sludge mass of 25%

STP Ahrensburg, Germany (2.64 MGD)

  • Preliminary test on pilot-scale by Technical University of Hamburg-Harburg, 6 months, 1999
  • increase in VS destruction of 20%
  • increase in biogas production of 20%

STP Bamberg, Germany (12.15 MGD)

  • Preliminary full-scale test, 4 months, 2002 2) Full-scale installation since June 2004
  • increase in VS destruction of 30%
  • increase in biogas production of 30%
  • avoided the construction of a new anaerobic digester

STP Freising, Germany (6.87 MGD)

  • Fundamental full-scale study by University of Armed Forces, Munich, 4 months, 2003
  • increase in biogas production of 15%
  • improved sludge dewatering of 10%

STP Meldorf, Germany (1.06 MGD)

  • Preliminary full-scale test, 3 months, 2004 2) Full-scale installation since December 2004
  • increase in VS destruction of 25%
  • increase in biogas production of 25%
  • no foam or filamentous organisms present in the anaerobic sludge digester

STP Ergolz 2, Switzerland (3.43 MGD)

  • Full-scale test, 3 months, 2004
  • increase in VS destruction of 15%
  • increase in biogas production of 25%

STP Beverungen, Germany (2.64 MGD)

  • Full-scale test, 3 months, 2004/2005
  • increase in VS destruction of 25%
  • increase in biogas production of 25%

To sum up, ultrasonication has a positive effect on sludge solubilisation, sludge volume, biogas production, flock size reduction and cells lyses. Ultrasonic pretreatment enhances the subsequent anaerobic digestion resulting in a better degradation of volatile solids and an increased production of biogas. The use of low power ultrasound in bioreactors may present a significant improvement in cost reduction. Therefore, ultrasonic pretreatment enhances the subsequent anaerobic digestion resulting in a better sludge digestion and efficient recovery of valuables.