To improve the quality of biomass, especially for cofiring purposes, biomass waste can be processed with torrefaction (also known as mild pyrolysis). With the torrefaction process, it becomes easier to make powder (high grindability) so that the desired particle size for cofiring of biomass is easier to obtain. Another advantage of the torrefaction process is that the caloric value of biomass increases by about 20%. Torrified biomass is essentially hydropobic which means ease in storage including outdoor storage. This condition also makes it easier to handle and use, in addition to reduction in transportation costs.
What is Torrefaction
Torrefaction, which is currently being considered for effective biomass utilization, is also a form of pyrolysis. In this process (named for the French word for roasting), the biomass is heated to 230 to 300 °C without contact with oxygen. For comparison, pyrolysis of biomass is typically carried out in a relatively low temperature range of 300 to 650 °C compared to 800 to 1000 °C for gasification. Torrefaction is a relatively new process that heats the biomass in the absence of air to improve its usefulness as a fuel.
Torrefaction, a process different from carbonization, is a mild pyrolysis process carried out in a temperature range of 230 to 300 °C in the absence of oxygen. During this process the biomass dries and partially devolatilizes, decreasing its mass while largely preserving its energy content. The torrefaction process removes H2O and CO2 from the biomass. As a result, both the O/C and the H/C ratios of the biomass decrease.
Advantages of Biomass Torrefaction
Torrefaction of biomass improves its energy density, reduces its oxygen-to-carbon (O/C) ratio, and reduces its hygroscopic nature. Torrefaction also increases the relative carbon content of the biomass. The properties of a torrefied biomass depends on torrefaction temperature, time, and on the type of biomass feed.
Torrefaction also modifies the structure of the biomass, making it more friable or brittle. This is caused by the depolymerization of hemicellulose. As a result, the process of size reduction becomes easier, lowering its energy consumption and the cost of handling. This makes it easier to cofire biomass in a pulverized coal-fired boiler or gasify it in an entrained-flow reactor.
Another special feature of torrefaction is that it reduces the hygroscopic property of biomass; therefore, when torrefied biomass is stored, it absorbs less moisture than that absorbed by fresh biomass. For example, while raw bagasse absorbed 186% moisture when immersed in water for two hours, it absorbed only 7.6% moisture under this condition after torrefying the bagasse for 60 minutes at 250 °C (Pimchua et al., 2009). The reduced hygroscopic (or enhanced hydrophobic) nature of torrefied biomass mitigates one of the major shortcomings for energy use of biomass.
In biomass, hemicellulose is like the cement in reinforced concrete, and cellulose is like the steel rods. The strands of microfibrils (cellulose) are supported by the hemicellulose. Decomposition of hemicellulose during torrefaction is like the melting away of the cement from the reinforced concrete. Thus, the size reduction of biomass consumes less energy after torrefaction. During torrefaction the weight loss of biomass comes primarily from the decomposition of its hemicellulose constituents. Hemicellulose decomposes mostly within the temperature range 150 to 280 °C, which is the temperature window of torrefaction.
As we can see from figure above, the hemicellulose component undergoes the greatest amount of degradation within the 200 to 300 °C temperature window. Thus, hemicellulose decomposition is the primary mechanism of torrefaction. At lower temperatures (< 160 °C), as biomass dries it releases H2O and CO2. Water and carbon dioxide, which make no contribution to the energy in the product gas, constitute a dominant portion of the weight loss during torrefaction.
Above 180 °C, the reaction becomes exothermic, releasing gas with small heating values. The initial stage (< 250 °C) involves hemicellulose depolymerization, leading to an altered and rearranged polysugar structures. At higher temperatures (250–300 °C) these form chars, CO, CO2, and H2O. The hygroscopic property of biomass is partly lost in torrefaction because of the destruction of OH groups through dehydration, which prevents the formation of hydrogen bonds.