Biofuels from Lignocellulosic Biomass

Lignocellulose is a generic term for describing the main constituents in most plants, namely cellulose, hemicelluloses, and lignin. Lignocellulose is a complex matrix, comprising many different polysaccharides, phenolic polymers and proteins. Cellulose, the major component of cell walls of land plants, is a glucan polysaccharide containing large reservoirs of energy that provide real potential for conversion into biofuels. Lignocellulosic biomass consists of a variety of materials with distinctive physical and chemical characteristics. It is the non-starch based fibrous part of plant material.

First-generation biofuels (produced primarily from food crops such as grains, sugar beet and oil seeds) are limited in their ability to achieve targets for oil-product substitution, climate change mitigation, and economic growth. Their sustainable production is under scanner, as is the possibility of creating undue competition for land and water used for food and fibre production.

The cumulative impacts of these concerns have increased the interest in developing biofuels produced from non-food biomass. Feedstocks from ligno-cellulosic materials include cereal straw, bagasse, forest residues, and purpose-grown energy crops such as vegetative grasses and short rotation forests. These second-generation biofuels could avoid many of the concerns facing first-generation biofuels and potentially offer greater cost reduction potential in the longer term.

The largest potential feedstock for ethanol is lignocellulosic biomass, which includes materials such as agricultural residues (corn stover, crop straws and bagasse), herbaceous crops (alfalfa, switchgrass), short rotation woody crops, forestry residues, waste paper and other wastes (municipal and industrial). Bioethanol production from these feedstocks could be an attractive alternative for disposal of these residues. Importantlylignocellulosic feedstocks do not interfere with food security. Moreover, bioethanol is very important for both rural and urban areas in terms of energy security reason, environmental concern, employment opportunities, agricultural development, foreign exchange saving, socioeconomic issues etc.

Lignocellulosic biomass consists mainly of lignin and the polysaccharides cellulose and hemicellulose. Compared with the production of ethanol from first-generation feedstocks, the use of lignocellulosic biomass is more complicated because the polysaccharides are more stable and the pentose sugars are not readily fermentable by Saccharomyces cerevisiae. In order to convert lignocellulosic biomass to biofuels the polysaccharides must first be hydrolysed, or broken down, into simple sugars using either acid or enzymes. Several biotechnology-based approaches are being used to overcome such problems, including the development of strains of Saccharomyces cerevisiae that can ferment pentose sugars, the use of alternative yeast species that naturally ferment pentose sugars, and the engineering of enzymes that are able to break down cellulose and hemicellulose into simple sugars.

Lignocellulosic processing pilot plants have been established in the EU, in Denmark, Spain and Sweden. The world’s largest demonstration facility of lignocellulose ethanol (from wheat, barley straw and corn stover), with a capacity of 2.5 Ml, was first established by Iogen Corporation in Ottawa, Canada. Many other processing facilities are now in operation or planning throughout the world.

Economically, lignocellulosic biomass has an advantage over other agriculturally important biofuels feedstocks such as corn starch, soybeans, and sugar cane, because it can be produced quickly and at significantly lower cost than food crops. Lignocellulosic biomass is an important component of the major food crops; it is the non-edible portion of the plant, which is currently underutilized, but could be used for biofuel production. In short, lignocellulosic biomass holds the key to supplying society’s basic needs for sustainable production of liquid transportation fuels without impacting the nation’s food supply.

Ethanol Production via Biochemical Route

Ethanol from lignocellulosic biomass is produced mainly via biochemical routes. The three major steps involved are pretreatment, enzymatic hydrolysis, and fermentation. Biomass is pretreated to improve the accessibility of enzymes. After pretreatment, biomass undergoes enzymatic hydrolysis for conversion of polysaccharides into monomer sugars, such as glucose and xylose. Subsequently, sugars are fermented to ethanol by the use of different microorganisms.

Pretreated biomass can directly be converted to ethanol by using the process called simultaneous saccharification and cofermentation (SSCF). Pretreatment is a critical step which enhances the enzymatic hydrolysis of biomass. Basically, it alters the physical and chemical properties of biomass and improves the enzyme access and effectiveness which may also lead to a change in crystallinity and degree of polymerization of cellulose. The internal surface area and pore volume of pretreated biomass are increased which facilitates substantial improvement in accessibility of enzymes. The process also helps in enhancing the rate and yield of monomeric sugars during enzymatic hydrolysis steps.

Pretreatment methods can be broadly classified into four groups – physical, chemical, physio-chemical and biological. Physical pretreatment processes employ the mechanical comminution or irradiation processes to change only the physical characteristics of biomass. The physio-chemical process utilizes steam or steam and gases, like SO2 and CO2. The chemical processes employs acids (H2SO4, HCl, organic acids etc) or alkalis (NaOH, Na2CO3, Ca(OH)2, NH3 etc). The acid treatment typically shows the selectivity towards hydrolyzing the hemicelluloses components, whereas alkalis have better selectivity for the lignin. The fractionation of biomass components after such processes help in improving the enzymes accessibility which is also important to the efficient utilization of enzymes.

The pretreated biomass is subjected to enzymatic hydrolysis using cellulase enzymes to convert the cellulose to fermentable sugars. Cellulase refers to a class of enzymes produced chiefly by fungi and bacteria which catalyzes the hydrolysis of cellulose by attacking the glycosidic linkages. Cellulase is mixture of mainly three different functional protein groups: exo-glucanase (Exo-G), endo-glucanase(Endo-G) and ?-glucosidase (?-G). The functional proteins work synergistically in hydrolyzing the cellulose into the glucose. These sugars are further fermented using microorganism and are converted to ethanol. The microorganisms are selected based on their efficiency for ethanol productivity and higher product and inhibitors tolerance. Yeast Saccharomyces cerevisiae is used commercially to produce the ethanol from starch and sucrose.

Escherichia coli strain has also been developed recently for ethanol production by the first successful application of metabolic engineering. E. coli can consume variety of sugars and does not require the complex growth media but has very narrow operable range of pH. E. coli has higher optimal temperature than other known strains of bacteria.

Lower GHG emissions and empowerment of rural economy are major benefits associated with bioethanol

The major cost components in bioethanol production from lignocellulosic biomass are the pretreatment and the enzymatic hydrolysis steps. In fact, these two process are someway interrelated too where an efficient pretreatment strategy can save substantial enzyme consumption. Pretreatment step can also affect the cost of other operations such as size reduction prior to pretreatment. Therefore, optimization of these two important steps, which collectively contributes about 70% of the total processing cost, are the major challenges in the commercialization of bioethanol from 2nd generation feedstock.

Enzyme cost is the prime concern in full scale commercialization. The trend in enzyme cost is encouraging because of enormous research focus in this area and the cost is expected to go downward in future, which will make bioethanol an attractive option considering the benefits derived its lower greenhouse gas emissions and the empowerment of rural economy.

The Promise of Algae

This year has witnessed the U.S. Navy debut their “Great Green Fleet,” the first aircraft carrier strike group powered largely by alternative, nonpetroleum-based fuels, the British Ministry of Defence launch a competition to reduce its equipment energy spend and the Pentagon increase its investment in clean-energy technologies, including biofuels development.  Could we be witnessing the start of the end of our reliance on “fossil fuel” petroleum?

In 2010, the MOD spent £628m on equipment energy and, for every 1p per litre rise in the price of fuel, the MOD’s annual equipment energy bill increases by £13m. These rising oil prices have once again positioned biofuels centre stage as a potential substitute to fulfil our global thirst for fuel.

With so many biofuel crops needing to compete for space and freshwater supplies with agriculture, algae are being seen as an ideal, sustainable alternative.  Algae can be grown in areas where crops cannot, but until now, it’s been difficult to achieve the scale needed for commercial  algal production.

Leading international authority on algal biotechnology and head of the Culture Collection of Algae and Protozoa (www.CCAP.ac.uk), Dr John Day, thinks it’s a major step forward.  Dr Day has over 25 years’ experience in biotechnology and applied algal research and comments “Commercial confidence in the scalability of algal biofuel production is an exciting step forward in the journey towards sustainable, economic biofuel production using microalgae.

Algae Cultures at the Scottish Association for Marine Science

“A major driver for the development of algal biofuels has been fuel security and the US Navy has successfully tested nearly all of its ships and aircraft on biofuel blends containing algal oils — including an F-18 fighter flying at twice the speed of sound and a ship moving at 50 knots.”

“Scientists at SAMS and elsewhere have been contributing to the global development of knowledge on algal biofuel. It is this understanding of the biology of these enigmatic microbes and our capacity to successfully cultivate them that will be the key to producing algal biofuels and other products.”

Driven by the desire to reduce reliance on foreign countries for petroleum, and the constant pressure to reduce costs, Governments are taking sustainable fuels very seriously.  (A recent report highlighted that Pentagon investment in green technologies rose to $1.2 billion, up from $400 million, and is projected to reach $10 billion annually by 2030.)  The Pentagon’s Defence Advanced Research Projects Agency (which finances and monitors research into algae fuels,) says it has now managed to produce algafuel for $2 per gallon and that it will produce jet aircraft quality algafuel for $3 per gallon by 2013. Unsurprisingly, commercial aviation companies around the world are also taking an interest in algae biofuels to reduce their own costs and carbon footprints.

As interest grows and more funding becomes available, the industry is blossoming and more skilled people are needed. Could we witness a global shift to sustainable fuels in our lifetime?  We certainly hope so.

What is Algaculture

High oil prices, competing demands between foods and other biofuel sources, and the world food crisis, have ignited interest in algaculture (farming algae) for making vegetable oil, biodiesel, bioethanol, biogasoline, biomethanol, biobutanol and other biofuels, using land that is not suitable for agriculture. Algae holds enormous potential to provide a non-food, high-yield, non-arable land use source of biodiesel, ethanol and hydrogen fuels. Microalgae are the fastest growing photosynthesizing organism capable of completing an entire growing cycle every few days. Up to 50% of algae’s weight is comprised of oil, compared with, for example, oil palm which yields just about 20% of its weight in oil.

Algaculture (farming of algae) can be a route to making vegetable oils, biodiesel, bioethanol and other biofuels. Microalgae are one-celled, photosynthetic microorganisms that are abundant in fresh water, brackish water, and marine environments everywhere on earth. The potential for commercial algae production is expected to come from growth in translucent tubes or containers called photo bioreactors or open ocean algae bloom harvesting. The other advantages of algal systems include:

  • carbon capture from smokestacks to increase algae growth rates
  • processing of algae biomass through gasification to create syngas
  • growing carbohydrate rich algae strains for cellulosic ethanol
  • using waste streams from municipalities as water sources

Algae have certain qualities that make the organism an attractive option for biodiesel production. Unlike corn-based biodiesel which competes with food crops for land resources, algae-based production methods, such as algae ponds or photobioreactors, would “complement, rather than compete” with other biomass-based fuels. Unlike corn or other biodiesel crops, algae do not require significant inputs of carbon intensive fertilizers.  Some algae species can even grow in waters that contain a large amount of salt, which means that algae-based fuel production need not place a large burden on freshwater supplies.

Several companies and government agencies are funding efforts to reduce capital and operating costs and make algae fuel production commercially viable. Companies such as Sapphire Energy and Bio Solar Cellsare using genetic engineering to make algae fuel production more efficient. According to Klein Lankhorst of Bio Solar Cells, genetic engineering could vastly improve algae fuel efficiency as algae can be modified to only build short carbon chains instead of long chains of carbohydrates.

Sapphire Energy also uses chemically induced mutations to produce algae suitable for use as a crop. Some commercial interests into large-scale algal-cultivation systems are looking to tie in to existing infrastructures, such as cement factories, coal power plants, or sewage treatment facilities. This approach changes wastes into resources to provide the raw materials, CO2 and nutrients, for the system.

Could Biomass Be The Answer To South Africa’s Energy Problem?

South Africa is experiencing a mammoth energy crisis with its debt-laden national power utility, Eskom, being unable to meet the electricity needs of the nation. After extensive periods of load shedding in 2018 and again earlier this year, it is becoming increasingly important to find an alternative source of energy. According to Marko Nokkala, senior sales manager at VTT Technical Research Centre of Finland, South Africa is in the perfect position to utilize biomass as an alternative source of energy.

Things to Consider

Should South Africa choose to delve deeper into biomass energy production, there are a few things that need to be considered. At present, a lot of biomass (such as fruit and vegetables) is utilized as food. It will, therefore, be necessary to identify alternative biomass sources that are not typically used as food, so that a food shortage is never created in the process.

biomass-sustainability

One alternative would be to use municipal solid waste from landfills and dumpsites as well as the wood waste from the very large and lucrative forestry industry in the country. It is also essential to keep in mind that an enormous amount of biomass will be needed to replace even a portion of the 90 million tons of coal that Eskom utilizes every year at its various power stations.

Potential Biomass Conversion Routes

There are a number of processing technologies that South Africans can utilize to turn their biomass into a sustainable energy source. Biochemical conversion involving technology such as anaerobic digestion and fermentation makes use of enzymes, microorganisms, and bacteria to breakdown the biomass into a variety of liquid or vaporous fuels.

WTE_Pathways

Fermentation is especially suitable when the biomass waste boasts a high sugar or water content, as is the case with a variety of agricultural wastes. By placing some focus on microbial fermentation process development, a system can effectively be created that will allow for large-scale biofuel production. Other technologies to consider include thermal methods like co-firing, pyrolysis, and gasification.

Future of biomass energy in South Africa

Despite the various obstacles that may slow down the introduction of large-scale biomass energy production in the country, it still promises to be a viable solution to the pressing energy concern. Biomass energy production does not require any of the major infrastructures that Eskom is currently relying on.

Although the initial setup will require a substantial amount of electricity, running a biomass conversion plant will cost significantly less than a coal-powered power plant in the long run. With the unemployment rate hovering around 27.1% in South Africa at present, any jobs created through the implementation of biomass energy conversion will be of great benefit to the nation.

Conclusion

Without speedy intervention, South Africa may very soon be left in the dark. Although there are already a number of wind farms in operation in the country, the addition of biomass conversion facilities will undoubtedly be of great benefit to Africa’s southernmost country.

A Primer on Biofuels

The term ‘Biofuel’ refers to liquid or gaseous fuels for the transport sector that are predominantly produced from biomass. A variety of fuels can be produced from biomass resources including liquid fuels, such as ethanol, methanol, biodiesel, Fischer-Tropsch diesel, and gaseous fuels, such as hydrogen and methane. The biomass resource base for biofuel production is composed of a wide variety of forestry and agricultural resources, industrial processing residues, and municipal solid and urban wood residues.

The agricultural resources include grains used for biofuels production, animal manures and residues, and crop residues derived primarily from corn and small grains (e.g., wheat straw). A variety of regionally significant crops, such as cotton, sugarcane, rice, and fruit and nut orchards can also be a source of crop residues. The forest resources include residues produced during the harvesting of forest products, fuelwood extracted from forestlands, residues generated at primary forest product processing mills, and forest resources that could become available through initiatives to reduce fire hazards and improve forest health. Municipal and urban wood residues are widely available and include a variety of materials — yard and tree trimmings, land-clearing wood residues, wooden pallets, organic wastes, packaging materials, and construction and demolition debris.

Globally, biofuels are most commonly used to power vehicles, heat homes, and for cooking. Biofuel industries are expanding in Europe, Asia and the Americas. Biofuels are generally considered as offering many priorities, including sustainability, reduction of greenhouse gas emissions, regional development, social structure and agriculture, and security of supply.

First-generation biofuels are made from sugar, starch, vegetable oil, or animal fats using conventional technology. The basic feedstocks for the production of first-generation biofuels come from agriculture and food processing. The most common first-generation biofuels are:

  • Biodiesel: extraction with or without esterification of vegetable oils from seeds of plants like soybean, oil palm, oilseed rape and sunflower or residues including animal fats derived from rendering applied as fuel in diesel engines
  • Bioethanol: fermentation of simple sugars from sugar crops like sugarcane or from starch crops like maize and wheat applied as fuel in petrol engines
  • Bio-oil: thermo-chemical conversion of biomass. A process still in the development phase
  • Biogas: anaerobic fermentation or organic waste, animal manures, crop residues an energy crops applied as fuel in engines suitable for compressed natural gas.

First-generation biofuels can be used in low-percentage blends with conventional fuels in most vehicles and can be distributed through existing infrastructure. Some diesel vehicles can run on 100 % biodiesel, and ‘flex-fuel’ vehicles are already available in many countries around the world.

Second-generation biofuels are derived from non-food feedstock including lignocellulosic biomass like crop residues or wood. Two transformative technologies are under development.

  • Biochemical: modification of the bio-ethanol fermentation process including a pre-treatment procedure
  • Thermochemical: modification of the bio-oil process to produce syngas and methanol, Fisher-Tropsch diesel or dimethyl ether (DME).

Advanced conversion technologies are needed for a second generation of biofuels. The second generation technologies use a wider range of biomass resources – agriculture, forestry and waste materials. One of the most promising second-generation biofuel technologies – ligno-cellulosic processing (e. g. from forest materials) – is already well advanced. Pilot plants have been established in the EU, in Denmark, Spain and Sweden.

Third-generation biofuels may include production of bio-based hydrogen for use in fuel cell vehicles, e.g. Algae fuel, also called oilgae. Algae are low-input, high-yield feedstocks to produce biofuels.

Utilization of Date Palm Biomass

Date palm trees produce huge amount of agricultural wastes in the form of dry leaves, stems, pits, seeds etc. A typical date tree can generate as much as 20 kilograms of dry leaves per annum while date pits account for almost 10 percent of date fruits.

date-wastes

Date palm biomass is found in large quantities across the Middle East

Date palm is considered a renewable natural resource because it can be replaced in a relatively short period of time. It takes 4 to 8 years for date palms to bear fruit after planting, and 7 to 10 years to produce viable yields for commercial harvest. Usually date palm wastes are burned in farms or disposed in landfills which cause environmental pollution in dates-producing nations.

The major constituents of date palm biomass are cellulose, hemicelluloses and lignin. In addition, date palm has high volatile solids content and low moisture content. These factors make date palm residues an excellent biomass resource in date-palm producing nations.

Date palm biomass is an excellent resource for charcoal production in Middle East

A wide range of physico-chemical, thermal and biochemical technologies exists for sustainable utilization of date palm biomass. Apart from charcoal production and energy conversion (using technologies like combustion and gasification), below are few ways for utilization of date palm wastes:

Conversion into fuel pellets or briquettes

Biomass pellets are a popular type of alternative fuel (analogous to coal), generally made from wood wastes and agricultural biomass. The biomass pelletization process consists of multiple steps including pre-treatment, pelletization and post-treatment of biomass wastes. Biomass pellets can be used as a coal replacement in power plant, industries and other application.

Conversion into energy-rich products

Biomass pyrolysis is the thermal decomposition of date palm biomass occurring in the absence of oxygen. The products of biomass pyrolysis include biochar, bio-oil and gases including methane, hydrogen, carbon monoxide, and carbon dioxide.

Depending on the thermal environment and the final temperature, pyrolysis will yield mainly biochar at low temperatures, less than 450 0C, when the heating rate is quite slow, and mainly gases at high temperatures, greater than 800 0C, with rapid heating rates. At an intermediate temperature and under relatively high heating rates, the main product is bio-oil.

Bio-oil can be upgraded to either a special engine fuel or through gasification processes to a syngas which can then be processed into biofuels. Bio-oil is particularly attractive for co-firing because it can be more readily handled and burned than solid fuel and is cheaper to transport and store.

Conversion into biofertilizer

Composting is the most popular method for biological decomposition of organic wastes. Date palm waste has around 80% organic content which makes it very well-suited for the composting process. Commercial-scale composting of date palm wastes can be carried out by using the traditional windrow method or a more advanced method like vermicomposting.

Ethanol from Lignocellulosic Biomass

Cellulosic ethanol technology is one of the most commonly discussed second-generation biofuel technologies worldwide. Cellulosic biofuels are derived from the cellulose in plants, some of which are being developed specifically as “energy” crops rather than for food production. These include perennial grasses and trees, such as switchgrass and Miscanthus. Crop residues, in the form of stems and leaves, represent another substantial source of cellulosic biomass.

The largest potential feedstock for ethanol is lignocellulosic biomass, which includes materials such as agricultural residues (corn stover, crop straws, husks and bagasse), herbaceous crops (alfalfa, switchgrass), short rotation woody crops, forestry residues, waste paper and other wastes (municipal and industrial). Bioethanol production from these feedstocks could be an attractive alternative for disposal of these residues. Lignocellulosic feedstocks do not interfere with food security and are important for both rural and urban areas in terms of energy security reason, environmental concern, employment opportunities, agricultural development, foreign exchange saving, socioeconomic issues etc.

Production of Ethanol

The production of ethanol from lignocellulosic biomass can be achieved through two different processing routes. They are:

  • Biochemical – in which enzymes and other micro-organisms are used to convert cellulose and hemicellulose components of the feedstocks to sugars prior to their fermentation to produce ethanol;
  • Thermochemical – where pyrolysis/gasification technologies produce a synthesis gas (CO + H2) from which a wide range of long carbon chain biofuels, such as synthetic diesel or aviation fuel, can be reformed.

Lignocellulosic biomass consists mainly of lignin and the polysaccharides cellulose and hemicellulose. Compared with the production of ethanol from first-generation feedstocks, the use of lignocellulosic biomass is more complicated because the polysaccharides are more stable and the pentose sugars are not readily fermentable by Saccharomyces cerevisiae. In order to convert lignocellulosic biomass to biofuels the polysaccharides must first be hydrolysed, or broken down, into simple sugars using either acid or enzymes. Several biotechnology-based approaches are being used to overcome such problems, including the development of strains of Saccharomyces cerevisiae that can ferment pentose sugars, the use of alternative yeast species that naturally ferment pentose sugars, and the engineering of enzymes that are able to break down cellulose and hemicellulose into simple sugars.

Ethanol from lignocellulosic biomass is produced mainly via biochemical routes. The three major steps involved are pretreatment, enzymatic hydrolysis, and fermentation. Biomass is pretreated to improve the accessibility of enzymes. After pretreatment, biomass undergoes enzymatic hydrolysis for conversion of polysaccharides into monomer sugars, such as glucose and xylose. Subsequently, sugars are fermented to ethanol by the use of different microorganisms.

Pretreated biomass can directly be converted to ethanol by using the process called simultaneous saccharification and cofermentation (SSCF).  Pretreatment is a critical step which enhances the enzymatic hydrolysis of biomass. Basically, it alters the physical and chemical properties of biomass and improves the enzyme access and effectiveness which may also lead to a change in crystallinity and degree of polymerization of cellulose. The internal surface area and pore volume of pretreated biomass are increased which facilitates substantial improvement in accessibility of enzymes. The process also helps in enhancing the rate and yield of monomeric sugars during enzymatic hydrolysis steps.

Pretreatment of Lignocellulosic Biomass

Pretreatment methods can be broadly classified into four groups – physical, chemical, physio-chemical and biological. Physical pretreatment processes employ the mechanical comminution or irradiation processes to change only the physical characteristics of biomass. The physio-chemical process utilizes steam or steam and gases, like SO2 and CO2. The chemical processes employs acids (H2SO4, HCl, organic acids etc) or alkalis (NaOH, Na2CO3, Ca(OH)2, NH3 etc). The acid treatment typically shows the selectivity towards hydrolyzing the hemicelluloses components, whereas alkalis have better selectivity for the lignin. The fractionation of biomass components after such processes help in improving the enzymes accessibility which is also important to the efficient utilization of enzymes.

Conclusions

The major cost components in bioethanol production from lignocellulosic biomass are the pretreatment and the enzymatic hydrolysis steps. In fact, these two process are someway interrelated too where an efficient pretreatment strategy can save substantial enzyme consumption. Pretreatment step can also affect the cost of other operations such as size reduction prior to pretreatment. Therefore, optimization of these two important steps, which collectively contributes about 70% of the total processing cost, are the major challenges in the commercialization of bioethanol from 2nd generation feedstock.

The Concept of Biorefinery

A biorefinery is a facility that integrates biomass conversion processes and equipment to produce fuels, power, and value-added chemicals from biomass. Biorefinery is analogous to today’s petroleum refinery, which produces multiple fuels and products from petroleum. By producing several products, a biorefinery takes advantage of the various components in biomass and their intermediates, therefore maximizing the value derived from the biomass feedstock.

A biorefinery could, for example, produce one or several low-volume, but high-value, chemical products and a low-value, but high-volume liquid transportation fuel such as biodiesel or bioethanol. At the same time, it can generate electricity and process heat, through CHP technology, for its own use and perhaps enough for sale of electricity to the local utility. The high value products increase profitability, the high-volume fuel helps meet energy needs, and the power production helps to lower energy costs and reduce GHG emissions from traditional power plant facilities.

Biorefinery Platforms

There are several platforms which can be employed in a biorefinery with the major ones being the sugar platform and the thermochemical platform (also known as syngas platform).

Sugar platform biorefineries breaks down biomass into different types of component sugars for fermentation or other biological processing into various fuels and chemicals. On the other hand, thermochemical biorefineries transform biomass into synthesis gas (hydrogen and carbon monoxide) or pyrolysis oil.

The thermochemical biomass conversion process is complex, and uses components, configurations, and operating conditions that are more typical of petroleum refining. Biomass is converted into syngas, and syngas is converted into an ethanol-rich mixture. However, syngas created from biomass contains contaminants such as tar and sulphur that interfere with the conversion of the syngas into products. These contaminants can be removed by tar-reforming catalysts and catalytic reforming processes. This not only cleans the syngas, it also creates more of it, improving process economics and ultimately cutting the cost of the resulting ethanol.

Plus Points

Biorefineries can help in utilizing the optimum energy potential of organic wastes and may also resolve the problems of waste management and GHGs emissions. Biomass wastes can be converted, through appropriate enzymatic/chemical treatment, into either gaseous or liquid fuels. The pre-treatment processes involved in biorefining generate products like paper-pulp, HFCS, solvents, acetate, resins, laminates, adhesives, flavour chemicals, activated carbon, fuel enhancers, undigested sugars etc. which generally remain untapped in the traditional processes. The suitability of this process is further enhanced from the fact that it can utilize a variety of biomass resources, whether plant-derived or animal-derived.

Future Perspectives

The concept of biorefinery is still in early stages at most places in the world. Problems like raw material availability, feasibility in product supply chain, scalability of the model are hampering its development at commercial-scales. The National Renewable Energy Laboratory (NREL) of USA is leading the front in biorefinery research with path-breaking discoveries and inventions. Although the technology is still in nascent stages, but it holds the key to the optimum utilization of wastes and natural resources that humans have always tried to achieve. The onus now lies on governments and corporate sector to incentivize or finance the research and development in this highly promising field.

Biobutanol as a Biofuel

The major techno-commercial limitations of existing biofuels has catalyzed the development of advanced biofuels such as cellulosic ethanol, biobutanol and mixed alcohols. Biobutanol is generating good deal of interest as a potential green alternative to petroleum fuels. It is increasingly being considered as a superior automobile fuel in comparison to bioethanol as its energy content is higher. The problem of demixing that is encountered with ethanol-petrol blends is considerably less serious with biobutanol-petrol blends. Besides, it reduces the harmful emissions substantially. It is less corrosive and can be blended in any concentration with petrol (gasoline). Several research studies suggest that butanol can be blended into either petrol or diesel to as much as 45 percent without engine modifications or severe performance degradation.

Production of Biobutanol

Biobutanol is produced by microbial fermentation, similar to bioethanol, and can be made from the same range of sugar, starch or cellulosic feedstocks. The most commonly used microorganisms are strains of Clostridium acetobutylicum and Clostridium beijerinckii. In addition to butanol, these organisms also produce acetone and ethanol, so the process is often referred to as the “ABE fermentation”.

The main concern with Clostridium acetobutylicum is that it easily gets poisoned at concentrations above 2% of biobutanol in the fermenting mixture. This hinders the production of bio-butanol in economically viable quantities. In recent years, there has been renewed interest in biobutanol due to increasing petroleum prices and search for clean energy resources. Researchers have made significant advances in designing new microorganisms capable of surviving in high butanol concentrations. The new genetically modified micro-organisms have the capacity to degrade even the cellulosic feedstocks.

Latest Trends

Biobutanol production is currently more expensive than bioethanol which has hampered its commercialization. However, biobutanol has several advantages over ethanol and is currently the focus of extensive research and development. There is now increasing interest in use of biobutanol as a transport fuel. As a fuel, it can be transported in existing infrastructure and does not require flex-fuel vehicle pipes and hoses. Fleet testing of biobutanol has begun in the United States and the European Union. A number of companies are now investigating novel alternatives to traditional ABE fermentation, which would enable biobutanol to be produced on an industrial scale.