Tag Archives: gasification

Thermal Conversion of Biomass

  By | | , ,
14 Comments

A wide range of thermal technologies exists to harness the energy stored in biomass. These biomass thermal technologies can be classified according to the principal energy carrier produced in the conversion process. Carriers are in the form of heat, gas, liquid and/or solid products, depending on the extent to which oxygen is admitted to the conversion process (usually as air). The major methods for thermal conversion of biomass are combustion, gasification and pyrolysis.

biomass-gasification

1. Combustion

Conventional combustion technologies raise steam through the combustion of biomass. This steam may then be expanded through a conventional turbo-alternator to produce electricity. A number of combustion technology variants have been developed. Underfeed stokers are suitable for small scale boilers up to 6 MWth.

Grate type boilers are widely deployed. They have relatively low investment costs, low operating costs and good operation at partial loads. However, they can have higher NOx emissions and decreased efficiencies due to the requirement of excess air, and they have lower efficiencies.

Fluidized bed combustors (FBC), which use a bed of hot inert material such as sand, are a more recent development. Bubbling FBCs are generally used at 10-30 MWth capacity, while Circulating FBCs are more applicable at larger scales. Advantages of FBCs are that they can tolerate a wider range of poor quality fuel, while emitting lower NOx levels.

2. Co-Firing

Co-firing or co-combustion of biomass wastes with coal and other fossil fuels can provide a short-term, low-risk, low-cost option for producing renewable energy while simultaneously reducing the use of fossil fuels. Co-firing involves utilizing existing power generating plants that are fired with fossil fuel (generally coal), and displacing a small proportion of the fossil fuel with renewable biomass fuels.

types-of-biomass-cofiring

Co-firing has the major advantage of avoiding the construction of new, dedicated, waste-to-energy power plant. Co-firing may be implemented using different types and percentages of wastes in a range of combustion and gasification technologies. Most forms of biomass wastes are suitable for co-firing. These include dedicated municipal solid wastes, wood waste and agricultural residues such as straw and husk.

3. Gasification

Gasification of biomass takes place in a restricted supply of oxygen and occurs through initial devolatilization of the biomass, combustion of the volatile material and char, and further reduction to produce a fuel gas rich in carbon monoxide and hydrogen. This combustible gas has a lower calorific value than natural gas but can still be used as fuel for boilers, for engines, and potentially for combustion turbines after cleaning the gas stream of tars and particulates.

Biomass_Gasification_Process

Layout of a Typical Biomass Gasification Plant

If gasifiers are ‘air blown’, atmospheric nitrogen dilutes the fuel gas to a level of 10-14 percent that of the calorific value of natural gas. Oxygen and steam blown gasifiers produce a gas with a somewhat higher calorific value. Pressurized gasifiers are under development to reduce the physical size of major equipment items.

A variety of gasification reactors have been developed over several decades. These include the smaller scale fixed bed updraft, downdraft and cross flow gasifiers, as well as fluidized bed gasifiers for larger applications. At the small scale, downdraft gasifiers are noted for their relatively low tar production, but are not suitable for fuels with low ash melting point (such as straw). They also require fuel moisture levels to be controlled within narrow levels.

4. Pyrolysis

Pyrolysis is the term given to the thermal degradation of wood in the absence of oxygen. It enables biomass to be converted to a combination of solid char, gas and a liquid bio-oil. Pyrolysis technologies are generally categorized as “fast” or “slow” according to the time taken for processing the feed into pyrolysis products. These products are generated in roughly equal proportions with slow pyrolysis. Using fast pyrolysis, bio-oil yield can be as high as 80 percent of the product on a dry fuel basis.

Biomass-Pyrolysis

Bio-oil can act as a liquid fuel or as a feedstock for chemical production. A range of bio-oil production processes are under development, including fluid bed reactors, ablative pyrolysis, entrained flow reactors, rotating cone reactors, and vacuum pyrolysis.

Thermal Conversion of Tannery Wastes

  By | | , ,
2 Comments

Tanneries generate considerable quantities of sludge, shavings, trimmings, hair, buffing dusts and other general wastes and can consist of up to 70% of hide weight processed. Thermal conversion technologies by virtue of chemically reducing conditions, provides a viable alternative thermal treatment for tannery wastes, especially for chrome containing materials, and generates a chrome (III) containing ash. This ash has significant commercial value as it can be reconstituted.

tannery-wastes

All of the wastes generated by the tannery can be gasified following pre-treatment methods such as maceration, drying and subsequent densification or briquetting. A combined drying and gasification process could eliminate solid waste, whilst providing a combustible gas as a tax-exempt renewable energy source, which the tannery can directly reuse. Gasification trials have illustrated that up to 70% of the intrinsic energy value of the wastes currently disposed can be recovered as “synthesis gas” energy.

Gasification technology has the potential to provide significant cost benefits in terms of power generation and waste disposal, and increase sustainability within the leather industry. The gasification process converts any carbon-containing material into a combustible gas comprised primarily of carbon monoxide, hydrogen and methane, which can be used as a fuel to generate electricity and heat.

A wide range of tannery wastes can be macerated, flash dried, densified and gasified to generate a clean syngas for reuse in boilers or other Combined Heat and Power systems. As a result up to 70% of the intrinsic energy value of the waste can be recovered as syngas, with up to 60% of this being surplus to process drying requirements so can be recovered for on-site boiler or thermal energy recovery uses.

A proprietary technology has been in commercial operation at a tanyard on the West Coast of Norway since mid 2001. The process employs gasification-and-plasma-cracking and offer the capability of turning the tannery waste problem to a valorising source that may add values to the plant owner in terms of excessive energy and ferrochrome, a harmless alloy that is widely used by the metallurgical industry. The process leaves no ashes but a non-leaching slag that is useful for civil engineering works, and, hence, no residues for landfill disposal

Biofuels from MSW – An Introduction

  By | | , ,
Leave a comment

Nowadays, biofuels are in high demand for transportation, industrial heating and electricity generation. Different technologies are being tested for using MSW as feedstock for producing biofuels. This article will provide brief description of biochemical and thermochemical conversion routes for the production of biofuels from municipal solid wastes.

drop-in-biofuels

Biochemical conversion

The waste is collected and milled, particles are shredded to reduce the size of 0.2-1.22 mm. MSW is pretreated to improve the accessibility of enzymes and make use of the enzymes in the bacteria for biological degradation on solid waste. The mixture of biomass is mixed with sulfuric acid and sodium hydroxide and autoclaved. After steam treatment, the mixture is filtered and washed with deionized water. The pre-treated mixture is then dried and drained overnight. The pre-treatment process improves the formation of sugars by enzymatic hydrolysis, avoids the loss of carbohydrate and avoids the formation of by-products inhibitory.

After pre-treatment (pre-hydrolysis), the mixture undergoes enzymatic hydrolysis for conversion of polysaccharides into monomer sugars, such as glucose and xylose. The common enzymes used for starch-based substrates are amylase, pullulanase, isomylase and glucoamylase. Whereas for lignocellulose based substrates cellulases and glucosidases.

Finally, the mixture is fermented; sugars are converted to ethanol by using microorganisms such as, bacteria, yeast or fungi. The cellulosic and starch hydrolysates ethanolic fermentation were fermented by M. indicus at 37 °C for 72 h. The fungus uses the hexoses and pentoses sugars with a high concentration of inhibitors (i.e. furfural, hydroxymethyl furfural, and acetic acid).

The composition of MSW feedstock effects the yield of the subsequent processes. A high composition of food and vegetable waste is more desirable, as these wastes are easily degradable and result in high yields compared to paper and cardboard.

Thermochemical conversion

Gasification process is carried out by treating carbon-based material with either oxygen or steam to produce a gaseous fuel which requires high temperature and pressure. It can be described as partial oxidation of the waste. At first waste is reduced in size and dried to reduce the amount of energy used in the gasifier.

Biomass_Gasification_Process

Layout of a Typical Biomass Gasification Plant

 

The carbonaceous material oxidizes (combines with oxygen) to produce syngas (carbon monoxide and hydrogen) along with carbon dioxide, methane, water vapor, char, slag, and trace gases (depending on the composition of the feedstock). The syngas is then cleaned to remove any sulfur or acid gases and trace metals (depending on the composition of the feedstock).

The main uses of syngas are direct burning on site to provide heat or energy (by using boilers, gas turbines or steam driven engines) and refined to liquid fuels such as gasoline or ethanol.

Syngas can then be converted into biofuels and chemicals via catalytic processes such as the Fischer-Tropsch process. The Fischer-Tropsch process is a series of catalytic chemical reactions that convert syngas into liquid hydrocarbons by applying heat and pressure. Hydrocracking, hydro-treating, and hydro-isomerization can also be part of the “upgrading” process to maximize quantities of different products.

Biomass Gasification Process

  By | | , ,
20 Comments

Biomass gasification involves burning of biomass in a limited supply of air to give a combustible gas consisting of carbon monoxide, carbon dioxide, hydrogen, methane, water, nitrogen, along with contaminants like small char particles, ash and tars. The gas is cleaned to make it suitable for use in boilers, engines and turbines to produce heat and power (CHP).

Biomass gasification provides a means of deriving more diverse forms of energy from the thermochemical conversion of biomass than conventional combustion. The basic gasification process involves devolatization, combustion and reduction.

biomass-gasification

During devolatization, methane and other hydrocarbons are produced from the biomass by the action of heat which leaves a reactive char.

During combustion, the volatiles and char are partially burned in air or oxygen to generate heat and carbon dioxide. In the reduction phase, carbon dioxide absorbs heat and reacts with the remaining char to produce carbon monoxide (producer gas). The presence of water vapour in a gasifier results in the production of hydrogen as a secondary fuel component.

There are two main types of gasifier that can be used to carry out this conversion, fixed bed gasifiers and fluidized bed gasifiers. The conversion of biomass into a combustible gas involves a two-stage process. The first, which is called pyrolysis, takes place below 600°C, when volatile components contained within the biomass are released. These may include organic compounds, hydrogen, carbon monoxide, tars and water vapour.

Pyrolysis leaves a solid residue called char. In the second stage of the gasification process, this char is reacted with steam or burnt in a restricted quantity of air or oxygen to produce further combustible gas. Depending on the precise design of gasifier chosen, the product gas may have a heating value of 6 – 19 MJ/Nm3.

Layout of a Typical Biomass Gasification Plant

The products of gasification are a mixture of carbon monoxide, carbon dioxide, methane, hydrogen and various hydrocarbons, which can then be used directly in gas turbines, and boilers, or used as precursors for synthesising a wide range of other chemicals.

In addition there are a number of methods that can be used to produce higher quality product gases, including indirect heating, oxygen blowing, and pressurisation. After appropriate treatment, the resulting gases can be burned directly for cooking or heat supply, or used in secondary conversion devices, such as internal combustion engines or gas turbines, for producing electricity or shaft power (where it also has the potential for CHP applications).

See some of our favorite inspirational quotes

Everything You Should Know About MSW-to-Energy

  By | | , , ,
7 Comments

You know the saying: One person’s trash is another’s treasure. When it comes to recovering energy from municipal solid waste — commonly called garbage or trash— that treasure can be especially useful. Instead of taking up space in a landfill, we can process our trash to produce energy to power our homes, businesses and public buildings.

In 2015, the United States got about 14 billion kilowatt-hours of electricity from burning municipal solid waste, or MSW. Seventy-one waste-to-energy plants and four additional power plants burned around 29 million tons of MSW in the U.S. that year. However, just 13 percent of the country’s waste becomes energy. Around 35 percent is recycled or composted, and the rest ends up in landfills.

MSW-to-Energy

Recovering Energy Through Incineration

The predominant technology for MSW-to-energy plants is incineration, which involves burning the trash at high temperatures. Similarly to how some facilities use coal or natural gas as fuel sources, power plants can also burn MSW as fuel to heat water, which creates steam, turns a turbine and produces electricity.

Several methods and technologies can play a role in burning trash to create electricity. The most common type of incineration plant is what’s called a mass-burn facility. These units burn the trash in one large chamber. The facility might sort the MSW before sending it to the combustion chamber to remove non-combustible materials and recyclables.

These mass-burn incineration systems use excess air to facilitate mixing, and ensure air gets to all the waste. Many of these units also burn the fuel on a sloped, moving grate to mix the waste even further. These steps are vital because solid waste is inconsistent, and its content varies. Some facilities also shred the MSW before moving it to the combustion chamber.

Gasification Plants

Another method for converting trash into electricity is gasification. This type of waste-to-energy plant doesn’t burn MSW directly, but instead uses it as feedstock for reactions that produce a fuel gas known as synthesis gas, or syngas. This gas typically contains carbon monoxide, carbon dioxide, methane, hydrogen and water vapor.

Approaches to gasification vary, but typically include high temperatures, high-pressure environments, very little oxygen and shredding MSW before the process begins. Common MSW gasification methods include:

  • Pyrolysis, which involves little to no oxygen, partial pressure and temperatures between approximately 600 and 800 degrees Celsius.
  • Air-fed systems, which use air instead of pure oxygen and temperatures between 800 and 1,800 degrees Celsius.
  • Plasma or plasma arc gasification, which uses plasma torches to increase temperatures to 2,000 to 2,800 degrees Celsius.

Syngas can be burned to create electricity, but it can also be a component in the production of transportation fuels, fertilizers and chemicals. Proponents of gasification report that it is a more efficient waste-to-energy method than incineration, and can produce around 1,000 kilowatt-hours of electricity from one ton of MSW. Incineration, on average, produces 550 kilowatt-hours.

Also Read: The Role of an Electrician in a Waste-to-Energy Plant

Challenges of MSW-to-Energy

Turning trash into energy seems like an ideal solution. We have a lot of trash to deal with, and we need to produce energy. MSW-to-energy plants solve both of those problems. However, a relatively small amount of waste becomes energy, especially in the U.S.

Typical layout of MSW-to-Energy Plant

This lack may be due largely to the upfront costs of building a waste-to-energy plant. It is much cheaper in the short term to send trash straight to a landfill. Some people believe these energy production processes are just too complicated and expensive. Gasification, especially, has a reputation for being too complex.

Environmental concerns also play a role, since burning waste can release greenhouse gases. Although modern technologies can make burning waste a cleaner process, its proponents still complain it is too dirty.

Despite these challenges, as trash piles up and we continue to look for new sources of energy, waste-to-energy plants may begin to play a more integral role in our energy production and waste management processes. If we handle it responsibly and efficiently, it could become a very viable solution to several of the issues our society faces.

Waste-to-Energy in Saudi Arabia

  By | | ,
3 Comments

Urban waste management has emerged as a big challenge for the government and local bodies in Saudi Arabia. The country generates more than 15 million tons of municipal solid waste each year with per capita waste production estimated to be 2 kg per day, among the highest worldwide. Municipal waste production in three largest cities – Riyadh, Jeddah and Dammam – exceeds 6 million tons per annum which gives an indication of the enormity of the problem faced by civic bodies.

waste-jeddah

The Problem of Waste

Municipal waste generation in Saudi Arabia is increasing at an unprecedented rate. Due to high population growth rate, rapid urbanization and fast-paced economic development, MSW generation is expected to cross 30 million tons per year by 2033. More than 75 percent of Kingdom’s population is concentrated in urban areas, and collected garbage is thrown in landfills or dumpsites without any processing or treatment.

Most of the landfills in Saudi Arabia are non-sanitary and prone to problems like leachate, vermin, flies and spontaneous fires, apart from greenhouse gas emissions.  It has become necessary for the Saudi government to devise an integrated waste management strategy, using international best practices and modern technologies, to tackle heaps of garbage accumulating across the country.

Promise of Waste-to-Energy

Waste-to-energy provides a cost-effective and eco-friendly solution to both energy demand and MSW disposal problems in Saudi Arabia. Increasing waste generation, inability of existing solutions to tackle waste and expansion of cities into ex-dump sites are strong drivers for large-scale deployment of WTE systems in the Kingdom.

Saudi Arabia has tremendous waste-to-energy potential due to plentiful availability of good quality municipal waste. Modern waste-to-energy technologies, such as RDF-based incineration, gasification, pyrolysis and anaerobic digestion have the ability to transform power demand and waste management scenario in the country.

A typical 250 – 300 tons per day garbage-to-energy plant can produce around 3 – 4 MW of electricity and a network of such plants in cities around the country can make a real difference in waste management as well as energy sectors.  In fact, such plants also produce tremendous about of heat energy which can be utilized in process industries and district cooling systems, further maximizing their usefulness.

Key Challenges

Around the world, waste-to-energy finds wide acceptance as a tool to manage urban wastes, with more than 1,000 waste-to-energy plants in operation globally, especially in Europe, China and the Asia-Pacific. However, waste-to-energy is struggling to get off-the-ground in Saudi Arabia due to several issues, the main reason being the cheap and plentiful availability of oil which prevents decision-makers to set effective regulations for waste-to-energy development in the country.

Waste-to-Energy is widely accepted as a part of sustainable waste management strategy worldwide.

Waste-to-Energy is widely accepted as a part of sustainable waste management strategy worldwide.

Policy-makers in KSA should consider waste-to-energy as a sustainable waste management solution, rather than as a power-producing industry. Unlike Western countries, waste management services are practically free-of-cost for the waste generators which act as a deterrent for governmental investment in new waste management solutions and technologies, such as waste-to-energy. Infact, waste collection, transport and disposal methods in Saudi Arabia do not match the standards of a developed country.

Future Outlook

Vision 2030, touted as most comprehensive economic reform package in Saudi history, puts forward a strong regulatory and investment framework to develop Saudi waste-to-energy sector. An ambitious target of 3GW of energy from waste is to be achieved by 2025.  A methodical introduction of modern waste management techniques like material recovery facilities, waste-to-energy systems and recycling infrastructure can significantly improve waste management scenario and can also generate good business opportunities.

To sum up, environmental issues associated with non-sanitary landfills, ineffectiveness of prevalent waste management model and rising energy demand are key drivers for development of waste-to-energy sector in Saudi Arabia.

Know About Popular Waste to Energy Conversion Routes

  By | | ,
7 Comments

Waste-to-energy is the use of combustion and biological technologies to recover energy from urban wastes. There are three major waste to energy conversion routes – thermochemical, biochemical and physico-chemical. Thermochemical conversion, characterized by higher temperature and conversion rates, is best suited for lower moisture feedstock and is generally less selective for products. On the other hand, biochemical technologies are more suitable for wet wastes which are rich in organic matter.

Teesside-WTE-plant

Thermochemical Conversion of Waste

The three principal methods of thermochemical conversion of waste are combustion in excess air, gasification in reduced air, and pyrolysis in the absence of air. The most common technique for producing both heat and electrical energy from household wastes is direct combustion.

Combined heat and power (CHP) or cogeneration systems, ranging from small-scale technology to large grid-connected facilities, provide significantly higher efficiencies than systems that only generate electricity.

WTE_Pathways

Combustion technology is the controlled combustion of waste with the recovery of heat to produce steam which in turn produces power through steam turbines. Pyrolysis and gasification represent refined thermal treatment methods as alternatives to incineration and are characterized by the transformation of the waste into product gas as energy carrier for later combustion in, for example, a boiler or a gas engine. Plasma gasification, which takes place at extremely high temperature, is also hogging limelight nowadays.

Biochemical Conversion of Waste

Biochemical processes, like anaerobic digestion, can also produce clean energy in the form of biogas which can be converted to power and heat using a gas engine. Anaerobic digestion is the natural biological process which stabilizes organic waste in the absence of air and transforms it into biofertilizer and biogas.

Anaerobic digestion is a reliable technology for the treatment of wet, organic waste.  Organic waste from various sources is biochemically degraded in highly controlled, oxygen-free conditions circumstances resulting in the production of biogas which can be used to produce both electricity and heat.

anaerobic_digestion_plant

In addition, a variety of fuels can be produced from waste resources including liquid fuels, such as ethanol, methanol, biodiesel, Fischer-Tropsch diesel, and gaseous fuels, such as hydrogen and methane. The resource base for biofuel production is composed of a wide variety of forestry and agricultural resources, industrial processing residues, and municipal solid and urban wood residues. Globally, biofuels are most commonly used to power vehicles, heat homes, and for cooking.

Physico-chemical Conversion of Waste

The physico-chemical conversion of waste involves various processes to improve physical and chemical properties of solid waste. The combustible fraction of the waste is converted into high-energy fuel pellets which may be used in steam generation.

RDF pellet

The waste is first dried to bring down the high moisture levels. Sand, grit, and other incombustible matter are then mechanically separated before the waste is compacted and converted into fuel pellets or RDF.

Fuel pellets have several distinct advantages over coal and wood because it is cleaner, free from incombustibles, has lower ash and moisture contents, is of uniform size, cost-effective, and eco-friendly.

Energy Potential of Coconut Biomass

  By | | , ,
15 Comments

Coconuts are produced in 92 countries worldwide on about more than 10 million hectares. Indonesia, Philippines and India account for almost 75% of world coconut production with Indonesia being the world’s largest coconut producer. A coconut plantation is analogous to energy crop plantations, however coconut plantations are a source of wide variety of products, in addition to energy. The current world production of coconuts has the potential to produce electricity, heat, fiberboards, organic fertilizer, animal feeds, fuel additives for cleaner emissions, eco-friendly cutlery, health drinks, etc.

coconut-shell-biomass

The coconut fruit yields 40 % coconut husks containing 30 % fiber, with dust making up the rest. The chemical composition of coconut husks consists of cellulose, lignin, pyroligneous acid, gas, charcoal, tar, tannin, and potassium. Coconut dust has high lignin and cellulose content. The materials contained in the casing of coco dusts and coconut fibers are resistant to bacteria and fungi.

Coconut biomass is available in the form of coconut husk and coconut shells. Coconut husk and shells are an attractive biomass fuel and are also a good source of charcoal. The major advantage of using coconut biomass as a fuel is that coconut is a permanent crop and available round the year so there is constant whole year supply. Activated carbon manufactured from coconut shell is considered extremely effective for the removal of impurities in wastewater treatment processes.

Coconut Shell

Coconut shell is an agricultural waste and is available in plentiful quantities throughout tropical countries worldwide. In many countries, coconut shell is subjected to open burning which contributes significantly to CO2 and methane emissions.

Coconut shell is widely used for making charcoal. The traditional pit method of production has a charcoal yield of 25–30% of the dry weight of shells used. The charcoal produced by this method is of variable quality, and often contaminated with extraneous matter and soil. The smoke evolved from pit method is not only a nuisance but also a health hazard.

The coconut shell has a high calorific value of 20.8MJ/kg and can be used to produce steam, energy-rich gases, bio-oil, biochar etc. It is to be noted that coconut shell and coconut husk are solid fuels and have the peculiarities and problems inherent in this kind of fuel.

Coconut shell is more suitable for pyrolysis process as it contain lower ash content, high volatile matter content and available at a cheap cost. The higher fixed carbon content leads to the production to a high-quality solid residue which can be used as activated carbon in wastewater treatment. Coconut shell can be easily collected in places where coconut meat is traditionally used in food processing.

Coconut Husk

Coconut husk has high amount of lignin and cellulose, and that is why it has a high calorific value of 18.62MJ/kg. The chemical composition of coconut husks consists of cellulose, lignin, pyroligneous acid, gas, charcoal, tar, tannin, and potassium.

The predominant use of coconut husks is in direct combustion in order to make charcoal, otherwise husks are simply thrown away. Coconut husk can be transformed into a value-added fuel source which can replace wood and other traditional fuel sources. In terms of the availability and costs of coconut husks, they have good potential for use in power plants.

Gasification of Municipal Wastes

  By | | , , ,
16 Comments

Gasification of municipal wastes involves the reaction of carbonaceous feedstock with an oxygen-containing reagent, usually oxygen, air, steam or carbon dioxide, generally at temperatures above 800°C. The process is largely exothermic but some heat may be required to initialise and sustain the gasification process.

utishinai-gasification-plant

The main product of the gasification process is syngas, which contains carbon monoxide, hydrogen and methane. Typically, the gas generated from gasification has a low heating value (LHV) of 3 – 6 MJ/Nm3.The other main product produced by gasification is a solid residue of non-combustible materials (ash) which contains a relatively low level of carbon.

Syngas can be used in a number of ways, including:

  • Syngas can be burned in a boiler to generate steam for power generation or industrial heating.
  • Syngas can be used as a fuel in a dedicated gas engine.
  • Syngas, after reforming, can be used in a gas turbine
  • Syngas can also be used as a chemical feedstock.

Gasification has been used worldwide on a commercial scale for several decades by the chemical, refining, fertilizer and electric power industries. MSW gasification plants are relatively small-scale, flexible to different inputs and modular development. The quantity of power produced per tonne of waste by gasification process is larger than when applying the incineration method.

The most important reason for the growing popularity of gasification of municipal solid wastes has been the increasing technical, environmental and public dissatisfaction with the performance of conventional incinerators.

Plasma Gasification

Plasma gasification uses extremely high temperatures in an oxygen-starved environment to completely decompose input waste material into very simple molecules in a process similar to pyrolysis. The heat source is a plasma discharge torch, a device that produces a very high temperature plasma gas. It is carried out under oxygen-starved conditions and the main products are vitrified slag, syngas and molten metal.

plasma-gasification

Vitrified slag may be used as an aggregate in construction; the syngas may be used in energy recovery systems or as a chemical feedstock; and the molten metal may have a commercial value depending on quality and market availability. The technology has been in use for steel-making and is used to melt ash to meet limits on dioxin/furan content. There are several commercial-scale plants already in operation in Japan for treating MSW and auto shredder residue.

Advantages of MSW Gasification

There are numerous MSW gasification facilities operating or under construction around the world. Gasification of solid wastes has several advantages over traditional combustion processes for MSW treatment. It takes place in a low oxygen environment that limits the formation of dioxins and of large quantities of SOx and NOx. Furthermore, it requires just a fraction of the stoichiometric amount of oxygen necessary for combustion. As a result, the volume of process gas is low, requiring smaller and less expensive gas cleaning equipment.

The lower gas volume also means a higher partial pressure of contaminants in the off-gas, which favours more complete adsorption and particulate capture. Finally, gasification generates a fuel gas that can be integrated with combined cycle turbines, reciprocating engines and, potentially, with fuel cells that convert fuel energy to electricity more efficiently than conventional steam boilers.

Disadvantages of Gasification

The gas resulting from gasification of municipal wastes contains various tars, particulates, halogens, heavy metals and alkaline compounds depending on the fuel composition and the particular gasification process. This can result in agglomeration in the gasification vessel, which can lead to clogging of fluidised beds and increased tar formation. In general, no slagging occurs with fuels having ash content below 5%. MSW has a relatively high ash content of 10-12%.

Utilization of Date Palm Biomass

  By | | , , ,
3 Comments

Date palm trees produce huge amount of agricultural wastes in the form of dry leaves, stems, pits, seeds etc. A typical date tree can generate as much as 20 kilograms of dry leaves per annum while date pits account for almost 10 percent of date fruits.

date-wastes

Date palm biomass is found in large quantities across the Middle East

Date palm is considered a renewable natural resource because it can be replaced in a relatively short period of time. It takes 4 to 8 years for date palms to bear fruit after planting, and 7 to 10 years to produce viable yields for commercial harvest. Usually date palm wastes are burned in farms or disposed in landfills which cause environmental pollution in dates-producing nations.

The major constituents of date palm biomass are cellulose, hemicelluloses and lignin. In addition, date palm has high volatile solids content and low moisture content. These factors make date palm residues an excellent biomass resource in date-palm producing nations.

Date palm biomass is an excellent resource for charcoal production in Middle East

A wide range of physico-chemical, thermal and biochemical technologies exists for sustainable utilization of date palm biomass. Apart from charcoal production and energy conversion (using technologies like combustion and gasification), below are few ways for utilization of date palm wastes:

Conversion into fuel pellets or briquettes

Biomass pellets are a popular type of alternative fuel (analogous to coal), generally made from wood wastes and agricultural biomass. The biomass pelletization process consists of multiple steps including pre-treatment, pelletization and post-treatment of biomass wastes. Biomass pellets can be used as a coal replacement in power plant, industries and other application.

Conversion into energy-rich products

Biomass pyrolysis is the thermal decomposition of date palm biomass occurring in the absence of oxygen. The products of biomass pyrolysis include biochar, bio-oil and gases including methane, hydrogen, carbon monoxide, and carbon dioxide.

Depending on the thermal environment and the final temperature, pyrolysis will yield mainly biochar at low temperatures, less than 450 0C, when the heating rate is quite slow, and mainly gases at high temperatures, greater than 800 0C, with rapid heating rates. At an intermediate temperature and under relatively high heating rates, the main product is bio-oil.

Bio-oil can be upgraded to either a special engine fuel or through gasification processes to a syngas which can then be processed into biofuels. Bio-oil is particularly attractive for co-firing because it can be more readily handled and burned than solid fuel and is cheaper to transport and store.

Conversion into biofertilizer

Composting is the most popular method for biological decomposition of organic wastes. Date palm waste has around 80% organic content which makes it very well-suited for the composting process. Commercial-scale composting of date palm wastes can be carried out by using the traditional windrow method or a more advanced method like vermicomposting.