Biomass Resources from Rice Industry

The cultivation of Rice results in two major types of residues – Straw and Husk –having attractive potential in terms of energy. Although the technology for Rice Husk utilization is well-proven in industrialized countries of Europe and North America, such technologies are yet to be introduced in the developing world on commercial scale. The importance of Rice Husk and Rice Straw as an attractive source of energy can be gauged from the following statistics:

Rice Straw

  • 1 ton of Rice paddy produces 290 kg Rice Straw
  • 290 kg Rice Straw can produce 100 kWh of power
  • Calorific value = 2400 kcal/kg

Rice Husk

  • 1 ton of Rice paddy produces 220 kg Rice Husk
  • 1 ton Rice Husk is equivalent to 410- 570 kWh electricity
  • Calorific value = 3000 kcal/kg
  • Moisture content = 5 – 12%

Rice husk is the most prolific agricultural residue in rice producing countries around the world. It is one of the major by-products from the rice milling process and constitutes about 20% of paddy by weight. Rice husk, which consists mainly of lingo-cellulose and silica, is not utilized to any significant extent and has great potential as an energy source.

Rice husk can be used for power generation through either the steam or gasification route. For small scale power generation, the gasification route has attracted more attention as a small steam power plant is very inefficient and is very difficult to maintain due to the presence of a boiler. In addition for rice mills with diesel engines, the gas produced from rice husk can be used in the existing engine in a dual fuel operation.

The benefits of using rice husk technology are numerous. Primarily, it provides electricity and serves as a way to dispose of agricultural waste. In addition, steam, a byproduct of power generation, can be used for paddy drying applications, thereby increasing local incomes and reducing the need to import fossil fuels. Rice husk ash, the byproduct of rice husk power plants, can be used in the cement and steel industries further decreasing the need to import these materials.

Rice straw can either be used alone or mixed with other biomass materials in direct combustion. In this technology, combustion boilers are used in combination with steam turbines to produce electricity and heat. The energy content of rice straw is around 14 MJ per kg at 10 percent moisture content.  The by-products are fly ash and bottom ash, which have an economic value and could be used in cement and/or brick manufacturing, construction of roads and embankments, etc.

Straw fuels have proved to be extremely difficult to burn in most combustion furnaces, especially those designed for power generation. The primary issue concerning the use of rice straw and other herbaceous biomass for power generation is fouling, slagging, and corrosion of the boiler due to alkaline and chlorine components in the ash. Europe, and in particular, Denmark, currently has the greatest experience with straw fired power and CHP plants.

Biomass Combustion Systems

Direct combustion is the best established and most commonly used technology for converting biomass to heat. During combustion, biomass fuel is burnt in excess air to produce heat. The first stage of combustion involves the evolution of combustible vapours from the biomass, which burn as flames. The residual material, in the form of charcoal, is burnt in a forced air supply to give more heat. The hot combustion gases are sometimes used directly for product drying, but more usually they are passed through a heat exchanger to produce hot air, hot water or steam.

The combustion efficiency depends primarily on good contact between the oxygen in the air and the biomass fuel. The main products of efficient biomass combustion are carbon dioxide and water vapor, however tars, smoke and alkaline ash particles are also emitted. Minimization of these emissions and accommodation of their possible effects are important concerns in the design of environmentally acceptable biomass combustion systems.

Biomass combustion systems, based on a range of furnace designs, can be very efficient at producing hot gases, hot air, hot water or steam, typically recovering from 65-90% of the energy contained in the fuel. Lower efficiencies are generally associated with wetter fuels. To cope with a diversity of fuel characteristics and combustion requirements, a number of designs of combustion furnaces or combustors are routinely utilized around the world

Underfeed Stokers

Biomass is fed into the combustion zone from underneath a firing grate. These stoker designs are only suitable for small scale systems up to a nominal boiler capacity of 6 MWth and for biomass fuels with low ash content, such as wood chips and sawdust. High ash content fuels such as bark, straw and cereals need more efficient ash removal systems. Sintered or molten ash particles covering the upper surface of the fuel bed can cause problems in underfeed stokers due to unstable combustion conditions when the fuel and the air are breaking through the ash covered surface.

Grate Stokers

The most common type of biomass boiler is based on a grate to support a bed of fuel and to mix a controlled amount of combustion air, which often enters from beneath the grate. Biomass fuel is added at one end of the grate and is burned in a fuel bed which moves progressively down the grate, either via gravity or with mechanical assistance, to an ash removal system at the other end. In more sophisticated designs this allows the overall combustion process to be separated into its three main activities:

  • Initial fuel drying
  • Ignition and combustion of volatile constituents
  • Burning out of the char.

Grate stokers are well proven and reliable and can tolerate wide variations in fuel quality (i.e. variations in moisture content and particle size) as well as fuels with high ash content. They are also controllable and efficient.

Fluidized Bed Boilers

The basis for a fluidized bed combustion system is a bed of an inert mineral such as sand or limestone through which air is blown from below. The air is pumped through the bed in sufficient volume and at a high enough pressure to entrain the small particles of the bed material so that they behave much like a fluid.

The combustion chamber of a fluidized bed plant is shaped so that above a certain height the air velocity drops below that necessary to entrain the particles. This helps retain the bulk of the entrained bed material towards the bottom of the chamber. Once the bed becomes hot, combustible material introduced into it will burn, generating heat as in a more conventional furnace. The proportion of combustible material such as biomass within the bed is normally only around 5%. The primary driving force for development of fluidized bed combustion is reduced SO2 and NOx emissions from coal combustion.

Bubbling fluidized bed (BFB) combustors are of interest for plants with a nominal boiler capacity greater than 10 MWth. Circulating fluidized bed (CFB) combustors are more suitable for plants larger than 30 MWth. The minimum plant size below which CFB and BFB technologies are not economically competitive is considered to be around 5-10 MWe.

Rice Straw As Bioenergy Resource

The cultivation of rice results in two types of residues – straw and husk – having attractive potential in terms of energy. Rice husk, the main by-product from rice milling, accounts for roughly 22% of paddy weight, while rice straw to paddy ratio ranges from 1.0 to 4.3. Although the technology for rice husk utilization is well-established worldwide, rice straw is sparingly used as a source of renewable energy. One of the main reasons for the preferred use of husk is its easy procurement. In case of rice straw, however, its collection is difficult and its availability is limited to harvest time.

Rice straw can either be used alone or mixed with other biomass materials in direct combustion. In this technology, combustion boilers are used in combination with steam turbines to produce electricity and heat. The energy content of rice straw is around 14 MJ per kg at 10 percent moisture content.  The by-products are fly ash and bottom ash, which have an economic value and could be used in cement and/or brick manufacturing, construction of roads and embankments, etc.

Straw fuels have proved to be extremely difficult to burn in most combustion furnaces, especially those designed for power generation. The primary issue concerning the use of rice straw and other herbaceous biomass for power generation is fouling, slagging, and corrosion of the boiler due to alkaline and chlorine components in the ash. Europe, and in particular, Denmark, currently has the greatest experience with straw fired power and CHP plants. Because of the large amount of cereal grains (wheat and oats) grown in Denmark, the surplus straw plays a large role in the country’s renewable energy strategy. Technology developed includes combustion furnaces, boilers, and superheat concepts purportedly capable of operating with high alkali fuels and having handling systems which minimize fuel preparation.

A variety of methods are employed by the European plants to prepare straw for combustion. Most use automated truck unloading bridge cranes that clamp up to 12 bales at a time and stack them 4-5 bales high in covered storage. Some systems feed whole bales into the boiler. Probably the best known whole bale feeder is the “Vølund cigar feeding” concept, originally applied by Vølund (now Babcock and Wilcox-Vølund). Whole bales are pushed into the combustion chamber and the straw burned off the face of the bale. However, the newer Danish plants have moved away from whole-bale systems to shredded straw feed for higher efficiency. For pulverized coal co-firing, the straw usually needs to be ground or cut to small sizes in order to burn completely within relatively short residence times (suspension fired systems) or to feed and mix upon injection with bed media in fluidized bed systems.

The chemical composition of feedstock has a major influence on the efficiency of cogeneration. The low feedstock quality of rice straw is primarily determined by high ash content (10–17%) as compared with wheat straw (around 3%) and also high silica content in ash. On the other hand, rice straw as feedstock has the advantage of having a relatively low total alkali content, whereas wheat straw can typically have more than 25% alkali content in ash. However, straw quality varies substantially within seasons as well as within regions. If straw is exposed to precipitation in the field, alkali and alkaline compounds are leached, improving the feedstock quality. In turn, moisture content should be less than 10% for combustion technology.

In straw combustion at high temperatures, potassium is transformed and combines with other alkali earth materials such as calcium. This in turn reacts with silicates, leading to the formation of tightly sintered structures on the grates and at the furnace wall. Alkali earths are also important in the formation of slag and deposits. This means that fuels with lower alkali content are less problematic when fired in a boiler.

Thermochemical Conversion Technologies

A wide range of technologies exists to convert the energy stored in biomass to more useful forms of energy. These technologies can be classified according to the principal energy carrier produced in the conversion process. Carriers are in the form of heat, gas, liquid and/or solid products, depending on the extent to which oxygen is admitted to the conversion process (usually as air). The three principal methods of thermo-chemical conversion corresponding to each of these energy carriers are combustion in excess air, gasification in reduced air, and pyrolysis in the absence of air.

Combustion

Conventional combustion technologies raise steam through the combustion of biomass. This steam may then be expanded through a conventional turbo-alternator to produce electricity. A number of combustion technology variants have been developed. Underfeed stokers are suitable for small scale boilers up to 6 MWth. Grate type boilers are widely deployed. They have relatively low investment costs, low operating costs and good operation at partial loads. However, they can have higher NOx emissions and decreased efficiencies due to the requirement of excess air, and they have lower efficiencies.

Fluidized bed combustors (FBC), which use a bed of hot inert material such as sand, are a more recent development. Bubbling FBCs are generally used at 10-30 MWth capacity, while Circulating FBCs are more applicable at larger scales. Advantages of FBCs are that they can tolerate a wider range of poor quality fuel, while emitting lower NOx levels.

Co-Firing

Co-firing or co-combustion of biomass wastes with coal and other fossil fuels can provide a short-term, low-risk, low-cost option for producing renewable energy while simultaneously reducing the use of fossil fuels. Co-firing involves utilizing existing power generating plants that are fired with fossil fuel (generally coal), and displacing a small proportion of the fossil fuel with renewable biomass fuels. Co-firing has the major advantage of avoiding the construction of new, dedicated, waste-to-energy power plant. Co-firing may be implemented using different types and percentages of wastes in a range of combustion and gasification technologies. Most forms of biomass wastes are suitable for co-firing. These include dedicated municipal solid wastes, wood waste and agricultural residues such as straw and husk.

Gasification

Gasification of biomass takes place in a restricted supply of oxygen and occurs through initial devolatilization of the biomass, combustion of the volatile material and char, and further reduction to produce a fuel gas rich in carbon monoxide and hydrogen. This combustible gas has a lower calorific value than natural gas but can still be used as fuel for boilers, for engines, and potentially for combustion turbines after cleaning the gas stream of tars and particulates. If gasifiers are ‘air blown’, atmospheric nitrogen dilutes the fuel gas to a level of 10-14 percent that of the calorific value of natural gas. Oxygen and steam blown gasifiers produce a gas with a somewhat higher calorific value. Pressurized gasifiers are under development to reduce the physical size of major equipment items.

A variety of gasification reactors have been developed over several decades. These include the smaller scale fixed bed updraft, downdraft and cross flow gasifiers, as well as fluidized bed gasifiers for larger applications. At the small scale, downdraft gasifiers are noted for their relatively low tar production, but are not suitable for fuels with low ash melting point (such as straw). They also require fuel moisture levels to be controlled within narrow levels.

Pyrolysis

Pyrolysis is the term given to the thermal degradation of wood in the absence of oxygen. It enables biomass to be converted to a combination of solid char, gas and a liquid bio-oil. Pyrolysis technologies are generally categorized as “fast” or “slow” according to the time taken for processing the feed into pyrolysis products. These products are generated in roughly equal proportions with slow pyrolysis. Using fast pyrolysis, bio-oil yield can be as high as 80 percent of the product on a dry fuel basis. Bio-oil can act as a liquid fuel or as a feedstock for chemical production. A range of bio-oil production processes are under development, including fluid bed reactors, ablative pyrolysis, entrained flow reactors, rotating cone reactors, and vacuum pyrolysis.