Applications of Biochar

Biochar is a carbon-rich, fine-grained residue which can be produced either by ancient techniques (such as covering burning biomass with soil and allowing it to smoulder) or state-of-the-art modern biomass pyrolysis processes. Combustion and decomposition of woody biomass and agricultural residues results in the emission of a large amount of carbon dioxide. Biochar can store this CO2 in the soil leading to reduction in GHGs emission and enhancement of soil fertility. Biochar holds the promise to tackle chronic human development issues like hunger and food insecurity, low agricultural productivity and soil depletion, deforestation and biodiversity loss, energy poverty, water pollution, air pollution and climate change. Let us have a close look at some of the most promising applications of biochar.

 

Use of biochar in animal farming

At present approx. 90% of the biochar used in Europe goes into animal farming. Different to its application to fields, a farmer will notice its effects within a few days. Whether used in feeding, litter or in slurry treatment, a farmer will quickly notice less smell. Used as a feed supplement, the incidence of diarrhoea rapidly decreases, feed intake is improved, allergies disappear, and the animals become calmer.

In Germany, researchers conducted a controlled experiment in a dairy that was experiencing a number of common health problems: reduced performance, movement disorder, fertility disorders, inflammation of the urinary bladder, viscous salivas, and diarrhoea. Animals were fed different combinations of charcoal, sauerkraut juice or humic acids over periods of 4 to 6 weeks.

Experimenters found that oral application of charcoal (from 200 to 400 g/day), sauerkraut juice and humic acids influenced the antibody levels to C. botulinum, indicating reduced gastrointestinal neurotoxin burden. They found that when the feed supplements were ended, antibody levels increased, indicating that regular feeding of charcoal and other supplements had a tonic effect on cow health.

Biochar as soil conditioner

In certain poor soils (mainly in the tropics), positive effects on soil fertility were seen when applying untreated biochar. These include the higher capacity of the soil to store water, aeration of the soil and the release of nutrients through raising the soil’s pH-value. In temperate climates, soils tend to have humus content of over 1.5%, meaning that such effects only play a secondary role.

Indeed, fresh biochar may adsorb nutrients in the soil, causing at least in the short and medium term – a negative effect on plant growth. These are the reasons why in temperate climates biochar should only be used when first loaded with nutrients and when the char surfaces have been activated through microbial oxidation.

The best method of loading nutrients is to co-compost the char. This involves adding 10–30% biochar (by volume) to the biomass to be composted. Co-composting improves both the biochar and the compost. The resulting compost can be used as a highly efficient substitute for peat in potting soil, greenhouses, nurseries and other special cultures.

Because biochar serves as a carrier for plant nutrients, it can produce organic carbon-based fertilizers by mixing biochar with such organic waste as wool, molasses, ash, slurry and pomace. These are at least as efficient as conventional fertilizers, and have the advantage of not having the well-known adverse effects on the ecosystem. Such fertilizers prevent the leaching of nutrients, a negative aspect of conventional fertilizers. The nutrients are available as and when the plants need them. Through the stimulation of microbial symbiosis, the plant takes up the nutrients stored in the porous carbon structure and on its surfaces.
A range of organic chemicals are produced during pyrolysis. Some of these remain stuck to the pores and surfaces of the biochar and may have a role in stimulating a plant’s internal immune system, thereby increasing its resistance to pathogens. The effect on plant defence mechanisms was mainly observed when using low temperature biochars (pyrolysed at 350° to 450°C). This potential use is, however, only just now being developed and still requires a lot of research effort.

Biochar as construction material

The two interesting properties of biochar are its extremely low thermal conductivity and its ability to absorb water up to 6 times its weight. These properties mean that biochar is just the right material for insulating buildings and regulating humidity. In combination with clay, but also with lime and cement mortar, biochar can be added to clay at a ratio of up to 50% and replace sand in lime and cement mortars. This creates indoor plasters with excellent insulation and breathing properties, able to maintain humidity levels in a room at 45–70% in both summer and winter. This in turn prevents not just dry air, which can lead to respiratory disorders and allergies, but also dampness and air condensing on the walls, which can lead to mould developing.

As per study by the Ithaka Institute’s biochar-plaster wine cellar and seminar rooms in the Ithaka Journal. Such biochar-mud plaster adsorbs smells and toxins, a property not just benefiting smokers. Biochar-mud plasters can improve working conditions in libraries, schools, warehouses, factories and agricultural buildings.

Biochar is an efficient adsorber of electromagnetic radiation, meaning that biochar-mud plaster can prevent “electrosmog”. Biochar can also be applied to the outside walls of a building by jet-spray technique mixing it with lime. Applied at thicknesses of up to 20 cm, it is a substitute for Styrofoam insulation. Houses insulated this way become carbon sinks, while at the same time having a more healthy indoor climate. Should such a house be demolished at a later date, the biochar-mud or biochar-lime plaster can be recycled as a valuable compost additive.

Biochar as decontaminant

As a soil additive for soil remediation – for use in particular on former mine-works, military bases and landfill sites.

Soil substrates – Highly adsorbing and effective for plantation soil substrates for use in cleaning wastewater; in particular urban wastewater contaminated by heavy metals.

A barrier preventing pesticides getting into surface water – berms around fields and ponds can be equipped with 30-50 cm deep barriers made of bio-char for filtering out pesticides.

Treating pond and lake water – bio-char is good for adsorbing pesticides and fertilizers, as well as for improving water aeration.

Use of biochar in wastewater treatment – Our Project

The biochar grounded to a particle size of less than 1.5 mm and surface area of 600 – 1000 m2/g. The figure below is the basic representation of production of bio-char for wastewater treatment.

We conducted a study for municipal wastewater which was obtained from a local municipal treatment plant. The municipal wastewater was tested for its physicochemical parameters including pH, chemical oxygen demand (COD), total suspended solids (TSS), total phosphates (TP) and total Kjeldahl nitrogen (TKN) using the APHA (2005) standard methods.

Bio filtration of the municipal wastewater with biochar acting as the bio adsorbent was allowed to take place over a 5 day period noting the changes in the wastewater parameters. The municipal wastewater and the treated effluent physicochemical.

The COD concentration in the municipal wastewater decreased by 90% upon treatment with bio-char. The decrease in the COD was attributed to the enhanced removal of bio contaminants as they were passed through the bio char due to the bio char’s adsorption properties as well as the high surface area of the bio char. An 89% reduction in the TSS was observed as the bio filtration process with bio char increased from one day to five days

The TKN concentration in the wastewater decreased by 64% upon treatment with bio char as a bio filter. The TP in the wastewater decreased by 78% as the bio filtration time with bio char increase. The wastewater pH changed from being alkaline to neutral during the treatment with bio char over the 5 day period

Use in Textiles

In Japan and China bamboo-based bio-chars are already being woven into textiles to gain better thermal and breathing properties and to reduce the development of odours through sweat. The same aim is pursued through the inclusion of bio-char in shoe soles and socks.

Salient Features of Sugar Industry in Mauritius

Sugar industry has always occupied a prominent position in the Mauritian economy since the introduction of sugarcane around three centuries ago. Mauritius has been a world pioneer in establishing sales of bagasse-based energy to the public grid, and is currently viewed as a model for other sugarcane producing countries, especially the developing ones.

Sugar factories in Mauritius produce about 600,000 tons of sugar from around 5.8 million tons of sugarcane which is cultivated on an agricultural area of about 72,000 hectares. Of the total sugarcane production, around 35 percent is contributed by nearly 30,000 small growers. There are more than 11 sugar factories presently operating in Mauritius having crushing capacities ranging from 75 to 310 tons cane per hour.

During the sugar extraction process, about 1.8 million tons of Bagasse is produced as a by-product, or about one third of the sugarcane weight. Traditionally, 50 percent of the dry matter is harvested as cane stalk to recover the sugar with the fibrous fraction, i.e. Bagasse being burned to power the process in cogeneration plant. Most factories in Mauritius have been upgraded and now export electricity to the grid during crop season, with some using coal to extend production during the intercrop season.

Surplus electricity is generated in almost all the sugar mills. The total installed capacity within the sugar industry is 243 MW out of which 140 MW is from firm power producers. Around 1.6 – 1.8 million tons of bagasse (wet basis) is generated on an annually renewable basis and an average of around 60 kWh per ton sugarcane is generated for the grid throughout the island.

The surplus exportable electricity in Mauritian power plants has been based on a fibre content ranging from 13- 16% of sugarcane, 48% moisture content in Bagasse, process steam consumption of 350–450 kg steam per ton sugarcane and a power consumption of 27-32 kWh per ton sugarcane.

In Mauritius, the sugarcane industry is gradually increasing its competitiveness in electricity generation. It has revamped its boiler houses by installing high pressure boilers and condensing extraction steam turbine. All the power plants are privately owned, and the programme has been a landmark to show how all the stakeholders (government, corporate and small planters) can co-operate. The approach is being recommended to other sugarcane producing countries worldwide to harness the untapped renewable energy potential of biomass wastes from the sugar industry.

How is Biomass Transported

Transporting biomass fuel to a power plant is an important aspect of any biomass energy project. Because a number of low moisture fuels can be readily collected and transported to a centralized biomass plant location or aggregated to enhance project size, this opportunity should be evaluated on a case-by-case basis.

It will be a good proposition to develop biomass energy plants at the location where the bulk of the agricultural waste stream is generated, without bearing the additional cost of transporting waste streams. Effective capture and use of thermal energy at the site for hot water, steam, and even chilled water requirements raises the energy efficiency of the project, thereby improving the value of the waste-to-energy project.

Important Factors

  • The maximum rate of biomass supply to the conversion facility.
  • The form and bulk density of biomass.
  • The hauling distance for biomass transportation to the processing plant.
  • Transportation infrastructure available between the points of biomass dispatch and processing plant

Transportation is primarily concerned with loading and unloading operation and transferring biomass from pre-processing sites to the main processing plant or biorefinery. Truck transport and for a few cases train transport may be the only modes of transport. Barge and pipeline transport and often train transport involve truck transport. Trucks interface with trains at loading and unloading facilities of a depot or processing facility. Barge and pipeline require interfacing with train and/or truck transport at major facilities either on land or at the shores.

Physical form and quality of biomass has the greatest influence on the selection of equipment for the lowest delivered cost possible. A higher bulk density will allow more mass of material to be transported per unit distance. Truck transport is generally well developed, is usually cheapest mode of transport but it becomes expensive as travel distance increases. Pipeline biomass transport is the least known technology and may prove to be the cheapest and safest mode of transport in the near future.

A biomass freight train in England

Transportation costs of low-density and high-moisture agricultural residues straw are a major constraint to their use as an energy source. As a rule of thumb, transportation distances beyond a 25–50- km radius (depending on local infrastructure) are uneconomical. For long distances, agricultural residues could be compressed as bales or briquettes in the field, rendering transport to the site of use a viable option.

Greater use of biomass and larger?scale conversion systems demand larger?scale feedstock handling and delivery infrastructure. To accommodate expansion in feedstock collection and transportation, production centres can be established where smaller quantities of biomass are consolidated, stored, and transferred to long?distance transportation systems, in much the same way that transfer stations are used in municipal waste handling. Pre?processing equipment may be used to densify biomass, increasing truck payloads and reducing transportation costs over longer haul distances.

A Primer on Agricultural Residues

The term agricultural residue is used to describe all the organic materials which are produced as by-products from harvesting and processing of agricultural crops. These residues can be further categorized into primary residues and secondary residues. Agricultural residues, which are generated in the field at the time of harvest, are defined as primary or field based residues whereas those co-produced during processing are called secondary or processing based residues.

  • Primary residues – paddy straw, sugarcane top, maize stalks, coconut empty bunches and frond, palm oil frond and bunches;
  • Secondary residues – paddy husk, bagasse, maize cob, coconut shell, coconut husk, coir dust, saw dust, palm oil shell, fiber and empty bunches, wastewater, black liquor.

Agricultural residues are highly important sources of biomass fuels for both the domestic and industrial sectors. Availability of primary residues for energy application is usually low since collection is difficult and they have other uses as fertilizer, animal feed etc. However secondary residues are usually available in relatively large quantities at the processing site and may be used as captive energy source for the same processing plant involving minimal transportation and handling cost.

Crop residues encompasses all agricultural wastes such as straw, stem, stalk, leaves, husk, shell, peel, pulp, stubble, etc. which come from cereals (rice, wheat, maize or corn, sorghum, barley, millet), cotton, groundnut, jute, legumes (tomato, bean, soy) coffee, cacao, tea, fruits (banana, mango, coco, cashew) and palm oil.

Rice produces both straw and rice husks at the processing plant which can be conveniently and easily converted into energy. Significant quantities of biomass remain in the fields in the form of cob when maize is harvested which can be converted into energy. Sugar cane harvesting leads to harvest residues in the fields while processing produces fibrous bagasse, both of which are good sources of energy. Harvesting and processing of coconuts produces quantities of shell and fibre that can be utilised while peanuts leave shells. All these materials can be converted into useful energy by a wide range of technologies..

Towards Sustainable Biomass Energy

biomass-balesBiomass is one of the oldest and simplest ways of getting heat and energy, and it’s starting to make a comeback due to its status as renewable resource. Some, however, aren’t so sure that using more of it would be good for our environment. So, how sustainable is biomass energy really?

What is Biomass?

Biomass is organic material from plants and animals. It naturally contains energy because plants absorb it from the sun through photosynthesis. When you burn biomass, it releases that energy. It’s also sometimes converted into a liquid or gas form before it is burned.

Biomass includes a wide variety of materials but includes:

  • Wood and wood processing waste
  • Agricultural crops
  • Garbage made up of food, yard and wood waste
  • Animal manure and human sewage

About five percent of the United States’ energy comes from biomass. Biomass fuel products such as ethanol make up about 48 percent of that five percent while wood makes up about 41 percent and municipal waste accounts for around 11 percent.

The Benefits of Biomass

Biomass is a renewable resource because the plants that store the energy released when it is burned can be regrown continuously. In theory, if you planted the same amount of vegetation that you burned, it would be carbon neutral because the plants would absorb all of the carbon released. Doing this is, however, much easier said than done.

Another potential is that it serves as a use for waste materials that have are already been created. It adds value to what otherwise would be purely waste.

Additionally, many forms of biomass are also relatively low-tech energy sources, so they may be useful, or even required for older buildings that need an electrical renovation.

Drawbacks of Biomass

A major drawback of using biomass fuel is that it is not an efficient process. In fact, burning it can release even more carbon dioxide than burning the same amount of a fossil fuel.

While you can replenish the organic matter you burn, doing so requires complex crop or forest management and the use of a large amount of land.  Also, some biomass, such as wood, takes a long time to grow back. This amounts to a delay in carbon absorption. Additionally, the harvesting of biomass will likely involve some sort of emissions.

 Is it Sustainable?

So, is biomass energy sustainable? Measuring the environmental impacts of biomass fuel use has proven to be complex due to the high number of variables, which has led to a lot of disagreement about this question.

Some assert that biomass use cannot be carbon neutral, because even if you burned and planted the same amount of organic matter, harvesting it would still result in some emissions. This could perhaps be avoided if you used renewable energy to harvest it. A continuous supply of biomass would likely require it to be transported long distances, worsening the challenge of going carbon neutral.

With careful planning, responsible land management and environmentally friendly harvesting and distribution, biomass could be close to, if not entirely, carbon neutral and sustainable. Given our reliance on fossil fuels, high energy consumption levels and the limited availability of land and other resources, this would be an immense challenge to undertake and require a complete overhaul of our energy use.

How to Improve the Biomass Industry

Biomass could emerge as a major solution to our energy and sustainability issues, but it isn’t likely to be a comprehensive solution. There are some things we can do, though, to make biomass use more sustainable when we do use it.

  • Source locally: Using biomass that comes from the local area reduces the impact of distributing it.
  • Clean distribution: If you do transport biofuel long distances, using an electric or hybrid vehicles powered largely by clean energy would be the most eco-friendly way to do it. This also applies to transporting it short distances.

Measuring the environmental impacts of biomass fuel use is complex due to high number of variables

  • Clean harvesting: Using environmentally friendly, non-emitting means of harvesting can greatly reduce the impact of using biomass. This might also involve electric vehicles.
  • Manage land sustainably: For biomass to be healthy for the ecosystem, you must manage land used to grow it with responsible farming practices.
  • Focus on waste: Waste is likely the most environmentally friendly form of biomass because it uses materials that would otherwise simply decompose and doesn’t require you to grow any new resources for your fuel or energy needs.

Is biomass energy sustainable? It has the potential to be, but doing so would be quite complex and require quite a bit of resources. Any easier way to address the problem is to look at small areas of land and portions of energy use first. First, make that sustainable and then we may be able to expand that model on to a broader scale.

Biogas in Agriculture Sector in India: Key Challenges

Although the conversion of agriculture waste – cattle dung and crop residues –  to biogas and digested slurry is an established and well-proven technology, it has been under-used, probably because until recently, firewood was easily available and chemical fertilizer was relatively affordable to most of the farmers in India.

The National Biogas and Manure Management Programme (NBMMP) was put in place to lower the environmental degradation and prevent greenhouse gas emissions, like carbon dioxide and methane, into the atmosphere. However, this objective of the program is less likely to motivate the farmers and their families to install biogas plants.

This program rolled out by Ministry of Non-Conventional Energy Sources (now Ministry of New and Renewable Energy), New Delhi, with heavy subsidies for family-type biogas plants to increase adoption, was successful with lakhs of biogas plants being installed across the country till now.

It was realised that due to poor dissemination of information and unsatisfactory communication about the plant operation & application of the digested biogas slurry, and unable to perceive the return in terms of value resulted in discontinuation of lakhs of biogas plants across the country.

The entire biogas technology marketing efforts failed to highlight major advantage – an increased revenue from agriculture with the use of high quality and a low-cost homegrown digested biogas slurry as fertiliser. Another advantage was to help farmers’ understand that their land quality and output per acre will increase over the years by the use of digested biogas slurry which has been degraded from the rampant use of chemical fertiliser and pesticides.

Challenges to be addressed

The farmer’s communities today are required to made to understand that their revenue from agriculture is decreasing year on year due to increasing deforestation, degradation of land quality, rampant use of chemical fertiliser and pesticides, lack of farm cattle, injudicious use of water for irrigation, and use heavy vehicles for ploughing.

These ill-advised decisions have made the farmers poorer, impacted the health of their families and the rural environment of villages. The years ahead are crucial if this trend is not reversed.

Unending benefits of biogas technology

Most of the rural and semi-urban areas have a poor perception of the Anaerobic Digestion (or biogas or biomethanation) technology. This technology offers benefits to all spheres of society but have a particular emphasis on the needs of the farmers in rural areas.

Farmers with dairy animals generally have free access to animal waste (dung), which provide input feed for the biogas digesters. Normally, these farmers stock-pile the dung obtained from their cattle as a plant fertilizer, but this has lower nitrogen content than the digested biogas slurry created by the biogas digestion process, which is odorless and makes a better fertilizer to substitute chemical fertilizers. They can use the gas for cooking or heating, for running power generators. The biogas technology helps farmers reduce their burden to buy LPG and harmful chemical fertilizers and pesticides.

In short, biogas technology is an integrated solution for sustainable agriculture, improving health and lowering environment degradation.

The promise of biogas technology

Biogas technology can help in the following manner:

  • Enhance bio-security for dairy animals – being fully fermented, bio-slurry is odorless and does not attract flies, repels termites and pests that are attracted to raw dung.
  • Provides high quality and low-cost homegrown fertiliser for sustainable agriculture.
  • Reduce energy poverty and ensure energy security.
  • Digested biogas slurry is an excellent soil conditioner with humic acid.
  • Save time for women for education and livelihood activities.
  • Increase forest cover as less firewood would be needed on a daily basis.
  • Reduce weed growth

Importance of Government Efforts

The agriculture sector is playing a major role in India economy and it comprises a huge vote bank. Our government has launched various initiatives like GOBAR-DHAN (Galvanizing Organic Bio-Agro Resources Dhan), Sustainable Alternative towards Affordable Transportation (SATAT), and New National Biogas and Organic Manure Programme (NNBOMP) in attempt to revive interest in biogas technology for farmers and entrepreneurs.

rice-straw-biogas

Agricultural residues, such as rice straw, are an important carbon source for anaerobic digestion

These initiatives are aimed at developmental efforts that would benefit the farmers, vehicle-users, and entrepreneurs. These initiatives also hold a great promise for efficient solid waste management and tackling problems of indoor air pollution caused by use of firewood, deforestation and methane gas release in the atmosphere due to open piling of cattle dung.

These initiatives aren’t marketing the value which solves a major challenge – degradation of agriculture land for farming in rural India. The initiative and efforts are majorly focused on waste management, environment and towards behavioral change. These changes are of global importance and can be managed effortlessly by generating tangible results for farmers.

India has an aspiring young workforce which is moving to urban settlements in hope for better opportunities, therefore, productivity and revenue from agriculture needs to grow. The biogas technology can restore agriculture productivity and strengthen revenue to make it attractive.

Note: This article was first published by author on LinkedIn.com. The link to this article – https://www.linkedin.com/pulse/bio-gas-misunderstood-agri-technology-zahir-kapasi/

Biogas from Crop Wastes: European Perspectives

Most, if not all of Europe has a suitable climate for biogas production. The specific type of system depends on the regional climate. Regions with harsher winters may rely more on animal waste and other readily available materials compared to warmer climates, which may have access to more crop waste or organic material.

Regardless of suitability, European opinions vary on the most ethical and appropriate materials to use for biogas production. Multiple proponents argue biogas production should be limited to waste materials derived from crops and animals, while others claim crops should be grown with the intention of being used for biogas production.

Biogas Production From Crops

Europeans in favor of biogas production from crops argue the crops improve the quality of the soil. Additionally, they point to the fact that biogas is a renewable energy resource compared to fossil fuels. Crops can be rotated in fields and grown year after year as a sustainable source of fuel.

Extra crops can also improve air quality. Plants respire carbon dioxide and can help reduce harmful greenhouse gasses in the air which contribute to global climate change.

Biogas crops can also improve water quality because of plant absorption. Crops grown in otherwise open fields reduce the volume of water runoff which makes it to lakes, streams and rivers. The flow of water and harmful pollutants is impeded by the plants and eventually absorbed into the soil, where it is purified.

Urban residents can also contribute to biogas production by growing rooftop or vertical gardens in their homes. Waste from tomatoes, beans and other vegetables is an excellent source of biogas material. Residents will benefit from improved air quality and improved water quality as well by reducing runoff.

Proponents of biogas production from crops aren’t against using organic waste material for biogas production in addition to crop material. They believe crops offer another means of using more sustainable energy resources.

Biogas Production From Waste Materials Only

Opponents to growing crops for biogas argue the crops used for biogas production degrade soil quality, making it less efficient for growing crops for human consumption. They also argue the overall emissions from biogas production from crops will be higher compared to fossil fuels.

Growing crops can be a labor-intensive process. Land must be cleared, fertilized and then seeded. While crops are growing, pesticides and additional fertilizers may be used to promote crop growth and decrease losses from pests. Excess chemicals can run off of fields and degrade the water quality of streams, lakes and rivers and kill off marine life.

Once crops reach maturity, they must be harvested and processed to be used for biogas material. Biogas is less efficient compared to fossil fuels, which means it requires more material to yield the same amount of energy. Opponents argue that when the entire supply chain is evaluated, biogas from crops creates higher rates of emissions and is more harmful to the environment.

Agricultural residues, such as rice straw, are an important carbon source for anaerobic digestion

The supply chain for biogas from agricultural waste materials is more efficient compared to crop materials. Regardless of whether or not the organic waste is reused, it must be disposed of appropriately to prevent any detrimental environmental impacts. When the waste material is then used for biogas production, it creates an economical means of generating useful electricity from material which would otherwise be disposed of.

Rural farms which are further away from the electric grid can create their own sources of energy through biogas production from waste material as well. The cost of the energy will be less expensive and more eco-friendly as it doesn’t have the associated transportation costs.

Although perspectives differ on the type of materials which should be used for biogas production, both sides agree biogas offers an environmentally friendly and sustainable alternative to using fossil fuels.

Bagasse-Based Cogeneration in Pakistan: Challenges and Opportunities

Considering the fact that Pakistan is among the world’s top-10 sugarcane producers, the potential of generating electricity from bagasse is huge.  Almost all the sugar mills in Pakistan have in-house plants for cogeneration but they are inefficient in the consumption of bagasse. If instead, high pressure boilers are installed then the production capacity can be significantly improved with more efficient utilization of bagasse.

However, due to several reasons; mostly due to financing issues, the sugar mill owners were not able to set up these plants. Only recently, after financial incentives have been offered and a tariff rate agreed upon between the government and mill owners, are these projects moving ahead.

The sugar mill owners are more than willing to supply excess electricity generated form the in-house power plants to the national grid but were not able to before, because they couldn’t reach an agreement with the government over tariff. The demand for higher tariff was justified because of large investments in setting up new boilers. It would also have saved precious foreign exchange which is spent on imported oil.

By estimating the CDM potential of cogeneration (or CHP) projects based on biofuels, getting financing for these projects would be easier. Renewable energy projects can be developed through Carbon Development Mechanism or any other carbon credit scheme for additional revenue.

Since bagasse is a clean fuel which emits very little carbon emissions it can be financed through Carbon Development Mechanism. One of the reasons high cogeneration power plants are difficult to implement is because of the high amount of costs associated. The payback period for the power plants is unknown which makes the investors reluctant to invest in the high cogeneration project. CDM financing can help improve the rate of return of the project.

Bagasse power plants generate Carbon Emission Reductions in 2 ways; one by replacing electricity produced from fossil fuels.  Secondly if not used as a fuel, it would be otherwise disposed off in an unsafe manner and the methane emissions present in biomass would pollute the environment far more than CO2 does.

Currently there are around 83 sugar mills in Pakistan producing about 3.5 million metric tons of sugar per annum with total crushing capacity 597900 TCD, which can produce approximately 3000 MW during crop season Although it may seem far-fetched at the moment, if the government starts to give more attention to  sugar industry biomass rather than coal, Pakistan can fulfill its energy needs without negative repercussions or damage to the environment.

However some sugar mills are opting to use coal as a secondary fuel since the crushing period of sugarcane lasts only 4 months in Pakistan. The plants would be using coal as the main fuel during the non-crushing season. The CDM effect is reduced with the use of coal. If a high cogeneration plant is using even 80% bagasse and 20% of coal then the CERs are almost nullified. If more than 20% coal is used then the CDM potential is completely lost because the emissions are increased. However some sugar mills are not moving ahead with coal as a secondary fuel because separate tariff rates have to be obtained for electricity generation if coal is being used in the mix which is not easily obtained.

Pakistan has huge untapped potential for bagasse-based power generation

One of the incentives being offered by the State Bank of Pakistan is that if a project qualifies as a renewable project it is eligible to get loan at 6% instead of 12%. However ones drawback is that, in order to qualify as a renewable project, CDM registration of a project is not taken into account.

Although Pakistan is on the right track by setting up high cogeneration power plants, the use of coal as a secondary fuel remains debatable.  The issue that remains to be addressed is that with such huge amounts of investment on these plants, how to use these plants efficiently during non-crushing period when bagasse is not available. It seems almost counter-productive to use coal on plants which are supposed to be based on biofuels.

Conclusion

With the demand for energy in Pakistan growing, the country is finally exploring alternatives to expand its power production. Pakistan has to rely largely on fossils for their energy needs since electricity generation from biomass energy sources is considered to be an expensive option despite abundance of natural resources. However by focusing on growing its alternate energy options such as bagasse-based cogeneration, the country will not only mitigate climate change but also tap the unharnessed energy potential of sugar industry biomass.

Unending Benefits of Biomass Energy

Biomass is material originating from plant and animal matter. Biomass energy uses biomass to create energy by burning organic materials. The heat energy released through burning these materials can heat homes or water. Heated water produces steam, which in turn can generate electricity. Using organic materials to create heat and power is an eco-friendlier alternative compared to using fossil fuels.

Indefinitely Renewable

The majority of the world’s energy comes from burning fossil fuels. Fossil fuels are a finite resource. Once fossil fuel resources run out, new fuel sources will be needed to meet global energy demands. Biomass offers a solution to meet this need.

Organic waste material from agriculture and logging operations, animal manure, and sludge from wastewater treatment are all viable fuels for generating biomass energy. As long as the earth is inhabited, these materials will be readily available.

Reduce, Reuse, Recycle

Waste organic material that would typically be disposed of in landfills could be redirected for biomass energy use. This reduces the amount of material in landfills and slows the rate at which landfills are filled. Some of the most common waste products used for biomass energy are wood chips and agricultural waste products. Wood materials can easily be converted from already existing wood structures that will be destroyed, such as wooden furniture and log cabins, preferably both would also come from responsible logging and practices as well.

As more organic material is diverted from landfills, the number of new landfills needed would be reduced. Older landfills are at risk for leaking leachate. Leachate contains many environmental pollutants that can contaminate groundwater sources.

Burning fossil fuel releases carbon into the atmosphere which was previously trapped below ground. Trapped carbon isn’t at risk for contributing to global climate change since it can’t interact with air. Each time fossil fuels are burned, they allow previously trapped carbon to enter the atmosphere and contribute to global climate change. In comparison, biofuel is carbon-neutral.

The materials used to create biomass energy naturally release carbon into the environment as they decompose. Living plants and trees use carbon dioxide to grow and release oxygen into the atmosphere. Carbon dioxide released by burning organic material will be absorbed by existing plants and trees. The biomass cycle is carbon-neutral as no new carbon is introduced to the system.

Smaller Carbon Footprint

The amount of unused farmland is increasing as agriculture becomes more efficient. Maintaining open land is expensive. As a result, farmers are selling off their property for new developments. Unused open agricultural land could be used to grow organic material for biofuels.

Converting open tracts of land to developed areas increases the amount of storm-water runoff. Storm-water runoff from developed areas contains more pollutants than storm-water runoff from undeveloped areas. Using open areas to grow biomass sources instead of creating new developments would reduce water pollution.

Biomass-Resources

A quick glance at popular biomass resources

Forested areas also provide sources of biofuel material. Open land converted to sustainable forestry would create new animal habitats and offset carbon emissions from existing fossil fuel sources as more plants and trees would be available to absorb carbon dioxide.

Societal Benefits

Burning fossil fuels releases sulfur dioxide, mercury and particulate matter into the atmosphere which can cause asthma, cancer and respiratory problems. Biomass energy emits less harmful byproducts compared to fossil fuels, which means cleaner air and healthier people.

Biofuel can improve rural economies by providing more people with unused land the opportunity to grown biomass material for energy use. Workers would be needed to harvest and process the materials needed to generate biofuel.

Since biofuel is a renewable energy source, energy providers can receive tax credits and incentives. Countries with land resources will be less reliant on foreign fossil fuel providers and can improve their local economies.

Increasing biofuel energy usage can reduce forest fires. Selectively reducing brush can still reduce the risk of wildfires spreading. Exposing underbrush and groundcover to rainfall decreases the change of it drying out and creating optimal, fire spreading conditions.

Denmark and Biomass Energy

Denmark is an example of how effective biomass energy can be in developing energy efficiency. Approximately 70 percent of renewable-energy consumption in Denmark comes from biomass.

Woody biomass creates an increasing percentage of heating from combined heat and power (CHP) plants with a goal to for 100 percent of hearing to be derived from woody biomass by 2035. Another form of biomass is agricultural biomass. This form utilizes materials such as straw and corn to create end-products like electricity, heating and biofuels.

The Danish Energy Agency has developed a plan including four scenarios that will help Denmark become fossil fuel free by 2050. The biomass scenario involves CHP for electricity and district heating, indicating that biomass energy is important in Denmark’s energy sector today and will play an increasingly important role in the future.

Biomass offers an eco-friendly and renewable method of reducing pollution and the effects of global climate change. And, like other forms of renewable energy, the products needed to develop biomass energy are readily available.

A Glance at Drop-in Biofuels

drop-in-biofuelsBiofuel commercialization has proved to be costly and lingering than expected due to its high production cost and modification to flexibility in engines. Drop-in fuels are alternatives to existing liquid fuels without any significant modification in engines and infrastructures. According to IEA, “Drop-in biofuels are liquid bio-hydrocarbons that are functionally equivalent to petroleum fuels and are fully compatible with existing petroleum infrastructure”.

What are Drop-in Biofuels

Drop-in biofuels are can be produced from oilseeds via trans-esterification, lignocellulosic biomass via thermochemical process, sugars and alcohol via biochemical conversion or by hybrids of the above methods. Drop-in fuels encompass high hydrogen to carbon ratio with no/low sulfur and oxygen content, low water solubility and high carbon bond saturation. In short drop-in fuel is a modified fuel with close functional resemblance to fossil fuel.

Existing biofuels – bioethanol and biodiesel – have wide variation from fossil fuels in their blend wall properties – high oxygen content, hydrophilicity, energy density and mainly compatibility in existing engines and infrastructures. Oxygenated groups in biofuel have a domino effect such as reduction in the energy density, production of impurities which are highly undesirable to transportation components, instability during storage etc.

Major advantages of drop-in fuels over existing fuels are as follows:

  • Reduced sulphur oxide emissions by ultra low sulphur content.
  • Reduced ignition delay by high cetane value
  • Reduced hydrocarbons and nitrogen oxides emissions
  • Low aromatic content
  • Low olefin content, presence of olefin compounds undergo auto-oxidation leading to surface depositions.
  • High saturates, therefore leaving minimum residues
  • Low particulate emissions
  • No oxygenates therefore has high stability.

Potential Biomass Feedstock

Drop-in biofuels can be produced from various biomass sources- lipids (vegetable oils, animal fats, greases, and algae) and lignocellulosic material (such as crop residues, woody biomass, and dedicated energy crops). The prominent technologies for biomass conversion to drop-in fuel are the thermochemical and the biochemical process.

The major factor playing role in selection of biomass for thermochemical methods is the energy content or heating value of the material, which is correlated with ash content. Wood, wood chips accounts for less than 1% ash content, which is favorable thermal processing than biochemical process, whereas straws, husks, and majority of the other biomass have ash content ranging up to 25% of dry mass.

Free sugar generating plants such as sugarcane and sweet sorghum, are desirable feedstock for Acetone-Butanol-Ethanol fermentation and have been widely implemented. Presently there is a focus to exploit lignocellulosic residues, rich in hydrocarbon, for fuel production. However, this biomass requires harsh pretreatment to remove lignin and to transform holocellulose (cellulose & hemicelluloses) into fermentable products.

The lignocellulose transformation technology must be circumspectly chosen by its life cycle assessment, as it resists any changes in their structural integrity owing to its complexity. Lignocellulosic biomass, when deoxygenated, has better flexibility to turn to drop-in fuels. This is because, in its native state of the feedstock, each oxygen atom consumes two hydrogen atoms during combustion which in turn reduces effective H: C ratio. Biomass feedstock is characterized with oxygen up to 40%, and higher the oxygen content higher it has to be deoxygenated.

Thermochemical Route

Thermochemical methods adopted for biomass are pyrolysis and gasification, on thermolysis of biomass produce intermediate gas (syngas) and liquid (bio crude) serving as precursors for drop-in fuel. Biomass when exposed to temperature of 500oC-600oC in absence of oxygen (pyrolysis) produce bio-oil, which constitutes a considerable percentage of oxygen. After down streaming by hydroprocessing (hydrotreating and hydrocracking) the rich hydrocarbon tar (bio-oil) can be converted to an efficient precursor for drop-in fuel.

At a higher temperature, above 700, under controlled oxygen, biomass can be converted to liquid fuel via gas phase by the process, gasification. Syngas produced is converted to liquid fuel by Fischer-Tropsch with the help of ‘water gas shift’ for hydroprocessing. Hydroprocessing after the thermochemical method is however costly and complex process in case of pyrolysis and inefficient biomass to fuel yield with gasification process.

Biochemical Pathway

The advanced biocatalytic processes can divert the conventional sugar-ethanol pathway and convert sugars to fatty acids. Modified microbial strain with engineered cellular machineries, can reroute the pathway to free fatty acid that can be transformed into butanol or drop-in fuel with necessary processing.

Schematic for the preparation of jet fuel from biomass

Schematic for the preparation of jet fuel from biomass

Biological processing requires operation under the stressful conditions on the organisms to reroute the pathways, in additional to lowering NADPH (hydrogen) consumption. Other value added products like carboxylic acid, polyols, and alcohol in the same biological routes with lower operational requirements have higher market demands and commercial success. Therefore little attention is given by chemical manufacturers to the biological pathways for drop-in fuel production.

The mechanisms of utilization of lignocellulosic biomass to fuel by biological pathway rely heavily on the availability of monomeric C5 and C6 sugars during fermentation. Ethanol is perhaps the best-known and commercially successful alcohol from ABE fermentation. However, butanol has various significant advantages over ethanol- in the perception of energy content, feasibility to existing infrastructures, zero blend wall, safety and clean aspects. Although butanol is a closer drop-in replacement, existing biofuel ethanol, is a major commercial competitor. Low yield from fermentation due to the toxicity of butanol and complexity in down streaming are the vital reasons that hamper successful large scale butanol production.

Challenges to Overcome

Zero oxygen and sulphur content mark major challenges for production of drop-in fuels from conventional biomass. This demands high hydrogen input on the conventional biomass, with H: C ratio below 0.5, like sugar, starch, cellulose, lignocellulose to meet the effective hydrogen to carbon ratio of 2 as in drop-in fuel. This characterizes most of the existing biomass feedstock as a low-quality input for drop-in fuels. However oleochemicals like fats, oils, and lipids have closer H: C ratio to diesel, gasoline and drop-in fuels, thus easier to conversion. Oleochemical feedstock has been commercially successful, but to prolong in the platform will be a major challenge. Lipid feedstock is generally availed from crop-based vegetable oil, which is used in food sectors. Therefore availability, food security concerns, and economics are the major constraints to sustaining the raw material. Consequently switching to lignocellulosic biomass feedstock for drop-in holds on.

Conclusions

Despite the hurdles on biomass characteristics and process technology for drop-in fuel, it is a vital requirement to switch to better replacement fuel for fossil fuel, considering environmental and economic benefits. Understanding its concepts and features, drop-in fuel, can solve existing greenhouse emission debate on current biofuels. Through crucial ambiguities existing on future of alternative fuels, drop-in fuel has a substantial potential to repute itself as an efficient sustainable eco-friendly fuel in the naear future.

References

  • Neal K Van Alfen: ENCYCLOPEDIA OF AGRICULTURE AND FOOD SYSTEMS, Elsevier, Academic Press.
  • Pablo Domínguez de María John: INDUSTRIAL BIORENEWABLES:A Practical Viewpoint: Wiley & Sons.
  • Ram Sarup Singh, Ashok Pandey, Edgard Gnansounou: BIOFUELS- PRODUCTION AND FUTURE PERSPECTIVES, CRC Press.
  • Satinder Kaur Brar, Saurabh Jyoti Sarma, Kannan Pakshirajan : PLATFORM CHEMICAL BIOREFINERY-FUTURE GREEN CHEMISTRY, Elsevier.
  • Sergios Karatzos, James D. McMillan, Jack N. Saddle: Summary of IEA BIOENERGY TASK 39 REPORT-THE POTENTIAL AND CHALLENGES OF DROP-IN BIOFUELS, IEA Bioenergy.
  • Vijai Kumar Gupta, Monika Schmoll, Minna Maki, Maria Tuohy, Marcio Antonio Mazutti: APPLICATIONS OF MICROBIAL ENGINEERING, CRC Press.