A Glance at Drop-in Biofuels

drop-in-biofuelsBiofuel commercialization has proved to be costly and lingering than expected due to its high production cost and modification to flexibility in engines. Drop-in fuels are alternatives to existing liquid fuels without any significant modification in engines and infrastructures. According to IEA, “Drop-in biofuels are liquid bio-hydrocarbons that are functionally equivalent to petroleum fuels and are fully compatible with existing petroleum infrastructure”.

What are Drop-in Biofuels

Drop-in biofuels are can be produced from oilseeds via trans-esterification, lignocellulosic biomass via thermochemical process, sugars and alcohol via biochemical conversion or by hybrids of the above methods. Drop-in fuels encompass high hydrogen to carbon ratio with no/low sulfur and oxygen content, low water solubility and high carbon bond saturation. In short drop-in fuel is a modified fuel with close functional resemblance to fossil fuel.

Existing biofuels – bioethanol and biodiesel – have wide variation from fossil fuels in their blend wall properties – high oxygen content, hydrophilicity, energy density and mainly compatibility in existing engines and infrastructures. Oxygenated groups in biofuel have a domino effect such as reduction in the energy density, production of impurities which are highly undesirable to transportation components, instability during storage etc.

Major advantages of drop-in fuels over existing fuels are as follows:

  • Reduced sulphur oxide emissions by ultra low sulphur content.
  • Reduced ignition delay by high cetane value
  • Reduced hydrocarbons and nitrogen oxides emissions
  • Low aromatic content
  • Low olefin content, presence of olefin compounds undergo auto-oxidation leading to surface depositions.
  • High saturates, therefore leaving minimum residues
  • Low particulate emissions
  • No oxygenates therefore has high stability.

Potential Biomass Feedstock

Drop-in biofuels can be produced from various biomass sources- lipids (vegetable oils, animal fats, greases, and algae) and cellulosic material (such as crop residues, woody biomass, and dedicated energy crops). The prominent technologies for biomass conversion to drop-in fuel are the thermochemical and the biochemical process.

The major factor playing role in selection of biomass for thermochemical methods is the energy content or heating value of the material, which is correlated with ash content. Wood, wood chips accounts for less than 1% ash content, which is favorable thermal processing than biochemical process, whereas straws, husks, and majority of the other biomass have ash content ranging up to 25% of dry mass.

Free sugar generating plants such as sugarcane and sweet sorghum, are desirable feedstock for Acetone-Butanol-Ethanol fermentation and have been widely implemented. Presently there is a focus to exploit lignocellulosic residues, rich in hydrocarbon, for fuel production. However, this biomass requires harsh pretreatment to remove lignin and to transform holocellulose (cellulose & hemicelluloses) into fermentable products.

The lignocellulose transformation technology must be circumspectly chosen by its life cycle assessment, as it resists any changes in their structural integrity owing to its complexity. Lignocellulosic biomass, when deoxygenated, has better flexibility to turn to drop-in fuels. This is because, in its native state of the feedstock, each oxygen atom consumes two hydrogen atoms during combustion which in turn reduces effective H: C ratio. Biomass feedstock is characterized with oxygen up to 40%, and higher the oxygen content higher it has to be deoxygenated.

Thermochemical Route

Thermochemical methods adopted for biomass are pyrolysis and gasification, on thermolysis of biomass produce intermediate gas (syngas) and liquid (bio crude) serving as precursors for drop-in fuel. Biomass when exposed to temperature of 500oC-600oC in absence of oxygen (pyrolysis) produce bio-oil, which constitutes a considerable percentage of oxygen. After down streaming by hydroprocessing (hydrotreating and hydrocracking) the rich hydrocarbon tar (bio-oil) can be converted to an efficient precursor for drop-in fuel.

At a higher temperature, above 700, under controlled oxygen, biomass can be converted to liquid fuel via gas phase by the process, gasification. Syngas produced is converted to liquid fuel by Fischer-Tropsch with the help of ‘water gas shift’ for hydroprocessing. Hydroprocessing after the thermochemical method is however costly and complex process in case of pyrolysis and inefficient biomass to fuel yield with gasification process.

Biochemical Pathway

The advanced biocatalytic processes can divert the conventional sugar-ethanol pathway and convert sugars to fatty acids. Modified microbial strain with engineered cellular machineries, can reroute the pathway to free fatty acid that can be transformed into butanol or drop-in fuel with necessary processing.

Schematic for the preparation of jet fuel from biomass

Schematic for the preparation of jet fuel from biomass

Biological processing requires operation under the stressful conditions on the organisms to reroute the pathways, in additional to lowering NADPH (hydrogen) consumption. Other value added products like carboxylic acid, polyols, and alcohol in the same biological routes with lower operational requirements have higher market demands and commercial success. Therefore little attention is given by chemical manufacturers to the biological pathways for drop-in fuel production.

The mechanisms of utilization of lignocellulosic biomass to fuel by biological pathway rely heavily on the availability of monomeric C5 and C6 sugars during fermentation. Ethanol is perhaps the best-known and commercially successful alcohol from ABE fermentation. However, butanol has various significant advantages over ethanol- in the perception of energy content, feasibility to existing infrastructures, zero blend wall, safety and clean aspects. Although butanol is a closer drop-in replacement, existing biofuel ethanol, is a major commercial competitor. Low yield from fermentation due to the toxicity of butanol and complexity in down streaming are the vital reasons that hamper successful large scale butanol production.

Challenges to Overcome

Zero oxygen and sulphur content mark major challenges for production of drop-in fuels from conventional biomass. This demands high hydrogen input on the conventional biomass, with H: C ratio below 0.5, like sugar, starch, cellulose, lignocellulose to meet the effective hydrogen to carbon ratio of 2 as in drop-in fuel. This characterizes most of the existing biomass feedstock as a low-quality input for drop-in fuels. However oleochemicals like fats, oils, and lipids have closer H: C ratio to diesel, gasoline and drop-in fuels, thus easier to conversion. Oleochemical feedstock has been commercially successful, but to prolong in the platform will be a major challenge. Lipid feedstock is generally availed from crop-based vegetable oil, which is used in food sectors. Therefore availability, food security concerns, and economics are the major constraints to sustaining the raw material. Consequently switching to lignocellulosic biomass feedstock for drop-in holds on.

Conclusions

Despite the hurdles on biomass characteristics and process technology for drop-in fuel, it is a vital requirement to switch to better replacement fuel for fossil fuel, considering environmental and economic benefits. Understanding its concepts and features, drop-in fuel, can solve existing greenhouse emission debate on current biofuels. Through crucial ambiguities existing on future of alternative fuels, drop-in fuel has a substantial potential to repute itself as an efficient sustainable eco-friendly fuel in the naear future.

References

  • Neal K Van Alfen: ENCYCLOPEDIA OF AGRICULTURE AND FOOD SYSTEMS, Elsevier, Academic Press.
  • Pablo Domínguez de María John: INDUSTRIAL BIORENEWABLES:A Practical Viewpoint: Wiley & Sons.
  • Ram Sarup Singh, Ashok Pandey, Edgard Gnansounou: BIOFUELS- PRODUCTION AND FUTURE PERSPECTIVES, CRC Press.
  • Satinder Kaur Brar, Saurabh Jyoti Sarma, Kannan Pakshirajan : PLATFORM CHEMICAL BIOREFINERY-FUTURE GREEN CHEMISTRY, Elsevier.
  • Sergios Karatzos, James D. McMillan, Jack N. Saddle: Summary of IEA BIOENERGY TASK 39 REPORT-THE POTENTIAL AND CHALLENGES OF DROP-IN BIOFUELS, IEA Bioenergy.
  • Vijai Kumar Gupta, Monika Schmoll, Minna Maki, Maria Tuohy, Marcio Antonio Mazutti: APPLICATIONS OF MICROBIAL ENGINEERING, CRC Press.

Biomass Market in Japan: Perspectives

Biomass-Power-Plant-JapanBiomass is being increasingly used in power plants in Japan as a source of fuel, particularly after the tragic accident at Fukushima nuclear power plant in 2011.  Palm kernel shell (PKS) has emerged as a favorite choice of biomass-based power plants in the country. Most of these biomass power plants use PKS as their energy source, and only a few operate with wood pellets. Interestingly, most of the biomass power plants in Japan have been built after 2015.

Palm Kernel Shells

Palm Kernel Shell is generating very good traction as a renewable energy resource and biomass commodity in Japan. This is because PKS is the cheapest biomass fuel and is available in large quantities across Southeast Asia. PKS, a biomass waste generated by palm oil mills, can be found in plentiful quantities in Indonesia, Malaysia and Thailand.

PKS must meet the specifications before being exported to Japan. Some key specifications for PKS exports are: moisture content, calorific value and impurities or contaminants (foreign materials). All three variables must meet a certain level to achieve export quality. Japanese markets or their consumers generally require contaminants from 0.5 to 2%, while European 2% – 3%. Japan usually buys with a volume of 10,000 tonnes per shipment, so PKS suppliers must prepare a sufficient stockpile of the PKS. The location of PKS stockpile that is closest to the seaport is the ideal condition to facilitate transportation of shipment.

PKS has emerged as an attractive biomass commodity in Japan

PKS has emerged as an attractive biomass commodity in Japan

Wood Pellets

Wood pellets are mostly produced in from wood waste such as sawdust, wood shaving, plywood waste, forestry residues and related materials. The development potential for quantity enlargement is also possible with energy plantations. Technically the properties of wood pellets are not much different from the PKS.

Wood pellet price is more expensive than PKS. Wood pellet production process is more complex than PKS, so wood pellet is categorized as finished product. The quality of wood pellet is generally viewed from its density, calorific value and ash content. Indonesia wood pellet export is not as big as PKS, it is also because of the limited producers of wood pellet itself. Japan buys wood pellets from Indonesia mostly for testing on their biomass power plants. Shipping or export by container is still common in wood pellet sector because the volume is still small. Currently, the world’s leading producer of wood pellets come from North America and Scandinavia. Even for Indonesia itself wood pellet is a new thing, so its production capacity is also not big.

Future Perspectives

For a short-term solution, exporting PKS is a profitable business.  Wood pellets with raw materials from energy plantations by planting the legume types such as calliandra are medium-term solutions to meet biomass fuel needs in Japan.  Torrefaction followed by densification can be a long-term orientation. Torrified pellet is superior to wood pellet because it can save transportation and facilitate handling, are hydrophobic and has higher calorific value.

 

Bioethanol: Challenges in India

bioethanol-indiaGlobal demand for fuel efficiency, environmental quality and energy security have elicited global attention towards liquid biofuels, such as bioethanol and biodiesel. Around the world, governments have introduced various policy measurements, mandatory fuel blending programmes, incentives for flex-fuel vehicles and agricultural subsidies for the farmers. In India, the government launched Ethanol Blended Petrol (EBP) programme in January 2013 for 5% ethanol blended petrol. The policy had significant focus on India’s opportunity to agricultural and industrial sectors with motive of boosting biofuel usage and reducing the existing dependency on fossil fuel.

The Government of India initiated significant investments in improving storage and blending infrastructure. The National Policy on Biofuels has set a target of 20% blending of biofuel by 2017. However, India has managed to achieve only 5% by September 2016 due to certain technical, market and regulatory hurdles.

In India, sugar cane molasses is the major resource for bioethanol production and inconsistency of raw material supply holds the major liability for sluggish response to blending targets.  Technically speaking, blend wall and transportation-storage are the major challenges towards the biofuel targets. Blending wall is the maximum percent of ethanol that can be blended to fuel without decreasing the fuel efficiency. Various vehicles are adaptable to various blending ratio based on the flexibility of engines. The technology for the engine modification for flex fuel is not new but making the engines available in India along with the supply chain and calibrating the engine for Indian conditions is the halting phase. The commonly used motor vehicles in the country are not effectual with flex fuel.

Sugarcane molasses is the most common feedstock for bioethanol production in India

Sugarcane molasses is the most common feedstock for bioethanol production in India

Ethanol being a highly flammable liquid marks obligatory safety and risk assessment measures during all phases of production, storage and transportation. The non-uniform distribution of raw material throughout the country, demands a compulsory transportation and storage, especially inter-state movement, encountering diverse climatic and topographic conditions.

Major ethanol consumers in India are potable liquor sector (45%), alcohol based chemical industry (40%), the rest for blending and other purposes. The yearly profit elevation in major sectors is a dare to an economical ethanol supply for Ethanol Blending Programme. Drastic fluctuation in pricing of sugar cane farming and sugar milling resulted to huge debt to farmers by mill owners. Gradually the farmers shifted from sugarcane cultivation other crops.

Regulatory and policy approaches on excise duty on storage and transportation of ethanol and pricing strategy of ethanol compared to crude oil are to be revised and implemented effectively. Diversifying the feedstocks and advanced technology for domestic ethanol production in blending sectors are to be fetched out from research laboratories to commercial scale. Above all the knowledge of economic and environmental benefits of biofuel like reduction in pollutants and import bills, need to be amplified for the common man.

Miscanthus: Reducing the Establishment Costs

Miscanthus-Elephant-GrassMiscanthus has been lauded as a dynamic high potential biomass crop for some time now due to its high yields, low input requirements and perennial nature. Miscanthus is commonly used as a biomass fuel to produce heat and electricity through combustion, but studies have found that miscanthus can produce similar biogas yields to maize when harvested at certain times of the year.  Miscanthus is a C4 grass closely related to maize and sugarcane, it can grow to heights of three metres in a single growing season.

High Establishment Costs

However, high establishment costs have impeded the popularity of the crop. High establishment costs of miscanthus are as a result of the sterile nature of the crop, which means that miscanthus cannot be propagated from seed and instead must be propagated from vegetative material. The vegetative material commonly used is taken from the root structure known as rhizomes; rhizome harvesting is a laborious process and when combined with low multiplication rates, results in a high cost for miscanthus rhizomes. The current figure based on Irish figures is €1,900 ha for rhizomes.

Promising Breakthrough

Research conducted in Teagasc Oak Park Carlow Ireland, suggests that there may be a cost effective of method of propagating miscanthus by using the stem as the vegetative material rather than having to dig up expensive rhizomes. The system has been proven in a field setting over two growing seasons and plants have been shown to be perennial.

A prototype planter suitable for commercial up scaling has been developed to sow stem segments of miscanthus. Initial costs are predicted at €130 ha for plant material. The image below shows the initial stem that was planted in a field setting and the shoots, roots, and rhizome developed by the stem at the end of the first growing season.

miscanthus-stem

Feedstock for AD Plants

Switching from maize to miscanthus as a feedstock for anaerobic digestion plants would increase profitability and boost the GHG abatement credentials of the systems. Miscanthus is a perennial crop which would provide a harvest every year once established for 20 years in a row without having to be replanted compared to maize which is replanted every year. This would provide an obvious economic saving as well as allowing carbon sequestration in the undisturbed soil.

There would be further GHG savings from the reduced diesel consumption required for the single planting as opposed to carrying out heavy seedbed cultivation each year for maize. Miscanthus harvested as an AD feedstock would also alleviate soil compaction problems associated with maize production through an earlier harvest in more favourable conditions.

Future Perspectives

Miscanthus is a nutrient efficient crop due to nutrient cycling. With the onset of senescence nutrients in the stem are transferred back to the rhizome and over-wintered for the following year’s growth. However the optimum date to harvest biomass to produce biogas is before senescence. This would mean that a significant proportion of the plants nutrient stores would be removed which would need to be replaced. Fertiliser in the form of digestate generated from a biogas plant could be land spread to bridge nutrient deficiencies. However additional more readily available chemical N fertiliser may have to be applied.

Some work at Oak Park on September harvested miscanthus crops has seen significant responses from a range of N application rates. With dwindling subsidies to support anaerobic digestion finding a low cost perennial high yielding feedstock could be key to ensuring economic viability.

Renewable Energy in Refugee Camps

dabaab-refugee-campAccess to clean and affordable energy is a prerequisite for sustainable development of mankind, and refugees are no exception. Refugee camps across the world house more than 65 million people, and almost all refugee camps are plagued by fuel poverty. Needless to say, urgent measure are required to make camps livable and sustainable.

Rapid advancements in renewable energy technologies have made it possible to deploy such systems on various scales.  The scalability potential of renewable energy systems makes them well-suited for refugee camps, especially in conflict-afflicted areas of the Middle East, Asia and Africa.

Renewable energy in refugee camps can be made available in the form of solar energy, biomass energy and wind energy. Solar panels, solar cooking units, solar lanterns, biomass cookstoves and biogas plants are some of the popular renewable energy technologies that can improve living standards in refugee camps. It is important to focus on specific needs of refugees and customization of technology towards local conditions. For example, solar technologies are better understood than biogas systems in Jordan.

Solar Energy

Solar energy can provide long-term resilience to people living in refugee camps. With many camps effectively transformed into full-fledged towns and cities, it is essential to harness the power of sun to run these camps smoothly. Solar cookers, solar lanterns and solar water heaters are already being used in several refugee camps, and focus has now shifted to grid-connected solar power projects. The 5MW Azraq solar project is the world’s first grid-connected renewable energy project to be established in a refugee camp. The project is being funded entirely by Ikea through the Brighter Lives for Refugees campaign. The program, now in its third year, seeks to improve the lives of refugees around the world by providing access to sustainable energy supplies.

Biomass Energy

Due to lack of land and resources, refugee camps puts tremendous pressure on natural vegetation, especially supply of fuel wood to camp-dwellers. Replacement of traditional stoves with efficient biomass-fired cook stoves can save as much as 80% of cooking fuel. Instead of wood, it would be also be a good option to use agricultural wastes, like husk and straw. Another interesting proposition for refugee camps is to set up small-scale DIY biogas plants, based on human wastes and food residuals. The biogas produced can be used as a cooking medium as well as for power/heat generation.

Wind Energy

Small wind turbines can also play a key role in providing energy to dwellers of refugee camps. Such turbines are used for micro-generation and can provide power from 1kW to 300kW. Majority of small wind turbines are traditional horizontal axis wind turbines but vertical axis wind turbines are a growing type of wind turbine in the small wind market. Small wind turbines are usually mounted on a tower to raise them above any nearby obstacles, and can sited in refugee camps experiencing wind speeds of 4m/s or more.

Solar lights in Azraq Refugee Camp (Jordan)

Solar lights in Azraq Refugee Camp (Jordan)

Conclusions

Renewable energy systems have the potential to improve living standards in refugee camps and ease the sufferings of displaced and impoverished communities. Solar panels, biogas system, biomass stoves and micro wind turbines are some of the renewable energy systems that can be customized for refugee camps and transform them into a less harsh place for displaced people.

Biomass Energy and Sustainability

biomass-sustainabilityBiomass energy systems offer significant possibilities for reducing greenhouse gas emissions due to their immense potential to replace fossil fuels in energy production. Biomass reduces emissions and enhances carbon sequestration since short-rotation crops or forests established on abandoned agricultural land accumulate carbon in the soil. Biomass energy usually provides an irreversible mitigation effect by reducing carbon dioxide at source, but it may emit more carbon per unit of energy than fossil fuels unless biomass fuels are produced in a sustainable manner.

Biomass resources can play a major role in reducing the reliance on fossil fuels by making use of thermo-chemical conversion technologies. In addition, the increased utilization of biomass-based fuels will be instrumental in safeguarding the environment, generation of new job opportunities, sustainable development and health improvements in rural areas.

The development of efficient biomass handling technology, improvement of agro-forestry systems and establishment of small and large-scale biomass-based power plants can play a major role in sustainable development of rural as well as urban areas. Biomass energy could also aid in modernizing the agricultural economy and creating significant job opportunities.

Harvesting practices remove only a small portion of branches and tops leaving sufficient biomass to conserve organic matter and nutrients. Moreover, the ash obtained after combustion of biomass compensates for nutrient losses by fertilizing the soil periodically in natural forests as well as fields.

The impact of forest biomass utilization on the ecology and biodiversity has been found to be insignificant. Infact, forest residues are environmentally beneficial because of their potential to replace fossil fuels as an energy source.

A quick glance at popular biomass resources

A quick glance at popular biomass resources

Plantation of energy crops on abandoned agricultural land will lead to an increase in species diversity. The creation of structurally and species diverse forests helps in reducing the impacts of insects, diseases and weeds. Similarly the artificial creation of diversity is essential when genetically modified or genetically identical species are being planted.

Short-rotation crops give higher yields than forests so smaller tracts are needed to produce biomass which results in the reduction of area under intensive forest management. An intelligent approach in forest management will go a long way in the realization of sustainability goals.

Improvements in agricultural practices promises to increased biomass yields, reductions in cultivation costs, and improved environmental quality. Extensive research in the fields of plant genetics, analytical techniques, remote sensing and geographic information systems (GIS) will immensely help in increasing the energy potential of biomass feedstock.

A large amount of energy is expended in the cultivation and processing of crops like sugarcane, coconut, and rice which can met by utilizing energy-rich residues for electricity production. The integration of biomass-fueled gasifiers in coal-fired power stations would be advantageous in terms of improved flexibility in response to fluctuations in biomass availability and lower investment costs. The growth of the biomass energy industry can also be achieved by laying more stress on green power marketing.

Role of Biomass Energy in Rural Development

biomass-balesBiomass energy systems not only offer significant possibilities for clean energy production and agricultural waste management but also foster sustainable development in rural areas. The increased utilization of biomass wastes will be instrumental in safeguarding the environment, generation of new job opportunities, sustainable development and health improvements in rural areas.

Biomass energy has the potential to modernize the agricultural economy and catalyze rural development. The development of efficient biomass handling technology, improvement of agro-forestry systems and establishment of small, medium and large-scale biomass-based power plants can play a major role in rural development.

Sustainable harvesting practices remove only a small portion of branches and tops leaving sufficient biomass to conserve organic matter and nutrients. Moreover, the ash obtained after combustion of biomass compensates for nutrient losses by fertilizing the soil periodically in natural forests as well as fields.

Planting of energy crops on abandoned agricultural lands will lead to an increase in species diversity. The creation of structurally and species diverse forests helps in reducing the impacts of insects, diseases and weeds. Similarly the artificial creation of diversity is essential when genetically modified or genetically identical species are being planted.

Improvements in agricultural practices promises to increased biomass yields, reductions in cultivation costs, and improved environmental quality. Extensive research in the fields of plant genetics, analytical techniques, remote sensing and geographic information systems (GIS) will immensely help in increasing the energy potential of biomass feedstock.

Rural areas are the preferred hunting ground for the development of biomass sector worldwide. By making use of various biological and thermal processes (anaerobic digestion, combustion, gasification, pyrolysis), agricultural wastes can be converted into biofuels, heat or electricity, and thus catalyzing sustainable development of rural areas economically, socially and environmentally.

Biomass energy can reduce 'fuel poverty' in remote and isolated communities

Biomass energy can reduce ‘fuel poverty’ in remote and isolated communities

A large amount of energy is utilized in the cultivation and processing of crops like sugarcane, wheat and rice which can met by utilizing energy-rich residues for electricity production. The integration of biomass-fueled gasifiers in coal-fired power stations would be advantageous in terms of improved flexibility in response to fluctuations in biomass availability and lower investment costs.

There are many areas in India where people still lack access to electricity and thus face enormous hardship in day-to-day lives. Biomass energy promises to reduce ‘fuel poverty’ commonly prevalent among remote and isolated communities.  Obviously, when a remote area is able to access reliable and cheap energy, it will lead to economic development and youth empowerment.

Biomass Energy in China

biomass-chinaBiomass energy in China has been developing at a rapid pace. Installed biomass power generation capacity in China increased sharply from 1.4 GW in 2006 to 8.5 GW in 2013. While the energy share of biomass remains relatively low compared to other sources of renewable energy, China plans to increase the proportion of biomass energy up to 15 percent and total installed capacity of biomass power generation to 30 GW by 2030.  In terms of impact, the theoretical biomass energy resource in China is about 5 billion tons coal equivalent, which equals 4 times of all energy consumption. As per conservative estimates, currently China is only using 5 percent of its total biomass potential.

According to IRENA, the majority of biomass capacity is in Eastern China, with the coastal province of Shandong accounting for 14 percent of the total alone. While the direct burning of mass for heat remains the primary use of biomass in China, in 2009, composition of China’s biomass power generation consisted in 62 percent of straw direct-fired power generation and 29 percent of waste incineration, with a mix of other feedstock accounting for the remaining 9 percent.

Biomass Resources in China

Major biomass resources in China include waste from agricultural, forestry, industrial, animal and sewage, and municipal solid waste. While the largest contributing sources are estimated to be residues from annual crop production like wheat straw, much of the straw and stalk are presently used for cooking and heating in rural households at low efficiencies. Therefore, agricultural residues, forestry residues, and garden waste were found to be the most cited resources with big potential for energy production in China.

Agricultural residues are derived from agriculture harvesting such as maize, rice and cotton stalks, wheat straw and husks, and are most available in Central and northeastern China where most of the large stalk and straw potential is located. Because straw and stalks are produced as by-products of food production systems, they are perceived to be sustainable sources of biomass for energy that do not threaten food security. Furthermore, it is estimated that China produces around 700 Mt of straw per year, 37 percent of which is corn straw, 28 percent rice, 20 percent wheat and 15 percent from various other crops. Around 50 percent of this straw is used for fertilizers, for which 350 Mt of straw is available for energy production per year.

Biomass resources are underutilized across China

Biomass resources are underutilized across China

Forestry residues are mostly available in the southern and central parts of China. While a few projects that use forestry wastes like tree bark and wood processing wastes are under way, one of the most cited resources with analyzed potential is garden waste. According to research, energy production from garden waste biomass accounted for 20.7 percent of China’s urban residential electricity consumption, or 12.6 percent of China’s transport gasoline demand in 2008.

Future Perspectives

The Chinese government believes that biomass feedstock should neither compete with edible food crops nor cause carbon debt or negative environmental impacts. As biomass takes on an increasing significant role in the China’s national energy-mix, future research specific to technology assessment, in addition to data collection and supply chain management of potential resources is necessary to continue to understand how biomass can become a game-changer in China’s energy future.

References

IRENA, 2014. Renewable Energy Prospects: China, REmap 2030 analysis. IRENA, Abu Dhabi. www.irena.org/remap

National Academy of Engineering and NRC, 2007: Energy Futures and Urban Air Pollution: Challenges for China and the United States.

Xingang, Z., Zhongfu, T., Pingkuo, L, 2013. Development goal of 30 GW for China’s biomass power generation: Will it be achieved? Renewable and Sustainable Energy Reviews, Volume 25, September 2013, 310–317.

Xingang, Z., Jieyu, W., Xiaomeng, L., Tiantian, F., Pingkuo, L, 2012. Focus on situation and policies for biomass power generation in China. Renewable and Sustainable Energy Reviews, Volume 16, Issue 6, August 2012, 3722–3729.

Li, J., Jinming, B. MOA/DOE Project Expert Team, 1998. Assessment of Biomass Resource Availability in China. China Environmental Science Press, Beijing, China.

Klimowicz, G., 2014. “China’s big plans for biomass,” Eco-Business, Global Biomass Series, accessed on Apr 6, 2015.

Shi, Y., Ge, Y., Chang, J., Shao, H., and Tang, Y., 2013. Garden waste biomass for renewable and sustainable energy production in China: Potential, challenges and development. Renewable and Sustainable Energy Reviews 22 (2013) 432–437

Xu, J. and Yuan, Z, 2015. “An overview of the biomass energy policy in China,” BESustainable, May 21, 2015.

Summary of Biomass Combustion Technologies

Direct combustion is the best established and most commonly used technology for converting biomass to heat. During combustion, biomass fuel is burnt in excess air to produce heat. The first stage of combustion involves the evolution of combustible vapours from the biomass, which burn as flames. The residual material, in the form of charcoal, is burnt in a forced air supply to give more heat. The hot combustion gases are sometimes used directly for product drying, but more usually they are passed through a heat exchanger to produce hot air, hot water or steam.

The combustion efficiency depends primarily on good contact between the oxygen in the air and the biomass fuel. The main products of efficient biomass combustion are carbon dioxide and water vapor, however tars, smoke and alkaline ash particles are also emitted. Minimization of these emissions and accommodation of their possible effects are important concerns in the design of environmentally acceptable biomass combustion systems.

Biomass combustion systems, based on a range of furnace designs, can be very efficient at producing hot gases, hot air, hot water or steam, typically recovering 65-90% of the energy contained in the fuel. Lower efficiencies are generally associated with wetter fuels. To cope with a diversity of fuel characteristics and combustion requirements, a number of designs of combustion furnaces or combustors are routinely utilized around the world

Underfeed Stokers

Biomass is fed into the combustion zone from underneath a firing grate. These stoker designs are only suitable for small scale systems up to a nominal boiler capacity of 6 MWth and for biomass fuels with low ash content, such as wood chips and sawdust. High ash content fuels such as bark, straw and cereals need more efficient ash removal systems. Sintered or molten ash particles covering the upper surface of the fuel bed can cause problems in underfeed stokers due to unstable combustion conditions when the fuel and the air are breaking through the ash covered surface.

Grate Stokers

The most common type of biomass boiler is based on a grate to support a bed of fuel and to mix a controlled amount of combustion air, which often enters from beneath the grate. Biomass fuel is added at one end of the grate and is burned in a fuel bed which moves progressively down the grate, either via gravity or with mechanical assistance, to an ash removal system at the other end. In more sophisticated designs this allows the overall combustion process to be separated into its three main activities:

  • Initial fuel drying
  • Ignition and combustion of volatile constituents
  • Burning out of the char.

Grate stokers are well proven and reliable and can tolerate wide variations in fuel quality (i.e. variations in moisture content and particle size) as well as fuels with high ash content. They are also controllable and efficient.

Fluidized Bed Boilers

The basis for a fluidized bed combustion system is a bed of an inert mineral such as sand or limestone through which air is blown from below. The air is pumped through the bed in sufficient volume and at a high enough pressure to entrain the small particles of the bed material so that they behave much like a fluid.

The combustion chamber of a fluidized bed plant is shaped so that above a certain height the air velocity drops below that necessary to entrain the particles. This helps retain the bulk of the entrained bed material towards the bottom of the chamber. Once the bed becomes hot, combustible material introduced into it will burn, generating heat as in a more conventional furnace. The proportion of combustible material such as biomass within the bed is normally only around 5%. The primary driving force for development of fluidized bed combustion is reduced SO2 and NOx emissions from coal combustion.

Bubbling fluidized bed (BFB) combustors are of interest for plants with a nominal boiler capacity greater than 10 MWth. Circulating fluidized bed (CFB) combustors are more suitable for plants larger than 30 MWth. The minimum plant size below which CFB and BFB technologies are not economically competitive is considered to be around 5-10 MWe.

Biomass Resources from Sugar Industry

Sugarcane is one of the most promising agricultural sources of biomass energy in the world. It is the most appropriate agricultural energy crop in most sugarcane producing countries due to its resistance to cyclonic winds, drought, pests and diseases, and its geographically widespread cultivation. Due to its high energy-to-volume ratio, it is considered one of nature’s most effective storage devices for solar energy and the most economically significant energy crop. The climatic and physiological factors that limit its cultivation to tropical and sub-tropical regions have resulted in its concentration in developing countries, and this, in turn, gives these countries a particular role in the world’s transition to sustainable use of natural resources.

According to the International Sugar Organization (ISO), Sugarcane is a highly efficient converter of solar energy, and has the highest energy-to-volume ratio among energy crops. Indeed, it gives the highest annual yield of biomass of all species. Roughly, 1 ton of Sugarcane biomass-based on Bagasse, foliage and ethanol output – has an energy content equivalent to one barrel of crude oil.   Sugarcane produces mainly two types of biomass, Cane Trash and Bagasse. Cane Trash is the field residue remaining after harvesting the Cane stalk and Bagasse is the milling by-product which remains after extracting sugar from the stalk. The potential energy value of these residues has traditionally been ignored by policy-makers and masses in developing countries. However, with rising fossil fuel prices and dwindling firewood supplies, this material is increasingly viewed as a valuable renewable energy resource.

Sugar mills have been using Bagasse to generate steam and electricity for internal plant requirements while Cane Trash remains underutilized to a great extent. Cane Trash and Bagasse are produced during the harvesting and milling process of Sugarcane which normally lasts 6 to 7 months.

Around the world, a portion of the Cane Trash is collected for sale to feed mills, while freshly cut green tops are sometimes collected for farm animals. In most cases, however, the residues are burned or left in the fields to decompose. Cane Trash, consisting of Sugarcane tops and leaves can potentially be converted into around 1kWh/kg, but is mostly burned in the field due to its bulkiness and its related high cost for collection/transportation.

On the other hand, Bagasse has been traditionally used as a fuel in the Sugar mill itself, to produce steam for the process and electricity for its own use. In general, for every ton of Sugarcane processed in the mill, around 190 kg Bagasse is produced. Low pressure boilers and low efficiency steam turbines are commonly used in developing countries. It would be a good business proposition to upgrade the present cogeneration systems to highly efficient, high pressure systems with higher capacities to ensure utilization of surplus Bagasse.