Biorefinery Prospects in India

India has a tremendous biomass potential which could easily be relied upon to fulfil most of our energy needs. An estimated 50 MMT (million metric tonnes) of liquid fuels are consumed annually in India, but with the actual biomass potential and its full utilization, India is capable of generating almost double that amount per annum. These biomass estimates only constitute the crop residues available in the country and essentially the second-generation fuels since the use of first-generation crop bases fuels in such food-starved nations is a criminal thought.

Existing Technologies

Currently, there are various technologies available to process such crop residues and generate value products from them. However, essentially, they all revolve around two main kinds of processes, either biochemical or thermal.

The biochemical process involves application of aerobic/anaerobic digestion for the production of biogas; or fermentation, which results in the generation of ethanol. Both these products could be subsequently treated chemically and through trans-esterification process, leading to production of biodiesel.

Alternatively, the thermochemical processes involve either the combustion, gasification or pyrolysis techniques, which produces heat, energy-rich gas and liquid fuels respectively. These products can be used as such, or could be further processed to generate high quality biofuels or chemicals.

The Need

The estimated organized energy breakup for India is 40 percent each for domestic and transport sectors and 20 percent for the industrial sectors. The current share of crude oil and gases is nearly 90 percent for the primary and transport sectors and the remaining 10 percent for the generation of industrial chemicals. The escalating prices of crude oil in the international market and the resulting concern over energy security, has lead developing nations to explore alternative and cheap sources of energy to meet the growing energy demand. One of the promising solution for agrarian economies is Biorefinery.

The Concept

Biorefinery is analogous to the traditional petroleum refineries employing fractional distillation process for obtaining different fractions or components from the same raw material, i.e. the crude oil. Biorefinery involve the integration of different biomass treatment and processing methods into one system, which results in the production of different components from the same biomass.  This makes the entire chain more viable economically and also reduces the waste generated.

Typical Model of a Biorefinery

The outcome ranges from high-volume, low-energy content liquid fuels, which could serve the transportation industry needs, to the low-volume but high-value chemicals, which could add to the feasibility of such a project. Steam and heat generated in the process could be utilized for meeting process heat requirements. By-products like chemicals, fertilizers, pharmaceuticals, polymers etc are also obtained which provide additional revenue streams.

Benefits

Biorefineries can help in utilizing the optimum energy potential of organic wastes and may also resolve the problems of waste management and GHGs emissions. Wastes can be converted, through appropriate enzymatic/chemical treatment, into either gaseous or liquid fuels. The pre-treatment processes involved in biorefining generate products like paper-pulp, HFCS, solvents, acetate, resins, laminates, adhesives, flavour chemicals, activated carbon, fuel enhancers, undigested sugars etc. which generally remain untapped in the traditional processes. The suitability of this process is further enhanced from the fact that it can utilize a variety of biomass resources, whether plant-derived or animal-derived.

Applicability

The concept of biorefinery is still in early stages at most places in the world. Problems like raw material availability, feasibility in product supply chain, scalability of the model are hampering its development at commercial-scales. The National Renewable Energy Laboratory (NREL) of USA is leading the front in biorefinery research with path-breaking discoveries and inventions. Although the technology is still in nascent stages, but it holds the key to the optimum utilization of wastes and natural resources that humans have always tried to achieve. The onus now lies on governments and corporate to incentivize or finance the research and development in this field.

Prospects of Algae Biofuels in Middle East

Algae biofuels have the potential to become a renewable, cost-effective alternative for fossil fuels with reduced impact on the environment. Algae hold tremendous potential to provide a non-food, high-yield, non-arable land use source of renewable fuels like biodiesel, bioethanol, hydrogen etc. Microalgae are considered as a potential oleo-feedstock, as they produce lipids through photosynthesis, i.e. using only CO2, water, sunlight, phosphates, nitrates and other (oligo) elements that can be found in residual waters.

Algae also produce proteins, isoprenoids and polysaccharides. Some strains of algae ferment sugars to produce alcohols, under the right growing conditions. Their biomass can be processed to different sorts of chemicals and polymers (Polysaccharides, enzymes, pigments and minerals), biofuels (e.g. biodiesel, alkanes and alcohols), food and animal feed (PUFA, vitamins, etc.) as well as bioactive compounds (antibiotics, antioxidant and metabolites) through down-processing technology such as transesterification, pyrolysis and continuous catalysis using microspheres.

Microalgae are the fastest growing photosynthesizing organism capable of completing an entire growing cycle every few days. Up to 50% of algae’s weight is comprised of oil, compared with, for example, oil palm which yields just about 20% of its weight in oil. Algae can be grown on non-arable land (including deserts), most of them do not require fresh water, and their nutritional value is high. Extensive R&D efforts are underway worldwide, especially in North America and Europe, with a high number of start-up companies developing different options for commercializing algae farming.

Prospects of Algae Biofuels in the Middle East

The demand for fossil fuels is growing continuously all around the world and the Middle East is not an exception. The domestic consumption of energy in the Middle East is increasing at an astonishing rate, e.g. Saudi Arabia’s consumption of oil and gas rose by about 5.9 percent over the past five years while electricity demand is witnessing annual growth rate of 8 percent. Although Middle Eastern countries are world’s leading producers of fossil fuels, several cleantech initiatives have been launched in last few years which shows the commitment of regional countries in exploiting renewable sources of energy.

Algae biofuels is an attractive proposition for Middle East countries to offset the environmental impact of the oil and gas industry. The region is highly suitable for mass production of algae because of the following reasons:

  • Presence of large tracts of non-arable lands and extensive coastline.
  • Presence of numerous oil refineries and power plants (as points of CO2 capture) and desalination plants (for salt reuse).
  • Extremely favorable climatic conditions (highest annual solar irradiance).
  • Presence of a large number of sewage and wastewater treatment plants.
  • Existence of highly lipid productive microalgae species in coastal waters.

These factors makes it imperative on Middle East nations to develop a robust Research, Development and Market Deployment plan for a comprehensive microalgal biomass-based biorefinery approach for bio-product synthesis. An integrated and gradual appreciation of technical, economic, social and environmental issues should be considered for a successful implementation of the microalgae-based oleo-feedstock (MBOFs) industry in the region.

How the Biofuel Industry is Growing in the US

drop-in-biofuelsBiofuels were once forgotten in the United States, mainly when huge petroleum deposits kept fuel prices low.  With the increase in oil prices recently, the biofuel industry in the US is rising significantly.  Experts predict that this green energy efficient industry will continue to grow within the next 7 to 10 years.

The Source of Biofuels

Those who are concerned with the prospect of global warming love the potential use of biofuels. Produced either directly or indirectly from animal waste and plant materials, biofuels are less costly than other types of fuel.  Already in the national and global market, the trend for this fuel is rising.

Online Reverse Auction Software

Due to the growth of the biofuel industry, online software for energy brokers and energy suppliers is an available market for entrepreneurs.  The software to efficiently sell energy services to purchasers is a must have for suppliers and brokers.  The reverse auction process effectively conducts online business for those in the biofuel industry.

Both regulated and deregulated gas and electricity markets are involved in the reverse auction process in which the buyer and seller roles are reversed.  The buyer is given the option of testing and evaluating multiple pricing parameters to find a good fit.  Commercial, industrial, and manufacturing facilities take advantage of this platform.

Reverse Auction Benefits

Reverse auctions in the biofuel industry have been said to cut costs tremendously.  Although the seller pays a fee to the service provider, the bidding process cuts costs all around for both buyer and seller.  A situation in which both sides win is seen as a huge benefit by all involved.

As a very lucrative market, the biofuel industry benefits from reverse auctions.  Market efficiency is increased, and the process of obtaining the goods and services is enhanced.  Proper software and other technical aspects of the process is essential thus the reason that the online reverse auction software market is critical.  Quality and professional relationships are enhanced rather than compromised as is often the case in other markets.

Biofuel Market Projections and Uses

According to market research, the biofuel industry is expected to reach approximately 218 billion dollars by 2022.  A 4.5% growth is expected by 2022 as well.  Investors see these projections as an open door of opportunity.  By the year 2025, the increase is predicted to be at approximately 240 billion dollars.

Biofuel is used for other purposes besides first-generation fuel.  It is used in vegetable oil and cosmetics, and it is used to treat Vitamin A deficiency and other health issues. Biofuel is predicted to aid the improvement of economic conditions due to its health benefits and appeal to green energy supporters.  These factors explain the reasons for the projected growth and profit for this industry.

With the continued growth of the biofuel industry, reverse auctions will be a much-needed process.  The efficient software to accompany reverse auctions will keep the market flowing which will further aid the growth of the industry for years to come.

Overview of Biomass Pyrolysis

Biomass pyrolysis is the thermal decomposition of biomass occurring in the absence of oxygen. It is the fundamental chemical reaction that is the precursor of both the combustion and gasification processes and occurs naturally in the first two seconds. The products of biomass pyrolysis include biochar, bio-oil and gases including methane, hydrogen, carbon monoxide, and carbon dioxide.

The pyrolysis process consists of both simultaneous and successive reactions when organic material is heated in a non-reactive atmosphere. Thermal decomposition of organic components in biomass starts at 350 °C–550 °C and goes up to 700 °C–800 °C in the absence of air/oxygen. The long chains of carbon, hydrogen and oxygen compounds in biomass break down into smaller molecules in the form of gases, condensable vapours (tars and oils) and solid charcoal under pyrolysis conditions. Rate and extent of decomposition of each of these components depends on the process parameters of the reactor temperature, biomass heating rate, pressure, reactor configuration, feedstock etc

Depending on the thermal environment and the final temperature, pyrolysis will yield mainly biochar at low temperatures, less than 450 0C, when the heating rate is quite slow, and mainly gases at high temperatures, greater than 800 0C, with rapid heating rates. At an intermediate temperature and under relatively high heating rates, the main product is bio-oil.

Slow and Fast Pyrolysis

Pyrolysis processes can be categorized as slow or fast. Slow pyrolysis takes several hours to complete and results in biochar as the main product. On the other hand, fast pyrolysis yields 60% bio-oil and takes seconds for complete pyrolysis. In addition, it gives 20% biochar and 20% syngas.  Fast pyrolysis is currently the most widely used pyrolysis system.

The essential features of a fast pyrolysis process are:

  • Very high heating and heat transfer rates, which require a finely ground feed.
  • Carefully controlled reaction temperature of around 500oC in the vapour phase
  •  Residence time of pyrolysis vapours in the reactor less than 1 sec
  • Quenching (rapid cooling) of the pyrolysis vapours to give the bio-oil product.

Advantages of Biomass Pyrolysis

Pyrolysis can be performed at relatively small scale and at remote locations which enhance energy density of the biomass resource and reduce transport and handling costs.  Heat transfer is a critical area in pyrolysis as the pyrolysis process is endothermic and sufficient heat transfer surface has to be provided to meet process heat needs. Biomass pyrolysis offers a flexible and attractive way of converting organic matter into energy products which can be successfully used for the production of heat, power and chemicals.

A wide range of biomass feedstocks can be used in pyrolysis processes. The pyrolysis process is very dependent on the moisture content of the feedstock, which should be around 10%. At higher moisture contents, high levels of water are produced and at lower levels there is a risk that the process only produces dust instead of oil. High-moisture waste streams, such as sludge and meat processing wastes, require drying before subjecting to pyrolysis.

Furthermore, the bio-char produced can be used on the farm as an excellent soil amender as it is highly absorbent and therefore increases the soil’s ability to retain water, nutrients and agricultural chemicals, preventing water contamination and soil erosion. Soil application of bio-char may enhance both soil quality and be an effective means of sequestering large amounts of carbon, thereby helping to mitigate global climate change through carbon sequestration.  Use of bio-char as a soil amendment will offset many of the problems associated with removing crop residues from the land.

Biomass pyrolysis has been garnering much attention due to its high efficiency and good environmental performance characteristics. It also provides an opportunity for the processing of agricultural residues, wood wastes and municipal solid waste into clean energy. In addition, biochar sequestration could make a big difference in the fossil fuel emissions worldwide and act as a major player in the global carbon market with its robust, clean and simple production technology.

Overview of Bioenergy Technologies

A wide range of technologies are available for realizing the energy potential of biomass wastes, ranging from very simple systems for disposing of dry waste to more complex technologies capable of dealing with large amounts of industrial waste. Conversion routes for biomass wastes are generally thermo-chemical or bio-chemical, but may also include chemical and physical.

Thermal Technologies

The three principal methods of thermo-chemical conversion corresponding to each of these energy carriers are combustion in excess air, gasification in reduced air, and pyrolysis in the absence of air. Direct combustion is the best established and most commonly used technology for converting wastes to heat. During combustion, biomass is burnt in excess air to produce heat. The first stage of combustion involves the evolution of combustible vapours from wastes, which burn as flames. Steam is expanded through a conventional turbo-alternator to produce electricity. The residual material, in the form of charcoal, is burnt in a forced air supply to give more heat.

Co-firing or co-combustion of biomass wastes with coal and other fossil fuels can provide a short-term, low-risk, low-cost option for producing renewable energy while simultaneously reducing the use of fossil fuels. Co-firing involves utilizing existing power generating plants that are fired with fossil fuel (generally coal), and displacing a small proportion of the fossil fuel with renewable biomass fuels. Co-firing has the major advantage of avoiding the construction of new, dedicated, waste-to-energy power plant. An existing power station is modified to accept the waste resource and utilize it to produce a minor proportion of its electricity.

Gasification systems operate by heating biomass wastes in an environment where the solid waste breaks down to form a flammable gas. The gasification of biomass takes place in a restricted supply of air or oxygen at temperatures up to 1200–1300°C. The gas produced—synthesis gas, or syngas—can be cleaned, filtered, and then burned in a gas turbine in simple or combined-cycle mode, comparable to LFG or biogas produced from an anaerobic digester. The final fuel gas consists principally of carbon monoxide, hydrogen and methane with small amounts of higher hydrocarbons. This fuel gas may be burnt to generate heat; alternatively it may be processed and then used as fuel for gas-fired engines or gas turbines to drive generators. In smaller systems, the syngas can be fired in reciprocating engines, micro-turbines, Stirling engines, or fuel cells.

Pyrolysis is thermal decomposition occurring in the absence of oxygen. During the pyrolysis process, biomass waste is heated either in the absence of air (i.e. indirectly), or by the partial combustion of some of the waste in a restricted air or oxygen supply. This results in the thermal decomposition of the waste to form a combination of a solid char, gas, and liquid bio-oil, which can be used as a liquid fuel or upgraded and further processed to value-added products.

Biochemical Technologies

Biochemical processes, like anaerobic digestion, can also produce clean energy in the form of biogas which can be converted to power and heat using a gas engine. Anaerobic digestion is a series of chemical reactions during which organic material is decomposed through the metabolic pathways of naturally occurring microorganisms in an oxygen depleted environment. In addition, wastes can also yield liquid fuels, such as cellulosic ethanol and biodiesel, which can be used to replace petroleum-based fuels.

Anaerobic digestion is the natural biological process which stabilizes organic waste in the absence of air and transforms it into biogas and biofertilizer. Almost any organic material can be processed with anaerobic digestion. This includes biodegradable waste materials such as municipal solid waste, animal manure, poultry litter, food wastes, sewage and industrial wastes. An anaerobic digestion plant produces two outputs, biogas and digestate, both can be further processed or utilized to produce secondary outputs. Biogas can be used for producing electricity and heat, as a natural gas substitute and also a transportation fuel. Digestate can be further processed to produce liquor and a fibrous material. The fiber, which can be processed into compost, is a bulky material with low levels of nutrients and can be used as a soil conditioner or a low level fertilizer.

A variety of fuels can be produced from biomass wastes including liquid fuels, such as ethanol, methanol, biodiesel, Fischer-Tropsch diesel, and gaseous fuels, such as hydrogen and methane. The resource base for biofuel production is composed of a wide variety of forestry and agricultural resources, industrial processing residues, and municipal solid and urban wood residues. The largest potential feedstock for ethanol is lignocellulosic biomass wastes, which includes materials such as agricultural residues (corn stover, crop straws and bagasse), herbaceous crops (alfalfa, switchgrass), short rotation woody crops, forestry residues, waste paper and other wastes (municipal and industrial). The three major steps involved in cellulosic ethanol production are pretreatment, enzymatic hydrolysis, and fermentation. Biomass is pretreated to improve the accessibility of enzymes. After pretreatment, biomass undergoes enzymatic hydrolysis for conversion of polysaccharides into monomer sugars, such as glucose and xylose. Subsequently, sugars are fermented to ethanol by the use of different microorganisms. Bioethanol production from these feedstocks could be an attractive alternative for disposal of these residues. Importantly, lignocellulosic feedstocks do not interfere with food security.