Pyrolysis of Municipal Wastes

Pyrolysis is rapidly developing biomass thermal conversion technology and has been garnering much attention worldwide due to its high efficiency and good eco-friendly performance characteristics. Pyrolysis technology provides an opportunity for the conversion of municipal solid wastes, agricultural residues, scrap tires, non-recyclable plastics etc into clean energy. It offers an attractive way of converting urban wastes into products which can be effectively used for the production of heat, electricity and chemicals.

Pyrolysis-MSW

Pyrolysis of Municipal Wastes

Pyrolysis process consists of both simultaneous and successive reactions when carbon-rich organic material is heated in a non-reactive atmosphere. Simply speaking, pyrolysis is the thermal degradation of organic materials in the absence of oxygen. Thermal decomposition of organic components in the waste stream starts at 350°C–550°C and goes up to 700°C–800°C in the absence of air/oxygen.

Pyrolysis of municipal wastes begins with mechanical preparation and separation of glass, metals and inert materials prior to processing the remaining waste in a pyrolysis reactor. The commonly used pyrolysis reactors are rotary kilns, rotary hearth furnaces, and fluidized bed furnaces. The process requires an external heat source to maintain the high temperature required.

Pyrolysis can be performed at relatively small-scale which may help in reducing transport and handling costs.  In pyrolysis of MSW, heat transfer is a critical area as the process is endothermic and sufficient heat transfer surface has to be provided to meet process heat requirements.

The main products obtained from pyrolysis of municipal wastes are a high calorific value gas (synthesis gas or syngas), a biofuel (bio oil or pyrolysis oil) and a solid residue (char). Depending on the final temperature, MSW pyrolysis will yield mainly solid residues at low temperatures, less than 4500C, when the heating rate is quite slow, and mainly gases at high temperatures, greater than 8000C, with rapid heating rates. At an intermediate temperature and under relatively high heating rates, the main product is a liquid fuel popularly known as bio oil.

Wide Range of Products

Bio oil is a dark brown liquid and can be upgraded to either engine fuel or through gasification processes to a syngas and then biodiesel. Pyrolysis oil may also be used as liquid fuel for diesel engines and gas turbines to generate electricity.

Bio oil is particularly attractive for co-firing because it can be relatively easy to handle and burn than solid fuel and is cheaper to transport and store. In addition, bio oil is also a vital source for a wide range of organic compounds and specialty chemicals.

Syngas is a mixture of energy-rich gases (combustible constituents include carbon monoxide, hydrogen, methane and a broad range of other VOCs). The net calorific value (NCV) of syngas is between 10 and 20MJ/Nm3. Syngas is cleaned to remove particulates, hydrocarbons, and soluble matter, and then combusted to generate electricity.

Diesel engines, gas turbines, steam turbines and boilers can be used directly to generate electricity and heat in CHP systems using syngas and pyrolysis oil. Syngas may also be used as a basic chemical in petrochemical and refining industries.

The solid residue from MSW pyrolysis, called char, is a combination of non-combustible materials and carbon. Char is almost pure carbon and can be used in the manufacture of activated carbon filtration media (for water treatment applications) or as an agricultural soil amendment.

A Primer on Waste-to-Energy

Waste-to-Energy (also known as energy-from-waste) is the use of thermochemical and biochemical technologies to recover energy, usually in the form of electricity, steam and fuels, from urban wastes.These new technologies can reduce the volume of the original waste by 90%, depending upon composition and use of outputs.

Energy is the driving force for development in all countries of the world. The increasing clamor for energy and satisfying it with a combination of conventional and renewable resources is a big challenge. Accompanying energy problems in different parts of the world, another problem that is assuming critical proportions is that of urban waste accumulation.

The quantity of waste produced all over the world amounted to more than 12 billion tonnes in 2006, with estimates of up to 13 billion tonnes in 2011. The rapid increase in population coupled with changing lifestyle and consumption patterns is expected to result in an exponential increase in waste generation of upto 18 billion tonnes by year 2020.

Waste generation rates are affected by socio-economic development, degree of industrialization, and climate. Generally, the greater the economic prosperity and the higher percentage of urban population, the greater the amount of solid waste produced. Reduction in the volume and mass of solid waste is a crucial issue especially in the light of limited availability of final disposal sites in many parts of the world. Millions of tonnes of household wastes are generated each year with the vast majority disposed of in open fields or burnt wantonly.

The main categories of waste-to-energy technologies are physical technologies, which process waste to make it more useful as fuel; thermal technologies, which can yield heat, fuel oil, or syngas from both organic and inorganic wastes; and biological technologies, in which bacterial fermentation is used to digest organic wastes to yield fuel.

The three principal methods of thermochemical conversion are combustion in excess air, gasification in reduced air, and pyrolysis in the absence of air. The most common technique for producing both heat and electrical energy from wastes is direct combustion. Combined heat and power (CHP) or cogeneration systems, ranging from small-scale technology to large grid-connected facilities, provide significantly higher efficiencies than systems that only generate electricity.

Biochemical processes, like anaerobic digestion, can also produce clean energy in the form of biogas which can be converted to power and heat using a gas engine. In addition, wastes can also yield liquid fuels, such as cellulosic ethanol, which can be used to replace petroleum-based fuels. Cellulosic ethanol can be produced from grasses, wood chips and agricultural residues by biochemical route using heat, pressure, chemicals and enzymes to unlock the sugars in biomass wastes.

Waste-to-energy plants offer two important benefits of environmentally safe waste management and disposal, as well as the generation of clean electric power.  The growing use of waste-to-energy as a method to dispose of solid and liquid wastes and generate power has greatly reduced environmental impacts of municipal solid waste management, including emissions of greenhouse gases.