A Glance at Drop-in Biofuels

drop-in-biofuelsBiofuel commercialization has proved to be costly and lingering than expected due to its high production cost and modification to flexibility in engines. Drop-in fuels are alternatives to existing liquid fuels without any significant modification in engines and infrastructures. According to IEA, “Drop-in biofuels are liquid bio-hydrocarbons that are functionally equivalent to petroleum fuels and are fully compatible with existing petroleum infrastructure”.

What are Drop-in Biofuels

Drop-in biofuels are can be produced from oilseeds via trans-esterification, lignocellulosic biomass via thermochemical process, sugars and alcohol via biochemical conversion or by hybrids of the above methods. Drop-in fuels encompass high hydrogen to carbon ratio with no/low sulfur and oxygen content, low water solubility and high carbon bond saturation. In short drop-in fuel is a modified fuel with close functional resemblance to fossil fuel.

Existing biofuels – bioethanol and biodiesel – have wide variation from fossil fuels in their blend wall properties – high oxygen content, hydrophilicity, energy density and mainly compatibility in existing engines and infrastructures. Oxygenated groups in biofuel have a domino effect such as reduction in the energy density, production of impurities which are highly undesirable to transportation components, instability during storage etc.

Major advantages of drop-in fuels over existing fuels are as follows:

  • Reduced sulphur oxide emissions by ultra low sulphur content.
  • Reduced ignition delay by high cetane value
  • Reduced hydrocarbons and nitrogen oxides emissions
  • Low aromatic content
  • Low olefin content, presence of olefin compounds undergo auto-oxidation leading to surface depositions.
  • High saturates, therefore leaving minimum residues
  • Low particulate emissions
  • No oxygenates therefore has high stability.

Potential Biomass Feedstock

Drop-in biofuels can be produced from various biomass sources- lipids (vegetable oils, animal fats, greases, and algae) and cellulosic material (such as crop residues, woody biomass, and dedicated energy crops). The prominent technologies for biomass conversion to drop-in fuel are the thermochemical and the biochemical process.

The major factor playing role in selection of biomass for thermochemical methods is the energy content or heating value of the material, which is correlated with ash content. Wood, wood chips accounts for less than 1% ash content, which is favorable thermal processing than biochemical process, whereas straws, husks, and majority of the other biomass have ash content ranging up to 25% of dry mass.

Free sugar generating plants such as sugarcane and sweet sorghum, are desirable feedstock for Acetone-Butanol-Ethanol fermentation and have been widely implemented. Presently there is a focus to exploit lignocellulosic residues, rich in hydrocarbon, for fuel production. However, this biomass requires harsh pretreatment to remove lignin and to transform holocellulose (cellulose & hemicelluloses) into fermentable products.

The lignocellulose transformation technology must be circumspectly chosen by its life cycle assessment, as it resists any changes in their structural integrity owing to its complexity. Lignocellulosic biomass, when deoxygenated, has better flexibility to turn to drop-in fuels. This is because, in its native state of the feedstock, each oxygen atom consumes two hydrogen atoms during combustion which in turn reduces effective H: C ratio. Biomass feedstock is characterized with oxygen up to 40%, and higher the oxygen content higher it has to be deoxygenated.

Thermochemical Route

Thermochemical methods adopted for biomass are pyrolysis and gasification, on thermolysis of biomass produce intermediate gas (syngas) and liquid (bio crude) serving as precursors for drop-in fuel. Biomass when exposed to temperature of 500oC-600oC in absence of oxygen (pyrolysis) produce bio-oil, which constitutes a considerable percentage of oxygen. After down streaming by hydroprocessing (hydrotreating and hydrocracking) the rich hydrocarbon tar (bio-oil) can be converted to an efficient precursor for drop-in fuel.

At a higher temperature, above 700, under controlled oxygen, biomass can be converted to liquid fuel via gas phase by the process, gasification. Syngas produced is converted to liquid fuel by Fischer-Tropsch with the help of ‘water gas shift’ for hydroprocessing. Hydroprocessing after the thermochemical method is however costly and complex process in case of pyrolysis and inefficient biomass to fuel yield with gasification process.

Biochemical Pathway

The advanced biocatalytic processes can divert the conventional sugar-ethanol pathway and convert sugars to fatty acids. Modified microbial strain with engineered cellular machineries, can reroute the pathway to free fatty acid that can be transformed into butanol or drop-in fuel with necessary processing.

Schematic for the preparation of jet fuel from biomass

Schematic for the preparation of jet fuel from biomass

Biological processing requires operation under the stressful conditions on the organisms to reroute the pathways, in additional to lowering NADPH (hydrogen) consumption. Other value added products like carboxylic acid, polyols, and alcohol in the same biological routes with lower operational requirements have higher market demands and commercial success. Therefore little attention is given by chemical manufacturers to the biological pathways for drop-in fuel production.

The mechanisms of utilization of lignocellulosic biomass to fuel by biological pathway rely heavily on the availability of monomeric C5 and C6 sugars during fermentation. Ethanol is perhaps the best-known and commercially successful alcohol from ABE fermentation. However, butanol has various significant advantages over ethanol- in the perception of energy content, feasibility to existing infrastructures, zero blend wall, safety and clean aspects. Although butanol is a closer drop-in replacement, existing biofuel ethanol, is a major commercial competitor. Low yield from fermentation due to the toxicity of butanol and complexity in down streaming are the vital reasons that hamper successful large scale butanol production.

Challenges to Overcome

Zero oxygen and sulphur content mark major challenges for production of drop-in fuels from conventional biomass. This demands high hydrogen input on the conventional biomass, with H: C ratio below 0.5, like sugar, starch, cellulose, lignocellulose to meet the effective hydrogen to carbon ratio of 2 as in drop-in fuel. This characterizes most of the existing biomass feedstock as a low-quality input for drop-in fuels. However oleochemicals like fats, oils, and lipids have closer H: C ratio to diesel, gasoline and drop-in fuels, thus easier to conversion. Oleochemical feedstock has been commercially successful, but to prolong in the platform will be a major challenge. Lipid feedstock is generally availed from crop-based vegetable oil, which is used in food sectors. Therefore availability, food security concerns, and economics are the major constraints to sustaining the raw material. Consequently switching to lignocellulosic biomass feedstock for drop-in holds on.

Conclusions

Despite the hurdles on biomass characteristics and process technology for drop-in fuel, it is a vital requirement to switch to better replacement fuel for fossil fuel, considering environmental and economic benefits. Understanding its concepts and features, drop-in fuel, can solve existing greenhouse emission debate on current biofuels. Through crucial ambiguities existing on future of alternative fuels, drop-in fuel has a substantial potential to repute itself as an efficient sustainable eco-friendly fuel in the naear future.

References

  • Neal K Van Alfen: ENCYCLOPEDIA OF AGRICULTURE AND FOOD SYSTEMS, Elsevier, Academic Press.
  • Pablo Domínguez de María John: INDUSTRIAL BIORENEWABLES:A Practical Viewpoint: Wiley & Sons.
  • Ram Sarup Singh, Ashok Pandey, Edgard Gnansounou: BIOFUELS- PRODUCTION AND FUTURE PERSPECTIVES, CRC Press.
  • Satinder Kaur Brar, Saurabh Jyoti Sarma, Kannan Pakshirajan : PLATFORM CHEMICAL BIOREFINERY-FUTURE GREEN CHEMISTRY, Elsevier.
  • Sergios Karatzos, James D. McMillan, Jack N. Saddle: Summary of IEA BIOENERGY TASK 39 REPORT-THE POTENTIAL AND CHALLENGES OF DROP-IN BIOFUELS, IEA Bioenergy.
  • Vijai Kumar Gupta, Monika Schmoll, Minna Maki, Maria Tuohy, Marcio Antonio Mazutti: APPLICATIONS OF MICROBIAL ENGINEERING, CRC Press.

Bioethanol: Challenges in India

bioethanol-indiaGlobal demand for fuel efficiency, environmental quality and energy security have elicited global attention towards liquid biofuels, such as bioethanol and biodiesel. Around the world, governments have introduced various policy measurements, mandatory fuel blending programmes, incentives for flex-fuel vehicles and agricultural subsidies for the farmers. In India, the government launched Ethanol Blended Petrol (EBP) programme in January 2013 for 5% ethanol blended petrol. The policy had significant focus on India’s opportunity to agricultural and industrial sectors with motive of boosting biofuel usage and reducing the existing dependency on fossil fuel.

The Government of India initiated significant investments in improving storage and blending infrastructure. The National Policy on Biofuels has set a target of 20% blending of biofuel by 2017. However, India has managed to achieve only 5% by September 2016 due to certain technical, market and regulatory hurdles.

In India, sugar cane molasses is the major resource for bioethanol production and inconsistency of raw material supply holds the major liability for sluggish response to blending targets.  Technically speaking, blend wall and transportation-storage are the major challenges towards the biofuel targets. Blending wall is the maximum percent of ethanol that can be blended to fuel without decreasing the fuel efficiency. Various vehicles are adaptable to various blending ratio based on the flexibility of engines. The technology for the engine modification for flex fuel is not new but making the engines available in India along with the supply chain and calibrating the engine for Indian conditions is the halting phase. The commonly used motor vehicles in the country are not effectual with flex fuel.

Sugarcane molasses is the most common feedstock for bioethanol production in India

Sugarcane molasses is the most common feedstock for bioethanol production in India

Ethanol being a highly flammable liquid marks obligatory safety and risk assessment measures during all phases of production, storage and transportation. The non-uniform distribution of raw material throughout the country, demands a compulsory transportation and storage, especially inter-state movement, encountering diverse climatic and topographic conditions.

Major ethanol consumers in India are potable liquor sector (45%), alcohol based chemical industry (40%), the rest for blending and other purposes. The yearly profit elevation in major sectors is a dare to an economical ethanol supply for Ethanol Blending Programme. Drastic fluctuation in pricing of sugar cane farming and sugar milling resulted to huge debt to farmers by mill owners. Gradually the farmers shifted from sugarcane cultivation other crops.

Regulatory and policy approaches on excise duty on storage and transportation of ethanol and pricing strategy of ethanol compared to crude oil are to be revised and implemented effectively. Diversifying the feedstocks and advanced technology for domestic ethanol production in blending sectors are to be fetched out from research laboratories to commercial scale. Above all the knowledge of economic and environmental benefits of biofuel like reduction in pollutants and import bills, need to be amplified for the common man.

Biomass Energy and Sustainability

biomass-sustainabilityBiomass energy systems offer significant possibilities for reducing greenhouse gas emissions due to their immense potential to replace fossil fuels in energy production. Biomass reduces emissions and enhances carbon sequestration since short-rotation crops or forests established on abandoned agricultural land accumulate carbon in the soil. Biomass energy usually provides an irreversible mitigation effect by reducing carbon dioxide at source, but it may emit more carbon per unit of energy than fossil fuels unless biomass fuels are produced in a sustainable manner.

Biomass resources can play a major role in reducing the reliance on fossil fuels by making use of thermo-chemical conversion technologies. In addition, the increased utilization of biomass-based fuels will be instrumental in safeguarding the environment, generation of new job opportunities, sustainable development and health improvements in rural areas.

The development of efficient biomass handling technology, improvement of agro-forestry systems and establishment of small and large-scale biomass-based power plants can play a major role in sustainable development of rural as well as urban areas. Biomass energy could also aid in modernizing the agricultural economy and creating significant job opportunities.

Harvesting practices remove only a small portion of branches and tops leaving sufficient biomass to conserve organic matter and nutrients. Moreover, the ash obtained after combustion of biomass compensates for nutrient losses by fertilizing the soil periodically in natural forests as well as fields.

The impact of forest biomass utilization on the ecology and biodiversity has been found to be insignificant. Infact, forest residues are environmentally beneficial because of their potential to replace fossil fuels as an energy source.

A quick glance at popular biomass resources

A quick glance at popular biomass resources

Plantation of energy crops on abandoned agricultural land will lead to an increase in species diversity. The creation of structurally and species diverse forests helps in reducing the impacts of insects, diseases and weeds. Similarly the artificial creation of diversity is essential when genetically modified or genetically identical species are being planted.

Short-rotation crops give higher yields than forests so smaller tracts are needed to produce biomass which results in the reduction of area under intensive forest management. An intelligent approach in forest management will go a long way in the realization of sustainability goals.

Improvements in agricultural practices promises to increased biomass yields, reductions in cultivation costs, and improved environmental quality. Extensive research in the fields of plant genetics, analytical techniques, remote sensing and geographic information systems (GIS) will immensely help in increasing the energy potential of biomass feedstock.

A large amount of energy is expended in the cultivation and processing of crops like sugarcane, coconut, and rice which can met by utilizing energy-rich residues for electricity production. The integration of biomass-fueled gasifiers in coal-fired power stations would be advantageous in terms of improved flexibility in response to fluctuations in biomass availability and lower investment costs. The growth of the biomass energy industry can also be achieved by laying more stress on green power marketing.

Role of Biomass Energy in Rural Development

biomass-balesBiomass energy systems not only offer significant possibilities for clean energy production and agricultural waste management but also foster sustainable development in rural areas. The increased utilization of biomass wastes will be instrumental in safeguarding the environment, generation of new job opportunities, sustainable development and health improvements in rural areas.

Biomass energy has the potential to modernize the agricultural economy and catalyze rural development. The development of efficient biomass handling technology, improvement of agro-forestry systems and establishment of small, medium and large-scale biomass-based power plants can play a major role in rural development.

Sustainable harvesting practices remove only a small portion of branches and tops leaving sufficient biomass to conserve organic matter and nutrients. Moreover, the ash obtained after combustion of biomass compensates for nutrient losses by fertilizing the soil periodically in natural forests as well as fields.

Planting of energy crops on abandoned agricultural lands will lead to an increase in species diversity. The creation of structurally and species diverse forests helps in reducing the impacts of insects, diseases and weeds. Similarly the artificial creation of diversity is essential when genetically modified or genetically identical species are being planted.

Improvements in agricultural practices promises to increased biomass yields, reductions in cultivation costs, and improved environmental quality. Extensive research in the fields of plant genetics, analytical techniques, remote sensing and geographic information systems (GIS) will immensely help in increasing the energy potential of biomass feedstock.

Rural areas are the preferred hunting ground for the development of biomass sector worldwide. By making use of various biological and thermal processes (anaerobic digestion, combustion, gasification, pyrolysis), agricultural wastes can be converted into biofuels, heat or electricity, and thus catalyzing sustainable development of rural areas economically, socially and environmentally.

Biomass energy can reduce 'fuel poverty' in remote and isolated communities

Biomass energy can reduce ‘fuel poverty’ in remote and isolated communities

A large amount of energy is utilized in the cultivation and processing of crops like sugarcane, wheat and rice which can met by utilizing energy-rich residues for electricity production. The integration of biomass-fueled gasifiers in coal-fired power stations would be advantageous in terms of improved flexibility in response to fluctuations in biomass availability and lower investment costs.

There are many areas in India where people still lack access to electricity and thus face enormous hardship in day-to-day lives. Biomass energy promises to reduce ‘fuel poverty’ commonly prevalent among remote and isolated communities.  Obviously, when a remote area is able to access reliable and cheap energy, it will lead to economic development and youth empowerment.

Biomass Energy in China

biomass-chinaBiomass energy in China has been developing at a rapid pace. Installed biomass power generation capacity in China increased sharply from 1.4 GW in 2006 to 8.5 GW in 2013. While the energy share of biomass remains relatively low compared to other sources of renewable energy, China plans to increase the proportion of biomass energy up to 15 percent and total installed capacity of biomass power generation to 30 GW by 2030.  In terms of impact, the theoretical biomass energy resource in China is about 5 billion tons coal equivalent, which equals 4 times of all energy consumption. As per conservative estimates, currently China is only using 5 percent of its total biomass potential.

According to IRENA, the majority of biomass capacity is in Eastern China, with the coastal province of Shandong accounting for 14 percent of the total alone. While the direct burning of mass for heat remains the primary use of biomass in China, in 2009, composition of China’s biomass power generation consisted in 62 percent of straw direct-fired power generation and 29 percent of waste incineration, with a mix of other feedstock accounting for the remaining 9 percent.

Biomass Resources in China

Major biomass resources in China include waste from agricultural, forestry, industrial, animal and sewage, and municipal solid waste. While the largest contributing sources are estimated to be residues from annual crop production like wheat straw, much of the straw and stalk are presently used for cooking and heating in rural households at low efficiencies. Therefore, agricultural residues, forestry residues, and garden waste were found to be the most cited resources with big potential for energy production in China.

Agricultural residues are derived from agriculture harvesting such as maize, rice and cotton stalks, wheat straw and husks, and are most available in Central and northeastern China where most of the large stalk and straw potential is located. Because straw and stalks are produced as by-products of food production systems, they are perceived to be sustainable sources of biomass for energy that do not threaten food security. Furthermore, it is estimated that China produces around 700 Mt of straw per year, 37 percent of which is corn straw, 28 percent rice, 20 percent wheat and 15 percent from various other crops. Around 50 percent of this straw is used for fertilizers, for which 350 Mt of straw is available for energy production per year.

Biomass resources are underutilized across China

Biomass resources are underutilized across China

Forestry residues are mostly available in the southern and central parts of China. While a few projects that use forestry wastes like tree bark and wood processing wastes are under way, one of the most cited resources with analyzed potential is garden waste. According to research, energy production from garden waste biomass accounted for 20.7 percent of China’s urban residential electricity consumption, or 12.6 percent of China’s transport gasoline demand in 2008.

Future Perspectives

The Chinese government believes that biomass feedstock should neither compete with edible food crops nor cause carbon debt or negative environmental impacts. As biomass takes on an increasing significant role in the China’s national energy-mix, future research specific to technology assessment, in addition to data collection and supply chain management of potential resources is necessary to continue to understand how biomass can become a game-changer in China’s energy future.

References

IRENA, 2014. Renewable Energy Prospects: China, REmap 2030 analysis. IRENA, Abu Dhabi. www.irena.org/remap

National Academy of Engineering and NRC, 2007: Energy Futures and Urban Air Pollution: Challenges for China and the United States.

Xingang, Z., Zhongfu, T., Pingkuo, L, 2013. Development goal of 30 GW for China’s biomass power generation: Will it be achieved? Renewable and Sustainable Energy Reviews, Volume 25, September 2013, 310–317.

Xingang, Z., Jieyu, W., Xiaomeng, L., Tiantian, F., Pingkuo, L, 2012. Focus on situation and policies for biomass power generation in China. Renewable and Sustainable Energy Reviews, Volume 16, Issue 6, August 2012, 3722–3729.

Li, J., Jinming, B. MOA/DOE Project Expert Team, 1998. Assessment of Biomass Resource Availability in China. China Environmental Science Press, Beijing, China.

Klimowicz, G., 2014. “China’s big plans for biomass,” Eco-Business, Global Biomass Series, accessed on Apr 6, 2015.

Shi, Y., Ge, Y., Chang, J., Shao, H., and Tang, Y., 2013. Garden waste biomass for renewable and sustainable energy production in China: Potential, challenges and development. Renewable and Sustainable Energy Reviews 22 (2013) 432–437

Xu, J. and Yuan, Z, 2015. “An overview of the biomass energy policy in China,” BESustainable, May 21, 2015.

Resource Base for Second-Generation Biofuels

second-generation-biofuelsSecond-generation biofuels, also known as advanced biofuels, primarily includes cellulosic ethanol. The feedstocks used for the production of second-generation biofuel are non-edible lignocellulosic biomass resources (such as leaves, stem and husk) which do not compete with food resources. The resource base for second-generation biofuels production is broadly divided into three categories – agricultural residues, forestry wastes and energy crops.

Agricultural Residues

Agricultural (or crop) residues encompasses all agricultural wastes such as straw, stem, stalk, leaves, husk, shell, peel, pulp, stubble, etc. which come from cereals (rice, wheat, maize or corn, sorghum, barley, millet), cotton, groundnut, jute, legumes (tomato, bean, soy) coffee, cacao, tea, fruits (banana, mango, coco, cashew) and palm oil.

Rice produces both straw and rice husks at the processing plant which can be conveniently and easily converted into energy. Significant quantities of biomass remain in the fields in the form of cob when maize is harvested which can be converted into energy. Sugar cane harvesting leads to harvest residues in the fields while processing produces fibrous bagasse, both of which are good sources of energy. Harvesting and processing of coconuts produces quantities of shell and fibre that can be utilised while peanuts leave shells. All these lignocellulosic materials can be converted into biofuels by a wide range of technologies.

Forestry Biomass

Forest harvesting is a major source of biomass energy. Harvesting in forests may occur as thinning in young stands, or cutting in older stands for timber or pulp that also yields tops and branches usable for production of cellulosic ethanol. Harvesting operations usually remove only 25 to 50 percent of the volume, leaving the residues available as biomass for energy. Stands damaged by insects, disease or fire are additional sources of biomass. Forest residues normally have low density and fuel values that keep transport costs high, and so it is economical to reduce the biomass density in the forest itself.

Energy Crops

Energy crops are non-food crops which provide an additional potential source of feedstock for the production of second-generation biofuels. Corn and soybeans are considered as the first-generation energy crops as these crops can be also used as the food crops. Second-generation energy crops are grouped into grassy (herbaceous or forage) and woody (tree) energy crops.

Grassy energy crops or perennial forage crops mainly include switchgrass and miscanthus. Switchgrass is the most commonly used feedstock because it requires relatively low water and nutrients, and has positive environmental impact and adaptability to low-quality land. Miscanthus is a grass mainly found in Asia and is a popular feedstock for second-generation biofuel production in Europe. Woody energy crops mainly consists of fast-growing tree species like poplar, willow, and eucalyptus. The most important attributes of these class species are the low level of input required when compared with annual crops. In short, dedicated energy crops as feedstock are less demanding in terms of input, helpful in reducing soil erosion and useful in improving soil properties.

Biomass Resources from Sugar Industry

Sugarcane is one of the most promising agricultural sources of biomass energy in the world. It is the most appropriate agricultural energy crop in most sugarcane producing countries due to its resistance to cyclonic winds, drought, pests and diseases, and its geographically widespread cultivation. Due to its high energy-to-volume ratio, it is considered one of nature’s most effective storage devices for solar energy and the most economically significant energy crop. The climatic and physiological factors that limit its cultivation to tropical and sub-tropical regions have resulted in its concentration in developing countries, and this, in turn, gives these countries a particular role in the world’s transition to sustainable use of natural resources.

According to the International Sugar Organization (ISO), Sugarcane is a highly efficient converter of solar energy, and has the highest energy-to-volume ratio among energy crops. Indeed, it gives the highest annual yield of biomass of all species. Roughly, 1 ton of Sugarcane biomass-based on Bagasse, foliage and ethanol output – has an energy content equivalent to one barrel of crude oil.   Sugarcane produces mainly two types of biomass, Cane Trash and Bagasse. Cane Trash is the field residue remaining after harvesting the Cane stalk and Bagasse is the milling by-product which remains after extracting sugar from the stalk. The potential energy value of these residues has traditionally been ignored by policy-makers and masses in developing countries. However, with rising fossil fuel prices and dwindling firewood supplies, this material is increasingly viewed as a valuable renewable energy resource.

Sugar mills have been using Bagasse to generate steam and electricity for internal plant requirements while Cane Trash remains underutilized to a great extent. Cane Trash and Bagasse are produced during the harvesting and milling process of Sugarcane which normally lasts 6 to 7 months.

Around the world, a portion of the Cane Trash is collected for sale to feed mills, while freshly cut green tops are sometimes collected for farm animals. In most cases, however, the residues are burned or left in the fields to decompose. Cane Trash, consisting of Sugarcane tops and leaves can potentially be converted into around 1kWh/kg, but is mostly burned in the field due to its bulkiness and its related high cost for collection/transportation.

On the other hand, Bagasse has been traditionally used as a fuel in the Sugar mill itself, to produce steam for the process and electricity for its own use. In general, for every ton of Sugarcane processed in the mill, around 190 kg Bagasse is produced. Low pressure boilers and low efficiency steam turbines are commonly used in developing countries. It would be a good business proposition to upgrade the present cogeneration systems to highly efficient, high pressure systems with higher capacities to ensure utilization of surplus Bagasse.

Energy Potential of Coconut Biomass

coconut-shell-biomassCoconuts are produced in 92 countries worldwide on about more than 10 million hectares. Indonesia, Philippines and India account for almost 75% of world coconut production with Indonesia being the world’s largest coconut producer. A coconut plantation is analogous to energy crop plantations, however coconut plantations are a source of wide variety of products, in addition to energy. The current world production of coconuts has the potential to produce electricity, heat, fiberboards, organic fertilizer, animal feeds, fuel additives for cleaner emissions, health drinks, etc.

The coconut fruit yields 40 % coconut husks containing 30 % fiber, with dust making up the rest. The chemical composition of coconut husks consists of cellulose, lignin, pyroligneous acid, gas, charcoal, tar, tannin, and potassium. Coconut dust has high lignin and cellulose content. The materials contained in the casing of coco dusts and coconut fibers are resistant to bacteria and fungi.

Coconut husk and shells are an attractive biomass fuel and are also a good source of charcoal. The major advantage of using coconut biomass as a fuel is that coconut is a permanent crop and available round the year so there is constant whole year supply. Activated carbon manufactured from coconut shell is considered extremely effective for the removal of impurities in wastewater treatment processes.

Coconut Shell

Coconut shell is an agricultural waste and is available in plentiful quantities throughout tropical countries worldwide. In many countries, coconut shell is subjected to open burning which contributes significantly to CO2 and methane emissions.  Coconut shell is widely used for making charcoal. The traditional pit method of production has a charcoal yield of 25–30% of the dry weight of shells used. The charcoal produced by this method is of variable quality, and often contaminated with extraneous matter and soil. The smoke evolved from pit method is not only a nuisance but also a health hazard.

The coconut shell has a high calorific value of 20.8MJ/kg and can be used to produce steam, energy-rich gases, bio-oil, biochar etc. It is to be noted that coconut shell and coconut husk are solid fuels and have the peculiarities and problems inherent in this kind of fuel.  Coconut shell is more suitable for pyrolysis process as it contain lower ash content, high volatile matter content and available at a cheap cost. The higher fixed carbon content leads to the production to a high-quality solid residue which can be used as activated carbon in wastewater treatment. Coconut shell can be easily collected in places where coconut meat is traditionally used in food processing.

Coconut Husk

Coconut husk has high amount of lignin and cellulose, and that is why it has a high calorific value of 18.62MJ/kg. The chemical composition of coconut husks consists of cellulose, lignin, pyroligneous acid, gas, charcoal, tar, tannin, and potassium. The predominant use of coconut husks is in direct combustion in order to make charcoal, otherwise husks are simply thrown away. Coconut husk can be transformed into a value-added fuel source which can replace wood and other traditional fuel sources. In terms of the availability and costs of coconut husks, they have good potential for use in power plants.

Overview of Biomass Logistics

Biomass logistics include all the unit operations necessary to move biomass feedstocks from the land to the biomass energy plant and to ensure that the delivered feedstock meets the specifications of the conversion process. The packaged biomass can be transported directly from farm or from stacks next to the farm to the processing plant.

Biomass may be minimally processed (i.e. ground) before being shipped to the plant, as in case of biomass supply from the stacks. Generally the biomass is trucked directly from farm to biorefinery if no processing is involved.

Another option is to transfer the biomass to a central location where the material is accumulated and subsequently dispatched to the energy conversion facility. While in depot, the biomass could be pre-processed minimally (ground) or extensively (pelletized). The depot also provides an opportunity to interface with rail transport if that is an available option.

The choice of any of the options depends on the economics and cultural practices. For example in irrigated areas, there is always space on the farm (corner of the land) where quantities of biomass can be stacked. The key components to reduce costs in harvesting, collecting and transportation of biomass can be summarized as:

  • Reduce the number of passes through the field by amalgamating collection operations.
  • Increase the bulk density of biomass
  • Work with minimal moisture content.
  • Granulation/pelletization is the best option, though the existing technology is expensive.
  • Trucking seems to be the most common mode of biomass transportation option but rail and pipeline may become attractive once the capital costs for these transport modes are reduced.

The logistics of transporting, handling and storing the bulky and variable biomass material for delivery to the bioenergy processing plant is a key part of the supply chain that is often overlooked by project developers. Whether the biomass comes from forest residues on hill country, straw residues from cereal crops grown on arable land, or the non-edible components of small scale, subsistence farming systems, the relative cost of collection will be considerable. Careful development of a system to minimize machinery use, human effort and energy inputs can have a considerable impact on the cost of the biomass as delivered to the processing plant gate.

The logistics of supplying a biomass power plant with sufficient volumes of biomass from a number of sources at suitable quality specifications and possibly all year round, are complex. Agricultural residues can be stored on the farm until needed. Then they can be collected and delivered directly to the conversion plant on demand. Infact, this requires considerable logistics to ensure only a few days of supply are available on-site but that the risk of non-supply at any time is low.

Biomass Resources from Rice Industry

The cultivation of rice results in two major types of residues – Straw and Husk –having attractive potential in terms of energy. Although the technology for rice husk utilization is well-proven in industrialized countries of Europe and North America, such technologies are yet to be introduced in the developing world on commercial scale. The importance of Rice Husk and Rice Straw as an attractive source of energy can be gauged from the following statistics:

Rice Straw

  • 1 ton of Rice paddy produces 290 kg Rice Straw
  • 290 kg Rice Straw can produce 100 kWh of power
  • Calorific value = 2400 kcal/kg

Rice Husk

  • 1 ton of Rice paddy produces 220 kg Rice Husk
  • 1 ton Rice Husk is equivalent to 410- 570 kWh electricity
  • Calorific value = 3000 kcal/kg
  • Moisture content = 5 – 12%

Rice husk is the most prolific agricultural residue in rice producing countries around the world. It is one of the major by-products from the rice milling process and constitutes about 20% of paddy by weight. Rice husk, which consists mainly of lingo-cellulose and silica, is not utilized to any significant extent and has great potential as an energy source.

Rice husk can be used for power generation through either the steam or gasification route. For small scale power generation, the gasification route has attracted more attention as a small steam power plant is very inefficient and is very difficult to maintain due to the presence of a boiler. In addition for rice mills with diesel engines, the gas produced from rice husk can be used in the existing engine in a dual fuel operation.

The benefits of using rice husk technology are numerous. Primarily, it provides electricity and serves as a way to dispose of agricultural waste. In addition, steam, a byproduct of power generation, can be used for paddy drying applications, thereby increasing local incomes and reducing the need to import fossil fuels. Rice husk ash, the byproduct of rice husk power plants, can be used in the cement and steel industries further decreasing the need to import these materials.

Rice straw can either be used alone or mixed with other biomass materials in direct combustion. In this technology, combustion boilers are used in combination with steam turbines to produce electricity and heat. The energy content of rice straw is around 14 MJ per kg at 10 percent moisture content.  The by-products are fly ash and bottom ash, which have an economic value and could be used in cement and/or brick manufacturing, construction of roads and embankments, etc.

Straw fuels have proved to be extremely difficult to burn in most combustion furnaces, especially those designed for power generation. The primary issue concerning the use of rice straw and other herbaceous biomass for power generation is fouling, slagging, and corrosion of the boiler due to alkaline and chlorine components in the ash. Europe, and in particular, Denmark, currently has the greatest experience with straw fired power and CHP plants.