Biogas Plants at Akshaya Patra Kitchens

The Akshaya Patra Foundation, a not-for-profit organization, is focused on addressing two of the most important challenges in India – hunger and education. Established in year 2000, the Foundation began its work by providing quality mid-day meals to 1500 children in 5 schools in Bangalore with the understanding that the meal would attract children to schools, after which it would be easier to retain them and focus on their holistic development. 14 years later, the Foundation has expanded its footprint to cover over 1.4 million children in 10 states and 24 locations across India.

Akshaya-Patra-Kitchen-BioGas

The Foundation has centralised, automated kitchens that can cook close to 6,000 kilos of rice, 4.5 to 5 tonnes of vegetables and 6,000 litres of sambar, in only 4 hours. In order to make sustainable use of organic waste generated in their kitchens, Akshaya Patra Foundation has set up anaerobic digestion plants to produce biogas which is then used as a cooking fuel. The primary equipment used in the biogas plant includes size reduction equipment, feed preparation tank for hydrolysis of waste stream, anaerobic digester, H2S scrubber and biogas holder.

Working Principle

Vegetable peels, rejects and cooked food waste are shredded and soaked with cooked rice water (also known as ganji) in a feed preparation tank for preparation of homogeneous slurry and fermentative intermediates. The hydrolyzed products are then utilized by the microbial culture, anaerobically in the next stage. This pre-digestion step enables faster and better digestion of organics, making our process highly efficient.

The hydrolyzed organic slurry is fed to the anaerobic digester, exclusively for the high rate biomethanation of organic substrates like food waste. The digester is equipped with slurry distribution mechanism for uniform distribution of slurry over the bacterial culture.

Optimum solids are retained in the digester to maintain the required food-to-microorganism ratio in the digester with the help of a unique baffle arrangement. Mechanical slurry mixing and gas mixing provisions are also included in the AD design to felicitate maximum degradation of organic material for efficient biogas production.

After trapping moisture and scrubbing off hydrogen sulphide from the biogas, it is collected in a gas-holder and a pressurized gas tank. This biogas is piped to the kitchen to be used as a cooking fuel, replacing LPG.

Basic Design Data and Performance Projections

Waste handling capacity 1 ton per day cooked and uncooked food waste with 1 ton per day ganji water

Input Parameters                      

Amount of solid organic waste 1000 Kg/day
Amount of organic wastewater ~ 1000 liters/day ganji (cooked rice water)

Biogas Production

Biogas production ~ 120 – 135 m3/day

Output Parameters

Equivalent LPG to replace 50 – 55 Kg/day (> 2.5 commercial LPG cylinders)
Fertilizer (digested leachate) ~ 1500 – 2000 liters/day

Major Benefits

Modern biogas installations are providing Akshaya Patra, an ideal platform for managing organic waste on a daily basis. The major benefits are:

  • Solid waste disposal at kitchen site avoiding waste management costs
  • Immediate waste processing overcomes problems of flies, mosquitos etc.
  • Avoiding instances when the municipality does not pick up waste, creating nuisance, smell, spillage etc.
  • Anaerobic digestion of Ganji water instead of directly treating it in ETP, therefore reducing organic load on the ETPs and also contributing to additional biogas production.

The decentralized model of biogas based waste-to-energy plants at Akshaya Patra kitchens ensure waste destruction at source and also reduce the cost incurred by municipalities on waste collection and disposal.

akshayapatra-kitchen

An on-site system, converting food and vegetable waste into green energy is improving our operations and profits by delivering the heat needed to replace cooking LPG while supplying a rich liquid fertilizer as a by-product.  Replacement of fossil fuel with LPG highlights our organization’s commitment towards sustainable development and environment protection.

The typical ROI of a plug and play system (without considering waste disposal costs, subsidies and tax benifts) is around three years.

Future Plans

Our future strategy for kitchen-based biogas plant revolves around two major points:

  • Utilization of surplus biogas – After consumption of biogas for cooking purposes, Akshaya Patra will consider utilizing surplus biogas for other thermal applications. Additional biogas may be used to heat water before boiler operations, thereby reducing our briquette consumption.
  • Digested slurry to be used as a fertilizer – the digested slurry from biogas plant is a good soil amendment for landscaping purposes and we plan to use it in order to reduce the consumption of water for irrigation as well as consumption of chemical fertilizers.

Trends in Utilization of Biogas

The valuable component of biogas is methane (CH4) which typically makes up 60%, with the balance being carbon dioxide (CO2) and small percentages of other gases. The proportion of methane depends on the feedstock and the efficiency of the process, with the range for methane content being 40% to 70%. Biogas is saturated and contains H2S, and the simplest use is in a boiler to produce hot water or steam.

DaishThe gas can also be upgraded and used in gas supply networks. The use of biogas in solid oxide fuel cells is also being researched.

Biogas can be combusted directly to produce heat. In this case, there is no need to scrub the hydrogen sulphide in the biogas. Usually the process utilize dual-fuel burner and the conversion efficiency is 80 to 90%. The main components of the system are anaerobic digester, biogas holder, pressure switch, booster fan, solenoid valve, dual fuel burner and combustion air blower.

The most common method for utilization of biogas in developing countries is for cooking and lighting. Conventional gas burners and gas lamps can easily be adjusted to biogas by changing the air to gas ratio. In more industrialized countries boilers are present only in a small number of plants where biogas is used as fuel only without additional CHP. In a number of industrial applications biogas is used for steam production.

Burning biogas in a boiler is an established and reliable technology. Low demands are set on the biogas quality for this application. Pressure usually has to be around 8 to 25 mbar. Furthermore it is recommended to reduce the level of hydrogen sulphide to below 1 000 ppm, this allows to maintain the dew point around 150 °C.

CHP Applications

Biogas is the ideal fuel for generation of electric power or combined heat and power. A number of different technologies are available and applied. The most common technology for power generation is internal combustion. Engines are available in sizes from a few kilowatts up to several megawatts. Gas engines can either be SI-engines (spark ignition) or dual fuel engines. Dual fuel engines with injection of diesel (10% and up) or sometimes plant oil are very popular in smaller scales because they have good electric efficiencies up to guaranteed 43%.

The biogas pressure is turbo-charged and after-cooled and has a high compression ratio in the gas engines. The cooling tower provides cooling water for the gas engines. The main component of the system required for utilizing the technology are anaerobic digester, moisture remover, flame arrester, waste gas burner, scrubber, compressor, storage, receiver, regulator, pressure switch and switch board.

Gas turbines are an established technology in sizes above 500 kW. In recent years also small scale engines, so called micro-turbines in the range of 25 to 100kW have been successfully introduced in biogas applications. They have efficiencies comparable to small SI-engines with low emissions and allow recovery of low pressure steam which is interesting for industrial applications. Micro turbines are small, high-speed, integrated power plants that include a turbine, compressor, generator and power electronics to produce power.

New Trends

The benefit of the anaerobic treatment will depend on the improvement of the process regarding a higher biogas yield per m3 of biomass and an increase in the degree of degradation. Furthermore, the benefit of the process can be multiplied by the conversion of the effluent from the process into a valuable product.

In order to improve the economical benefit of biogas production, the future trend will go to integrated concepts of different conversion processes, where biogas production will still be a significant part. In a so-called biorefinery concept, close to 100% of the biomass is converted into energy or valuable by-products, making the whole concept more economically profitable and increasing the value in terms of sustainability.

Typical layout of a modern biogas facility

One example of such biorefinery concept is the Danish Bioethanol Concept that combines the production of bioethanol from lignocellulosic biomass with biogas production of the residue stream. Another example is the combination of biogas production from manure with manure separation into a liquid and a solid fraction for separation of nutrients. One of the most promising concepts is the treatment of the liquid fraction on the farm-site in a UASB reactor while the solid fraction is transported to the centralized biogas plant where wet-oxidation can be implemented to increase the biogas yield of the fiber fraction. Integration of the wet oxidation pre-treatment of the solid fraction leads to a high degradation efficiency of the lignocellulosic solid fraction.

Biological Desulphurization of Biogas

The most valuable component of biogas is methane (CH4) which typically makes up 60%, with the balance being carbon dioxide (CO2) and small percentages of other gases. However, biogas also contain significant amount of hydrogen sulfide (H2S) gas which needs to be stripped off due to its highly corrosive nature. Hydrogen sulfide is oxidized into sulfur dioxide which dissolves as sulfuric acid. Sulphuric acid, even in trace amounts, can make a solution extremely acidic. Extremely acidic electrolytes dissolve metals rapidly and speed up the corrosion process.

The corrosive nature of H2S has the potential to destroy expensive biogas processing equipment. Even if there is no oxygen present, biogas can corrode metal. Hydrogen sulphide can become its own electrolyte and absorb directly onto the metal to form corrosion. If the hydrogen sulphide concentration is very low, the corrosion will be slow but will still occur due to the presence of carbon dioxide.

Biogas_Cleanup-H2S

The obvious solution is the use of a biogas cleanup process whereby contaminants in the raw biogas stream are absorbed or scrubbed. Desulphurization of biogas can be performed by biological as well as chemical methods. Biological treatment of hydrogen sulphide typically involves passing the biogas through biologically active media. These treatments may include open bed soil filters, biofilters, fixed film bioscrubbers, suspended growth bioscrubbers and fluidized bed bioreactors.

Biological Desulphurization

The simplest method of desulphurization is the addition of oxygen or air directly into the digester or in a storage tank serving at the same time as gas holder. Thiobacilli are ubiquitous and thus systems do not require inoculation. They grow on the surface of the digestate, which offers the necessary micro-aerophilic surface and at the same time the necessary nutrients. They form yellow clusters of sulphur. Depending on the temperature, the reaction time, the amount and place of the air added the hydrogen sulphide concentration can be reduced by 95 % to less than 50 ppm.

Most of the sulphide oxidising micro-organisms belong to the family of Thiobacillus. For the microbiological oxidation of sulphide it is essential to add stoichiometric amounts of oxygen to the biogas. Depending on the concentration of hydrogen sulphide this corresponds to 2 to 6 % air in biogas. Measures of safety have to be taken to avoid overdosing of air in case of pump failures.

Biofiltration

Biofiltration is one of the most promising clean technologies for reducing emissions of malodorous gases and other pollutants into the atmosphere. In a biofiltration system, the gas stream is passed through a packed bed on which pollutant-degrading microbes are immobilized as biofilm. A biological filter combines water scrubbing and biological desulfurization.

Biogas and the separated digestate meet in a counter-current flow in a filter bed. The biogas is mixed with 4% to 6% air before entry into the filter bed. The filter media offer the required surface area for scrubbing, as well as for the attachment of the desulphurizing microorganisms. Microorganisms in the biofilm convert the absorbed H2S into elemental sulphur by metabolic activity. Oxygen is the key parameter that controls the level of oxidation.

The capital costs for biological treatment of biogas are moderate and operational costs are low. This technology is widely available worldwide. However, it may be noted that the biological system is capable to remove even very high amounts of hydrogen sulphide from the biogas but its adaptability to fluctuating hydrogen sulphide contents is not yet proven.

Biogas and Rural Development

Anaerobic digestion has proven to be a beneficial technology in various spheres for rural development. Biogas produced is a green replacement of unprocessed fuels (like fuel wood, dung cakes, crop residues). It is a cost effective replacement for dung cakes and conventional domestic fuels like LPG or kerosene. Biogas technology has the potential to meet the energy requirements in rural areas, and also counter the effects of reckless burning of biomass resources.

Biogas has the potential to rejuvenate India’s agricultural sector

An additional benefit is that the quantity of digested slurry is the same as that of the feedstock fed in a biogas plant. This slurry can be dried and sold as high quality compost. The nitrogen-rich compost indirectly reduces the costs associated with use of fertilizers. It enriches the soil, improves its porosity, buffering capacity and ion exchange capacity and prevents nutrient depletion thus improving the crop quality. This means increased income for the farmer.

Further, being relatively-clean cooking fuel; biogas reduces the health risks associated with conventional chulhas. Thinking regionally, decreased residue burning brings down the seasonal high pollutant levels in air, ensuring a better environmental quality. Anaerobic digestion thus proves to be more efficient in utilization of crop residues. The social benefits associated with biomethanation, along with its capacity to generate income for the rural households make it a viable alternative for conventional methods.

The Way Forward

The federal and stage governments needs to be more proactive in providing easy access to these technologies to the poor farmers. The policies and support of the government are decisive in persuading the farmers to adopt such technologies and to make a transition from wasteful traditional approaches to efficient resource utilization. The farmers are largely unaware of the possible ways in which farm and cattle wastes could be efficiently utilised. The government agencies and NGOs are major stakeholders in creating awareness in this respect.

Moreover, many farmers find it difficult to bear the construction and operational costs of setting up the digester. This again requires the government to introduce incentives (like soft loans) and subsidies to enhance the approachability of the technology and thus increase its market diffusion.

Feedstock for AD Plants

Anaerobic digestion is the natural biological process which stabilizes organic waste in the absence of air and transforms it into biofertilizer and biogas. Almost any organic material can be processed with anaerobic digestion.

Biogas_Plant

Anaerobic digestion is particularly suited to wet organic material and is commonly used for effluent and sewage treatment.  This includes biodegradable waste materials such as waste paper, grass clippings, leftover food, sewage and animal waste. Large quantity of waste, in both solid and liquid forms, is generated by the industrial sector like breweries, sugar mills, distilleries, food-processing industries, tanneries, and paper and pulp industries. Poultry waste has the highest per ton energy potential of electricity per ton but livestock have the greatest potential for energy generation in the agricultural sector.

Agricultural Feedstock

Community-Based Feedstock

  • Organic fraction of MSW (OFMSW)
  • MSW
  • Sewage sludge
  • Grass clippings/garden waste
  • Food wastes
  • Institutional wastes etc.

 Industrial Feedstock

  • Food/beverage processing
  • Dairy
  • Starch industry
  • Sugar industry
  • Pharmaceutical industry
  • Cosmetic industry
  • Biochemical industry
  • Pulp and paper
  • Slaughterhouse/rendering plant etc.

Anaerobic digestion is particularly suited to wet organic material and is commonly used for effluent and sewage treatment. Almost any organic material can be processed with anaerobic digestion process. This includes biodegradable waste materials such as waste paper, grass clippings, leftover food, sewage and animal waste. The exception to this is woody wastes that are largely unaffected by digestion as most anaerobic microorganisms are unable to degrade lignin.

Anaerobic digesters can also be fed with specially grown energy crops such as silage for dedicated biogas production. A wide range of crops, especially C-4 plants, demonstrate good biogas potentials. Corn is one of the most popular co-substrate in Germany while Sudan grass is grown as an energy crop for co-digestion in Austria. Crops like maize, sunflower, grass, beets etc., are finding increasing use in agricultural digesters as co-substrates as well as single substrate.

A wide range of organic substances are anaerobically easily degradable without major pretreatment. Among these are leachates, slops, sludges, oils, fats or whey. Some wastes can form inhibiting metabolites (e.g.NH3) during anaerobic digestion which require higher dilutions with substrates like manure or sewage sludge. A number of other waste materials often require pre-treatment steps (e.g. source separated municipal organic waste, food residuals, expired food, market wastes and crop residues).

Food Waste Management in USA

food_wasteFood waste is an untapped energy source that mostly ends up rotting in landfills, thereby releasing greenhouse gases into the atmosphere. Food waste is difficult to treat or recycle since it contains high levels of sodium salt and moisture, and is mixed with other waste during collection. Major generators of food wastes include hotels, restaurants, supermarkets, residential blocks, cafeterias, airline caterers, food processing industries, etc.

In United States, food waste is the third largest waste stream after paper and yard waste. Around 13 percent of the total municipal solid waste generated in the country is contributed by food scraps. According to USEPA, more than 35 million tons of food waste are thrown away into landfills or incinerators each year, which is around 40 percent of all food consumed in the country. As far as United Kingdom is concerned, households throw away around 8 million tons of food each year. These statistics are an indication of tremendous amount of food waste generated all over the world.

Food Waste Management Strategy

The proportion of food waste in municipal waste stream is gradually increasing and hence a proper food waste management strategy needs to be devised to ensure its eco-friendly and sustainable disposal. The two most common methods for food waste recycling are:

  • Composting: A treatment that breaks down biodegradable waste by naturally occurring micro-organisms with oxygen, in an enclosed vessel or tunnel;
  • Anaerobic digestion (AD): A treatment that breaks down biodegradable waste in the absence of oxygen, producing a renewable energy (biogas) that can be used to generate electricity and heat.

Currently, only about 3 percent of food waste is recycled throughout U.S., mainly through composting. Composting provides an alternative to landfill disposal of food waste, however it requires large areas of land, produces volatile organic compounds and consumes energy. Consequently, there is an urgent need to explore better recycling alternatives.

Anaerobic digestion has been successfully used in several European and Asian countries to stabilize food wastes, and to provide beneficial end-products. Sweden, Austria, Denmark, Germany and England have led the way in developing new advanced biogas technologies and setting up new projects for conversion of food waste into energy.

Of the different types of organic wastes available, food waste holds the highest potential in terms of economic exploitation as it contains high amount of carbon and can be efficiently converted into biogas and organic fertilizer. Food waste can either be used as a single substrate in a biogas plant, or can be co-digested with organic wastes like cow manure, poultry litter, sewage, crop residues, abattoir wastes, etc.

Food waste is one of the single largest constituent of municipal solid waste stream.  Diversion of food waste from landfills can provide significant contribution towards climate change mitigation, apart from generating revenues and creating employment opportunities. Rising energy prices and increasing environmental pollution makes it more important to harness renewable energy from food wastes. Anaerobic digestion technology is widely available worldwide and successful projects are already in place in several European as well as Asian countries which makes it imperative on waste generators and environmental agencies in USA to strive for a sustainable food waste management system.

Ultrasonic Pretreatment in Anaerobic Digestion of Sewage Sludge

Anaerobic digestion process comprises of four major steps – hydrolysis, acidogenesis, acetogenesis and methanogenesis. The biological hydrolysis is the rate limiting step and pretreatment of sludge by chemical, mechanical or thermal disintegration can improve the anaerobic digestion process. Ultrasonic disintegration is a method for breakup of microbial cells to extract intracellular material.

Ultrasound activated sludge disintegration could positively affect anaerobic digestion of sewage sludge. Due to sludge disintegration, organic compounds are transferred from the sludge solids into the aqueous phase resulting in an enhanced biodegradability. Therefore disintegration of sewage sludge is a promising method to enhance anaerobic digestion rates and lead to reduce the volume of sludge digesters.

The addition of disintegrated surplus activated sludge and/or foam to the process of sludge anaerobic digestion can lead to markedly better effects of sludge handling at wastewater treatment plants. In the case of disintegrated activated sludge and/or foam addition to the process of anaerobic digestion it is possible to achieve an even twice a higher production of biogas. Here are few examples:

STP Bad Bramstedt, Germany (4.49 MGD)

  • First fundamental study on pilot scale by Technical University of Hamburg-Harburg, 3 years, 1997 – 1999
  • reduction in digestion time from 20 to 4 days without losses in degradation efficiency
  • increase in biogas production by a factor of 4
  • reduction of digested sludge mass of 25%

STP Ahrensburg, Germany (2.64 MGD)

  • Preliminary test on pilot-scale by Technical University of Hamburg-Harburg, 6 months, 1999
  • increase in VS destruction of 20%
  • increase in biogas production of 20%

STP Bamberg, Germany (12.15 MGD)

  • Preliminary full-scale test, 4 months, 2002 2) Full-scale installation since June 2004
  • increase in VS destruction of 30%
  • increase in biogas production of 30%
  • avoided the construction of a new anaerobic digester

STP Freising, Germany (6.87 MGD)

  • Fundamental full-scale study by University of Armed Forces, Munich, 4 months, 2003
  • increase in biogas production of 15%
  • improved sludge dewatering of 10%

STP Meldorf, Germany (1.06 MGD)

  • Preliminary full-scale test, 3 months, 2004 2) Full-scale installation since December 2004
  • increase in VS destruction of 25%
  • increase in biogas production of 25%
  • no foam or filamentous organisms present in the anaerobic sludge digester

STP Ergolz 2, Switzerland (3.43 MGD)

  • Full-scale test, 3 months, 2004
  • increase in VS destruction of 15%
  • increase in biogas production of 25%

STP Beverungen, Germany (2.64 MGD)

  • Full-scale test, 3 months, 2004/2005
  • increase in VS destruction of 25%
  • increase in biogas production of 25%

To sum up, ultrasonication has a positive effect on sludge solubilisation, sludge volume, biogas production, flock size reduction and cells lyses. Ultrasonic pretreatment enhances the subsequent anaerobic digestion resulting in a better degradation of volatile solids and an increased production of biogas.

The use of low power ultrasound in bioreactors may present a significant improvement in cost reduction. Therefore, ultrasonic pretreatment enhances the subsequent anaerobic digestion resulting in a better sludge digestion and efficient recovery of valuables.

Anaerobic Digestion of Tannery Wastes

The conventional leather tanning technology is highly polluting as it produces large amounts of organic and chemical pollutants. Wastes generated by tanneries pose a major challenge to the environment. Anaerobic digestion of tannery wastes is an attractive method to recover energy from tannery wastes.

According to conservative estimates, more than 600,000 tons per year of solid waste are generated worldwide by leather industry and approximately 40–50% of the hides are lost to shavings and trimmings. Everyday a huge quantity of solid waste, including trimmings of finished leather, shaving dusts, hair, fleshing, trimming of raw hides and skins, are being produced from the industries. Chromium, sulphur, oils and noxious gas (methane, ammonia, and hydrogen sulphide) are the elements of liquid, gas and solid waste of tannery industries.

Biogas from Tannery Wastes

Anaerobic digestion (or biomethanation) systems are mature and proven processes that have the potential to convert tannery wastes into energy efficiently, and achieve the goals of pollution prevention/reduction, elimination of uncontrolled methane emissions and odour, recovery of biomass energy potential as biogas, production of stabilized residue for use as low grade fertilizer.

Anaerobic digestion of tannery wastes is an attractive method to recover energy from tannery wastes. This method degrades a substantial part of the organic matter contained in the sludge and tannery solid wastes, generating valuable biogas, contributing to alleviate the environmental problem, giving time to set-up more sustainable treatment and disposal routes. Digested solid waste is biologically stabilized and can be reused in agriculture.

Until now, biogas generation from tannery wastewater was considered that the complexity of the waste water stream originating from tanneries in combination with the presence of chroming would result in the poisoning of the process in a high loaded anaerobic reactor.

When the locally available industrial wastewater treatment plant is not provided by anaerobic digester, a large scale digestion can be planned in regions accommodating a big cluster of tanneries, if there is enough waste to make the facility economically attractive.

In this circumstance, an anaerobic co-digestion plant based on sludge and tanneries may be a recommendable option, which reduces the quantity of landfilled waste and recovers its energy potential. It can also incorporate any other domestic, industrial or agricultural wastes. Chrome-free digested tannery sludge also has a definite value as a fertilizer based on its nutrient content.

Potential Applications of Biogas

Biogas produced in anaerobic digesters consists of methane (50%–80%), carbon dioxide (20%–50%), and trace levels of other gases such as hydrogen, carbon monoxide, nitrogen, oxygen, and hydrogen sulfide.  Biogas can be used for producing electricity and heat, as a natural gas substitute and also a transportation fuel. A combined heat and power plant (CHP) not only generates power but also produces heat for in-house requirements to maintain desired temperature level in the digester during cold season.

CHP systems cover a range of technologies but indicative energy outputs per m3 of biogas are approximately 1.7 kWh electricity and 2.5kWh heat. The combined production of electricity and heat is highly desirable because it displaces non-renewable energy demand elsewhere and therefore reduces the amount of carbon dioxide released into the atmosphere.

AD Plant at ECCO’s Tannery (Netherlands)

A highly advanced wastewater treatment plant and biogas system became fully operational in 2012 at ECCO’s tannery in the Netherlands. A large percentage of the waste is piped directly into the wastewater plant to be converted into biogas. This biogas digester provides a source of renewable fuel and also helps to dispose of waste materials by converting waste from both the leather-making processes, and the wastewater treatment plant, into biogas. All excess organic material from the hides is also converted into biogas.

This project enables ECCO Tannery to reduce waste and to substitute virtually all of its consumption of non-renewable natural gas with renewable biogas. The aim is to use more than 40% of the total tannery waste and replace up to 60% of the total natural gas consumption with biogas.

Methods for Hydrogen Sulphide Removal from Biogas

The major contaminant in biogas is H2S which is both poisonous and corrosive, and causes significant damage to piping, equipment and instrumentation. The concentration of various components of biogas has an impact on its ultimate end use. While boilers can withstand concentrations of H2S up to 1000 ppm, and relatively low pressures, internal combustion engines operate best when H2S is maintained below 100 ppm. The commonly used methods for hydrogen sulphide removal from biogas are internal to the anaerobic digestion process – air/oxygen dosing to digester biogas and iron chloride dosing to digester slurry.

Biological Desulphurization

Biological desulphurization of biogas can be performed by using micro-organisms. Most of the sulphide oxidising micro-organisms belong to the family of Thiobacillus. For the microbiological oxidation of sulphide it is essential to add stoichiometric amounts of oxygen to the biogas. Depending on the concentration of hydrogen sulphide this corresponds to 2 to 6 % air in biogas.

The simplest method of desulphurization is the addition of oxygen or air directly into the digester or in a storage tank serving at the same time as gas holder. Thiobacilli are ubiquitous and thus systems do not require inoculation. They grow on the surface of the digestate, which offers the necessary micro-aerophilic surface and at the same time the necessary nutrients. They form yellow clusters of sulphur. Depending on the temperature, the reaction time, the amount and place of the air added the hydrogen sulphide concentration can be reduced by 95 % to less than 50 ppm.

Measures of safety have to be taken to avoid overdosing of air in case of pump failures. Biogas in air is explosive in the range of 6 to 12 %, depending on the methane content). In steel digesters without rust protection there is a small risk of corrosion at the gas/liquid interface.

Iron Chloride Dosing

Iron chloride can be fed directly to the digester slurry or to the feed substrate in a pre-storage tank. Iron chloride then reacts with produced hydrogen sulphide and form iron sulphide salt (particles). This method is extremely effective in reducing high hydrogen sulphide levels but less effective in attaining a low and stable level of hydrogen sulphide in the range of vehicle fuel demands.

In this respect the method with iron chloride dosing to digester slurry can only be regarded as a partial removal process in order to avoid corrosion in the rest of the upgrading process equipment. The method need to be complemented with a final removal down to about 10 ppm.

The investment cost for such a removal process is limited since the only investment needed is a storage tank for iron chloride solution and a dosing pump. On the other hand the operational cost will be high due to the prime cost for iron chloride.

Biogas Upgradation Methods

Upgradation of biogas is primarily achieved by carbon dioxide removal which then enhances the energy value of the gas to give longer, driving distances with a fixed gas storage volume. Removal of carbon dioxide also provides a consistent gas quality with respect to energy value. The latter is regarded to be of great importance from the vehicle manufacturers in order to reach low emissions of nitrogen oxide.

biogas-enrichment

At present four different biogas upgradation methods are generally used for removal of carbon dioxide from biogas, either to reach vehicle fuel standard or to reach natural gas quality for injection to the natural gas grid. These methods are:

  • Water absorption
  • Polyethylene glycol absorption
  • Carbon molecular sieves
  • Membrane separation

Water Scrubbing

Water scrubbing is used to remove carbon dioxide but also hydrogen sulphide from biogas since these gases is more soluble in water than methane. The absorption process is purely physical. Usually the biogas is pressurized and fed to the bottom of a packed column where water is fed on the top and so the absorption process is operated counter-currently.

Polyethylene Glycol Scrubbing

Polyethylene glycol scrubbing is a physical absorption process. Selexol is one of the trade names used for a solvent. In this solvent, like in water, both carbon dioxide and hydrogen sulphide are more soluble than methane.

The big difference between water and Selexol is that carbon dioxide and hydrogen sulphide are more soluble in Selexol which results in a lower solvent demand and reduced pumping. In addition, water and halogenated hydrocarbons (contaminants in biogas from landfills) are removed when scrubbing biogas with Selexol.

Carbon Molecular Sieves

Molecular sieves are excellent products to separate specifically a number of different gaseous compounds in biogas. Thereby the molecules are usually loosely adsorbed in the cavities of the carbon sieve but not irreversibly bound. The selectivity of adsorption is achieved by different mesh sizes and/or application of different gas pressures.

When the pressure is released the compounds extracted from the biogas are desorbed. The process is therefore often called “pressure swing adsorption” (PSA). To enrich methane from biogas the molecular sieve is applied which is produced from coke rich in pores in the micrometer range. The pores are then further reduced by cracking of the hydrocarbons. In order to reduce the energy consumption for gas compression, a series of vessels are linked together.

Pressure swing adsoprtion process for biogas upgradation

The gas pressure released from one vessel is subsequently used by the others. Usually four vessels in a row are used filled with molecular sieve which removes at the same time CO2 and water vapour.

Membrane Purification

There are two basic systems of biogas purification with membranes: a high pressure gas separation with gas phases on both sides of the membrane, and a low-pressure gas liquid absorption separation where a liquid absorbs the molecules diffusing through the membrane.

  • High pressure gas separation

Pressurized gas (36 bar) is first cleaned over for example an activated carbon bed to remove (halogenated) hydrocarbons and hydrogen sulphide from the raw gas as well as oil vapour from the compressors. The carbon bed is followed by a particle filter and a heater. The raw gas is upgraded in 3 stages to a clean gas with 96 % methane or more.

The waste gas from the first two stages is recycled and the methane can be recovered. The waste gas from stage 3 (and in part of stage 2) is flared or used in a steam boiler as it still contains 10 to 20 % methane.

  • Gas-liquid absorption membranes

Gas-liquid absorption using membranes is a separation technique which was developed for biogas upgrading in the recent past. The essential element is a micro-porous hydrophobic membrane separating the gaseous from the liquid phase. The molecules from the gas stream, flowing in one direction, which are able to diffuse through the membrane will be absorbed on the other side by the liquid flowing in counter current.

The absorption membranes work at approx. atmospheric pressure (1 bar) which allows low-cost construction. The removal of gaseous components is very efficient. At a temperature of 25 to 35°C the H2S concentration in the raw gas of 2 % is reduced to less than 250 ppm.