Resource Base for Second-Generation Biofuels

Second-generation biofuels, also known as advanced biofuels, primarily includes cellulosic ethanol. The resource base for the production of second-generation biofuel are non-edible lignocellulosic biomass resources (such as leaves, stem and husk) which do not compete with food resources. The resource base for second-generation biofuels production is broadly divided into three categories – agricultural residues, forestry wastes and energy crops.

second-generation-biofuels

Agricultural Residues

Agricultural residues encompasses all agricultural wastes such as straw, stem, stalk, leaves, husk, shell, peel, pulp, stubble, etc. which come from cereals (rice, wheat, maize or corn, sorghum, barley, millet), cotton, groundnut, jute, legumes (tomato, bean, soy) coffee, cacao, tea, fruits (banana, mango, coco, cashew) and palm oil.

Rice produces both straw and rice husks at the processing plant which can be conveniently and easily converted into energy. Significant quantities of biomass remain in the fields in the form of cob when maize is harvested which can be converted into energy.

Sugarcane harvesting leads to harvest residues in the fields while processing produces fibrous bagasse, both of which are good sources of energy. Harvesting and processing of coconuts produces quantities of shell and fibre that can be utilised while peanuts leave shells. All these lignocellulosic materials can be converted into biofuels by a wide range of technologies.

Forestry Biomass

Forest harvesting is a major source of biomass energy. Harvesting in forests may occur as thinning in young stands, or cutting in older stands for timber or pulp that also yields tops and branches usable for production of cellulosic ethanol.

Biomass harvesting operations usually remove only 25 to 50 percent of the volume, leaving the residues available as biomass for energy. Stands damaged by insects, disease or fire are additional sources of biomass. Forest residues normally have low density and fuel values that keep transport costs high, and so it is economical to reduce the biomass density in the forest itself.

Energy Crops

Energy crops are non-food crops which provide an additional potential source of feedstock for the production of second-generation biofuels. Corn and soybeans are considered as the first-generation energy crops as these crops can be also used as the food crops. Second-generation energy crops are grouped into grassy (herbaceous or forage) and woody (tree) energy crops.

Grassy energy crops or perennial forage crops mainly include switchgrass and miscanthus. Switchgrass is the most commonly used feedstock because it requires relatively low water and nutrients, and has positive environmental impact and adaptability to low-quality land. Miscanthus is a grass mainly found in Asia and is a popular feedstock for second-generation biofuel production in Europe.

Woody energy crops mainly consists of fast-growing tree species like poplar, willow, and eucalyptus. The most important attributes of these class species are the low level of input required when compared with annual crops. In short, dedicated energy crops as feedstock are less demanding in terms of input, helpful in reducing soil erosion and useful in improving soil properties.

Biofuels from Lignocellulosic Biomass

Lignocellulosic biomass consists of a variety of materials with distinctive physical and chemical characteristics. It is the non-starch based fibrous part of plant material.

Lignocellulose is a generic term for describing the main constituents in most plants, namely cellulose, hemicelluloses, and lignin. Lignocellulose is a complex matrix, comprising many different polysaccharides, phenolic polymers and proteins. Cellulose, the major component of cell walls of land plants, is a glucan polysaccharide containing large reservoirs of energy that provide real potential for conversion into biofuels.

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First-generation biofuels (produced primarily from food crops such as grains, sugar beet and oil seeds) are limited in their ability to achieve targets for oil-product substitution, climate change mitigation, and economic growth. Their sustainable production is under scanner, as is the possibility of creating undue competition for land and water used for food and fibre production.

The cumulative impacts of these concerns have increased the interest in developing biofuels produced from non-food biomass. Feedstocks from lignocellulosic materials include cereal straw, bagasse, forest residues, and purpose-grown energy crops such as vegetative grasses and short rotation forests. These second-generation biofuels could avoid many of the concerns facing first-generation biofuels and potentially offer greater cost reduction potential in the longer term.

The largest potential feedstock for biofuels is lignocellulosic biomass, which includes materials such as agricultural residues (corn stover, crop straws and bagasse), herbaceous crops (alfalfa, switchgrass), short rotation woody crops, forestry residues, waste paper and other wastes (municipal and industrial). Bioethanol production from these feedstocks could be an attractive alternative for disposal of these residues.

Importantlylignocellulosic biomass resources do not interfere with food security. Moreover, bioethanol is very important for both rural and urban areas in terms of energy security reason, environmental concern, employment opportunities, agricultural development, foreign exchange saving, socioeconomic issues etc.

Lignocellulosic biomass consists mainly of lignin and the polysaccharides cellulose and hemicellulose. Compared with the production of ethanol from first-generation feedstocks, the use of lignocellulosic biomass is more complicated because the polysaccharides are more stable and the pentose sugars are not readily fermentable by Saccharomyces cerevisiae. 

In order to convert lignocellulosic biomass to biofuels the polysaccharides must first be hydrolysed, or broken down, into simple sugars using either acid or enzymes. Several biotechnology-based approaches are being used to overcome such problems, including the development of strains of Saccharomyces cerevisiae that can ferment pentose sugars, the use of alternative yeast species that naturally ferment pentose sugars, and the engineering of enzymes that are able to break down cellulose and hemicellulose into simple sugars.

Lignocellulosic biomass processing pilot plants have been established in the EU, in Denmark, Spain and Sweden. The world’s largest demonstration facility of lignocellulose ethanol (from wheat, barley straw and corn stover), with a capacity of 2.5 Ml, was first established by Iogen Corporation in Ottawa, Canada. Many other processing facilities are now in operation or planning throughout the world.

Economically, lignocellulosic biomass has an advantage over other agriculturally important biofuels feedstock such as corn starch, soybeans, and sugar cane, because it can be produced quickly and at significantly lower cost than food crops.

Lignocellulosic biomass is an important component of the major food crops; it is the non-edible portion of the plant, which is currently underutilized, but could be used for biofuel production. In short, biofuels from lignocellulosic biomass holds the key to supplying society’s basic needs without impacting the nation’s food supply.

Everything You Should Know About Biomass Storage Methods

Sufficient biomass storage is necessary to accommodate seasonality of production and ensure regular supply to the biomass utilization plant. The type of storage will depend on the properties of the biomass, especially moisture content.

For high moisture biomass intended to be used wet, such as in fermentation and anaerobic digestion systems, wet storage systems can be used, with storage times closely controlled to avoid excessive degradation of feedstock. Storage systems typically used with dry agricultural residues should be protected against spontaneous combustion and excess decomposition, and the maximum storage moisture depends on the type of storage employed.

Consistent and reliable supply of biomass is crucial for any biomass project

Moisture limits must be observed to avoid spontaneous combustion and the emission of regulated compounds. Cost of storage is important to the overall feasibility of the biomass enterprise. In some cases, the storage can be on the same site as the source of the feedstock. In others, necessary volumes can only be achieved by combining the feedstock from a number of relatively close sources. Typically, delivery within about 50 miles is economic, but longer range transport is sometimes acceptable, especially when disposal fees can be reduced.

Storage of biomass fuels is expensive and increases with capacity.

Agricultural residues such as wheat straw, rice husk, rice straw and corn stover are usually spread or windrowed behind the grain harvesters for later baling. Typically these residues are left in the field to air dry to moisture levels below about 14% preferred for bales in stacks or large piles of loose material.

After collection, biomass may be stored in the open or protected from the elements by tarps or various structures. Biomass pelletization may be employed to increase bulk density and reduce storage and transport volume and cost.

Biomass Storage Options

  • Feedstock is hauled directly to the plant with no storage at the production site.
  • Feedstock is stored at the production site and then transported to the plant as needed.
  • Feedstock is stored at a collective storage facility and then transported to the plant from the intermediate storage location.

Biomass Storage Systems

The type of biomass storage system used at the production site, intermediate site, or plant can greatly affect the cost and the quality of the fuel. The most expensive storage systems, no doubt, are the most efficient in terms of maintaining the high fuel quality. Typical storage systems, ranked from highest cost to lowest cost, include:

  • Enclosed structure with crushed rock floor
  • Open structure with crushed rock floor
  • Reusable tarp on crushed rock
  • Outside unprotected on crushed rock
  • Outside unprotected on ground
  • Subterranean

The storage of biomass is often necessary due to its seasonal production versus the need to produce energy all year round. Therefore to provide a constant and regular supply of fuel for the plant requires either storage or multi-feedstock to be used, both of which tend to add cost to the system.

Reducing the cost of handling and stable storage of biomass feedstock are both critical to developing a sustainable infrastructure capable of supplying large quantities of biomass to biomass processing plants. Storage and handling of biomass fuels is expensive and increases with capacity. The most suitable type of fuel store for solid biomass fuel depends on space available and the physical characteristics of the biomass fuel.