Sugarcane Trash as Biomass Resource

Sugarcane trash (or cane trash) is an excellent biomass resource in sugar-producing countries worldwide. The amount of cane trash produced depends on the plant variety, age of the crop at harvest and soil and weather conditions. Typically it represents about 15% of the total above ground biomass at harvest which is equivalent to about 10-15 tons per hectare of dry matter. During the harvesting operation around 70-80% of the cane trash is left in the field with 20-30% taken to the mill together with the sugarcane stalks as extraneous matter.

cane-trash

Cane trash’s calorific value is similar to that of bagasse but has an advantage of having lower moisture content, and hence dries more quickly. Nowadays only a small quantity of this biomass is used as fuel, mixed with bagasse or by itself, at the sugar mill. The rest is burned in the vicinity of the dry cleaning installation, creating a pollution problem in sugar-producing nations.

Cane trash and bagasse are produced during the harvesting and milling process of sugarcane which normally lasts between 6 to 7 months. Cane trash can potentially be converted into heat and electrical energy. However, most of the trash is burned in the field due to its bulky nature and high cost incurred in collection and transportation.

Cane trash could be used as an off-season fuel for year-round power generation at sugar mills. There is also a high demand for biomass as a boiler fuel during the sugar-milling season. Sugarcane trash can also converted in biomass pellets and used in dedicated biomass power stations or co-fired with coal in power plants and cement kilns.

Burning of cane trash creates pollution in sugar-producing countries

Burning of cane trash creates pollution in sugar-producing countries

Currently, a significant percentage of energy used for boilers in sugarcane processing is provided by imported bunker oil. Overall, the economic, environmental, and social implications of utilizing cane trash in the final crop year as a substitute for bunker oil appears promising. It represents an opportunity for developing biomass energy use in the Sugarcane industry as well as for industries / communities in the vicinity.

Positive socio-economic impacts include the provision of large-scale rural employment and the minimization of oil imports. It can also develop the expertise necessary to create a reliable biomass supply for year-round power generation.

Recovery of Cane Trash

Recovery of cane trash implies a change from traditional harvesting methods; which normally consists of destroying the trash by setting huge areas of sugarcane fields ablaze prior to the harvest.  There are a number of major technical and economic issues that need to be overcome to utilize cane trash as a renewable energy resource. For example, its recovery from the field and transportation to the mill, are major issues.

Alternatives include the current situation where the cane is separated from the trash by the harvester and the two are transported to the mill separately, to the harvesting of the whole crop with separation of the cane and the trash carried out at the mill. Where the trash is collected from the field it maybe baled incurring a range of costs associated with bale handling, transportation and storage. Baling also leaves about 10-20% (1-2 tons per hectare) of the recoverable trash in the field.

A second alternative is for the cane trash to be shredded and collected separately from the cane during the harvesting process. The development of such a harvester-mounted cane trash shredder and collection system has been achieved but the economics of this approach require evaluation. A third alternative is to harvest the sugarcane crop completely which would require an adequate collection, transport and storage system in addition to a mill based cleaning plant to separate the cane from the trash .

A widespread method for cane trash recovery is to cut the cane, chop into pieces and then it is blown in two stages in the harvester to remove the trash. The amount of trash that goes along with the cane is a function of the cleaning efficiency of the harvester. The blowers are adjusted to get adequate cleaning with a bearable cane loss.

On the average 68 % of the trash is blown out of the harvester, and stays on the ground, and 32 % is taken to the mill together with the cane as extraneous matter. The technique used to recover the trash staying on the ground is baling. Several baling machines have been tested with small, large, round and square bales. Cane trash can be considered as a viable fuel supplementary to bagasse to permit year-round power generation in sugar mills.

Thus, recovery of cane trash in developing nations of Asia, Africa and Latin America implies a change from traditional harvesting methods, which normally consists of destroying the trash by setting huge areas of cane fields ablaze prior to the harvest. To recover the trash, a new so-called “green mechanical harvesting” scheme will have to be introduced. By recovering the trash in this manner, the production of local air pollutants, as well as greenhouse gases contributing to adverse climatic change, from the fires are avoided and cane trash could be used as a means of regional sustainable development.

Cane Trash Recovery in Cuba

The sugarcane harvesting system in Cuba is unique among cane-producing countries in two important respects. First, an estimated 70 % of the sugarcane crop is harvested by machine without prior burning, which is far higher than for any other country. The second unique feature of Cuban harvesting practice is the long-standing commercial use of “dry cleaning stations” to remove trash from the cane stalks before the stalks are transported to the crushing mills.

Cuba has over 900 cleaning stations to serve its 156 sugar mills. The cleaning stations are generally not adjacent to the mills, but are connected to mills by a low-cost cane delivery system – a dedicated rail network with more than 7000 km of track. The cleaning stations take in green machine-cut or manually cut cane. Trash is removed from the stalk and blown out into a storage area. The stalks travel along a conveyor to waiting rail cars. The predominant practice today is to incinerate the trash at the cleaning station to reduce the “waste” volume.

Collection Systems for Agricultural Biomass

Biomass collection involves gathering, packaging, and transporting biomass to a nearby site for temporary storage. The amount of biomass resource that can be collected at a given time depends on a variety of factors. In case of agricultural residues, these considerations include the type and sequence of collection operations, the efficiency of collection equipment, tillage and crop management practices, and environmental restrictions, such as the need to control soil erosion, maintain soil productivity, and maintain soil carbon levels.

biomass-collection-systems

The most conventional method for collecting biomass is baling which can be either round or square. Some of the important modern biomass collection operations have been discussed below:

Baling

Large square bales are made with tractor pulled balers. A bale accumulator is pulled behind the baler that collects the bales in group of 4 and leaves them on the field. At a later date when available, an automatic bale collector travels through the field and collects the bales.

The automatic bale collector travels to the side of the road and unloads the bales into a stack. If the automatic bale collector is not available bales may be collected using a flat bed truck and a front end bale loader. A loader is needed at the stack yard to unload the truck and stack the bales. The stack is trapped using a forklift and manual labor.

biomass-collection

Loafing

When biomass is dry, a loafer picks the biomass from windrow and makes large stacks. The roof of the stacker acts as a press pushing the material down to increase the density of the biomass. Once filled, loafer transports the biomass to storage area and unloads the stack. The top of the stack gets the dome shape of the stacker roof and thus easily sheds water.

Dry Chop

In this system a forage harvester picks up the dry biomass from windrow, chops it into smaller pieces (2.5 – 5.0 cm). The chopped biomass is blown into a forage wagon traveling along side of the forage harvester. Once filled, the forage wagon is pulled to the side of the farm and unloaded. A piler (inclined belt conveyor) is used to pile up the material in the form of a large cone.

Wet Chop

Here a forage harvester picks up the dry or wet biomass from the windrow. The chopped biomass is blown into a forage wagon that travels along side of the harvester. Once filled, the wagon is pulled to a silage pit where biomass is compacted to produce silage.

Whole Crop Harvest

The entire material (grain and biomass) is transferred to a central location where the crop is fractionated into grain and biomass.  The McLeod Harvester developed in Canada fractionates the harvested crop into straw and graff (graff is a mixture of grain and chaff). The straw is left on the field. Grain separation from chaff and other impurities take place in a stationary system at the farmyard.

McLeod Harvester fractionates the harvested crop into straw and graff

For the whole crop baling, the crop is cut and placed in a windrow for field drying. The entire crop is then baled and transported to the processing yard. The bales are unwrapped and fed through a stationary processor that performs all the functions of a normal combine. Subsequently, the straw is re-baled.

Properties and Uses of POME

Palm Oil processing gives rise to highly polluting wastewater, known as Palm Oil Mill Effluent (POME), which is often discarded in disposal ponds, resulting in the leaching of contaminants that pollute the groundwater and soil, and in the release of methane gas into the atmosphere. POME is an oily wastewater generated by palm oil processing mills and consists of various suspended components. This liquid waste combined with the wastes from steriliser condensate and cooling water is called palm oil mill effluent.

POME

On average, for each ton of FFB (fresh fruit bunches) processed, a standard palm oil mill generate about 1 tonne of liquid waste with biochemical oxygen demand 27 kg, chemical oxygen demand 62 kg, suspended solids (SS) 35 kg and oil and grease 6 kg. POME has a very high BOD and COD, which is 100 times more than the municipal sewage.

POME is a non-toxic waste, as no chemical is added during the oil extraction process, but will pose environmental issues due to large oxygen depleting capability in aquatic system due to organic and nutrient contents. The high organic matter is due to the presence of different sugars such as arabinose, xylose, glucose, galactose and manose. The suspended solids in the POME are mainly oil-bearing cellulosic materials from the fruits. Since the POME is non-toxic as no chemical is added in the oil extraction process, it is a good source of nutrients for microorganisms.

Biogas Potential of POME

POME is always regarded as a highly polluting wastewater generated from palm oil mills. However, reutilization of POME to generate renewable energies in commercial scale has great potential. Anaerobic digestion is widely adopted in the industry as a primary treatment for POME. Biogas is produced in the process in the amount of 20 mper ton FFB. This effluent could be used for biogas production through anaerobic digestion. At many palm oil mills this process is already in place to meet water quality standards for industrial effluent. The gas, however, is flared off.

Palm oil mills, being one of the largest industries in Malaysia and Indonesia, effluents from these mills can be anaerobically converted into biogas which in turn can be used to generate power through CHP systems such as gas turbines or gas-fired engines. A cost effective way to recover biogas from POME is to replace the existing ponding/lagoon system with a closed digester system which can be achieved by installing floating plastic membranes on the open ponds.

As per conservative estimates, potential POME produced from all Palm Oil Mills in Indonesia and Malaysia is more than 50 million m3 each year which is equivalent to power generation capacity of more than 800 GW.

New Trends

Recovery of organic-based product is a new approach in managing POME which is aimed at getting by-products such as volatile fatty acid, biogas and poly-hydroxyalkanoates to promote sustainability of the palm oil industry.  It is envisaged that POME can be sustainably reused as a fermentation substrate in production of various metabolites through biotechnological advances. In addition, POME consists of high organic acids and is suitable to be used as a carbon source.

POME has emerged as an alternative option as a chemical remediation to grow microalgae for biomass production and simultaneously act as part of wastewater treatment process. POME contains hemicelluloses and lignocelluloses material (complex carbohydrate polymers) which result in high COD value (15,000–100,000 mg/L).

POME-Biogas

Utilizing POME as nutrients source to culture microalgae is not a new scenario, especially in Malaysia. Most palm oil millers favor the culture of microalgae as a tertiary treatment before POME is discharged due to practically low cost and high efficiency. Therefore, most of the nutrients such as nitrate and ortho-phosphate that are not removed during anaerobic digestion will be further treated in a microalgae pond. Consequently, the cultured microalgae will be used as a diet supplement for live feed culture.

In recent years, POME is also gaining prominence as a feedstock for biodiesel production, especially in the European Union. The use of POME as a feedstock in biodiesel plants requires that the plant has an esterification unit in the back-end to prepare the feedstock and to breakdown the FFA. In recent years, biomethane production from POME is also getting traction in Indonesia and Malaysia.

Biofuels from Syngas

An attractive approach to converting biomass into liquid or gaseous fuels is direct gasification, followed by conversion of the syngas to final fuel. Ethanol can be produced this way, but other fuels can be produced more easily and potentially at lower cost, though none of the approaches is currently inexpensive.

The choice of which process to use is influenced by the fact that lignin cannot easily be converted into a gas through biochemical conversion. Lignin can, however, be gasified through a heat process. The lignin components of plants can range from near 0% to 35%. For those plants at the lower end of this range, the chemical conversion approach is better suited. For plants that have more lignin, the heat-dominated approach is more effective.

Gasification_Process

Layout of a Typical Biomass Gasification Plant

Once the gasification of biomass is complete, the resulting syngas or synthetic gas can be used in a variety of ways to produce liquid fuels as mentioned below

Fischer-Tropsch (F-T) fuels

The Fischer-Tropsch process converts “syngas” (mainly carbon monoxide and hydrogen) into diesel fuel and naphtha (basic gasoline) by building polymer chains out of these basic building blocks. Typically a variety of co-products (various chemicals) are also produced.

The Fisher-Tropsch process is an established technology and has been proven on a large scale but adoption has been limited by high capital and O&M costs. According to Choren Industries, a German based developer of the technology, it takes 5 tons of biomass to produce 1 ton of biodiesel, and 1 hectare generates 4 tons of biodiesel.

Methanol

Syngas can also be converted into methanol through dehydration or other techniques, and in fact methanol is an intermediate product of the F-T process (and is therefore cheaper to produce than F-T gasoline and diesel).

Methanol is somewhat out of favour as a transportation fuel due to its relatively low energy content and high toxicity, but might be a preferred fuel if fuel cell vehicles are developed with on-board reforming of hydrogen.

Dimethyl ether

DME also can be produced from syngas, in a manner similar to methanol. It is a promising fuel for diesel engines, due to its good combustion and emissions properties. However, like LPG, it requires special fuel handling and storage equipment and some modifications of diesel engines, and is still at an experimental phase.

If diesel vehicles were designed and produced to run on DME, they would become inherently very low pollutant emitting vehicles; with DME produced from biomass, they would also become very low GHG vehicles.

Global Trends in the Biomass Sector

There has been a flurry of activity in the biomass energy sector in recent year, with many new projects and initiatives being given the green light across the globe. This movement has been on both a regional and local level; thanks to the increased efficiency of biomass energy generators and a slight lowering in implementation costs, more businesses and even some homeowners are converting waste-to-energy systems or by installing biomass energy units.

biomass-power-trends

Latest from the United Kingdom

Our first notable example of this comes from Cornwall in the UK. As of this week, a small hotel has entirely replaced its previous oil-based heating system with biomass boilers. Fuelled from wood wastes brought in from a neighboring forest, the BudockVean hotel has so far been successful in keeping the entire establishment warm on two small boilers despite it being the height of British winter – and when warmer weather arrives, plans to install solar panels on the building’s roof is to follow.

Similar projects have been undertaken across small businesses in Britain, including the south-coast city of Plymouth that has just been announced to house a 10MW biomass power plant (alongside a 20MW plant already in construction). These developments arein part thanks to the UK government’s Renewable Heat Incentive which was launched back in 2011. The scheme only provides funding to non-domestic properties currently, but a domestic scheme is in the works this year to help homeowners also move away from fossil fuels.

Initiatives (and Setbacks) in the US

Back across the pond, and the state of New York is also launching a similar scheme. The short-term plan is to increase public education on low-emission heating and persuade a number of large business to make the switch; in the longer term, $800m will be used to install advanced biomass systems in large, state-owned buildings.

A further $40m will be used as part of a competition to help create a series of standalone energy grids in small towns and rural areas, which is a scheme that could hopefully see adopted beyond New York if all goes well.


Unfortunately, the move away from fossil fuels hasn’t been totally plain sailing across the US. Georgia suffered a blow this week as plans to convert a 155MW coal plant to biomass have been abandoned, citing large overheads and low projected returns. The company behind the project have met similar difficulties at other sites, but as of this week are moving ahead with further plans to convert over 2000MW of oil and coal energy generation in the coming years.

Elsewhere in the US, a company has conducted a similar study as to whether biomass plant building will be feasible in both Florida and Louisiana. Surveying has only just been completed, but if things go better than the recent developments in Georgia, the plants will go a long way to converting biomass to fertilizer for widespread use in agriculture in both states.

Far East Leading the Way

One country that is performing particularly well in biomass energy investment market is Japan. Biomass is being increasingly used in power plants in Japan as a source of fuel, particularly after the tragic accident at Fukushima nuclear power plant in 2011.  Palm kernel shell (PKS) has emerged as a favorite choice of biomass-based power plants in the country. Most of these biomass power plants use PKS as their energy source, and only a few operate with wood pellets. Interestingly, most of the biomass power plants in Japan have been built after 2015..

On the contrary, the US and Europe saw a fairly big fall in financing during this period; it should be noted, however, that this relates to the green energy investment market as a whole as opposed to biomass-specific funding. The increase seen in Japan has been attributed to an uptake in solar paneling, and if we look specifically to things such as the global demand for biomass pellets, we see that the most recent figures paint the overall market in a much more favorable light for the rest of the world.

Brighter Times Ahead

All in all, it’s an exciting time for the biomass industry despite the set backs which are being experienced in some regions.  On the whole, legislators and businesses are working remarkably well together in order to pave the way forward – being a fairly new market (from a commercially viable sense at least), it has taken a little while to get the ball rolling, but expect to see it blossom quickly now that the idea of biomass is starting to take hold.

Palm Kernel Shells: An Attractive Biomass Fuel for Europe

Europe is targeting an ambitious renewable energy program aimed at 20% renewable energy in the energy mix by 2020 with biomass energy being key renewable energy resource across the continent. However, the lack of locally-available biomass resources has hampered the progress of biomass energy industry in Europe as compared with solar and wind energy industries. The European biomass industry is largely dependent on wood pellets and crop residues.

palm-kernel-shells

Europe is the largest producer of wood pellets, which is currently estimated at 13.5 million tons per year while its consumption is 18.8 million tons per year. The biggest wood pellet producing countries in Europe are Germany and Sweden. Europe relies on America and Canada to meet its wood pellet requirements and there is an urgent need to explore alternative biomass resources. In recent years, palm kernel shells (popularly known as PKS) from Southeast Asia and Africa has emerged as an attractive biomass resources which can replace wood pellets in biomass power plants across Europe.

What are Palm Kernel Shells

Palm kernel shells are the shell fractions left after the nut has been removed after crushing in the Palm Oil Mill. Kernel shells are a fibrous material and can be easily handled in bulk directly from the product line to the end use. Large and small shell fractions are mixed with dust-like fractions and small fibres.

Moisture content in kernel shells is low compared to other biomass residues with different sources suggesting values between 11% and 13%. Palm kernel shells contain residues of Palm Oil, which accounts for its slightly higher heating value than average lignocellulosic biomass. Compared to other residues from the industry, it is a good quality biomass fuel with uniform size distribution, easy handling, easy crushing, and limited biological activity due to low moisture content.

Press fibre and shell generated by the palm oil mills are traditionally used as solid fuels for steam boilers. The steam generated is used to run turbines for electricity production. These two solid fuels alone are able to generate more than enough energy to meet the energy demands of a palm oil mill.

Advantages of Palm Kernel Shells

PKS has almost the same combustion characteristics as wood pellets, abundantly available are and are cheap. Indonesia and Malaysia are the two main producers of PKS. Indonesian oil palm plantations cover 12 million hectares in Indonesia and 5 million hectares in Malaysia, the number of PKS produced from both countries has exceeded 15 million tons per year. Infact, the quantity of PKS generated in both countries exceeds the production of wood pellets from the United States and Canada, or the two largest producers of wood pellets today.

Interestingly, United States and Canada cannot produce PKS, because they do not have oil palm plantations, but Indonesia and Malaysia can also produce wood pellets because they have large forests. The production of wood pellets in Indonesia and Malaysia is still small today, which is less than 1 million tons per year, but the production of PKS is much higher which can power biomass power plants across Europe and protect forests which are being cut down to produce wood pellets in North America and other parts of the world.

PKS as a Boiler Fuel

Although most power plants currently use pulverized coal boiler technology which reaches around 50% of the world’s electricity generation, the use of grate combustion boiler technology and fluidized bed boilers is also increasing. Pulverized coal boiler is mainly used for very large capacity plants (> 100 MW), while for ordinary medium capacity uses fluidized bed technology (between 20-100 MW) and for smaller capacity with combustor grate (<20 MW). The advantage of boiler combustion and fluidized bed technology is fuel flexibility including tolerance to particle size.

When the pulverized coal boiler requires a small particle size (1-2 cm) like sawdust so that it can be atomized on the pulverizer nozzle, the combustor grate and fluidized bed the particle size of gravel (max. 8 cm) can be accepted. Based on these conditions, palm kernel shells has a great opportunity to be used as a boiler fuel in large-scale power plants.

Use of PKS in pulverized coal boiler

There are several things that need to be considered for the use of PKS in pulverized coal boilers. The first thing that can be done is to reduce PKS particle size to a maximum of 2 cm so that it can be atomized in a pulverized system. The second thing to note is the percentage of PKS in coal, or the term cofiring. Unlike a grate and a fluidized bed combustion that can be flexible with various types of fuel, pulverized coal boilers use coal only. There are specific things that distinguish biomass and coal fuels, namely ash content and ash chemistry, both of which greatly influence the combustion characteristics in the pulverized system.

PKS-biomass

PKS has emerged as an attractive biomass commodity in Japan

Coal ash content is generally greater than biomass, and coal ash chemistry is very different from biomass ash chemistry. Biomass ash has lower inorganic content than coal, but the alkali content in biomass can change the properties of coal ash, especially aluminosilicate ash.

Biomass cofiring with coal in small portions for example 3-5% does not require modification of the pulverized coal power plant. For example, Shinci in Japan with a capacity of 2 x 1,000 MW of supercritical pulverized fuel with 3% cofiring requires 16,000 tons per year of biomass and no modification. Similarly, Korea Southeast Power (KOSEP) 5,000 MW with 5% cofiring requires 600,000 tons per year of biomass without modification.

PKS cofiring in coal-based power plants

Pulverized coal-based power plants are the predominant method of large-scale electricity production worldwide including Europe. If pulverised fuel power plants make a switch to co-firing of biomass fuels, it will make a huge impact on reducing coal usage, reducing carbon emissions and making a transition to renewable energy. Additionally, the cheapest and most effective way for big coal-based power plants to enter renewable energy sector is biomass cofiring. Palm kernel shells can be pyrolyzed to produce charcoal while coal will produce coke if it is pyrolyzed. Charcoal can be used for fuel, briquette production and activated charcoal.

Torrified PKS: An Attractive Biomass Commodity in West Africa

Even though palm kernel shell has many similarities with wood pellets, it is not easy to reduce its size which makes it difficult for its optimum cofiring with coal in power plants and industries. Few years ago, Indonesia had exported PKS to Poland for cofiring purposes but because PKS was difficult to make powder (low grindability) it made cofiring performance poor, so the use of PKS for cofiring is currently discontinued.

palm-kernel-shells

 

To improve the quality of PKS, especially for the use of cofiring, PKS must be processed with torrefaction (mild pyrolysis). With the torrefaction process, it becomes easier to make powder from PKS, so that the desired particle size for cofiring is easier to obtain. Another advantage of the torrefaction process is that the caloric value of PKS will also increase by about 20%, Torrified biomass is hygroscopic which means ease in indoor as well as outdoor storage.

During the torrefaction process, PKS is heated at a temperature of around 230 to 300 °C in the absence of oxygen. With continuous pyrolysis technology, torrified PKS production can be carried out at large capacities. The need for biomass fuel for electricity generation is also large, usually requiring 10 thousand tons for each shipment. PKS torrified producers must be able to reach this capacity. The production of 10 thousand tons of PKS that are burned can be done per month or several months, for example, to reach 10 thousand tons it takes 2 months because the factory capacity is 5000 tons per month.

PKS-torrefaction

In general, the advantages of the PKS torrefaction process are as follows:

  • It increases the O/C ratio of the biomass, which improves its thermal process
  • It reduces power requirements for size reduction, and improves handling.
  • It offers cleaner-burning fuel with little acid in the smoke.
  • Torrefied PKS absorbs less moisture when stored.
  • One can produce superior-quality PKS pellets with higher volumetric energy density.

Pelletizing of torrefied PKS can be an option to increase the energy density in volume basis. The pelletizing process resolves some typical problems of biomass fuels: transport and storing costs are minimized, handling is improved, and the volumetric calorific value is increased. Pelletization may not increase the energy density on a mass basis, but it can increase the energy content of the fuel on a volume basis.

Africa, especially West Africa, which has many palm oil plantations and also the location where the palm oil trees originate, can supply torrified PKS to Europe to meet its rapidly-increasing biomass fuel demand.

In Africa, palm kernel shell is generally produced from PKO mills. CPO production is generally carried out on a small scale and only processes the fiber portion of the palm oil fruit. This palm oil mesocarp fibre is processed to produce CPO, while the nut that consist kernels and shells are processed elsewhere to produce the main product of PKO (palm kernel oil). PKO mills are usually quite large by collecting nuts from these small scale CPO producers. PKS is produced from this PKO mills.

nut-cracker-machine-palm-mill

The nut cracker machine separates kernel and shell

The distance between Africa and Europe is also closer than Europe to Malaysia and Indonesia. Currently, even though Europe has produced wood pellets for their renewable energy program to mitigate climate change and the environment, the numbers are still insufficient and they are importing wood pellets from the United States and Canada in large quantities. European wood pellet imports are estimated to reach more than 1.5 million tons per year. Torrified PKS from West Africa can help in meeting the biomass fuel demands for power plants across Europe.

For more information about PKS trading opportunities and our technical consulting services, please email on salman@bioenergyconsult.com or eko.sb.setyawan@gmail.com

Energy Potential of Bagasse

Sugarcane is one of the most promising agricultural sources of biomass energy in the world. Sugarcane produces mainly two types of biomass – sugarcane trash and bagasse. Sugarcane trash is the field residue remaining after harvesting the sugarcane stalk while bagasse is the fibrous residue left over after milling of the sugarcane, with 45-50% moisture content and consisting of a mixture of hard fibre, with soft and smooth parenchymatous (pith) tissue with high hygroscopic property.

Bagasse contains mainly cellulose, hemicellulose, pentosans, lignin, sugars, wax, and minerals. The quantity obtained varies from 22 to 36% on sugarcane and is mainly due to the fibre portion in the sugarcane and the cleanliness of sugarcane supplied, which, in turn, depends on harvesting practices.

The composition of bagasse depends on the variety and maturity of sugarcane as well as harvesting methods applied and efficiency of the sugar processing. Bagasse is usually combusted in furnaces to produce steam for power generation. Bagasse is also emerging as an attractive feedstock for bioethanol production.

It is also utilized as the raw material for production of paper and as feedstock for cattle. The value of Bagasse as a fuel depends largely on its calorific value, which in turn is affected by its composition, especially with respect to its water content and to the calorific value of the sugarcane crop, which depends mainly on its sucrose content.

Moisture contents is the main determinant of calorific value i.e. the lower the moisture content, the higher the calorific value. A good milling process will result in low moisture of 45% whereas 52% moisture would indicate poor milling efficiency. Most mills produce Bagasse of 48% moisture content, and most boilers are designed to burn Bagasse at around 50% moisture.

Bagasse also contains approximately equal proportion of fibre (cellulose), the components of which are carbon, hydrogen and oxygen, some sucrose (1-2 %), and ash originating from extraneous matter. Extraneous matter content is higher with mechanical harvesting and subsequently results in lower calorific value.

For every 100 tons of Sugarcane crushed, a Sugar factory produces nearly 30 tons of wet Bagasse. Bagasse is often used as a primary fuel source for Sugar mills; when burned in quantity, it produces sufficient heat and electrical energy to supply all the needs of a typical Sugar mill, with energy to spare. The resulting CO2 emissions are equal to the amount of CO2 that the Sugarcane plant absorbed from the atmosphere during its growing phase, which makes the process of cogeneration greenhouse gas-neutral.

35MW Bagasse and Coal CHP Plant in Mauritius

Cogeneration of bagasse is one of the most attractive and successful biomass energy projects that have already been demonstrated in many sugarcane producing countries such as Mauritius, Reunion Island, India and Brazil. Combined heat and power from sugarcane in the form of power generation offers renewable energy options that promote sustainable development, take advantage of domestic resources, increase profitability and competitiveness in the industry, and cost-effectively address climate mitigation and other environmental goals.

Torrefaction of Biomass: An Overview

To improve the quality of biomass, especially for cofiring purposes, biomass waste can be processed with torrefaction (also known as mild pyrolysis). With the torrefaction process, it becomes easier to make powder (high grindability) so that the desired particle size for cofiring of biomass is easier to obtain. Another advantage of the torrefaction process is that the caloric value of biomass increases by about 20%. Torrified biomass is essentially hydropobic which means ease in storage including outdoor storage. This condition also makes it easier to handle and use, in addition to reduction in transportation costs.

torrefaction-of-biomass

What is Torrefaction

Torrefaction, which is currently being considered for effective biomass utilization, is also a form of pyrolysis. In this process (named for the French word for roasting), the biomass is heated to 230 to 300 °C without contact with oxygen. For comparison, pyrolysis of biomass is typically carried out in a relatively low temperature range of 300 to 650 °C compared to 800 to 1000 °C for gasification. Torrefaction is a relatively new process that heats the biomass in the absence of air to improve its usefulness as a fuel.

Torrefaction, a process different from carbonization, is a mild pyrolysis process carried out in a temperature range of 230 to 300 °C in the absence of oxygen. During this process the biomass dries and partially devolatilizes, decreasing its mass while largely preserving its energy content. The torrefaction process removes H2O and CO2 from the biomass. As a result, both the O/C and the H/C ratios of the biomass decrease.

steps-in-biomass-torrefaction

Advantages of Biomass Torrefaction

Torrefaction of biomass improves its energy density, reduces its oxygen-to-carbon (O/C) ratio, and reduces its hygroscopic nature. Torrefaction also increases the relative carbon content of the biomass. The properties of a torrefied biomass depends on torrefaction temperature, time, and on the type of biomass feed.

Torrefaction also modifies the structure of the biomass, making it more friable or brittle. This is caused by the depolymerization of hemicellulose. As a result, the process of size reduction becomes easier, lowering its energy consumption and the cost of handling. This makes it easier to cofire biomass in a pulverized coal-fired boiler or gasify it in an entrained-flow reactor.

Another special feature of torrefaction is that it reduces the hygroscopic property of biomass; therefore, when torrefied biomass is stored, it absorbs less moisture than that absorbed by fresh biomass. For example, while raw bagasse absorbed 186% moisture when immersed in water for two hours, it absorbed only 7.6% moisture under this condition after torrefying the bagasse for 60 minutes at 250 °C (Pimchua et al., 2009). The reduced hygroscopic (or enhanced hydrophobic) nature of torrefied biomass mitigates one of the major shortcomings for energy use of biomass.

In biomass, hemicellulose is like the cement in reinforced concrete, and cellulose is like the steel rods. The strands of microfibrils (cellulose) are supported by the hemicellulose. Decomposition of hemicellulose during torrefaction is like the melting away of the cement from the reinforced concrete. Thus, the size reduction of biomass consumes less energy after torrefaction. During torrefaction the weight loss of biomass comes primarily from the decomposition of its hemicellulose constituents. Hemicellulose decomposes mostly within the temperature range 150 to 280 °C, which is the temperature window of torrefaction.

torrified-biomass

As we can see from figure above, the hemicellulose component undergoes the greatest amount of degradation within the 200 to 300 °C temperature window. Thus, hemicellulose decomposition is the primary mechanism of torrefaction. At lower temperatures (< 160 °C), as biomass dries it releases H2O and CO2. Water and carbon dioxide, which make no contribution to the energy in the product gas, constitute a dominant portion of the weight loss during torrefaction.

Above 180 °C, the reaction becomes exothermic, releasing gas with small heating values. The initial stage (< 250 °C) involves hemicellulose depolymerization, leading to an altered and rearranged polysugar structures. At higher temperatures (250–300 °C) these form chars, CO, CO2, and H2O. The hygroscopic property of biomass is partly lost in torrefaction because of the destruction of OH groups through dehydration, which prevents the formation of hydrogen bonds.

How Batteries Can Benefit From Biomass Energy?

Organisations and more importantly, battery manufacturers are recognising the need to overcome the problem of global warming. The objective is to develop ways of producing carbon-neutral sources of energy. One of the areas currently being explored is the use of biomass resources to create sustainable, eco-friendly batteries which are suitable for use across a wide range of business sectors. With different forms of biomass energy available, the challenge is finding products that provide high performance along with being commercially viable.

Biomass-Resources

A quick glance at popular biomass resources

What is Biomass Energy?

Biomass is something that we are all familiar with. It is derived from plants and animals and is now becoming an increasingly viable form of renewable energy. Initially, the energy comes from the sun, and in plants, it is converted via photosynthesis.

Regardless of its origin, the biomass will either be converted into biogas, biofuels or burnt directly to create heat. Of course, different sources of biomass produce varying amounts of energy, affecting their efficiency. As a result, high precision battery testing equipment is required to ascertain their viability.

Forms of Biomass Used for Energy

Wood and Products: Renewable sources of timber and the by-products of wood such as wood chip are burned in the home to create heat and in industry, burned to generate electricity. Typically, softwood such as pine is used as it is quicker to replenish than hardwood such as oak.

Agricultural Crops and Waste: With large amounts of waste produced from the farming sector, it is natural that this is an ideal source of energy. The materials are either converted to liquid biofuels or burned directly to generate heat or electricity.

Food and Household Waste: The amount of waste households produced has been increasing annually, and up until recently, the majority was disposed of it landfill sites. Nowadays, this garbage is thermochemically processed in waste-to-energy plants to produce electricity or converted into biogas at existing landfill sites.

Animal Manure and Human Waste: We frequently hear about the link between animal waste and global warming. Inevitably, the same is also true of human waste. Both can be converted into biogas and burned as a fuel.

How is Biomass Converted to Energy?

Biomass can be converted to energy using different methods depending on the source. Solid forms of biomass such as garbage and wood are generally burned to created heat while other types will be initially converted into either biogas or biofuels such as ethanol or other biodiesel-related fuels used to power vehicles or generators.

Human sewage and animal manure are placed in vessels known as digesters to create biogas. Liquid fuels such as biodiesel are derived from oils and animal fats. Any form of biomass must be burned at some point to generate energy.

Biomass and Batteries

The most common form of battery used in domestic appliances and mobile devices is lithium-ion batteries. However, the performance and capacity are still below what is demanded by manufacturers and consumers. As a result, manufacturers are investigating alternatives such as biomass. Naturally, high precision testing equipment such as that produced by Arbin is required to assess their potential and commercial viability accurately.

The potential of elemental sulphur has been explored although due to its poor electrical conductivity, has failed to make it onto the mass market. A composite of sulphur and porous carbon appears to be a far more viable option although this is a complicated and time-consuming process. Carbon is one of the best conductors available, albeit at a relatively high cost. Therefore, the objective is to source carbon from biowaste, such as popular catkin that can be combined with sulphur. Popular catkin is a highly porous carbon and ideal for Li/S batteries.

High Precision Battery Testing

High precision battery testing is required to establish the commercial viability of popular catkin and other biowaste products. Marginal improvement could have a significant impact and give cell manufacturers a competitive advantage over their rivals.

Naturally, extensive research needs to be conducted to assess a variety of bioproducts that are presenting themselves as potentially viable alternative products. Increasing battery capacity and battery life is something that is required in several sectors such as with EVs, mobile devices and home appliances. Major manufacturers will be eagerly awaiting the findings of testing that is currently ongoing.