Tag Archives: Agricultural residues

Biomass Pelletization Process

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Biomass pellets are a popular type of biomass fuel, generally made from wood wastes, agricultural biomass, commercial grasses and forestry residues. In addition to savings in transportation and storage, pelletization of biomass facilitates easy and cost effective handling. Dense cubes pellets have the flowability characteristics similar to those of cereal grains. The regular geometry and small size of biomass pellets allow automatic feeding with very fine calibration. High density of pellets also permits compact storage and rational transport over long distance. Pellets are extremely dense and can be produced with a low moisture content that allows them to be burned with very high combustion efficiency.

biomass-pellets

Biomass pelletization is a standard method for the production of high density, solid energy carriers from biomass. Pellets are manufactured in several types and grades as fuels for electric power plants, homes, and other applications. Pellet-making equipment is available at a variety of sizes and scales, which allows manufacture at domestic as well industrial-scale production. Pellets have a cylindrical shape and are about 6-25 mm in diameter and 3-50 mm in length. There are European standards for biomass pellets and raw material classification (EN 14961-1, EN 14961-2 and EN 14961-6) and international ISO standards under development (ISO/DIS 17225-1, ISO/DIS 17225-2 and ISO/DIS 17225-6).

Process Description

The biomass pelletization process consists of multiple steps including raw material pre-treatment, pelletization and post-treatment. The first step in the pelletization process is the preparation of feedstock which includes selecting a feedstock suitable for this process, its filtration, storage and protection. Raw materials used are sawdust, wood shavings, wood wastes, agricultural residues like straw, switchgrass etc. Filtration is done to remove unwanted materials like stone, metal, etc. The feedstock should be stored in such a manner that it is away from impurities and moisture. In cases where there are different types of feedstock, a blending process is used to achieve consistency.

The moisture content in biomass can be considerably high and are usually up to 50% – 60% which should be reduced to 10 to 15%. Rotary drum dryer is the most common equipment used for this purpose. Superheated steam dryers, flash dryers, spouted bed dryers and belt dryers can also be used. Drying increases the efficiency of biomass and it produces almost no smoke on combustion. It should be noted that the feedstock should not be over dried, as a small amount of moisture helps in binding the biomass particles. The drying process is the most energy intensive process and accounts for about 70% of the total energy used in the pelletization process.

Schematic of Pelletization of Woody Biomass

Before feeding biomass to pellet mills, the biomass should be reduced to small particles of the order of not more than 3mm. If the pellet size is too large or too small, it affects the quality of pellet and in turn increases the energy consumption. Therefore the particles should have proper size and should be consistent. Size reduction is done by grinding using a hammer mill equipped with a screen of size 3.2 to 6.4 mm. If the feedstock is quite large, it goes through a chipper before grinding.

The next and the most important step is pelletization where biomass is compressed against a heated metal plate (known as die) using a roller. The die consists of holes of fixed diameter through which the biomass passes under high pressure. Due to the high pressure, frictional forces increase, leading to a considerable rise in temperature. High temperature causes the lignin and resins present in biomass to soften which acts as a binding agent between the biomass fibers. This way the biomass particles fuse to form pellets.

The rate of production and electrical energy used in the pelletization of biomass are strongly correlated to the raw material type and processing conditions such as moisture content and feed size. The The average energy required to pelletize biomass is roughly between 16 kWh/t and 49kWh/t. During pelletization, a large fraction of the process energy is used to make the biomass flow into the inlets of the press channels.

Binders or lubricants may be added in some cases to produce higher quality pellets. Binders increase the pellet density and durability. Wood contains natural resins which act as a binder. Similarly, sawdust contains lignin which holds the pellet together. However, agricultural residues do not contain much resins or lignin, and so a stabilizing agent needs to be added in this case. Distillers dry grains or potato starch is some commonly used binders. The use of natural additives depends on biomass composition and the mass proportion between cellulose, hemicelluloses, lignin and inorganics.

Due to the friction generated in the die, excess heat is developed. Thus, the pellets are very soft and hot (about 70 to 90oC). It needs to be cooled and dried before its storage or packaging. The pellets may then be passed through a vibrating screen to remove fine materials. This ensures that the fuel source is clean and dust free.

The pellets are packed into bags using an overhead hopper and a conveyor belt. Pellets are stored in elevated storage bins or ground level silos. The packaging should be such that the pellets are protected from moisture and pollutants. Commercial pellet mills and other pelletizing equipment are widely available across the globe.

The Logistics of a Biomass Power Plant

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Biomass logistics involves all the unit operations necessary to move biomass wastes from the land to the biomass energy plant. The biomass can be transported directly from farm or from stacks next to the farm to the processing plant. Biomass may be minimally processed before being shipped to the plant, as in case of biomass supply from the stacks. Generally the biomass is trucked directly from farm to the biomass processing facility if no processing is involved.

biomass_logistics

Another option is to transfer the biomass to a central location where the material is accumulated and subsequently dispatched to the energy conversion facility. While in depot, the biomass could be pre-processed minimally (ground) or extensively (pelletized). The depot also provides an opportunity to interface with rail transport if that is an available option. The choice of any of the options depends on the economics and cultural practices. For example in irrigated areas, there is always space on the farm (corner of the land) where quantities of biomass can be stacked.

The key components to reduce costs in harvesting, collecting and transportation of biomass can be summarized as:

  • Reduce the number of passes through the field by amalgamating collection operations.
  • Increase the bulk density of biomass
  • Work with minimal moisture content.
  • Granulation/pelletization is the best option, though the existing technology is expensive.
  • Trucking seems to be the most common mode of biomass transportation option but rail and pipeline may become attractive once the capital costs for these transport modes are reduced.

The logistics of transporting, handling and storing the bulky and variable biomass material for delivery to the biopower plant is a key part of the biomass supply chain that is often overlooked by project developers. Whether the biomass comes from forest residues on hill country, straw residues from cereal crops grown on arable land, or the non-edible components of small scale, subsistence farming systems, the relative cost of collection will be considerable.

Careful development of a system to minimize machinery use, human effort and energy inputs can have a considerable impact on the cost of the biomass as delivered to the biomass processing plant gate.

The logistics of supplying a biomass power plant with consistent and regular volumes of biomass are complex.

Most of the agricultural biomass resources tend to have a relatively low energy density compared with fossil fuels. This often makes handling, storage and transportation more costly per unit of energy carried. Some crop residues are often not competitive because the biomass resource is dispersed over large areas leading to high collection and transport costs.

The costs for long distance haulage of bulky biomass will be minimized if the biomass can be sourced from a location where it is already concentrated, such as sugar mill. It can then be converted in the nearby biomass energy plant to more transportable forms of energy carrier if not to be utilized on-site.

The logistics of supplying a biopower plant with sufficient volumes of biomass from a number of sources at suitable quality specifications and possibly all year round, are complex. Agricultural residues can be stored on the farm until needed. Then they can be collected and delivered directly to the conversion plant on demand. At times this requires considerable logistics to ensure only a few days of supply are available on-site but that the risk of non-supply at any time is low.

Losses of dry matter, and hence of energy content, commonly occur during the harvest transport and storage process. This can either be from physical losses of the biomass material in the field during the harvest operation or dropping off a truck, or by the reduction of dry matter of biomass material which occurs in storage over time as a result of respiration processes and as the product deteriorates. Dry matter loss is normally reduced over time if the moisture content of the biomass can be lowered or oxygen can be excluded in order to constrain pathological action.

To ensure sufficient and consistent biomass supplies, all agents involved with the production, collection, storage, and transportation of biomass require compensation for their share of costs incurred. In addition, a viable biomass production and distribution system must include producer incentives, encouraging them to sell their post-harvest plant residue.

How is Biomass Transported

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Transporting biomass fuel to a power plant is an important aspect of any biomass energy project. Because a number of low moisture fuels can be readily collected and transported to a centralized biomass plant location or aggregated to enhance project size, this opportunity should be evaluated on a case-by-case basis.

It will be a good proposition to develop biomass energy plants at the location where the bulk of the agricultural waste stream is generated, without bearing the additional cost of transporting waste streams. Effective capture and use of thermal energy at the site for hot water, steam, and even chilled water requirements raises the energy efficiency of the project, thereby improving the value of the waste-to-energy project.

biomass_transportation

Important Factors

  • The maximum rate of biomass supply to the conversion facility.
  • The form and bulk density of biomass.
  • The hauling distance for biomass transportation to the processing plant.
  • Transportation infrastructure available between the points of biomass dispatch and processing plant

Transportation is primarily concerned with loading and unloading operation and transferring biomass from pre-processing sites to the main processing plant or biorefinery. Truck transport and for a few cases train transport may be the only modes of transport. Barge and pipeline transport and often train transport involve truck transport. Trucks interface with trains at loading and unloading facilities of a depot or processing facility. Barge and pipeline require interfacing with train and/or truck transport at major facilities either on land or at the shores.

Physical form and quality of biomass has the greatest influence on the selection of handling equipment for the lowest delivered cost possible. A higher bulk density will allow more mass of material to be transported per unit distance. Truck transport is generally well developed, is usually cheapest mode of transport but it becomes expensive as travel distance increases. Pipeline biomass transport is the least known technology and may prove to be the cheapest and safest mode of transport in the near future.

Transportation costs of low-density and high-moisture agricultural residues are a major constraint to their use as an energy source. As a rule of thumb, transportation distances beyond a 25–50- km radius (depending on local infrastructure) are uneconomical. For long distances, agricultural residues could be compressed as bales or briquettes in the field, rendering transport to the site of use a viable option.

biomass-train

Greater use of biomass and larger scale conversion systems demand larger scale feedstock handling and delivery infrastructure. To accommodate expansion in feedstock collection and transportation, production centres can be established where smaller quantities of biomass are consolidated, stored, and transferred to long-distance transportation systems, in much the same way that transfer stations are used in municipal waste handling. Preprocessing equipment may be used to densify biomass, increasing truck payloads and reducing transportation costs over longer haul distances.

Everything You Should Know About Agricultural Residues

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The term agricultural residue is used to describe all the organic materials which are produced as by-products from harvesting and processing of agricultural crops. These residues can be further categorized into primary residues and secondary residues.

biomass energy in china

Agricultural residues, which are generated in the field at the time of harvest, are defined as primary or field based residues whereas those co-produced during processing are called secondary or processing based residues.

  • Primary agricultural residues – paddy straw, sugarcane top, maize stalks, coconut empty bunches and frond, palm oil frond and bunches;
  • Secondary agricultural residues – paddy husk, bagasse, maize cob, coconut shell, coconut husk, coir dust, saw dust, palm oil shell, fiber and empty bunches, wastewater, black liquor.

Agricultural residues are highly important sources of biomass fuels for both the domestic and industrial sectors. Availability of primary residues for energy application is usually low since collection is difficult and they have other uses as fertilizer, animal feed etc.

 

However secondary residues are usually available in relatively large quantities at the processing site and may be used as captive energy source for the same processing plant involving minimal transportation and handling cost.

torrefaction of biomass

 

Crop residues encompasses all agricultural wastes such as straw, stem, stalk, leaves, husk, shell, peel, pulp, stubble, etc. which come from cereals (rice, wheat, maize or corn, sorghum, barley, millet), cotton, groundnut, jute, legumes (tomato, bean, soy) coffee, cacao, tea, fruits (banana, mango, coco, cashew) and palm oil.

Rice produces both straw and rice husks at the processing plant which can be conveniently and easily converted into energy. Significant quantities of biomass remain in the fields in the form of cob when maize is harvested which can be converted into energy.

agricultural wastes

Storage of biomass fuels is expensive and increases with capacity.

Sugarcane harvesting leads to harvest residues in the fields while processing produces fibrous bagasse, both of which are good sources of energy. Harvesting and processing of coconuts produces quantities of shell and fibre that can be utilised while peanuts leave shells. All these materials can be converted into useful energy by a wide range of biomass conversion technologies.

Biomass Energy in Nigeria: An Overview

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Oil and gas accounts for over 70% of energy consumed in Nigeria, according to the World Bank. Considering this dependency on fossil oil and possibility of it running out in the future, there should be an urgent intervention to look into other ways to generate energy in Nigeria. The world is moving away gradually from fossil oil and aligning towards sustainable energy resources to substitute conventional fuel, Nigeria should not be exempted from this movement. Biomass, a popular form of renewable energy, is considered as a credible and green alternative source of energy which many developed and developing countries have been maximizing to its potential.

biomass-sustainability

Power generation and supply have been inadequate in Nigeria. This inadequacy of power limits human, commercial and industrial productivity and economic growth . What is the use of infrastructure without constant electricity? Even God created light first. Sustainable and constant supply of power should be one of the priority of government in nation development. Investing in biomass energy will cause an increase in the amount of power generated in Nigeria. Infact, biomass energy has the potential to resolve the energy crisis in the country in the not so distant future.

What is Biomass

The word biomass refers to organic matter (mainly plants) which acts as a source of sustainable and renewable energy. It is a renewable energy source because the plants can be replaced as oppose to the conventional fossil fuel which is not renewable. Biomass energy is a transferred energy from the sun; plants derives energy from the sun through photosynthesis which is further transferred through the food chain to animals’ bodies and their waste.

Biomass has the potential to provide an affordable and sustainable source of energy, while at the same time help in curbing the green house effect. In India the total biomass generation capacity is 8,700 MW according to U.S. of Commerce’s International Trade Administration, whereas the generating capacity in U.S. is 20,156  MW with 178 biomass power plants, according to Biomass Magazine.

Power Sector in Nigeria

Unfortunately, the total installed electricity capacity generated in Nigeria is 12,522 MW, well below the current demand of 98,000MW . The actual output is about 3,800MW, resulting in a demand shortfall of 94,500MW throughout the country. As a result of this wide gap between demand and output, only 45% of Nigeria’s population has access to electricity. Renewable energy contributed 19% of total electricity generated in Nigeria out of which biomass contribution is infinitesimal.

Electricity generation for Nigeria’s grid is largely dominated by two sources; non-renewable thermal (natural gas and coal) and renewable (hydro). Nigeria depends on non-renewable energy despite its vast potential in renewable sources such as solar, wind, biomass and hydro. The total potential of these renewables is estimated at over 68,000MW, which is more than five times the current power output.

Biomass Resources in Nigeria

Biomass can come in different forms like wood and wood waste, agriculture produce and waste, solid waste.

1. Wood

Electricity can be generated with wood and wood product/waste(like sawdust) in modern day through cogeneration, gasification or pyrolysis.

2. Agriculture Residues

In Nigeria, agricultural residues are highly important sources of biomass fuels for both the domestic and industrial sectors. Availability of primary residues for energy application is usually low since collection is difficult and they have other uses as fertilizer, animal feed etc.

However secondary residues are usually available in relatively large quantities at the processing site and may be used as captive energy source for the same processing plant involving minimal transportation and handling cost.

3. Municipal Solid Waste

Back then in secondary school, I learnt that gas could be tapped from septic tank which could further be used for cooking.  Any organic waste (like animal waste, human waste) when decomposed by anaerobic microorganisms releases biogas which can be tapped and stored for either cooking or to generate electricity.

Biomass can be used to provide heat and electricity as well as biofuel and biogas for transport. There are enough biomass capacity to meet our demand for electricity and other purposes. From climatic point of view, there is a warm climate in Nigeria which is a good breeding ground for bacteria to grow and decompose the wastes. There are plant and animal growth all year round which in turn create waste and consequently produce biomass.

In November 2016, The Ebonyi State Government  took over  the United Nations Industrial Development Organization (UNIDO) demonstration biomass gasifier power plant located at the UNIDO Mini -industrial cluster in Ekwashi Ngbo in Ohaukwu Local Government Area of the State. The power plant is to generate 5.5 Megawatt energy using rice husk and other available waste materials available. More of these type of power plants and commitment are needed to utilize the potential of biomass fully.

Why Biomass Energy?

Since biomass makes use of waste to supply energy, it helps in waste management. It also has the potential to supply more energy (10 times) than the one produced from sun and wind. Biomass energy in Nigeria will lead to increase in revenue generation and conserves our foreign exchange. Increase in energy generation will yield more productivity for industries and the rate at which they are shutting down due to the fact that they spend more on power will be reduced to minimal.

Many local factories/companies will spring up and foreign investors will be eager to invest in Nigeria with little concern about power. Establishment of biopower plants will surely create more jobs and indirectly reduce the number of people living in poverty which is increasing everyday at an alarming rate.

Africa’s most populous country needs more than 10 times its current electricity output to guarantee supply for its 198 million people – nearly half of whom have no access at all, according to power minister Babatunde Fashola. Biomass energy potential in Nigeria is promising –  with heavy investment, stake holder cooperation and development of indigenous technologies. The deployment of large-scale biomass energy systems will not only significantly increase Nigeria’s electricity capacity but also ease power shortages in the country.

Biomass Energy in China

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Biomass energy in China has been developing at a rapid pace. The installed biomass power generation capacity in China increased sharply from 1.4 GW in 2006 to 14.88 GW in 2017. While the energy share of biomass remains relatively low compared to other sources of renewable energy, China plans to increase the proportion of biomass energy up to 15 percent and total installed capacity of biomass power generation to 30 GW by 2030.

biomass-china

In terms of impact, the theoretical biomass energy resource in China is about 5 billion tons coal equivalent, which equals 4 times of all energy consumption. As per conservative estimates, currently China is only using 5 percent of its total biomass potential.

According to IRENA, the majority of biomass capacity is in Eastern China, with the coastal province of Shandong accounting for 14 percent of the total alone. While the direct burning of mass for heat remains the primary use of biomass in China, in 2009, composition of China’s biomass power generation consisted in 62 percent of straw direct-fired power generation and 29 percent of waste incineration, with a mix of other feedstock accounting for the remaining 9 percent.

Biomass Resources in China

Major biomass resources in China include waste from agriculture, forestry, industries, animal manure and sewage, and municipal solid waste. While the largest contributing sources are estimated to be residues from annual crop production like wheat straw, much of the straw and stalk are presently used for cooking and heating in rural households at low efficiencies. Therefore, agricultural residues, forestry residues, and garden waste were found to be the most cited resources with big potential for energy production in China.

Agricultural residues are derived from agriculture harvesting such as maize, rice and cotton stalks, wheat straw and husks, and are most available in Central and northeastern China where most of the large stalk and straw potential is located. Because straw and stalks are produced as by-products of food production systems, they are perceived to be sustainable sources of biomass for energy that do not threaten food security.

Furthermore, it is estimated that China produces around 700 Mt of straw per year, 37 percent of which is corn straw, 28 percent rice, 20 percent wheat and 15 percent from various other crops. Around 50 percent of this straw is used for fertilizers, for which 350 Mt of straw is available for energy production per year.

Biomass resources are underutilized across China

Biomass resources are underutilized across China

Forestry residues are mostly available in the southern and central parts of China. While a few projects that use forestry wastes like tree bark and wood processing wastes are under way, one of the most cited resources with analyzed potential is garden waste. According to research, energy production from garden waste biomass accounted for 20.7 percent of China’s urban residential electricity consumption, or 12.6 percent of China’s transport gasoline demand in 2008.

Future Perspectives

The Chinese government believes that biomass feedstock should neither compete with edible food crops nor cause carbon debt or negative environmental impacts. As biomass takes on an increasing significant role in the China’s national energy-mix, future research specific to technology assessment, in addition to data collection and supply chain management of potential resources is necessary to continue to understand how biomass can become a game-changer in China’s energy future.

References

IRENA, 2014. Renewable Energy Prospects: China, REmap 2030 analysis. IRENA, Abu Dhabi. www.irena.org/remap

National Academy of Engineering and NRC, 2007: Energy Futures and Urban Air Pollution: Challenges for China and the United States.

Xingang, Z., Zhongfu, T., Pingkuo, L, 2013. Development goal of 30 GW for China’s biomass power generation: Will it be achieved? Renewable and Sustainable Energy Reviews, Volume 25, September 2013, 310–317.

Xingang, Z., Jieyu, W., Xiaomeng, L., Tiantian, F., Pingkuo, L, 2012. Focus on situation and policies for biomass power generation in China. Renewable and Sustainable Energy Reviews, Volume 16, Issue 6, August 2012, 3722–3729.

Li, J., Jinming, B. MOA/DOE Project Expert Team, 1998. Assessment of Biomass Resource Availability in China. China Environmental Science Press, Beijing, China.

Klimowicz, G., 2014. “China’s big plans for biomass,” Eco-Business, Global Biomass Series, accessed on Apr 6, 2015.

Shi, Y., Ge, Y., Chang, J., Shao, H., and Tang, Y., 2013. Garden waste biomass for renewable and sustainable energy production in China: Potential, challenges and development. Renewable and Sustainable Energy Reviews 22 (2013) 432–437

Xu, J. and Yuan, Z, 2015. “An overview of the biomass energy policy in China,” BESustainable, May 21, 2015.

Biofuels from Lignocellulosic Biomass

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Lignocellulosic biomass consists of a variety of materials with distinctive physical and chemical characteristics. It is the non-starch based fibrous part of plant material.

Lignocellulose is a generic term for describing the main constituents in most plants, namely cellulose, hemicelluloses, and lignin. Lignocellulose is a complex matrix, comprising many different polysaccharides, phenolic polymers and proteins. Cellulose, the major component of cell walls of land plants, is a glucan polysaccharide containing large reservoirs of energy that provide real potential for conversion into biofuels.

Straw_Bales

First-generation biofuels (produced primarily from food crops such as grains, sugar beet and oil seeds) are limited in their ability to achieve targets for oil-product substitution, climate change mitigation, and economic growth. Their sustainable production is under scanner, as is the possibility of creating undue competition for land and water used for food and fibre production.

The cumulative impacts of these concerns have increased the interest in developing biofuels produced from non-food biomass. Feedstocks from lignocellulosic materials include cereal straw, bagasse, forest residues, and purpose-grown energy crops such as vegetative grasses and short rotation forests. These second-generation biofuels could avoid many of the concerns facing first-generation biofuels and potentially offer greater cost reduction potential in the longer term.

The largest potential feedstock for biofuels is lignocellulosic biomass, which includes materials such as agricultural residues (corn stover, crop straws and bagasse), herbaceous crops (alfalfa, switchgrass), short rotation woody crops, forestry residues, waste paper and other wastes (municipal and industrial). Bioethanol production from these feedstocks could be an attractive alternative for disposal of these residues.

Importantly, lignocellulosic biomass resources do not interfere with food security. Moreover, bioethanol is very important for both rural and urban areas in terms of energy security reason, environmental concern, employment opportunities, agricultural development, foreign exchange saving, socioeconomic issues etc.

Lignocellulosic biomass consists mainly of lignin and the polysaccharides cellulose and hemicellulose. Compared with the production of ethanol from first-generation feedstocks, the use of lignocellulosic biomass is more complicated because the polysaccharides are more stable and the pentose sugars are not readily fermentable by Saccharomyces cerevisiae. 

In order to convert lignocellulosic biomass to biofuels the polysaccharides must first be hydrolysed, or broken down, into simple sugars using either acid or enzymes. Several biotechnology-based approaches are being used to overcome such problems, including the development of strains of Saccharomyces cerevisiae that can ferment pentose sugars, the use of alternative yeast species that naturally ferment pentose sugars, and the engineering of enzymes that are able to break down cellulose and hemicellulose into simple sugars.

Lignocellulosic biomass processing pilot plants have been established in the EU, in Denmark, Spain and Sweden. The world’s largest demonstration facility of lignocellulose ethanol (from wheat, barley straw and corn stover), with a capacity of 2.5 Ml, was first established by Iogen Corporation in Ottawa, Canada. Many other processing facilities are now in operation or planning throughout the world.

Economically, lignocellulosic biomass has an advantage over other agriculturally important biofuels feedstock such as corn starch, soybeans, and sugar cane, because it can be produced quickly and at significantly lower cost than food crops.

Lignocellulosic biomass is an important component of the major food crops; it is the non-edible portion of the plant, which is currently underutilized, but could be used for biofuel production. In short, biofuels from lignocellulosic biomass holds the key to supplying society’s basic needs without impacting the nation’s food supply.

Issues Confronting Biomass Energy Ventures

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Biomass resources can be transformed into clean energy and/or fuels by thermal and biochemical technologies. Besides recovery of substantial energy, these technologies can lead to a substantial reduction in the overall waste quantities requiring final disposal.

Biomass_Cogeneration

However, biomass energy projects worldwide are often hampered by a variety of techno-commercial issues. The issues enumerated below are not geography-specific and are usually a matter of concern for project developers, entrepreneurs and technology companies:

Large Project Costs

In India, a 1 MW gasification plant usually costs about USD 1-1.5 million. A combustion-based 1 MW plant would need a little more expenditure, to the tune of USD 1-2 million. An anaerobic digestion-based plant of the same capacity, on the other hand, could range anywhere upwards USD 3 million. Such high capital costs prove to be a big hurdle for any entrepreneur or renewable energy enthusiast to come forward and invest into these technologies.

Low Conversion Efficiencies

In general, efficiencies of combustion-based systems are in the range of 20-25% and gasification-based systems are considered even poorer, with their efficiencies being in the range of a measly 10-15%. The biomass resources themselves are low in energy density, and such poor system efficiencies could add a double blow to the entire project.

Dearth of Mature Technologies

Poor efficiencies call for a larger quantum of resources needed to generate a unit amount of energy. Owing to this reason, investors and project developers find it hard to go for such plants on a larger scale. Moreover, the availability of only a few reliable technology and operation & maintenance service providers makes these technologies further undesirable.

Gasification technology is still limited to scales lesser than 1 MW in most parts of the world. Combustion-based systems have although gone upwards of 1 MW, a lot many are now facing hurdles because of factors like unreliable resource chain, grid availability, and many others.

Lack of Funding Options

Financing agencies usually give a tough time to biomass project developers as compared to what it takes to invest in other renewable energy technologies.

Non-Transparent Trade Markets

Usually, the biomass energy resources are obtained through forests, farms, industries, animal farms etc. There is no standard pricing mechanism for such resources and these usually vary from vendor to vendor, even with the same resource in consideration.

High Risks / Low Pay-Backs

Biomass energy projects are not much sought-after owing to high project risks which could entail from failed crops, natural disasters, local disturbances, etc.

Resource Price Escalation

Unrealistic fuel price escalation too is a major cause of worry for the plant owners. Usually, an escalation of 3-5% is considered while carrying out the project’s financial modelling. However, it has been observed that in some cases, the rise has been as staggering as 15-20% per annum, forcing the plants to shut down.

Ethanol Production from Lignocellulosic Biomass

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Cellulosic ethanol technology is one of the most commonly discussed second-generation biofuel technologies worldwide. Cellulosic biofuels are derived from the cellulose in plants, some of which are being developed specifically as “energy” crops rather than for food production. These include perennial grasses and trees, such as switchgrass and Miscanthus. Crop residues, in the form of stems and leaves, represent another substantial source of cellulosic biomass.

Bioethanol_Pump

The largest potential feedstock for ethanol is lignocellulosic biomass, which includes materials such as agricultural residues (corn stover, crop straws, husks and bagasse), herbaceous crops (alfalfa, switchgrass), short rotation woody crops, forestry residues, waste paper and other wastes (municipal and industrial).

Bioethanol production from these feedstocks could be an attractive alternative for disposal of these residues. Lignocellulosic biomass feedstocks do not interfere with food security and are important for both rural and urban areas in terms of energy security reason, environmental concern, employment opportunities, agricultural development, foreign exchange saving, socioeconomic issues etc.

Production of Ethanol

The production of ethanol from lignocellulosic biomass can be achieved through two different processing routes. They are:

  • Biochemical – in which enzymes and other micro-organisms are used to convert cellulose and hemicellulose components of the feedstocks to sugars prior to their fermentation to produce ethanol;
  • Thermochemical – where pyrolysis/gasification technologies produce a synthesis gas (CO + H2) from which a wide range of long carbon chain biofuels, such as synthetic diesel or aviation fuel, can be reformed.

Lignocellulosic biomass consists mainly of lignin and the polysaccharides cellulose and hemicellulose. Compared with the production of ethanol from first-generation feedstocks, the use of lignocellulosic biomass is more complicated because the polysaccharides are more stable and the pentose sugars are not readily fermentable by Saccharomyces cerevisiae. 

In order to convert lignocellulosic biomass to biofuels the polysaccharides must first be hydrolysed, or broken down, into simple sugars using either acid or enzymes. Several biotechnology-based approaches are being used to overcome such problems, including the development of strains of Saccharomyces cerevisiae that can ferment pentose sugars, the use of alternative yeast species that naturally ferment pentose sugars, and the engineering of enzymes that are able to break down cellulose and hemicellulose into simple sugars.

Ethanol from lignocellulosic biomass is produced mainly via biochemical routes. The three major steps involved are pretreatment, enzymatic hydrolysis, and fermentation. Biomass is pretreated to improve the accessibility of enzymes. After pretreatment, biomass undergoes enzymatic hydrolysis for conversion of polysaccharides into monomer sugars, such as glucose and xylose. Subsequently, sugars are fermented to ethanol by the use of different microorganisms.

Pretreated biomass can directly be converted to ethanol by using the process called simultaneous saccharification and cofermentation (SSCF).  Pretreatment is a critical step which enhances the enzymatic hydrolysis of biomass. Basically, it alters the physical and chemical properties of biomass and improves the enzyme access and effectiveness which may also lead to a change in crystallinity and degree of polymerization of cellulose.

The internal surface area and pore volume of pretreated biomass are increased which facilitates substantial improvement in accessibility of enzymes. The process also helps in enhancing the rate and yield of monomeric sugars during enzymatic hydrolysis steps.

Pretreatment of Lignocellulosic Biomass

Pretreatment methods can be broadly classified into four groups – physical, chemical, physio-chemical and biological. Physical pretreatment processes employ the mechanical comminution or irradiation processes to change only the physical characteristics of biomass. The physio-chemical process utilizes steam or steam and gases, like SO2 and CO2.

The chemical processes employs acids (H2SO4, HCl, organic acids etc) or alkalis (NaOH, Na2CO3, Ca(OH)2, NH3 etc). The acid treatment typically shows the selectivity towards hydrolyzing the hemicelluloses components, whereas alkalis have better selectivity for the lignin. The fractionation of biomass components after such processes help in improving the enzymes accessibility which is also important to the efficient utilization of enzymes.

Conclusions

The major cost components in bioethanol production from lignocellulosic biomass are the pretreatment and the enzymatic hydrolysis steps. In fact, these two process are someway interrelated too where an efficient pretreatment strategy can save substantial enzyme consumption. Pretreatment step can also affect the cost of other operations such as size reduction prior to pretreatment.

Therefore, optimization of these two important steps, which collectively contributes about 70% of the total processing cost, are the major challenges in the commercialization of bioethanol from 2nd generation biofuel feedstock.

Biomass Energy Potential in Pakistan

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Being an agricultural economy, biomass energy potential in Pakistan is highly promising. Pakistan is experiencing a severe energy crisis these days which is resulting in adverse long term economic and social problems. The electricity and gas shortages have directly impacted the common man, industry and commercial activities.

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The high cost of energy mix is the main underlying reason behind the power crisis. The main fuel for the local power industry is natural gas however due to the continued depletion of this source and demands elsewhere the power generation companies are now dependent on furnace oil which is relatively expensive.

The way out of this crisis is to look for fuel sources which are cheap and abundantly available within the country. This description and requirement is fulfilled by biomass resources which have been largely ignored in the past and are also available in sufficient quantities to tackle the energy crisis prevailing in the country.

Biomass Energy in Pakistan

The potential to produce power from biomass resources is very promising in Pakistan. Being an agrarian economy, more than 60% of the population is involved in agricultural activities in the country. As per World Bank statistics, around 26,280,000 hectares of land is under cultivation in Pakistan. The major sources of biomass energy are crop residues, animal manure and municipal solid wastes

Agricultural Residues

Wheat straw, rice husk, rice straw, cane trash, bagasse, cotton sticks are some of the major crop residues in Pakistan. Sugar cane is a major crop in the country and grown on a wide scale throughout Pakistan. During 2010-2011, the area under sugarcane cultivation was 1,029,000 hectares which is 4% of the total cropped area.

Sugarcane trash which constitutes 10% of the sugar cane is currently burned in the fields. During the year 2010-11, around 63,920,000 metric tons of sugarcane was grown in Pakistan which resulted in trash generation of around 5,752,800 metric tons. As per conservation estimates, the bioenergy potential of cane trash is around 9,475 GWh per year.

Cotton is another major cash crop in Pakistan and is the main source of raw material to the local textile industry. Cotton is grown on around 11% of the total cropped area in the country. The major residue from cotton crop is cotton sticks which is he material left after cotton picking and constitute as much as 3 times of the cotton produced.

Majority of the cotton sticks are used as domestic fuel in rural areas so only one-fourth of the total may be considered as biomass energy resource. The production of cotton sticks during 2010-2011 was approximately 1,474,693 metric tons which is equivalent to power generation potential of around 3,071 GWh.

Cotton sticks constitute as much as 3 times of the cotton produced.

Animal Manure

Pakistan is the world’s fourth largest producer of milk. The cattle and dairy population is around 67,294,000 while the animal manure generation is estimated at 368,434,650 metric tons. Biogas generation from animal manure is a very good proposition for Pakistan as the country has the potential to produce electrical energy equivalent to 23,654 GWh

Municipal Solid Waste

The generation or solid wastes in 9 major urban centers is around 7.12 million tons per annum which is increasing by 2.5% per year due to rapid increase in population and high rate of industrialization. The average calorific value of MSW in Pakistan is 6.89 MJ/kg which implies power generation potential of around 13,900 GWh per annum.