Tag Archives: tannery waste management

Wastes Generation in Tanneries

  By Salman Zafar | November 22, 2012 - 12:23 pm | Industrial Waste Management
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Wastes originate from all stages of leather making, such as fine leather particles, residues from various chemical discharges and reagents from different waste liquors comprising of large pieces of leather cuttings, trimmings and gross shavings, fleshing residues, solid hair debris and remnants of paper bags.

Tanning refers to the process by which collagen fibers in a hide react with a chemical agent (tannin, alum or other chemicals). However, the term leather tanning also commonly refers to the entire leather-making process. Hides and skins have the ability to absorb tannic acid and other chemical substances that prevent them from decaying, make them resistant to wetting, and keep them supple and durable. The flesh side of the hide or skin is much thicker and softer. The three types of hides and skins most often used in leather manufacture are from cattle, sheep, and pigs.

Out of 1000 kg of raw hide, nearly 850 kg is generated as solid wastes in leather processing. Only 150 Kg of the raw material is converted in to leather. A typical tannery generate huge amount of waste:

  • Fleshing: 56-60%
  • Chrome shaving, chrome splits and buffing dust: 35-40%
  • Skin trimming: 5-7%
  • Hair: 2-5%

Over 80 per cent of the organic pollution load in BOD terms emanates from the beamhouse (pre-tanning); much of this comes from degraded hide/skin and hair matter. During the tanning process at least 300 kg of chemicals (lime, salt etc.) are added per ton of hides. Excess of non-used salts will appear in the wastewater.

Because of the changing pH, these compounds can precipitate and contribute to the amount of solid waste or suspended solids. Every tanning process step, with the exception of finishing operations, produces wastewater. An average of 35 m3 is produced per ton of raw hide. The wastewater is made up of high concentration of salts, chromium, ammonia, dye and solvent chemicals etc.

A large amount of waste produced by tanneries is discharged in natural water bodies directly or indirectly through two open drains without any treatment. The water in the low lying areas in developing countries, like India and Bangladesh, is polluted in such a degree that it has become unsuitable for public uses. In summer when the rate of decomposition of the waste is higher, serious air pollution is caused in residential areas by producing intolerable obnoxious odours.

Anaerobic Digestion of Tannery Wastes

  By Salman Zafar | July 30, 2012 - 5:57 pm | Anaerobic Digestion, Biogas, Industrial Waste Management
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The conventional leather tanning technology is highly polluting as it produces large amounts of organic and chemical pollutants. Wastes generated by the leather processing industries pose a major challenge to the environment. According to conservative estimates, about 600,000 tons per year of solid waste are generated worldwide by leather industry and approximately 40–50% of the hides are lost to shavings and trimmings.

Everyday a huge quantity of solid waste, including trimmings of finished leather, shaving dusts, hair, fleshing, trimming of raw hides and skins, are being produced from the industries. Chromium, sulphur, oils and noxious gas (methane, ammonia, and hydrogen sulphide) are the elements of liquid, gas and solid waste of tannery industries.

Anaerobic digestion (or biomethanation) systems are mature and proven processes that have the potential to convert tannery wastes into energy efficiently, and achieve the goals of pollution prevention/reduction, elimination of uncontrolled methane emissions and odour, recovery of bio-energy potential as biogas, production of stabilized residue for use as low grade fertilizer.

Anaerobic digestion is a favorable technological solution which degrades a substantial part of the organic matter contained in the sludge and tannery solid wastes, generating valuable biogas, contributing to alleviate the environmental problem, giving time to set-up more sustainable treatment and disposal routes. Digested solid waste is biologically stabilized and can be reused in agriculture.

The application of an anaerobic treatment for the break down of COD from tannery waste water is an attractive method to recover energy from tannery wastewater. Until now it was considered that the complexity of the waste water stream originating from tanneries in combination with the presence of chroming would result in the poisoning of the process in a high loaded anaerobic reactor.

When the locally available industrial wastewater treatment plant is not provided by anaerobic digester, a large scale digestion can be planned in regions accommodating a big cluster of tanneries, if there is enough waste to make the facility economically attractive. In this circumstance, an anaerobic co-digestion plant based on sludge and tanneries may be a recommendable option, which reduces the quantity of landfilled waste and recovers its energy potential. It can also incorporate any other domestic, industrial or agricultural wastes. Chrome-free digested tannery sludge also has a definite value as a fertilizer based on its nutrient content.

Biogas produced in anaerobic digesters consists of methane (50%–80%), carbon dioxide (20%–50%), and trace levels of other gases such as hydrogen, carbon monoxide, nitrogen, oxygen, and hydrogen sulfide.  Biogas can be used for producing electricity and heat, as a natural gas substitute and also a transportation fuel. A combined heat and power plant system (CHP) not only generates power but also produces heat for in-house requirements to maintain desired temperature level in the digester during cold season.

CHP systems cover a range of technologies but indicative energy outputs per m3 of biogas are approximately 1.7 kWh electricity and 2.5kWh heat. The combined production of electricity and heat is highly desirable because it displaces non-renewable energy demand elsewhere and therefore reduces the amount of carbon dioxide released into the atmosphere.