Large quantities of agricultural wastes, resulting from crop cultivation activities, are a promising source of energy supply for production, processing and domestic activities in rural areas of the concerned region. The available agricultural residues are either being used inefficiently or burnt in the open to clear the fields for subsequent crop cultivation.
On an average 1.5 tons of crop residue are generated for processing 1 ton of the main product. In addition, substantial quantities of secondary residues are produced in agro-industries processing farm produce such as paddy, sugarcane, coconut, fruits and vegetables.
Agricultural crop residues often have a disposal cost associated with them. Therefore, the “waste-to-energy” conversion processes for heat and power generation, and even in some cases for transport fuel production, can have good economic and market potential. They have value particularly in rural community applications, and are used widely in countries such as Sweden, Denmark, Netherlands, USA, Canada, Austria and Finland.
The energy density and physical properties of agricultural biomass wastes are critical factors for feedstock considerations and need to be understood in order to match a feedstock and processing technology.
There are six generic biomass processing technologies based on direct combustion (for power), anaerobic digestion (for methane-rich biogas), fermentation (of sugars for alcohols), oil exaction (for biodiesel), pyrolysis (for biochar, gas and oils) and gasification (for carbon monoxide and hydrogen-rich syngas). These technologies can then be followed by an array of secondary treatments (stabilization, dewatering, upgrading, refining) depending on specific final products.
It is well-known that power plants based on baled agricultural residues are efficient and cost-effective energy generators. Residues such as Rice Husks, Wheat Straw and Maize Cobs are already concentrated at a point where it is an easily exploitable source of energy, particularly if it can be utilized on-site to provide combined heat and power.
The selection of processing technologies needs to be aligned to the nature and structure of the biomass feedstock and the desired project outputs. It can be seen that direct combustion or gasification of biomass are appropriate when heat and power are required.
Anaerobic digestion, fermentation and oil extraction are suitable when specific biomass wastes are available that have easily extractable oils and sugars or high water contents. On the other hand, only thermal processing of biomass by pyrolysis can provide the platform for all of the above forms of product.
Moisture content is of important interest since it corresponds to one of the main criteria for the selection of energy conversion process technology. Thermal conversion technology requires biomass fuels with low moisture content, while those with high moisture content are more appropriate for biological-based process such as fermentation or anaerobic digestion.
The ash content of biomass influences the expenses related to handling and processing to be included in the overall conversion cost. On the other hand, the chemical composition of ash is a determinant parameter in the consideration of a thermal conversion unit, since it gives rise to problems of slagging, fouling, sintering and corrosion.
Biomass fuels are typically used most efficiently and beneficially when generating both power and heat through biomass cogeneration systems (also known as combined heat and power or CHP system). Biomass conversion technologies transform a variety of wastes into heat, electricity and biofuels by employing a host of strategies. Conversion routes are generally thermochemical or biochemical, but may also include chemical and physical.
A typical biomass cogeneration (or biomass cogen) system provides:
Distributed generation of electrical and/or mechanical power.
Waste-heat recovery for heating, cooling, or process applications.
Seamless system integration for a variety of technologies, thermal applications, and fuel types into existing building infrastructure.
Biomass cogeneration systems consist of a number of individual components—prime mover (heat engine), generator, heat recovery, and electrical interconnection—configured into an integrated whole. The type of equipment that drives the overall system (i.e., the prime mover) typically identifies the CHP unit.
Prime movers for biomass cogeneration units include reciprocating engines, combustion or gas turbines, steam turbines, microturbines, and fuel cells. These prime movers are capable of burning a variety of fuels, including natural gas, coal, oil, and alternative fuels to produce shaft power or mechanical energy.
A biomass-fueled cogeneration facility is an integrated power system comprised of three major components:
Biomass receiving and feedstock preparation.
Energy conversion – Conversion of the biomass into steam for direct combustion systems or into biogas for the gasification systems.
Power and heat production – Conversion of the steam or syngas or biogas into electric power and process steam or hot water
Feedstock for Biomass Cogeneration Plants
The lowest cost forms of biomass for cogeneration plants are residues. Residues are the organic byproducts of food, fiber, and forest production, such as sawdust, rice husks, wheat straw, corn stalks, and sugarcane bagasse. Forest residues and wood wastes represent a large potential resource for energy production and include forest residues, forest thinnings, and primary mill residues.
Energy crops are perennial grasses and trees grown through traditional agricultural practices that are produced primarily to be used as feedstocks for energy generation, e.g. hybrid poplars, hybrid willows, and switchgrass. Animal manure can be digested anaerobically to produce biogas in large agricultural farms and dairies.
To turn a biomass resource into productive heat and/or electricity requires a number of steps and considerations, most notably evaluating the availability of suitable biomass resources; determining the economics of collection, storage, and transportation; and evaluating available technology options for converting biomass into useful heat or electricity.
The best way of dealing with waste, both economically and environmentally, is to avoid creating it in the first place. For effective waste management, waste minimization, reuse, recycle and energy recovery are more sustainable than conventional landfill or dumpsite disposal technique.
Waste minimization is the process of reducing the amount of waste produced by a person or a society. Waste minimization is about the way in which the products and services we all rely on are designed, made, bought and sold, used, consumed and disposed of.
Reuse means using an item more than once. This includes conventional reuse where the item is used again for the same function and new-life reuse where it is used for a new function. For example, concrete is a type of construction waste which can be recycled and used as a base for roads; inert material may be used as a layer that covers the dumped waste on landfill at the end of the day.
Recycling of waste involves reprocessing the particular waste materials so that it can be used as raw materials in another process. This is also known as material recovery. A well-known process for recycling waste is composting, where biodegradable wastes are biologically decomposed leading to the formation of nutrient-rich compost.
As far as waste-to-energy is concerned, major processes involved are mass-burn incineration, RDF incineration, anaerobic digestion, gasification and pyrolysis. Gasification and pyrolysis involves super-heating of municipal solid waste in an oxygen-controlled environment to avoid combustion. The primary differences among them relate to heat source, oxygen level, and temperature, from as low as about 300°C for pyrolysis to as high as 11 000°C for plasma gasification. The residual gases like carbon dioxide, hydrogen, methane etc are released after a sophisticated gas cleaning mechanism.
MSW incineration produce significant amounts of a waste called bottom ash, of which about 40% must be landfilled. The remaining 60% can be further treated to separate metals, which are sold, from inert materials, which are often used as road base.
The above mentioned techniques are trending in many countries and region. As of 2014, Tokyo (Japan) has nineteen advanced and sophisticated waste incinerator plants making it one of the cleanest cities. From the legislature standpoint, the country has implemented strict emission parameters in incinerator plants and waste transportation.
The European Union also has a similar legislature framework as they too faced similar challenges with regards to waste management. Some of these policies include – maximizing recycling and re-use, reducing landfill, ensuring the guidelines are followed by the member states.
Singapore has also turned to converting household waste into clean fuel, which both reduced the volume going into landfills and produced electricity. Now its four waste-to-energy plants account for almost 3% of the country’s electricity needs, and recycling rates are at an all-time high of 60%. By comparison, the U.S. sent 53% of its solid waste to landfills in 2013, recycled only 34% of waste and converted 13% into electricity, according to the US Environmental Protection Agency.
Trends in Waste Collection
Since the municipal solid waste can be a mixture of all possible wastes and not just ones belonging to the same category and recommended process, recent advances in physical processes, sensors, and actuators used as well as control and autonomy related issues in the area of automated sorting and recycling of source-separated municipal solid waste.
Automated vacuum waste collection systems that are located underground are also actively used in various parts of the world like Abu Dhabi, Barcelona, Leon, Mecca and New York etc. The utilization of the subsurface space can provide the setting for the development of infrastructure which is capable of addressing in a more efficient manner the limitations of existing waste management schemes.
AI-based waste management systems can help in route optimization and waste disposal
This technique also minimizes operational costs, noise and provides more flexibility. There are various new innovations like IoT-enabled garbage cans, electric garbage trucks, waste sorting robots and mechanisms etc are also being developed and deployed at various sites.
Waste management is a huge and ever growing industry that has to be analyzed and updated at every point based on the new emergence of threats and technology. With government educating the normal people and creating awareness among different sector of the society, setting sufficient budgets and assisting companies and facilities for planning, research and waste management processes can help to relax the issues to an extent if not eradicating it completely. These actions not only help in protecting environment, but also help in employment generation and boosting up the economy.
Biomass gasification power systems have followed two divergent pathways, which are a function of the scale of operations. At sizes much less than 1MW, the preferred technology combination today is a moving bed gasifier and ICE combination, while at scales much larger than 10 MW, the combination is of a fluidized bed gasifier and a gas turbine.
Larger scale units than 25 MW would justify the use of a combined cycle, as is the practice with natural gas fired gas turbine stations. In the future it is anticipated that extremely efficient gasification based power systems would be based on a combined cycle that incorporates a fuel cell, gas turbine and possibly a Rankine bottoming cycle.
Integrated Gasification Combined Cycle
The most attractive means of utilising a biomass gasifier for power generation is to integrate the gasification process into a gas turbine combined cycle power plant. This will normally require a gasifier capable of producing a gas with heat content close to 19 MJ/Nm3. A close integration of the two parts of the plant can lead to significant efficiency gains.
The gas from the gasifier must first be cleaned to remove impurities such as alkali metals that might damage the gas turbine. The clean gas is fed into the combustor of the gas turbine where it is burned, generating a flow of hot gas which drives the turbine, generating electricity.
Hot exhaust gases from the turbine are then utilised to generate steam in a heat recovery steam generator. The steam drives a steam turbine, producing more power. Low grade waste heat from the steam generator exhaust can be used within the plant, to dry the biomass fuel before it is fed into the gasifier or to preheat the fuel before entry into the gasifier reactor vessel.
Schematic of integrated biomass gasification combined cycle
The gas-fired combined cycle power plant has become one of the most popular configurations for power generation in regions of the world where natural gas is available. The integration of a combined cycle power plant with a coal gasifier is now considered a potentially attractive means of burning coal cleanly in the future.
Biomass Fuel Cell Power Plant
Another potential use for the combustible gas from a biomass gasification plant is as fuel for a fuel cell power plant. Modern high temperature fuel cells are capable of operating with hydrogen, methane and carbon monoxide. Thus product gas from a biomass gasifier could become a suitable fuel.
As with the integrated biomass gasification combined cycle plant, a fuel cell plant would offer high efficiency. A future high temperature fuel cell burning biomass might be able to achieve greater than 50% efficiency.
Waste-to-Energy is the use of modern combustion and biochemical technologies to recover energy, usually in the form of electricity and steam, from urban wastes. These new technologies can reduce the volume of the original waste by 90%, depending upon composition and use of outputs.
Energy is the driving force for development in all countries of the world. The increasing clamor for energy and satisfying it with a combination of conventional and renewable resources is a big challenge. Accompanying energy problems in different parts of the world, another problem that is assuming critical proportions is that of urban waste accumulation.
The quantity of waste produced all over the world amounted to more than 12 billion tonnes in 2006, with estimates of up to 13 billion tonnes in 2011. The rapid increase in population coupled with changing lifestyle and consumption patterns is expected to result in an exponential increase in waste generation of upto 18 billion tonnes by year 2020.
Waste generation rates are affected by socio-economic development, degree of industrialization, and climate. Generally, the greater the economic prosperity and the higher percentage of urban population, the greater the amount of solid waste produced. Reduction in the volume and mass of solid waste is a crucial issue especially in the light of limited availability of final disposal sites in many parts of the world. Millions of tonnes of household wastes are generated each year with the vast majority disposed of in open fields or burnt wantonly.
The main categories of waste-to-energy technologies are physical technologies, which process waste to make it more useful as fuel; thermal technologies, which can yield heat, fuel oil, or syngas from both organic and inorganic wastes; and biological technologies, in which bacterial fermentation is used to digest organic wastes to yield fuel.
The three principal methods of thermochemical conversion are combustion in excess air, gasification in reduced air, and pyrolysis in the absence of air. The most common technique for producing both heat and electrical energy from wastes is direct combustion.Combined heat and power (CHP) or cogeneration systems, ranging from small-scale technology to large grid-connected facilities, provide significantly higher efficiencies than systems that only generate electricity.
Biochemical processes, like anaerobic digestion, can also produce clean energy in the form of biogas which can be converted to power and heat using a gas engine. In addition, wastes can also yield liquid fuels, such as cellulosic ethanol, which can be used to replace petroleum-based fuels. Cellulosic ethanol can be produced from grasses, wood chips and agricultural residues by biochemical route using heat, pressure, chemicals and enzymes to unlock the sugars in biomass wastes.
Waste-to-energy plants offer two important benefits of environmentally safe waste management and disposal, as well as the generation of clean electric power. The growing use of waste-to-energy as a method to dispose of solid and liquid wastes and generate power has greatly reduced environmental impacts of municipal solid waste management, including emissions of greenhouse gases.
A wide range of technologies are available for realizing the energy potential of biomass wastes, ranging from very simple systems for disposing of dry waste to more complex technologies capable of dealing with large amounts of industrial waste. Conversion routes for biomass wastes are generally thermo-chemical or bio-chemical, but may also include chemical and physical.
The three principal methods of thermo-chemical conversion corresponding to each of these energy carriers are combustion in excess air, gasification in reduced air, and pyrolysis in the absence of air. Direct combustion is the best established and most commonly used technology for converting wastes to heat. During combustion, biomass is burnt in excess air to produce heat. The first stage of combustion involves the evolution of combustible vapours from wastes, which burn as flames. Steam is expanded through a conventional turbo-alternator to produce electricity. The residual material, in the form of charcoal, is burnt in a forced air supply to give more heat.
Co-firing or co-combustion of biomass wastes with coal and other fossil fuels can provide a short-term, low-risk, low-cost option for producing renewable energy while simultaneously reducing the use of fossil fuels. Co-firing involves utilizing existing power generating plants that are fired with fossil fuel (generally coal), and displacing a small proportion of the fossil fuel with renewable biomass fuels. Co-firing has the major advantage of avoiding the construction of new, dedicated, waste-to-energy power plant. An existing power station is modified to accept the waste resource and utilize it to produce a minor proportion of its electricity.
Gasification systems operate by heating biomass wastes in an environment where the solid waste breaks down to form a flammable gas. The gasification of biomass takes place in a restricted supply of air or oxygen at temperatures up to 1200–1300°C. The gas produced—synthesis gas, or syngas—can be cleaned, filtered, and then burned in a gas turbine in simple or combined-cycle mode, comparable to LFG or biogas produced from an anaerobic digester. The final fuel gas consists principally of carbon monoxide, hydrogen and methane with small amounts of higher hydrocarbons. This fuel gas may be burnt to generate heat; alternatively it may be processed and then used as fuel for gas-fired engines or gas turbines to drive generators. In smaller systems, the syngas can be fired in reciprocating engines, micro-turbines, Stirling engines, or fuel cells.
Pyrolysis is thermal decomposition occurring in the absence of oxygen. During the pyrolysis process, biomass waste is heated either in the absence of air (i.e. indirectly), or by the partial combustion of some of the waste in a restricted air or oxygen supply. This results in the thermal decomposition of the waste to form a combination of a solid char, gas, and liquid bio-oil, which can be used as a liquid fuel or upgraded and further processed to value-added products.
Biochemical processes, like anaerobic digestion, can also produce clean energy in the form of biogas which can be converted to power and heat using a gas engine. Anaerobic digestion is a series of chemical reactions during which organic material is decomposed through the metabolic pathways of naturally occurring microorganisms in an oxygen depleted environment. In addition, wastes can also yield liquid fuels, such as cellulosic ethanol and biodiesel, which can be used to replace petroleum-based fuels.
Anaerobic digestion is the natural biological process which stabilizes organic waste in the absence of air and transforms it into biogas and biofertilizer. Almost any organic material can be processed with anaerobic digestion. This includes biodegradable waste materials such as municipal solid waste, animal manure, poultry litter, food wastes, sewage and industrial wastes. An anaerobic digestion plant produces two outputs, biogas and digestate, both can be further processed or utilized to produce secondary outputs. Biogas can be used for producing electricity and heat, as a natural gas substitute and also a transportation fuel. Digestate can be further processed to produce liquor and a fibrous material. The fiber, which can be processed into compost, is a bulky material with low levels of nutrients and can be used as a soil conditioner or a low level fertilizer.
A variety of fuels can be produced from biomass wastes including liquid fuels, such as ethanol, methanol, biodiesel, Fischer-Tropsch diesel, and gaseous fuels, such as hydrogen and methane. The resource base for biofuel production is composed of a wide variety of forestry and agricultural resources, industrial processing residues, and municipal solid and urban wood residues. The largest potential feedstock for ethanol is lignocellulosic biomass wastes, which includes materials such as agricultural residues (corn stover, crop straws and bagasse), herbaceous crops (alfalfa, switchgrass), short rotation woody crops, forestry residues, waste paper and other wastes (municipal and industrial). The three major steps involved in cellulosic ethanol production are pretreatment, enzymatic hydrolysis, and fermentation. Biomass is pretreated to improve the accessibility of enzymes. After pretreatment, biomass undergoes enzymatic hydrolysis for conversion of polysaccharides into monomer sugars, such as glucose and xylose. Subsequently, sugars are fermented to ethanol by the use of different microorganisms. Bioethanol production from these feedstocks could be an attractive alternative for disposal of these residues. Importantly, lignocellulosic feedstocks do not interfere with food security.
A combination of high fuel prices and a search for alternative technologies, combined with massive waste generation has led to countries in the Middle East region to consider Waste to Energy (or WtE) as a sustainable waste management strategy and cost-effective fuel source for the future. We look at the current state of the WtE market in the region.
It is estimated that each person in the United Arab Emirates produces 2 kg of municipal solid waste per day – that puts the total waste production figure somewhere in the region of 150 million tonnes every year. Given that the population currently stands at over 9.4 million (2013) and is projected to see an annual average growth figure of 2.3% over the next six years, over three times the global average, it’s clear that this is a lot of waste to be disposed of. In addition, the GCC nations in general rank in the bottom 10% of the sustainable nations in the world and are also amongst the top per capita carbon-releasers.
When we also consider that UAE are actively pursuing alternative energy technologies to supplement rapidly-decreasing and increasingly-costly traditional fossil fuels, mitigate the harmful effects of landfill, and reduce an ever-increasing carbon footprint, it becomes apparent that high on their list of proposed solutions is Waste to Energy (WtE). It could be an ideal solution to the problem.
What is WtE
Waste-to-Energy works on the simple principle of taking waste and turning it into a form of energy. This can be electricity, heat or transport fuels, and can be achieved in a variety of ways – the most common of which is incineration. MSW is taken to a WtE plant, incinerated at high temperatures and the resultant heat is used to boil water which creates steam to turn turbines, in the same way that burning gas or coal produces power. Gasification and anaerobic digestion are two further WtE methods which are also used.
However, WtE has several advantages over burning fossil fuels. Primarily amongst them are the potential to minimise landfill sites which have caused serious concern for many years. They are not only unsightly, but can also be contaminated, biologically or chemically. Toxic waste can leach into the ground beneath them and enter the water table.
Landfill sites also continuously emit carbon dioxide and methane, both harmful greenhouse gases – in addition methane is potentially explosive. Sending MSW to landfill also discourages recycling and necessitates more demand for raw materials. Finally, landfill sites are unpleasant places which attract vermin and flies and give off offensive odours.
WtE has been used successfully in many countries around the world for a long time now. Europe is the most enthusiastic proponent of WtE, with around 450 facilities; the Asia-Pacific region has just over 300; the USA has almost 100. In the rest of the world there are less than 30 facilities but this number is growing. Globally, it is estimated that the WtE industry is growing at approximately US $2 billion per annum and will be valued at around US $80 billion by the year 2022.
The USA ranks third in the world for the percentage of waste which is incinerated for energy production. Around 16% of the rubbish that America produces every day is burned in its WtE plants. Advocates claims the advantages are clear: reducing the amount of greenhouse gas emitted into the environment (estimates say that burning one ton of waste in a WtE plant saves between one half and one ton of greenhouse gases compared to landfill emissions, or the burning of conventional fuels), freeing up land which would normally be used for landfill (and, therefore, extending the life of existing landfill sites), encouraging recycling (some facilities have managed to reduce the amount of waste they process by up to 90% and the recycling of ferrous and non-ferrous metals provides an additional income source), and, perhaps most importantly, producing a revenue stream from the sale of the electricity generated.
In one small county alone, Lancaster, Pennsylvania, with a population of just over half-a-million people, more than 4.4 billion kWh of electricity has been produced through WtE in the last 20 years. This has generated over USD $256 million through its sale to local residents.
WtE in the Middle East
Given WtE’s potential to not only reduce greenhouse gas emissions and pollution on a local scale, but also to produce much-needed electricity in the region, what is the current state of affairs in the Middle East. There are several WtE initiatives already underway in the region. Qatar was the first GCC country to implement a waste-to-energy programme and currently generates over 30MW of electricity from its Domestic Solid Waste Management Center (DSWMC) located at Messeid (Doha). Saudi Arabia and the UAE have both stated that they have WtE production capacity targets of 100MW. Bahrain, Kuwait and Oman are also seriously considering waste-to-energy as a means to tackle the worsening waste management problem.
Abu Dhabi’s government is currently spending around US $850 million to build a 100 MW plant which is expected to be operational by 2017 and which will supply around 20,000 households with electricity. In Sharjah, the world’s largest household waste gasification plant, costing in excess of US $480 million, is due to be open in 2015.
However, not all the GCC members are as enthusiastic about WtE. Dubai’s government has recently scrapped plans for a US $2 billion project which would have made use of the 7,800 tonnes of domestic waste which is produced in Dubai every single day.
We asked Salman Zafar, Founder of Doha-based EcoMENA, a popular sustainability advocacy, why given the sheer scale of the waste in the Gulf region, the production of this form of energy is still in its infancy. “The main deterrent in the implementation of WtE projects in the Middle East is the current availability of cheap sources of energy already available, especially in the GCC,” he commented.
Salman Zafar further says, “WtE projects demand a good deal of investment, heavy government subsidies, tipping fees, power purchase agreements etc, which are hard to obtain for such projects in the region.” “The absence of a sustainable waste management strategy in Middle East nations is also a vital factor behind the very slow pace of growth of the WtE sector in the region. Regional governments, municipalities and local SWM companies find it easier and cost-effective to dump untreated municipal waste in landfills,” he added.
So, how can WtE contribute towards the region’s growing power demand in the future?
“Modern WtE technologies, such as RDF-based incineration, gasification, pyrolysis, anaerobic digestion etc, all have the ability to transform power demand as well as the waste management scenario in the region,” he continued. “A typical 250 – 300 tons per day WtE plant can produce around 3 – 4 MW of electricity and a network of such plants in cities across the region can make a real difference in the energy sector as well as augmenting energy reserves in the Middle East. In fact, WtE plants also produce a tremendous about of heat energy which can be utilised in process industries, further maximising their usefulness,” Salman Zafar concluded.
New technologies naturally take time to become established as their efficiency versus cost ratios are analysed. However, it is becoming increasingly clearer that waste-to-energy is a viable and efficient method for solid waste management and generation of alternative energy in the Middle East.
A wide range of technologies exists to convert the energy stored in biomass to more useful forms of energy. These technologies can be classified according to the principal energy carrier produced in the conversion process. Carriers are in the form of heat, gas, liquid and/or solid products, depending on the extent to which oxygen is admitted to the conversion process (usually as air). The major methods of thermal conversion are combustion in excess air, gasification in reduced air, and pyrolysis in the absence of air.
Conventional combustion technologies raise steam through the combustion of biomass. This steam may then be expanded through a conventional turbo-alternator to produce electricity. A number of combustion technology variants have been developed. Underfeed stokers are suitable for small scale boilers up to 6 MWth. Grate type boilers are widely deployed. They have relatively low investment costs, low operating costs and good operation at partial loads. However, they can have higher NOx emissions and decreased efficiencies due to the requirement of excess air, and they have lower efficiencies.
Fluidized bed combustors (FBC), which use a bed of hot inert material such as sand, are a more recent development. Bubbling FBCs are generally used at 10-30 MWth capacity, while Circulating FBCs are more applicable at larger scales. Advantages of FBCs are that they can tolerate a wider range of poor quality fuel, while emitting lower NOx levels.
Co-firing or co-combustion of biomass wastes with coal and other fossil fuels can provide a short-term, low-risk, low-cost option for producing renewable energy while simultaneously reducing the use of fossil fuels. Co-firing involves utilizing existing power generating plants that are fired with fossil fuel (generally coal), and displacing a small proportion of the fossil fuel with renewable biomass fuels. Co-firing has the major advantage of avoiding the construction of new, dedicated, waste-to-energy power plant. Co-firing may be implemented using different types and percentages of wastes in a range of combustion and gasification technologies. Most forms of biomass wastes are suitable for co-firing. These include dedicated municipal solid wastes, wood waste and agricultural residues such as straw and husk.
Gasification of biomass takes place in a restricted supply of oxygen and occurs through initial devolatilization of the biomass, combustion of the volatile material and char, and further reduction to produce a fuel gas rich in carbon monoxide and hydrogen. This combustible gas has a lower calorific value than natural gas but can still be used as fuel for boilers, for engines, and potentially for combustion turbines after cleaning the gas stream of tars and particulates. If gasifiers are ‘air blown’, atmospheric nitrogen dilutes the fuel gas to a level of 10-14 percent that of the calorific value of natural gas. Oxygen and steam blown gasifiers produce a gas with a somewhat higher calorific value. Pressurized gasifiers are under development to reduce the physical size of major equipment items.
A variety of gasification reactors have been developed over several decades. These include the smaller scale fixed bed updraft, downdraft and cross flow gasifiers, as well as fluidized bed gasifiers for larger applications. At the small scale, downdraft gasifiers are noted for their relatively low tar production, but are not suitable for fuels with low ash melting point (such as straw). They also require fuel moisture levels to be controlled within narrow levels.
Pyrolysis is the term given to the thermal degradation of wood in the absence of oxygen. It enables biomass to be converted to a combination of solid char, gas and a liquid bio-oil. Pyrolysis technologies are generally categorized as “fast” or “slow” according to the time taken for processing the feed into pyrolysis products. These products are generated in roughly equal proportions with slow pyrolysis. Using fast pyrolysis, bio-oil yield can be as high as 80 percent of the product on a dry fuel basis. Bio-oil can act as a liquid fuel or as a feedstock for chemical production. A range of bio-oil production processes are under development, including fluid bed reactors, ablative pyrolysis, entrained flow reactors, rotating cone reactors, and vacuum pyrolysis.
Tanneries generate considerable quantities of sludge, shavings, trimmings, hair, buffing dusts and other general wastes and can consist of up to 70% of hide weight processed. Thermal technologies, gasification in particular, by virtue of chemically reducing conditions, provides a viable alternative thermal treatment for Chrome containing materials, and generates a chrome (III) containing ash. This ash has significant commercial value as it can be reconstituted.
All of the wastes created by the tannery can be gasified following pre-treatment methods such as maceration, drying and subsequent densification or briquetting. A combined drying and gasification process could eliminate solid waste, whilst providing a combustible gas as a tax-exempt renewable energy source, which the tannery can directly reuse. Gasification trials have illustrated that up to 70% of the intrinsic energy value of the wastes currently disposed can be recovered as “synthesis gas” energy.
Gasification technology has the potential to provide significant cost benefits in terms of power generation and waste disposal, and increase sustainability within the leather industry. The gasification process converts any carbon-containing material into a combustible gas comprised primarily of carbon monoxide, hydrogen and methane, which can be used as a fuel to generate electricity and heat.
A wide range of tannery wastes can be macerated, flash dried, densified and gasified to generate a clean syngas for reuse in boilers or other Combined Heat and Power systems. As a result up to 70% of the intrinsic energy value of the waste can be recovered as syngas, with up to 60% of this being surplus to process drying requirements so can be recovered for on-site boiler or thermal energy recovery uses.
A proprietary technology has been in commercial operation at a tanyard on the West Coast of Norway since mid 2001. The process employs gasification-and-plasma-cracking and offer the capability of turning the tannery waste problem to a valorising source that may add values to the plant owner in terms of excessive energy and ferrochrome, a harmless alloy that is widely used by the metallurgical industry. The process leaves no ashes but a non-leaching slag that is useful for civil engineering works, and, hence, no residues for landfill disposal
Nowadays, biofuels are in high demand for transportation, industrial heating and electricity generation. Different technologies are being tested for using MSW as feedstock for producing biofuels. This article will provide brief description of biochemical and thermochemical conversion routes for the production of biofuels from municipal solid wastes.
The waste is collected and milled, particles are shredded to reduce the size of 0.2-1.22 mm. MSW is pretreated to improve the accessibility of enzymes and make use of the enzymes in the bacteria for biological degradation on solid waste. The mixture of biomass is mixed with sulfuric acid and sodium hydroxide and autoclaved. After steam treatment, the mixture is filtered and washed with deionized water. The pre-treated mixture is then dried and drained overnight. The pre-treatment process improves the formation of sugars by enzymatic hydrolysis, avoids the loss of carbohydrate and avoids the formation of by-products inhibitory.
After pre-treatment (pre-hydrolysis), the mixture undergoes enzymatic hydrolysis for conversion of polysaccharides into monomer sugars, such as glucose and xylose. The common enzymes used for starch-based substrates are ?- and ?- amylase, pullulanase, isomylase and glucoamylase. Whereas for lignocellulose based substrates cellulases and ?- glucosidases.
Finally, the mixture is fermented; sugars are converted to ethanol by using microorganisms such as, bacteria, yeast or fungi. The cellulosic and starch hydrolysates ethanolic fermentation were fermented by M. indicus at 37 °C for 72 h. The fungus uses the hexoses and pentoses sugars with a high concentration of inhibitors (i.e. furfural, hydroxymethyl furfural, and acetic acid).
The composition of MSW feedstock effects the yield of the subsequent processes. A high composition of food and vegetable waste is more desirable, as these wastes are easily degradable and result in high yields compared to paper and cardboard.
Gasification process is carried out by treating carbon-based material with either oxygen or steam to produce a gaseous fuel which requires high temperature and pressure. It can be described as partial oxidation of the waste. At first waste is reduced in size and dried to reduce the amount of energy used in the gasifier.
Layout of a Typical Biomass Gasification Plant
The carbonaceous material oxidizes (combines with oxygen) to produce syngas (carbon monoxide and hydrogen) along with carbon dioxide, methane, water vapor, char, slag, and trace gases (depending on the composition of the feedstock). The syngas is then cleaned to remove any sulfur or acid gases and trace metals (depending on the composition of the feedstock).
The main uses of syngas are direct burning on site to provide heat or energy (by using boilers, gas turbines or steam driven engines) and refined to liquid fuels such as gasoline or ethanol.
Syngas can then be converted into biofuels and chemicals via catalytic processes such as the Fischer-Tropsch process. The Fischer-Tropsch process is a series of catalytic chemical reactions that convert syngas into liquid hydrocarbons by applying heat and pressure. Hydrocracking, hydro-treating, and hydro-isomerization can also be part of the “upgrading” process to maximize quantities of different products.
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