Biomass Energy in Vietnam

Vietnam is one of the few countries having a low level of energy consumption in the developing world with an estimated amount of 210 kg of oil equivalent per capita/year. A significant portion of the Vietnamese population does not have access to electricity. Vietnam is facing the difficult challenge of maintaining this growth in a sustainable manner, with no or minimal adverse impacts on society and the environment.

Being an agricultural country, Vietnam has very good biomass energy potential. Agricultural wastes are most abundant in the Mekong Delta region with approximately 50% of the amount of the whole country and Red River Delta with 15%. Major biomass resources includes rice husk from paddy milling stations, bagasse from sugar factories, coffee husk from coffee processing plants in the Central Highlands and wood chip from wood processing industries. Vietnam has set a target of having a combined capacity of 500 MW of biomass power by 2020, which is raised to 2,000 MW in 2030.

Rice husk and bagasse are the biomass resources with the greatest economic potential, estimated at 50 MW and 150 MW respectively. Biomass fuels sources that can also be developed include forest wood, rubber wood, logging residues, saw mill residues, sugar cane residues, bagasse, coffee husk and coconut residues.

Currently biomass is generally treated as a non-commercial energy source, and collected and used locally. Nearly 40 bagasse-based biomass power plants have been developed with a total designed capacity of 150 MW but they are still unable to connect with the national grid due to current low power prices. Five cogeneration systems selling extra electricity to national grid at average price of 4 US cents/kWh.

Biogas potential is approximately 10 billion m3/year, which can be collected from landfills, animal excrements, agricultural residues, industrial wastewater etc. The biogas potential in the country is large due to livestock population of more than 30 million, mostly pigs, cattle, and water buffalo. Although most livestock dung already is used in feeding fish and fertilizing fields and gardens, there is potential for higher-value utilization through biogas production.

It is estimated that more than 25,000 household biogas digesters with 1 to 50 m3, have been installed in rural areas. The Dutch-funded Biogas Program operated by SNV Vietnam constructed some 18,000 biogas facilities in 12 provinces between 2003 and 2005, with a second phase (2007-2010) target of 150,000 biogas tanks in both rural and semi-urban settings.

Municipal solid waste is also a good biomass resource as the amount of solid waste generated in Vietnam has been increasing steadily over the last few decades. In 1996, the average amount of waste produced per year was 5.9 million tons per annum which rose to 28 million tons per in 2008 and expected to reach 44 million tons per year by 2015.

Biological Desulphurization of Biogas

The most valuable component of biogas is methane (CH4) which typically makes up 60%, with the balance being carbon dioxide (CO2) and small percentages of other gases. However, biogas also contain significant amount of hydrogen sulfide (H2S) gas which needs to be stripped off due to its highly corrosive nature. Hydrogen sulfide is oxidized into sulfur dioxide which dissolves as sulfuric acid. Sulphuric acid, even in trace amounts, can make a solution extremely acidic. Extremely acidic electrolytes dissolve metals rapidly and speed up the corrosion process.

The corrosive nature of H2S has the potential to destroy expensive biogas processing equipment. Even if there is no oxygen present, biogas can corrode metal. Hydrogen sulphide can become its own electrolyte and absorb directly onto the metal to form corrosion. If the hydrogen sulphide concentration is very low, the corrosion will be slow but will still occur due to the presence of carbon dioxide.

Biogas_Cleanup-H2S

The obvious solution is the use of a biogas cleanup process whereby contaminants in the raw biogas stream are absorbed or scrubbed. Desulphurization of biogas can be performed by biological as well as chemical methods. Biological treatment of hydrogen sulphide typically involves passing the biogas through biologically active media. These treatments may include open bed soil filters, biofilters, fixed film bioscrubbers, suspended growth bioscrubbers and fluidized bed bioreactors.

Biological Desulphurization

The simplest method of desulphurization is the addition of oxygen or air directly into the digester or in a storage tank serving at the same time as gas holder. Thiobacilli are ubiquitous and thus systems do not require inoculation. They grow on the surface of the digestate, which offers the necessary micro-aerophilic surface and at the same time the necessary nutrients. They form yellow clusters of sulphur. Depending on the temperature, the reaction time, the amount and place of the air added the hydrogen sulphide concentration can be reduced by 95 % to less than 50 ppm.

Most of the sulphide oxidising micro-organisms belong to the family of Thiobacillus. For the microbiological oxidation of sulphide it is essential to add stoichiometric amounts of oxygen to the biogas. Depending on the concentration of hydrogen sulphide this corresponds to 2 to 6 % air in biogas. Measures of safety have to be taken to avoid overdosing of air in case of pump failures.

Biofiltration

Biofiltration is one of the most promising clean technologies for reducing emissions of malodorous gases and other pollutants into the atmosphere. In a biofiltration system, the gas stream is passed through a packed bed on which pollutant-degrading microbes are immobilized as biofilm. A biological filter combines water scrubbing and biological desulfurization.

Biogas and the separated digestate meet in a counter-current flow in a filter bed. The biogas is mixed with 4% to 6% air before entry into the filter bed. The filter media offer the required surface area for scrubbing, as well as for the attachment of the desulphurizing microorganisms. Microorganisms in the biofilm convert the absorbed H2S into elemental sulphur by metabolic activity. Oxygen is the key parameter that controls the level of oxidation.

The capital costs for biological treatment of biogas are moderate and operational costs are low. This technology is widely available worldwide. However, it may be noted that the biological system is capable to remove even very high amounts of hydrogen sulphide from the biogas but its adaptability to fluctuating hydrogen sulphide contents is not yet proven.

Role of Biogas in Rural Development

Anaerobic digestion has proven to be a beneficial technology in various spheres for rural development. Biogas produced is a green replacement of unprocessed fuels (like fuel wood, dung cakes, crop residues). It is a cost effective replacement for dung cakes and conventional domestic fuels like LPG or kerosene. Biogas technology has the potential to meet the energy requirements in rural areas, and also counter the effects of reckless burning of biomass resources.

Biogas has the potential to rejuvenate India’s agricultural sector

An additional benefit is that the quantity of digested slurry is the same as that of the feedstock fed in a biogas plant. This slurry can be dried and sold as high quality compost. The nitrogen-rich compost indirectly reduces the costs associated with use of fertilizers. It enriches the soil, improves its porosity, buffering capacity and ion exchange capacity and prevents nutrient depletion thus improving the crop quality. This means increased income for the farmer.

Further, being relatively-clean cooking fuel, biogas reduces the health risks associated with conventional chulhas. Thinking regionally, decreased residue burning brings down the seasonal high pollutant levels in air, ensuring a better environmental quality. Anaerobic digestion thus proves to be more efficient in utilization of crop residues. The social benefits associated with biomethanation, along with its capacity to generate income for the rural households make it a viable alternative for conventional methods.

The Way Forward

The federal and stage governments needs to be more proactive in providing easy access to these technologies to the poor farmers. The policies and support of the government are decisive in persuading the farmers to adopt such technologies and to make a transition from wasteful traditional approaches to efficient resource utilization. The farmers are largely unaware of the possible ways in which farm and cattle wastes could be efficiently utilised. The government agencies and NGOs are major stakeholders in creating awareness in this respect.

Moreover, many farmers find it difficult to bear the construction and operational costs of setting up the digester. This again requires the government to introduce incentives (like soft loans) and subsidies to enhance the approachability of the technology and thus increase its market diffusion.

Biomethane Industry in Europe

Biomethane is a well-known and well-proven source of clean energy, and is witnessing increasing demand worldwide, especially in European countries. Between 2012 and 2016, more than 500 biomethane production plants were built across Europe which indicates a steep rise of 165 percent. The main reasons behind the growth of biomethane industry in Europe is increasing interest in industrial waste-derived biogas sector and public interest in biogas.  Another important reason has been the guaranteed access to gas grid for all biomethane suppliers.

Biomethane production in Europe has swiftly increased from 752 GWh in 2011 to 17,264 GWh in 2016 with Germany being the market leader with 195 biomethane production plants, followed by United Kingdom with 92 facilities. Biogas generation across Europe also witnessed a rapid growth of 59% during the year 2011 and 2016. In terms of plant capacities, the regional trend is to establish large-scale biomethane plants.

Sources of Biomethane in Europe

Landfill gas and AD plants (based on energy crops, agricultural residues, food waste, industrial waste and sewage sludge) are the major resources for biomethane production in Europe, with the predominant source being agricultural crops (such as maize) and dedicated energy crops (like miscanthus). In countries, like Germany, Austria and Denmark, energy crops, agricultural by-products, sewage sludge and animal manure are the major feedstock for biomethane production. On the other hand, France, UK, Spain and Italy rely more on landfill gas to generate biomethane.

A large number of biogas plants in Europe are located in agricultural areas having abundant availability of organic wastes, such as grass silage and green waste, which are cheaper than crops. Maize is the most cost-effective raw material for biomethane production. In many parts of Europe, the practice of co-digestion is practised whereby energy crops are used in combination with animal manure as a substrate. After agricultural biogas plants, sewage sludge is one of the most popular substrates for biomethane production in Europe.

Biomethane Utilization Trends in Europe

Biomethane has a wide range of applications in the clean energy sector. In Europe, the main uses of biomethane include the following:

  1. Production of heat and/or steam
  2. Power generation and combined heat and power production(CHP)
  3. Replacement for natural gas (gas grid injection)
  4. Replacement for compressed natural gas & diesel – (bio-CNG for use as transport fuel)
  5. Replacement for liquid natural gas – (bio-LNG for use as transport fuel)

Prior to practically all utilization options, the biogas has to be dried (usually through application of a cooling/condensation step). Furthermore, elements such as hydrogen sulphide and other harmful trace elements must be removed (usually trough application of an activated carbon filter) to prevent adverse effects on downstream processing equipment (such as compressors, piping, boilers and CHP systems).

biomethane-transport

Biomethane is getting popularity as a clean vehicle fuel in Europe. For example, Germany has more than 900 CNG filling stations, with a fleet of around 100,000 gas-powered vehicles including cars, buses and trucks. Around 170 CNG filling stations in Germany sell a blend mixture of natural gas and biomethane while about 125 filling stations sell 100% biomethane from AD plants.

Barriers to Overcome

The fact that energy crops can put extra pressure on land availability for cultivation of food crops has led many European countries to initiate measures to reduce or restrict biogas production from energy crops. As far as waste-derived biomethane is concerned, most of the EU nations are phasing out landfill-based waste management systems which may lead to rapid decline in landfill gas production thus putting the onus of biomethane production largely on anaerobic digestion of food waste, sewage sludge, industrial waste and agricultural residues.

The high costs of biogas upgradation and natural gas grid connection is a major hurdle in the development of biomethane sector in Eastern European nations. The injection of biomethane is also limited by location of suitable biomethane production facilities, which should ideally be located close to the natural gas grid.  Several European nations have introduced industry standards for injecting biogas into the natural gas grid but these standards differ considerably with each other.

Another important issue is the insufficient number of biomethane filling stations and biomethane-powered vehicles in Europe. A large section of the population is still not aware about the benefits of biomethane as a vehicle fuel. Strong political backing and infrastructural support will provide greater thrust to biomethane industry in Europe.

Biomethane from Food Waste: A Window of Opportunity

For most of the world, reusing our food waste is limited to a compost pile and a home garden. While this isn’t a bad thing – it can be a great way to provide natural fertilizer for our home-grown produce and flower beds – it is fairly limited in its execution. Biomethane from food waste is an interesting idea which can be implemented in communities notorious for generating food wastes on a massive scale. Infact, the European Union is looking for a new way to reuse the millions of tons of food waste that are produced ever year in its member countries – and biomethane could be the way to go.

food-waste-behavior

Bin2Grid

The Bin2Grid project is designed to make use of the 88 million tons of food waste that are produced in the European Union every year. For the past two years, the program has focused on collecting the food waste and unwanted or unsold produce, and converting it, first to biogas and then later to biomethane. This biomethane was used to supply fueling stations in the program’s pilot cities – Paris, Malaga, Zagreb and Skopje.

Biomethane could potentially replace fossil fuels, but how viable is it when so many people still have cars that run on gasoline?

The Benefits of Biomethane

Harvesting fossil fuels is naturally detrimental to the environment. The crude oil needs to be pulled from the earth, transported and processed before it can be used.  It is a finite resource and experts estimate that we will exhaust all of our oil, gas and coal deposits by 2088.

Biomethane, on the other hand, is a sustainable and renewable resource – there is a nearly endless supply of food waste across the globe and by converting it to biomethane, we could potentially eliminate our dependence on our ever-shrinking supply of fossil fuels. Some companies, like ABP Food Group, even have anaerobic digestion facilities to convert waste into heat, power and biomethane.

Neutral Waste

While it is true that biomethane still releases CO2 into the atmosphere while burned, it is a neutral kind of waste. Just hear us out. The biggest difference between burning fossil fuels and burning biomethane is that the CO2 that was trapped in fossil fuels was trapped there millions of years ago.  The CO2 in biomethane is just the CO2 that was trapped while the plants that make up the fuel were alive.

Biofuel in all its forms has a bit of a negative reputation – namely, farmers deforesting areas and removing trees that store and convert CO2 in favor of planting crops specifically for conversion into biofuel or biomethane. This is one way that anti-biofuel and pro-fossil fuel lobbyists argue against the implementation of these sort of biomethane projects – but they couldn’t be more wrong, especially with the use of food waste for conversion into useful and clean energy.

Using biogas is a great way to reduce your fuel costs as well as reuse materials that would otherwise be wasted or introduced into the environment. Upgrading biogas into biomethane isn’t possible at home at this point, but it could be in the future.

If the test cities in the European Union prove successful, biomethane made from food wastes could potentially change the way we think of fuel sources.  It could also provide alternative fuel sources for areas where fossil fuels are too expensive or unavailable. We’ve got our fingers crossed that it works out well – if for no other reason that it could help us get away from our dependence on finite fossil fuel resources.

Popular Feedstock for Biogas Plants

Anaerobic digestion is the natural biological process which stabilizes organic waste in the absence of air and transforms it into biofertilizer and biogas. Almost any organic material can be processed with anaerobic digestion.

Biogas_Plant

Anaerobic digestion is particularly suited to wet organic material and is commonly used for effluent and sewage treatment.  The popular feedstock for biogas plants includes biodegradable waste materials such as waste paper, grass clippings, leftover food, sewage and animal waste.

Large quantity of waste, in both solid and liquid forms, is generated by the industrial sector like breweries, sugar mills, distilleries, food processing industries, tanneries, and paper and pulp industries. Poultry waste has the highest per ton energy potential of electricity per ton but livestock have the greatest potential for energy generation in the agricultural sector.

1. Agricultural Feedstock

2. Community-Based Feedstock

  • Organic fraction of MSW (OFMSW)
  • MSW
  • Sewage sludge
  • Grass clippings/garden waste
  • Food wastes
  • Institutional wastes etc.

 3. Industrial Feedstock

  • Food/beverage processing
  • Dairy
  • Starch industry
  • Sugar industry
  • Pharmaceutical industry
  • Cosmetic industry
  • Biochemical industry
  • Pulp and paper
  • Slaughterhouse/rendering plant etc.

Anaerobic digestion is particularly suited to wet organic material and is commonly used for effluent and sewage treatment. Almost any organic material can be processed with anaerobic digestion process. This includes biodegradable waste materials such as waste paper, grass clippings, leftover food, sewage and animal waste. The exception to this is woody wastes that are largely unaffected by digestion as most anaerobic microorganisms are unable to degrade lignin.

Anaerobic digesters can also be fed with specially grown energy crops such as silage for dedicated biogas production. A wide range of crops, especially C-4 plants, demonstrate good biogas potentials. Corn is one of the most popular co-substrate in Germany while Sudan grass is grown as an energy crop for co-digestion in Austria. Crops like maize, sunflower, grass, beets etc., are finding increasing use in agricultural digesters as co-substrates as well as single substrate.

biogas-energy-crop

A wide range of organic substances are anaerobically easily degradable without major pretreatment. Among these are leachates, slops, sludges, oils, fats or whey. Some wastes can form inhibiting metabolites (e.g.NH3) during anaerobic digestion which require higher dilutions with substrates like manure or sewage sludge. A number of other waste materials often require pre-treatment steps (e.g. source separated municipal organic waste, food residuals, expired food, market wastes and crop residues).

Ultrasonic Pretreatment in Anaerobic Digestion of Sewage Sludge

Anaerobic digestion process comprises of four major steps – hydrolysis, acidogenesis, acetogenesis and methanogenesis. The biological hydrolysis is the rate limiting step and pretreatment of sludge by chemical, mechanical or thermal disintegration can improve the anaerobic digestion process. Ultrasonic disintegration is a method for breakup of microbial cells to extract intracellular material.

Ultrasound activated sludge disintegration could positively affect anaerobic digestion of sewage sludge. Due to sludge disintegration, organic compounds are transferred from the sludge solids into the aqueous phase resulting in an enhanced biodegradability. Therefore disintegration of sewage sludge is a promising method to enhance anaerobic digestion rates and lead to reduce the volume of sludge digesters.

The addition of disintegrated surplus activated sludge and/or foam to the process of sludge anaerobic digestion can lead to markedly better effects of sludge handling at wastewater treatment plants. In the case of disintegrated activated sludge and/or foam addition to the process of anaerobic digestion it is possible to achieve an even twice a higher production of biogas. Here are few examples:

STP Bad Bramstedt, Germany (4.49 MGD)

  • First fundamental study on pilot scale by Technical University of Hamburg-Harburg, 3 years, 1997 – 1999
  • reduction in digestion time from 20 to 4 days without losses in degradation efficiency
  • increase in biogas production by a factor of 4
  • reduction of digested sludge mass of 25%

STP Ahrensburg, Germany (2.64 MGD)

  • Preliminary test on pilot-scale by Technical University of Hamburg-Harburg, 6 months, 1999
  • increase in VS destruction of 20%
  • increase in biogas production of 20%

STP Bamberg, Germany (12.15 MGD)

  • Preliminary full-scale test, 4 months, 2002 2) Full-scale installation since June 2004
  • increase in VS destruction of 30%
  • increase in biogas production of 30%
  • avoided the construction of a new anaerobic digester

STP Freising, Germany (6.87 MGD)

  • Fundamental full-scale study by University of Armed Forces, Munich, 4 months, 2003
  • increase in biogas production of 15%
  • improved sludge dewatering of 10%

STP Meldorf, Germany (1.06 MGD)

  • Preliminary full-scale test, 3 months, 2004 2) Full-scale installation since December 2004
  • increase in VS destruction of 25%
  • increase in biogas production of 25%
  • no foam or filamentous organisms present in the anaerobic sludge digester

STP Ergolz 2, Switzerland (3.43 MGD)

  • Full-scale test, 3 months, 2004
  • increase in VS destruction of 15%
  • increase in biogas production of 25%

STP Beverungen, Germany (2.64 MGD)

  • Full-scale test, 3 months, 2004/2005
  • increase in VS destruction of 25%
  • increase in biogas production of 25%

To sum up, ultrasonication has a positive effect on sludge solubilisation, sludge volume, biogas production, flock size reduction and cells lyses. Ultrasonic pretreatment enhances the subsequent anaerobic digestion resulting in a better degradation of volatile solids and an increased production of biogas.

The use of low power ultrasound in bioreactors may present a significant improvement in cost reduction. Therefore, ultrasonic pretreatment enhances the subsequent anaerobic digestion of sewage sludge resulting in a better sludge digestion and efficient recovery of valuables.

Anaerobic Digestion of Tannery Wastes

The conventional leather tanning technology is highly polluting as it produces large amounts of organic and chemical pollutants. Wastes generated by tanneries pose a major challenge to the environment. Anaerobic digestion of tannery wastes is an attractive method to recover energy from tannery wastes.

According to conservative estimates, more than 600,000 tons per year of solid waste are generated worldwide by leather industry and approximately 40–50% of the hides are lost to shavings and trimmings. Everyday a huge quantity of solid waste, including trimmings of finished leather, shaving dusts, hair, fleshing, trimming of raw hides and skins, are being produced from the industries. Chromium, sulphur, oils and noxious gas (methane, ammonia, and hydrogen sulphide) are the elements of liquid, gas and solid waste of tannery industries.

Biogas from Tannery Wastes

Anaerobic digestion (or biomethanation) systems are mature and proven processes that have the potential to convert tannery wastes into energy efficiently, and achieve the goals of pollution prevention/reduction, elimination of uncontrolled methane emissions and odour, recovery of biomass energy potential as biogas, production of stabilized residue for use as low grade fertilizer.

Anaerobic digestion of tannery wastes is an attractive method to recover energy from tannery wastes. This method degrades a substantial part of the organic matter contained in the sludge and tannery solid wastes, generating valuable biogas, contributing to alleviate the environmental problem, giving time to set-up more sustainable treatment and disposal routes. Digested solid waste is biologically stabilized and can be reused in agriculture.

Until now, biogas generation from tannery wastewater was considered that the complexity of the waste water stream originating from tanneries in combination with the presence of chroming would result in the poisoning of the process in a high loaded anaerobic reactor.

When the locally available industrial wastewater treatment plant is not provided by anaerobic digester, a large scale digestion can be planned in regions accommodating a big cluster of tanneries, if there is enough waste to make the facility economically attractive.

In this circumstance, an anaerobic co-digestion plant based on sludge and tanneries may be a recommendable option, which reduces the quantity of landfilled waste and recovers its energy potential. It can also incorporate any other domestic, industrial or agricultural wastes. Chrome-free digested tannery sludge also has a definite value as a fertilizer based on its nutrient content.

Potential Applications of Biogas

Biogas produced in anaerobic digesters consists of methane (50%–80%), carbon dioxide (20%–50%), and trace levels of other gases such as hydrogen, carbon monoxide, nitrogen, oxygen, and hydrogen sulfide.  Biogas can be used for producing electricity and heat, as a natural gas substitute and also a transportation fuel. A combined heat and power plant (CHP) not only generates power but also produces heat for in-house requirements to maintain desired temperature level in the digester during cold season.

CHP systems cover a range of technologies but indicative energy outputs per m3 of biogas are approximately 1.7 kWh electricity and 2.5kWh heat. The combined production of electricity and heat is highly desirable because it displaces non-renewable energy demand elsewhere and therefore reduces the amount of carbon dioxide released into the atmosphere.

AD Plant at ECCO’s Tannery (Netherlands)

A highly advanced wastewater treatment plant and biogas system became fully operational in 2012 at ECCO’s tannery in the Netherlands. A large percentage of the waste is piped directly into the wastewater plant to be converted into biogas. This biogas digester provides a source of renewable fuel and also helps to dispose of tannery waste materials by converting waste from both the leather-making processes, and the wastewater treatment plant, into biogas. All excess organic material from the hides is also converted into biogas.

This project enables ECCO Tannery to reduce waste and to substitute virtually all of its consumption of non-renewable natural gas with renewable biogas. The aim is to use more than 40% of the total tannery waste and replace up to 60% of the total natural gas consumption with biogas.

Biogas Prospects in Rural Areas: Perspectives

Biogas, sometimes called renewable natural gas, could be part of the solution for providing people in rural areas with reliable, clean and cheap energy. In fact, it could provide various benefits beyond clean fuel as well, including improved sanitation, health and environmental sustainability.

What is Biogas?

Biogas is the high calorific value gas produced by anaerobic decomposition of organic wastes. Biogas can come from a variety of sources including organic fraction of MSW, animal wastes, poultry litter, crop residues, food waste, sewage and organic industrial effluents. Biogas can be used to produce electricity, for heating, for lighting and to power vehicles.

Using manure for energy might seem unappealing, but you don’t burn the organic matter directly. Instead, you burn the methane gas it produces, which is odorless and clean burning.

Biogas Prospects in Rural Areas

Biogas finds wide application in all parts of the world, but it could be especially useful to developing countries, especially in rural areas. People that live in these places likely already use a form of biomass energy — burning wood. Using wood fires for heat, light and cooking releases large amounts of greenhouse gases into the atmosphere.

The smoke they release also has harmful health impacts, particularly when used indoors. You also need a lot to burn a lot of wood when it’s your primary energy source. Collecting this wood is a time-consuming and sometimes difficult as well as dangerous task.

Many of these same communities that rely on wood fires, however, also have an abundant supply of another fuel source. They just need the tools to capture and use it. Many of these have a lot of dung from livestock and lack sanitation equipment. This lack of sanitation creates health hazards.

Turning that waste into biogas could solve both the energy problem and the sanitation problem. Creating a biogas system for a rural home is much simpler than building other types of systems. It requires an airtight pit lined and covered with concrete and a way to feed waste from animals and latrines into the pit. Because the pit is sealed, the waste will decompose quickly, releasing methane.

This methane flows through a PCV pipe to the home where you can turn it on and light on when you need to use it. This system also produces manure that is free of pathogens, which farmers can use as fertilizer.

A similar but larger setup using rural small town business idea can provide similar benefits for urban areas in developing countries and elsewhere.

Benefits of Biogas for Rural Areas

Anaerobic digestion systems are beneficial to developing countries because they are low-cost compared to other technologies, low-tech, low-maintenance and safe. They provide reliable fuel as well as improved public health and sanitation. Also, they save people the labor of collecting large amounts of firewood, freeing them up to do other activities. Thus, biomass-based energy systems can help in rural development.

Biogas for rural areas also has environmental benefits. It reduces the need to burn wood fires, which helps to slow deforestation and eliminates the emissions those fires would have produced. On average, a single home biogas system can replace approximately 4.5 tons of firewood annually and eliminate the associated four tons of annual greenhouse gas emissions, according to the World Wildlife Fund.

Biogas is also a clean, renewable energy source and reduces the need for fossil fuels. Chemically, biogas is the same as natural gas. Biogas, however, is a renewable fuel source, while natural gas is a fossil fuel. The methane in organic wastes would release into the atmosphere through natural processes if left alone, while the greenhouse gases in natural gas would stay trapped underground. Using biogas as a fuel source reduces the amount of methane released by matter decomposing out in the open.

What Can We Do?

Although biogas systems cost less than some other technologies, affording them is often still a challenge for low-income families in developing countries, especially in villages. Many of these families need financial and technical assistance to build them. Both governments and non-governmental organizations can step in to help in this area.

Once people do have biogas systems in place though, with minimal maintenance of the system, they can live healthier, more comfortable lives, while also reducing their impacts on the environment.

Methods for Hydrogen Sulphide Removal from Biogas

The major contaminant in biogas is H2S which is both poisonous and corrosive, and causes significant damage to piping, equipment and instrumentation. The concentration of various components of biogas has an impact on its ultimate end use. While boilers can withstand concentrations of H2S up to 1000 ppm, and relatively low pressures, internal combustion engines operate best when H2S is maintained below 100 ppm.

The common methods for hydrogen sulphide removal from biogas are internal to the anaerobic digestion process – air/oxygen dosing to digester biogas and iron chloride dosing to digester slurry.

Biological Desulphurization

Biological desulphurization of biogas can be performed by using micro-organisms. Most of the sulphide oxidising micro-organisms belong to the family of Thiobacillus. For the microbiological oxidation of sulphide it is essential to add stoichiometric amounts of oxygen to the biogas. Depending on the concentration of hydrogen sulphide this corresponds to 2 to 6 % air in biogas.

biogas-desulphurization

The simplest method of desulphurization is the addition of oxygen or air directly into the digester or in a storage tank serving at the same time as gas holder. Thiobacilli are ubiquitous and thus systems do not require inoculation. They grow on the surface of the digestate, which offers the necessary micro-aerophilic surface and at the same time the necessary nutrients. They form yellow clusters of sulphur. Depending on the temperature, the reaction time, the amount and place of the air added the hydrogen sulphide concentration can be reduced by 95 % to less than 50 ppm.

Biogas Bus

Measures of safety have to be taken to avoid overdosing of air in case of pump failures. Biogas in air is explosive in the range of 6 to 12 %, depending on the methane content). In steel digesters without rust protection there is a small risk of corrosion at the gas/liquid interface.

Iron Chloride Dosing

Iron chloride can be fed directly to the digester slurry or to the feed substrate in a pre-storage tank. Iron chloride then reacts with produced hydrogen sulphide and form iron sulphide salt (particles). This method is extremely effective in reducing high hydrogen sulphide levels but less effective in attaining a low and stable level of hydrogen sulphide in the range of vehicle fuel demands.

In this respect the method with iron chloride dosing to digester slurry can only be regarded as a partial removal process in order to avoid corrosion in the rest of the upgrading process equipment. The method need to be complemented with a final removal down to about 10 ppm.

The investment cost for such a H2S removal process is limited since the only investment needed is a storage tank for iron chloride solution and a dosing pump. On the other hand the operational cost will be high due to the prime cost for iron chloride.