The Philippines has abundant supplies of biomass energy resources in the form of agricultural crop residues, forest residues, animal wastes, agro-industrial wastes, municipal solid wastes and aquatic biomass. The most common agricultural wastes are rice hull, bagasse, cane trash, coconut shell/husk and coconut coir. The use of crop residues as biofuels is increasing in the Philippines as fossil fuel prices continue to rise. Rice hull is perhaps the most important, underdeveloped biomass resource that could be fully utilized in a sustainable manner.
At present, biomass technologies utilized in the country vary from the use of bagasse as boiler fuel for cogeneration, rice/coconut husks dryers for crop drying, biomass gasifiers for mechanical and electrical applications, fuelwood and agricultural wastes for oven, kiln, furnace and cook-stoves for cooking and heating purposes. Biomass technologies represent the largest installations in the Philippines in comparison with the other renewable energy, energy efficiency and greenhouse gas abatement technologies.
Biomass energy plays a vital role in the nation’s energy supply. Nearly 30 percent of the energy for the 80 million people living in the Philippines comes from biomass, mainly used for household cooking by the rural poor. Biomass energy application accounts for around 15 percent of the primary energy use in the Philippines. The resources available in the Philippines can generate biomass projects with a potential capacity of more than 200 MW.
Almost 73 percent of this biomass use is traced to the cooking needs of the residential sector while industrial and commercial applications accounts for the rest. 92 percent of the biomass industrial use is traced to boiler fuel applications for power and steam generation followed by commercial applications like drying, ceramic processing and metal production. Commercial baking and cooking applications account for 1.3 percent of its use.
The EC-ASEAN COGEN Programme estimated that the volume of residues from rice, coconut, palm oil, sugar and wood industries is 16 million tons per year. Bagasse, coconut husks and shell can account for at least 12 percent of total national energy supply. The World Bank-Energy Sector Management Assistance Program estimated that residues from sugar, rice and coconut could produce 90 MW, 40 MW, and 20 MW, respectively.
The development of crop trash recovery systems, improvement of agro-forestry systems, introduction of latest energy conversion technologies and development of biomass supply chain can play a major role in biomass energy development in the Philippines. The Philippines is among the most vulnerable nations to climatic instability and experiences some of the largest crop losses due to unexpected climatic events. The country has strong self-interest in the advancement of clean energy technologies, and has the potential to become a role model for other developing nations on account of its broad portfolio of biomass energy resources and its potential to assist in rural development.
Considering the fact that Pakistan is among the world’s top-10 sugarcane producers, the potential of generating electricity from bagasse is huge. Almost all the sugar mills in Pakistan have in-house plants for cogeneration but they are inefficient in the consumption of bagasse. If instead, high pressure boilers are installed then the production capacity can be significantly improved with more efficient utilization of bagasse.
However, due to several reasons; mostly due to financing issues, the sugar mill owners were not able to set up these plants. Only recently, after financial incentives have been offered and a tariff rate agreed upon between the government and mill owners, are these projects moving ahead.
The sugar mill owners are more than willing to supply excess electricity generated form the in-house power plants to the national grid but were not able to before, because they couldn’t reach an agreement with the government over tariff. The demand for higher tariff was justified because of large investments in setting up new boilers. It would also have saved precious foreign exchange which is spent on imported oil.
By estimating the CDM potential of cogeneration (or CHP) projects based on biofuels, getting financing for these projects would be easier. Renewable energy projects can be developed through Carbon Development Mechanism or any other carbon credit scheme for additional revenue.
Since bagasse is a clean fuel which emits very little carbon emissions it can be financed through Carbon Development Mechanism. One of the reasons high cogeneration power plants are difficult to implement is because of the high amount of costs associated. The payback period for the power plants is unknown which makes the investors reluctant to invest in the high cogeneration project. CDM financing can help improve the rate of return of the project.
Bagasse power plants generate Carbon Emission Reductions in 2 ways; one by replacing electricity produced from fossil fuels. Secondly if not used as a fuel, it would be otherwise disposed off in an unsafe manner and the methane emissions present in biomass would pollute the environment far more than CO2 does.
Currently there are around 83 sugar mills in Pakistan producing about 3.5 million metric tons of sugar per annum with total crushing capacity 597900 TCD, which can produce approximately 3000 MW during crop season Although it may seem far-fetched at the moment, if the government starts to give more attention to sugar industry biomass rather than coal, Pakistan can fulfill its energy needs without negative repercussions or damage to the environment.
However some sugar mills are opting to use coal as a secondary fuel since the crushing period of sugarcane lasts only 4 months in Pakistan. The plants would be using coal as the main fuel during the non-crushing season. The CDM effect is reduced with the use of coal. If a high cogeneration plant is using even 80% bagasse and 20% of coal then the CERs are almost nullified. If more than 20% coal is used then the CDM potential is completely lost because the emissions are increased. However some sugar mills are not moving ahead with coal as a secondary fuel because separate tariff rates have to be obtained for electricity generation if coal is being used in the mix which is not easily obtained.
Pakistan has huge untapped potential for bagasse-based power generation
One of the incentives being offered by the State Bank of Pakistan is thatif a project qualifies as a renewable project it is eligible to get loan at 6% instead of 12%. However ones drawback is that, in order to qualify as a renewable project, CDM registration of a project is not taken into account.
Although Pakistan is on the right track by setting up high cogeneration power plants, the use of coal as a secondary fuel remains debatable. The issue that remains to be addressed is that with such huge amounts of investment on these plants, how to use these plants efficiently during non-crushing period when bagasse is not available. It seems almost counter-productive to use coal on plants which are supposed to be based on biofuels.
Conclusion
With the demand for energy in Pakistan growing, the country is finally exploring alternatives to expand its power production. Pakistan has to rely largely on fossils for their energy needs since electricity generation from biomass energy sources is considered to be an expensive option despite abundance of natural resources. However by focusing on growing its alternate energy options such as bagasse-based cogeneration, the country will not only mitigate climate change but also tap the unharnessed energy potential of sugar industry biomass.
Biofuel commercialization has proved to be costly and lingering than expected due to its high production cost and modification to flexibility in engines. Drop-in fuels are alternatives to existing liquid fuels without any significant modification in engines and infrastructures. According to IEA, “Drop-in biofuels are liquid bio-hydrocarbons that are functionally equivalent to petroleum fuels and are fully compatible with existing petroleum infrastructure”.
What are Drop-in Biofuels
Drop-in biofuels are can be produced from oilseeds via trans-esterification, lignocellulosic biomass via thermochemical process, sugars and alcohol via biochemical conversion or by hybrids of the above methods. Drop-in fuels encompass high hydrogen to carbon ratio with no/low sulfur and oxygen content, low water solubility and high carbon bond saturation. In short drop-in fuel is a modified fuel with close functional resemblance to fossil fuel.
Existing biofuels – bioethanol and biodiesel – have wide variation from fossil fuels in their blend wall properties – high oxygen content, hydrophilicity, energy density and mainly compatibility in existing engines and infrastructures. Oxygenated groups in biofuel have a domino effect such as reduction in the energy density, production of impurities which are highly undesirable to transportation components, instability during storage etc.
Major advantages of drop-in fuels over existing fuels are as follows:
Reduced sulphur oxide emissions by ultra low sulphur content.
Reduced ignition delay by high cetane value
Reduced hydrocarbons and nitrogen oxides emissions
Low aromatic content
Low olefin content, presence of olefin compounds undergo auto-oxidation leading to surface depositions.
High saturates, therefore leaving minimum residues
Low particulate emissions
No oxygenates therefore has high stability.
Potential Biomass Feedstock
Drop-in biofuels can be produced from various biomass sources- lipids (vegetable oils, animal fats, greases, and algae) and lignocellulosic material (such as crop residues, woody biomass, and dedicated energy crops). The prominent technologies for biomass conversion to drop-in fuel are the thermochemical and the biochemical process.
The major factor playing role in selection of biomass for thermochemical methods is the energy content or heating value of the material, which is correlated with ash content. Wood, wood chips accounts for less than 1% ash content, which is favorable thermal processing than biochemical process, whereas straws, husks, and majority of the other biomass have ash content ranging up to 25% of dry mass.
Free sugar generating plants such as sugarcane and sweet sorghum, are desirable feedstock for Acetone-Butanol-Ethanol fermentation and have been widely implemented. Presently there is a focus to exploit lignocellulosic residues, rich in hydrocarbon, for fuel production. However, this biomass requires harsh pretreatment to remove lignin and to transform holocellulose (cellulose & hemicelluloses) into fermentable products.
The lignocellulose transformation technology must be circumspectly chosen by its life cycle assessment, as it resists any changes in their structural integrity owing to its complexity. Lignocellulosic biomass, when deoxygenated, has better flexibility to turn to drop-in fuels. This is because, in its native state of the feedstock, each oxygen atom consumes two hydrogen atoms during combustion which in turn reduces effective H: C ratio. Biomass feedstock is characterized with oxygen up to 40%, and higher the oxygen content higher it has to be deoxygenated.
Thermochemical Route
Thermochemical methods adopted for biomass are pyrolysis and gasification, on thermolysis of biomass produce intermediate gas (syngas) and liquid (bio crude) serving as precursors for drop-in fuel. Biomass when exposed to temperature of 500oC-600oC in absence of oxygen (pyrolysis) produce bio-oil, which constitutes a considerable percentage of oxygen. After down streaming by hydroprocessing (hydrotreating and hydrocracking) the rich hydrocarbon tar (bio-oil) can be converted to an efficient precursor for drop-in fuel.
At a higher temperature, above 700, under controlled oxygen, biomass can be converted to liquid fuel via gas phase by the process, gasification. Syngas produced is converted to liquid fuel by Fischer-Tropsch with the help of ‘water gas shift’ for hydroprocessing. Hydroprocessing after the thermochemical method is however costly and complex process in case of pyrolysis and inefficient biomass to fuel yield with gasification process.
Biochemical Pathway
The advanced biocatalytic processes can divert the conventional sugar-ethanol pathway and convert sugars to fatty acids. Modified microbial strain with engineered cellular machineries, can reroute the pathway to free fatty acid that can be transformed into butanol or drop-in fuel with necessary processing.
Schematic for the preparation of jet fuel from biomass
Biological processing requires operation under the stressful conditions on the organisms to reroute the pathways, in additional to lowering NADPH (hydrogen) consumption. Other value added products like carboxylic acid, polyols, and alcohol in the same biological routes with lower operational requirements have higher market demands and commercial success. Therefore little attention is given by chemical manufacturers to the biological pathways for drop-in fuel production.
The mechanisms of utilization of lignocellulosic biomass to fuel by biological pathway rely heavily on the availability of monomeric C5 and C6 sugars during fermentation. Ethanol is perhaps the best-known and commercially successful alcohol from ABE fermentation. However, butanol has various significant advantages over ethanol- in the perception of energy content, feasibility to existing infrastructures, zero blend wall, safety and clean aspects.
Although butanol is a closer drop-in replacement, existing biofuel ethanol, is a major commercial competitor. Low yield from fermentation due to the toxicity of butanol and complexity in down streaming are the vital reasons that hamper successful large scale butanol production.
Zero oxygen and sulphur content mark major challenges for production of drop-in fuels from conventional biomass. This demands high hydrogen input on the conventional biomass, with H: C ratio below 0.5, like sugar, starch, cellulose, lignocellulose to meet the effective hydrogen to carbon ratio of 2 as in drop-in fuel. This characterizes most of the existing biomass feedstock as a low-quality input for drop-in fuels. However oleochemicals like fats, oils, and lipids have closer H: C ratio to diesel, gasoline and drop-in fuels, thus easier to conversion.
Oleochemical feedstock has been commercially successful, but to prolong in the platform will be a major challenge. Lipid feedstock is generally availed from crop-based vegetable oil, which is used in food sectors. Therefore availability, food security concerns, and economics are the major constraints to sustaining the raw material. Consequently switching to lignocellulosic biomass feedstock for drop-in holds on.
Conclusions
Despite the hurdles on biomass characteristics and process technology for drop-in fuel, it is a vital requirement to switch to better replacement fuel for fossil fuel, considering environmental and economic benefits. Understanding its concepts and features, drop-in fuel, can solve existing greenhouse emission debate on current biofuels. Through crucial ambiguities existing on future of alternative fuels, drop-in fuel has a substantial potential to repute itself as an efficient sustainable eco-friendly fuel in the near future.
References
Neal K Van Alfen: ENCYCLOPEDIA OF AGRICULTURE AND FOOD SYSTEMS, Elsevier, Academic Press.
Pablo Domínguez de María John: INDUSTRIAL BIORENEWABLES:A Practical Viewpoint: Wiley & Sons.
Ram Sarup Singh, Ashok Pandey, Edgard Gnansounou: BIOFUELS- PRODUCTION AND FUTURE PERSPECTIVES, CRC Press.
Satinder Kaur Brar, Saurabh Jyoti Sarma, Kannan Pakshirajan : PLATFORM CHEMICAL BIOREFINERY-FUTURE GREEN CHEMISTRY, Elsevier.
Sergios Karatzos, James D. McMillan, Jack N. Saddle: Summary of IEA BIOENERGY TASK 39 REPORT-THE POTENTIAL AND CHALLENGES OF DROP-IN BIOFUELS, IEA Bioenergy.
Vijai Kumar Gupta, Monika Schmoll, Minna Maki, Maria Tuohy, Marcio Antonio Mazutti: APPLICATIONS OF MICROBIAL ENGINEERING, CRC Press.
It is estimated that Indonesia produces 146.7 million tons of biomass per year, equivalent to about 470 GJ/y. Sources of biomass energy in Indonesia are scattered all over the country, but the biggest biomass energy potential in concentrated scale can be found in the Island of Kalimantan, Sumatera, Irian Jaya and Sulawesi.
Studies estimate the electricity generation potential from the roughly 150 Mt of biomass residues produced per year to be about 50 GW or equivalent to roughly 470 GJ/year. These studies assume that the main source of biomass energy in Indonesia will be rice residues with a technical energy potential of 150 GJ/year.
Other potential biomass sources are rubber wood residues (120 GJ/year), sugar mill residues (78 GJ/year), palm oil residues (67 GJ/year), and less than 20 GJ/year in total from plywood and veneer residues, logging residues, sawn timber residues, coconut residues, and other agricultural wastes.
Sustainable and renewable natural resources such as biomass can supply potential raw materials for energy conversion. In Indonesia, they comprise variable-sized wood from forests (i.e. natural forests, plantations and community forests that commonly produce small-diameter logs used as firewood by local people), woody residues from logging and wood industries, oil-palm shell waste from crude palm oil factories, coconut shell wastes from coconut plantations, as well as skimmed coconut oil and straw from rice cultivation.
The major crop residues to be considered for power generation in Indonesia are palm oil, sugar processing and rice processing residues. Currently, 67 sugar mills are in operation in Indonesia and eight more are under construction or planned. The mills range in size of milling capacity from less than 1,000 tons of cane per day to 12,000 tons of cane per day. Current sugar processing in Indonesia produces 8 millions MT bagasse and 11.5 millions MT canes top and leaves.
There are 39 palm oil plantations and mills currently operating in Indonesia, and at least eight new plantations are under construction. Most palm oil mills generate combined heat and power from fibres and palm kernel shells, making the operations energy self–efficient. However, the use of palm oil residues can still be optimized in more energy efficient systems.
Other potential source of biomass energy can also come from municipal wastes. The quantity of city or municipal wastes in Indonesia is comparable with other big cities of the world. Most of these wastes are originated from household in the form of organic wastes from the kitchen. At present the wastes are either burned at each household or collected by the municipalities and later to be dumped into a designated dumping ground or landfill.
Although the government is providing facilities to collect and clean all these wastes, however, due to the increasing number of populations coupled with inadequate number of waste treatment facilities in addition to inadequate amount of allocated budget for waste management, most of big cities in Indonesia had been suffering from the increasing problem of waste disposals.
With Indonesia’s recovery from the Asian financial crisis of 1998, energy consumption has grown rapidly in past decade. The priority of the Indonesian energy policy is to reduce oil consumption and to use renewable energy. For power generation, it is important to increase electricity power in order to meet national demand and to change fossil fuel consumption by utilization of biomass wastes. The development of renewable energy is one of priority targets in Indonesia.
The current pressure for cost savings and competitiveness in Indonesia’s most important biomass-based industries, along with the continually growing power demands of the country signal opportunities for increased exploitation of biomass wastes for power generation.
Malaysia is located in a region where biomass productivity is high which means that the country can capitalize on this renewable energy resource to supplements limited petroleum and coal reserves. Malaysia, as a major player in the palm oil and sago starch industries, produces a substantial amount of agricultural biomass waste which present a great opportunity for harnessing biomass energy in an eco-friendly and commercially-viable manner.
Peninsular Malaysia generates large amounts of wood and’ agricultural residues, the bulk of which are not being currently utilised for any further downstream operations. The major agricultural crops grown in Malaysia are rubber (39.67%), oil palm (34.56%), cocoa (6.75%), rice (12.68%) and coconut (6.34%). Out of the total quantity of residues generated, only 27.0% is used either as fuel for the kiln drying of timber, for the manufacture of bricks, the curing of tobacco leaves, the drying rubber-sheets and for the manufacture of products such as particleboard and fibreboard. The rest has to be disposed of by burning.
Palm Oil Industry
Oil palm is one of the world’s most important fruit crops. Malaysia is one of the largest producers and exporter of palm oil in the world, accounting for 30% of the world’s traded edible oils and fats supply. Palm oil industries in Malaysia have good potential for high pressure modern power plants and the annual power generation potential is about 8,000 GWh. Malaysia produced more than 20 million tonnes of palm oil in 2012 over 5 million hectares of land.
The palm oil industry is a significant branch in Malaysian agriculture. Almost 70% of the volume from the processing of fresh fruit bunch is removed as biomass waste in the form of empty fruit bunches (EFBs), fibers and shells, as well as liquid effluent. Fibres and shells are traditionally used as fuels to generate power and steam. Palm oil mill effluent, commonly known as POME, are sometimes converted into biogas that can be used in gas-fired gensets.
Sugar Industry
The cultivation of sugarcane in Malaysia is surprisingly small. Production is concentrated in the Northwest extremity of peninsular Malaysia in the states of Perlis and Kedah. This area has a distinct dry season needed for cost-efficient sugarcane production. Plantings in the states of Perak and Negri Sembilan were unsuccessful due to high unit costs as producing conditions were less suitable.
The lack of growth in cane areas largely reflects the higher remuneration received by farmers for other crops, especially oil palm. Over the past 20 years while the sugarcane area has remained at around 20000 hectares, that planted to oil palm has expanded from 600 000 hectares to 5 million hectares.
Other leading crops in terms of planted areas are rubber with 2.8 million hectares, rice with 670 000 hectares and cocoa with 380 000 hectares. Malaysia, the world’s third largest rubber producer, accounted for 1 million tons of natural rubber production in 2012. Like oil palm industry, the rubber industry produces a variety of biomass wastes whose energy potential is largely untapped until now.
There is immense potential of biomass energy in Southeast Asia due to plentiful supply of diverse forms of biomass wastes including agricultural residues, agro-industrial wastes, woody biomass, animal wastes, municipal solid waste, etc. Southeast Asia is a big producer of wood and agricultural products which, when processed in industries, produces large amounts of biomass residues.
The rapid economic growth and industrialization in Southeast Asian region is characterized by a significant gap between energy supply and demand. The energy demand in the region is expected to grow rapidly in the coming years which will have a profound impact on the global energy market. In addition, the region has many locations with high population density, which makes public health vulnerable to the pollution caused by fossil fuels.
Another important rationale for transition from fossil-fuel-based energy systems to renewable ones arises out of observed and projected impacts of climate change. Due to the rising share of greenhouse gas emissions from Asia, it is imperative on all Asian countries to promote sustainable energy to significantly reduce GHGs emissions and foster sustainable energy trends. Rising proportion of greenhouse gas emissions is causing large-scale ecological degradation, particularly in coastal and forest ecosystems, which may further deteriorate environmental sustainability in the region.
The reliance on conventional energy sources can be substantially reduced as the Southeast Asian region is one of the leading producers of biomass resources in the world. Southeast Asia, with its abundant biomass resources, holds a strategic position in the global biomass energy atlas.
Palm kernel shells is an abundant biomass resource in Southeast Asia
According to conservative estimates, the amount of biomass residues generated from sugar, rice and palm oil mills is more than 200-230 million tons per year which corresponds to cogeneration potential of 16-19 GW. Woody biomass is a good energy resource due to presence of large number of forests and wood processing industries in the region.
The prospects of biogas power generation are also high in the region due to the presence of well-established food processing, agricultural and dairy industries. Another important biomass resource is contributed by municipal solid wastes in heavily populated urban areas.
In addition, there are increasing efforts from the public and private sectors to develop biomass energy systems for efficient biofuel production, e.g. biodiesel and bioethanol. The rapid economic growth and industrialization in Southeast Asia has accelerated the drive to implement the latest biomass energy technologies in order to tap the unharnessed potential of biomass resources, thereby making a significant contribution to the regional energy mix.
Southeast Asia, with its abundant bioenergy resources, holds a strategic position in the global biomass energy atlas. There is immense biomass energy potential in Southeast Asian countries due to plentiful supply of diverse forms of biomass wastes, such as agricultural residues, woody biomass, animal wastes, municipal solid waste, etc. The rapid economic growth and industrialization in the region has accelerated the drive to implement the latest waste-to-energy technologies to tap the unharnessed potential of biomass resources.
Southeast Asia is a big producer of agricultural and wood products which, when processed in industries, produces large amounts of biomass residues. According to conservative estimates, the amount of biomass residues generated from sugar, rice and palm oil mills is more than 200-230 million tons per year which corresponds to cogeneration potential of 16-19 GW.
Rice mills in the region produce 38 million tonnes of rice husk as solid residue which is a good fuel for producing heat and power. Sugar industry is an integral part of the industrial scenario in Southeast Asia accounting for 7% of sugar production worldwide. Sugar mills in Thailand, Indonesia, Philippines and Vietnam generate 34 million tonnes of bagasse every year. Malaysia, Indonesia and Thailand account for 90% of global palm oil production leading to the generation of 27 million tonnes of waste per annum in the form of empty fruit bunches (EFBs), fibers and shells, as well as liquid effluent.
Woody biomass is a good energy resource due to presence of large number of forests in Southeast Asia. Apart from natural forests, non-industrial plantations of different types (e.g. coconut, rubber and oil palm plantations, fruit orchards, and trees in homesteads and gardens) have gained recognition as important sources of biomass. In addition, the presence of a large number of wood processing industries also generates significant quantity of wood wastes. The annual production of wood wastes in the region is estimated to be more than 30 million m3.
The prospects of biogas power generation are also high in the region, thanks to presence of well-established food-processing and dairy industries. Another important biomass resource is contributed by municipal solid wastes in heavily populated urban areas. In addition, there are increasing efforts both commercially and promoted by governments to develop biomass energy systems for efficient biofuel production, e.g. bio-diesel from palm oil.
Biomass resources, particularly residues from forests, wood processing, agricultural crops and agro-processing, are under-utilised in Southeast Asian countries. There is an urgent need to utilize biomass wastes for commercial electricity and heat production to cater to the needs of the industries as well as urban and rural communities.
Southeast Asian countries are yet to make optimum use of the additional power generation potential from biomass waste resources which could help them to partially overcome the long-term problem of energy supply. Technologies for biomass utilization which are at present widely used in Southeast counties need to be improved towards best practice by making use of the latest trends in the biomass energy sector.
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