Agricultural Residues

Agricultural residues encompasses all agricultural wastes such as straw, stem, stalk, leaves, husk, shell, peel, pulp, stubble, etc. which come from cereals (rice, wheat, maize or corn, sorghum, barley, millet), cotton, groundnut, jute, legumes (tomato, bean, soy) coffee, cacao, tea, fruits (banana, mango, coco, cashew) and palm oil.

Rice produces both straw and rice husks at the processing plant which can be conveniently and easily converted into energy. Significant quantities of biomass remain in the fields in the form of cob when maize is harvested which can be converted into energy.

Sugarcane harvesting leads to harvest residues in the fields while processing produces fibrous bagasse, both of which are good sources of energy. Harvesting and processing of coconuts produces quantities of shell and fibre that can be utilised while peanuts leave shells. All these lignocellulosic materials can be converted into biofuels by a wide range of technologies.

Forestry Biomass

Forest harvesting is a major source of biomass energy. Harvesting in forests may occur as thinning in young stands, or cutting in older stands for timber or pulp that also yields tops and branches usable for production of cellulosic ethanol.

Biomass harvesting operations usually remove only 25 to 50 percent of the volume, leaving the residues available as biomass for energy. Stands damaged by insects, disease or fire are additional sources of biomass. Forest residues normally have low density and fuel values that keep transport costs high, and so it is economical to reduce the biomass density in the forest itself.

Energy Crops

Energy crops are non-food crops which provide an additional potential source of feedstock for the production of second-generation biofuels. Corn and soybeans are considered as the first-generation energy crops as these crops can be also used as the food crops. Second-generation energy crops are grouped into grassy (herbaceous or forage) and woody (tree) energy crops.

Grassy energy crops or perennial forage crops mainly include switchgrass and miscanthus. Switchgrass is the most commonly used feedstock because it requires relatively low water and nutrients, and has positive environmental impact and adaptability to low-quality land. Miscanthus is a grass mainly found in Asia and is a popular feedstock for second-generation biofuel production in Europe.

Woody energy crops mainly consists of fast-growing tree species like poplar, willow, and eucalyptus. The most important attributes of these class species are the low level of input required when compared with annual crops. In short, dedicated energy crops as feedstock are less demanding in terms of input, helpful in reducing soil erosion and useful in improving soil properties.

The post Resource Base for Second-Generation Biofuels first appeared on BioEnergy Consult.

Lignocellulose is a generic term for describing the main constituents in most plants, namely cellulose, hemicelluloses, and lignin. Lignocellulose is a complex matrix, comprising many different polysaccharides, phenolic polymers and proteins. Cellulose, the major component of cell walls of land plants, is a glucan polysaccharide containing large reservoirs of energy that provide real potential for conversion into biofuels.

First-generation biofuels (produced primarily from food crops such as grains, sugar beet and oil seeds) are limited in their ability to achieve targets for oil-product substitution, climate change mitigation, and economic growth. Their sustainable production is under scanner, as is the possibility of creating undue competition for land and water used for food and fibre production.

The cumulative impacts of these concerns have increased the interest in developing biofuels produced from non-food biomass. Feedstocks from lignocellulosic materials include cereal straw, bagasse, forest residues, and purpose-grown energy crops such as vegetative grasses and short rotation forests. These second-generation biofuels could avoid many of the concerns facing first-generation biofuels and potentially offer greater cost reduction potential in the longer term.

The largest potential feedstock for biofuels is lignocellulosic biomass, which includes materials such as agricultural residues (corn stover, crop straws and bagasse), herbaceous crops (alfalfa, switchgrass), short rotation woody crops, forestry residues, waste paper and other wastes (municipal and industrial). Bioethanol production from these feedstocks could be an attractive alternative for disposal of these residues.

Importantly, lignocellulosic biomass resources do not interfere with food security. Moreover, bioethanol is very important for both rural and urban areas in terms of energy security reason, environmental concern, employment opportunities, agricultural development, foreign exchange saving, socioeconomic issues etc.

Lignocellulosic biomass consists mainly of lignin and the polysaccharides cellulose and hemicellulose. Compared with the production of ethanol from first-generation feedstocks, the use of lignocellulosic biomass is more complicated because the polysaccharides are more stable and the pentose sugars are not readily fermentable by Saccharomyces cerevisiae. 

In order to convert lignocellulosic biomass to biofuels the polysaccharides must first be hydrolysed, or broken down, into simple sugars using either acid or enzymes. Several biotechnology-based approaches are being used to overcome such problems, including the development of strains of Saccharomyces cerevisiae that can ferment pentose sugars, the use of alternative yeast species that naturally ferment pentose sugars, and the engineering of enzymes that are able to break down cellulose and hemicellulose into simple sugars.

Lignocellulosic biomass processing pilot plants have been established in the EU, in Denmark, Spain and Sweden. The world’s largest demonstration facility of lignocellulose ethanol (from wheat, barley straw and corn stover), with a capacity of 2.5 Ml, was first established by Iogen Corporation in Ottawa, Canada. Many other processing facilities are now in operation or planning throughout the world.

Economically, lignocellulosic biomass has an advantage over other agriculturally important biofuels feedstock such as corn starch, soybeans, and sugar cane, because it can be produced quickly and at significantly lower cost than food crops.

Lignocellulosic biomass is an important component of the major food crops; it is the non-edible portion of the plant, which is currently underutilized, but could be used for biofuel production. In short, biofuels from lignocellulosic biomass holds the key to supplying society’s basic needs without impacting the nation’s food supply.

The post Biofuels from Lignocellulosic Biomass first appeared on BioEnergy Consult.

Pretreated biomass can directly be converted to ethanol by using the process called simultaneous saccharification and cofermentation (SSCF). Pretreatment is a critical step which enhances the enzymatic hydrolysis of biomass.

Basically, it alters the physical and chemical properties of biomass and improves the enzyme access and effectiveness which may also lead to a change in crystallinity and degree of polymerization of cellulose. The internal surface area and pore volume of pretreated biomass are increased which facilitates substantial improvement in accessibility of enzymes. The process also helps in enhancing the rate and yield of monomeric sugars during enzymatic hydrolysis steps.

Pretreatment methods can be broadly classified into four groups – physical, chemical, physio-chemical and biological. Physical pretreatment processes employ the mechanical comminution or irradiation processes to change only the physical characteristics of biomass. The physio-chemical process utilizes steam or steam and gases, like SO2 and CO2. The chemical processes employs acids (H2SO4, HCl, organic acids etc) or alkalis (NaOH, Na2CO3, Ca(OH)2, NH3 etc).

The acid treatment typically shows the selectivity towards hydrolyzing the hemicelluloses components, whereas alkalis have better selectivity for the lignin. The fractionation of biomass components after such processes help in improving the enzymes accessibility which is also important to the efficient utilization of enzymes.

The pretreated biomass is subjected to enzymatic hydrolysis using cellulase enzymes to convert the cellulose to fermentable sugars. Cellulase refers to a class of enzymes produced chiefly by fungi and bacteria which catalyzes the hydrolysis of cellulose by attacking the glycosidic linkages. Cellulase is mixture of mainly three different functional protein groups: exo-glucanase (Exo-G), endo-glucanase(Endo-G) and ?-glucosidase (?-G).

The functional proteins work synergistically in hydrolyzing the cellulose into the glucose. These sugars are further fermented using microorganism and are converted to ethanol. The microorganisms are selected based on their efficiency for ethanol productivity and higher product and inhibitors tolerance. Yeast Saccharomyces cerevisiae is used commercially to produce the ethanol from starch and sucrose.

Escherichia coli strain has also been developed recently for ethanol production by the first successful application of metabolic engineering. E. coli can consume variety of sugars and does not require the complex growth media but has very narrow operable range of pH. E. coli has higher optimal temperature than other known strains of bacteria.

The major cost components in bioethanol production from lignocellulosic biomass are the pretreatment and the enzymatic hydrolysis steps. In fact, these two process are someway interrelated too where an efficient pretreatment strategy can save substantial enzyme consumption.

Pretreatment step can also affect the cost of other operations such as size reduction prior to pretreatment. Therefore, optimization of these two important steps, which collectively contributes about 70% of the total processing cost, are the major challenges in the commercialization of bioethanol from 2nd generation feedstock.

Enzyme cost is the prime concern in full scale commercialization. The trend in enzyme cost is encouraging because of enormous research focus in this area and the cost is expected to go downward in future, which will make bioethanol an attractive option considering the benefits derived its lower greenhouse gas emissions and the empowerment of rural economy.

The post Biochemical Method for Ethanol Production first appeared on BioEnergy Consult.

Feedstock for biomass energy plants can include residues from agriculture, forestry, wood processing, and food processing industries, municipal solid wastes, industrial wastes and biomass produced from degraded and marginal lands.

The terms biomass energy, bioenergy and biofuels cover any energy products derived from plant or animal or organic material. The increasing interest in biomass energy and biofuels has been the result of the following associated benefits:

• Potential to reduce GHG emissions.
• Energy security benefits.
• Substitution for diminishing global oil supplies.
• Potential impacts on waste management strategy.
• Capacity to convert a wide variety of wastes into clean energy.
• Technological advancement in thermal and biochemical processes for waste-to-energy transformation.

Biomass can play the pivotal role in production of carbon-neutral fuels of high quality as well as providing feedstock for various industries. This is a unique property of biomass compared to other renewable energies and which makes biomass a prime alternative to the use of fossil fuels. Performance of biomass-based systems for heat and power generation has been already proved in many situations on commercial as well as domestic scales.

Biomass energy systems have the potential to address many environmental issues, especially global warming and greenhouse gases emissions, and foster sustainable development among poor communities. Biomass fuel sources are readily available in rural and urban areas of all countries. Biomass-based industries can provide appreciable employment opportunities and promote biomass re-growth through sustainable land management practices.

The negative aspects of traditional biomass utilization in developing countries can be mitigated by promotion of modern biomass-to-energy technologies which provide solid, liquid and gaseous fuels as well as electricity as shown. Biomass wastes can be transformed into clean and efficient energy by biochemical as well as thermochemical technologies.

The most common technique for producing both heat and electrical energy from biomass wastes is direct combustion. Thermal efficiencies as high as 80 – 90% can be achieved by advanced gasification technology with greatly reduced atmospheric emissions. Combined heat and power (CHP) systems, ranging from small-scale technology to large grid-connected facilities, provide significantly higher efficiencies than systems that only generate electricity.

Biochemical processes, like anaerobic digestion and sanitary landfills, can also produce clean energy in the form of biogas and producer gas which can be converted to power and heat using a gas engine.

In addition, biomass wastes can also yield liquid fuels, such as cellulosic ethanol, which can be used to replace petroleum-based fuels. Cellulosic ethanol can be produced from grasses, wood chips and agricultural residues by biochemical route using heat, pressure, chemicals and enzymes to unlock the sugars in lignocellulosic biomass. Algal biomass is also emerging as a good source of energy because it can serve as natural source of oil, which conventional refineries can transform into jet fuel or diesel fuel.

The post Everything You Need to Know About Biomass Energy Systems first appeared on BioEnergy Consult.

The largest potential feedstock for ethanol is lignocellulosic biomass, which includes materials such as agricultural residues (corn stover, crop straws, husks and bagasse), herbaceous crops (alfalfa, switchgrass), short rotation woody crops, forestry residues, waste paper and other wastes (municipal and industrial).

Bioethanol production from these feedstocks could be an attractive alternative for disposal of these residues. Lignocellulosic biomass feedstocks do not interfere with food security and are important for both rural and urban areas in terms of energy security reason, environmental concern, employment opportunities, agricultural development, foreign exchange saving, socioeconomic issues etc.

Production of Ethanol

The production of ethanol from lignocellulosic biomass can be achieved through two different processing routes. They are:

• Biochemical – in which enzymes and other micro-organisms are used to convert cellulose and hemicellulose components of the feedstocks to sugars prior to their fermentation to produce ethanol;
• Thermochemical – where pyrolysis/gasification technologies produce a synthesis gas (CO + H₂) from which a wide range of long carbon chain biofuels, such as synthetic diesel or aviation fuel, can be reformed.

Lignocellulosic biomass consists mainly of lignin and the polysaccharides cellulose and hemicellulose. Compared with the production of ethanol from first-generation feedstocks, the use of lignocellulosic biomass is more complicated because the polysaccharides are more stable and the pentose sugars are not readily fermentable by Saccharomyces cerevisiae. 

In order to convert lignocellulosic biomass to biofuels the polysaccharides must first be hydrolysed, or broken down, into simple sugars using either acid or enzymes. Several biotechnology-based approaches are being used to overcome such problems, including the development of strains of Saccharomyces cerevisiae that can ferment pentose sugars, the use of alternative yeast species that naturally ferment pentose sugars, and the engineering of enzymes that are able to break down cellulose and hemicellulose into simple sugars.

Ethanol from lignocellulosic biomass is produced mainly via biochemical routes. The three major steps involved are pretreatment, enzymatic hydrolysis, and fermentation. Biomass is pretreated to improve the accessibility of enzymes. After pretreatment, biomass undergoes enzymatic hydrolysis for conversion of polysaccharides into monomer sugars, such as glucose and xylose. Subsequently, sugars are fermented to ethanol by the use of different microorganisms.

Pretreated biomass can directly be converted to ethanol by using the process called simultaneous saccharification and cofermentation (SSCF).  Pretreatment is a critical step which enhances the enzymatic hydrolysis of biomass. Basically, it alters the physical and chemical properties of biomass and improves the enzyme access and effectiveness which may also lead to a change in crystallinity and degree of polymerization of cellulose.

The internal surface area and pore volume of pretreated biomass are increased which facilitates substantial improvement in accessibility of enzymes. The process also helps in enhancing the rate and yield of monomeric sugars during enzymatic hydrolysis steps.

Pretreatment of Lignocellulosic Biomass

Pretreatment methods can be broadly classified into four groups – physical, chemical, physio-chemical and biological. Physical pretreatment processes employ the mechanical comminution or irradiation processes to change only the physical characteristics of biomass. The physio-chemical process utilizes steam or steam and gases, like SO₂ and CO₂.

The chemical processes employs acids (H₂SO₄, HCl, organic acids etc) or alkalis (NaOH, Na₂CO₃, Ca(OH)₂, NH₃ etc). The acid treatment typically shows the selectivity towards hydrolyzing the hemicelluloses components, whereas alkalis have better selectivity for the lignin. The fractionation of biomass components after such processes help in improving the enzymes accessibility which is also important to the efficient utilization of enzymes.

Conclusions

The major cost components in bioethanol production from lignocellulosic biomass are the pretreatment and the enzymatic hydrolysis steps. In fact, these two process are someway interrelated too where an efficient pretreatment strategy can save substantial enzyme consumption. Pretreatment step can also affect the cost of other operations such as size reduction prior to pretreatment.

Therefore, optimization of these two important steps, which collectively contributes about 70% of the total processing cost, are the major challenges in the commercialization of bioethanol from 2^nd generation biofuel feedstock.

The post Ethanol Production from Lignocellulosic Biomass first appeared on BioEnergy Consult.

First-generation biofuels are things like methanol, ethanol, biodiesel and vegetable oil, while second-generation biofuels are produced by transforming crops into liquid fuels using highly advanced chemical processes, such as mixed alcohols and biohydrogen. Third-generation, or “advanced” biofuels, are created using oil that is made from algae or closed reactors and then refined to produce conventional fuels such as ethanol, methane, biodiesel, etc.

Cleaner Air and Less Impact on Climate Change

As biofuels come from renewable materials, they have less of an impact on climate change as compared to gasoline, according to multiple studies. Ethanol in gasoline has been helping to decrease smog in major cities, keeping the air cleaner and safer to breathe.

Starch-based biofuels can reduce carbon dioxide emissions by around 30- to 60-percent, as compared to gasoline, while cellulosic ethanol can lessen emissions even further, as much as 90 percent.

Reduced Danger of Environmental Disaster

Can you imagine buying one of the oceanfront Jacksonville condos in Florida, looking forward to enjoying peaceful beach strolls every morning only to find injured or killed animals and globs of oil all over the sand? Not exactly the vision of paradise you dreamed of.

A major benefit of using biofuels is the risk of environmental disaster is dramatically reduced. The 2010 Deepwater Horizon Spill that occurred in the Gulf of Mexico released millions of gallons of oil. It not only cost BP nearly $62 billion but caused extensive damage to wildlife and the environment. Biofuels are much safer. For example, a corn field won’t poison the ocean.

More Jobs and an Economic Boom

Numerous studies, including one conducted by the Renewable Fuels Association (RFA), have found that biofuels lead to more jobs for Americans. In 2014, the ethanol industry was responsible for nearly 84,000 direct jobs and over 295,000 indirect and induced jobs – all jobs that pay well and are non-exportable. The biofuels industry in the USA also added nearly $53 billion to the national GDP, $27 billion to the national GDP and over $10 billion in taxes, stimulating local, state and national economies.

Many experts predict that these figures will increase with significant job creation potential in biorefinery construction, operation and biomass collection. If the potential for producing cellulosic ethanol from household waste and forestry residues were utilized at commercial scale, even more jobs are likely to be added.

Energy Independence

When a nation has the land resources to grow biofuel feedstock, it is able to produce its own energy, eliminating dependence on fossil fuel resources. Considering the significant amount of conflict that tends to happen over fuel prices and supplies, this brings a net positive effect.

The post Why Biofuels Should Be a Key Part in America’s Future first appeared on BioEnergy Consult.