pyrolysis

Thermal Conversion of Biomass

A wide range of thermal technologies exists to harness the energy stored in biomass. These biomass thermal technologies can be classified according to the principal energy carrier produced in the conversion process. Carriers are in the form of heat, gas, liquid and/or solid products, depending on the extent to which oxygen is admitted to the conversion process (usually as air). The major methods for thermal conversion of biomass are combustion, gasification and pyrolysis.

1. Combustion

Conventional combustion technologies raise steam through the combustion of biomass. This steam may then be expanded through a conventional turbo-alternator to produce electricity. A number of combustion technology variants have been developed. Underfeed stokers are suitable for small scale boilers up to 6 MWth.

Grate type boilers are widely deployed. They have relatively low investment costs, low operating costs and good operation at partial loads. However, they can have higher NOx emissions and decreased efficiencies due to the requirement of excess air, and they have lower efficiencies.

Fluidized bed combustors (FBC), which use a bed of hot inert material such as sand, are a more recent development. Bubbling FBCs are generally used at 10-30 MWth capacity, while Circulating FBCs are more applicable at larger scales. Advantages of FBCs are that they can tolerate a wider range of poor quality fuel, while emitting lower NOx levels.

2. Co-Firing

Co-firing or co-combustion of biomass wastes with coal and other fossil fuels can provide a short-term, low-risk, low-cost option for producing renewable energy while simultaneously reducing the use of fossil fuels. Co-firing involves utilizing existing power generating plants that are fired with fossil fuel (generally coal), and displacing a small proportion of the fossil fuel with renewable biomass fuels.

Co-firing has the major advantage of avoiding the construction of new, dedicated, waste-to-energy power plant. Co-firing may be implemented using different types and percentages of wastes in a range of combustion and gasification technologies. Most forms of biomass wastes are suitable for co-firing. These include dedicated municipal solid wastes, wood waste and agricultural residues such as straw and husk.

3. Gasification

Gasification of biomass takes place in a restricted supply of oxygen and occurs through initial devolatilization of the biomass, combustion of the volatile material and char, and further reduction to produce a fuel gas rich in carbon monoxide and hydrogen. This combustible gas has a lower calorific value than natural gas but can still be used as fuel for boilers, for engines, and potentially for combustion turbines after cleaning the gas stream of tars and particulates.

Layout of a Typical Biomass Gasification Plant

If gasifiers are ‘air blown’, atmospheric nitrogen dilutes the fuel gas to a level of 10-14 percent that of the calorific value of natural gas. Oxygen and steam blown gasifiers produce a gas with a somewhat higher calorific value. Pressurized gasifiers are under development to reduce the physical size of major equipment items.

A variety of gasification reactors have been developed over several decades. These include the smaller scale fixed bed updraft, downdraft and cross flow gasifiers, as well as fluidized bed gasifiers for larger applications. At the small scale, downdraft gasifiers are noted for their relatively low tar production, but are not suitable for fuels with low ash melting point (such as straw). They also require fuel moisture levels to be controlled within narrow levels.

4. Pyrolysis

Pyrolysis is the term given to the thermal degradation of wood in the absence of oxygen. It enables biomass to be converted to a combination of solid char, gas and a liquid bio-oil. Pyrolysis technologies are generally categorized as “fast” or “slow” according to the time taken for processing the feed into pyrolysis products. These products are generated in roughly equal proportions with slow pyrolysis. Using fast pyrolysis, bio-oil yield can be as high as 80 percent of the product on a dry fuel basis.

Bio-oil can act as a liquid fuel or as a feedstock for chemical production. A range of bio-oil production processes are under development, including fluid bed reactors, ablative pyrolysis, entrained flow reactors, rotating cone reactors, and vacuum pyrolysis.

Everything You Should Know About MSW-to-Energy

By Emily Folk | May 11, 2023 - 5:30 am |July 30, 2023 Electricity, Industrial Equipment, Waste Management, Waste-to-energy

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You know the saying: One person’s trash is another’s treasure. When it comes to recovering energy from municipal solid waste — commonly called garbage or trash— that treasure can be especially useful. Instead of taking up space in a landfill, we can process our trash to produce energy to power our homes, businesses and public buildings.

In 2015, the United States got about 14 billion kilowatt-hours of electricity from burning municipal solid waste, or MSW. Seventy-one waste-to-energy plants and four additional power plants burned around 29 million tons of MSW in the U.S. that year. However, just 13 percent of the country’s waste becomes energy. Around 35 percent is recycled or composted, and the rest ends up in landfills.

Recovering Energy Through Incineration

The predominant technology for MSW-to-energy plants is incineration, which involves burning the trash at high temperatures. Similarly to how some facilities use coal or natural gas as fuel sources, power plants can also burn MSW as fuel to heat water, which creates steam, turns a turbine and produces electricity.

Several methods and technologies can play a role in burning trash to create electricity. The most common type of incineration plant is what’s called a mass-burn facility. These units burn the trash in one large chamber. The facility might sort the MSW before sending it to the combustion chamber to remove non-combustible materials and recyclables.

These mass-burn incineration systems use excess air to facilitate mixing, and ensure air gets to all the waste. Many of these units also burn the fuel on a sloped, moving grate to mix the waste even further. These steps are vital because solid waste is inconsistent, and its content varies. Some facilities also shred the MSW before moving it to the combustion chamber.

Gasification Plants

Another method for converting trash into electricity is gasification. This type of waste-to-energy plant doesn’t burn MSW directly, but instead uses it as feedstock for reactions that produce a fuel gas known as synthesis gas, or syngas. This gas typically contains carbon monoxide, carbon dioxide, methane, hydrogen and water vapor.

Approaches to gasification vary, but typically include high temperatures, high-pressure environments, very little oxygen and shredding MSW before the process begins. Common MSW gasification methods include:

Pyrolysis, which involves little to no oxygen, partial pressure and temperatures between approximately 600 and 800 degrees Celsius.
Air-fed systems, which use air instead of pure oxygen and temperatures between 800 and 1,800 degrees Celsius.
Plasma or plasma arc gasification, which uses plasma torches to increase temperatures to 2,000 to 2,800 degrees Celsius.

Syngas can be burned to create electricity, but it can also be a component in the production of transportation fuels, fertilizers and chemicals. Proponents of gasification report that it is a more efficient waste-to-energy method than incineration, and can produce around 1,000 kilowatt-hours of electricity from one ton of MSW. Incineration, on average, produces 550 kilowatt-hours.

Also Read: The Role of an Electrician in a Waste-to-Energy Plant

Challenges of MSW-to-Energy

Turning trash into energy seems like an ideal solution. We have a lot of trash to deal with, and we need to produce energy. MSW-to-energy plants solve both of those problems. However, a relatively small amount of waste becomes energy, especially in the U.S.

Typical layout of MSW-to-Energy Plant

This lack may be due largely to the upfront costs of building a waste-to-energy plant. It is much cheaper in the short term to send trash straight to a landfill. Some people believe these energy production processes are just too complicated and expensive. Gasification, especially, has a reputation for being too complex.

Environmental concerns also play a role, since burning waste can release greenhouse gases. Although modern technologies can make burning waste a cleaner process, its proponents still complain it is too dirty.

Despite these challenges, as trash piles up and we continue to look for new sources of energy, waste-to-energy plants may begin to play a more integral role in our energy production and waste management processes. If we handle it responsibly and efficiently, it could become a very viable solution to several of the issues our society faces.

Energy Potential of Coconut Biomass

By Salman Zafar | October 1, 2022 - 3:50 am |October 1, 2022 Agriculture, Biomass Energy, Waste Management

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Coconuts are produced in 92 countries worldwide on about more than 10 million hectares. Indonesia, Philippines and India account for almost 75% of world coconut production with Indonesia being the world’s largest coconut producer. A coconut plantation is analogous to energy crop plantations, however coconut plantations are a source of wide variety of products, in addition to energy. The current world production of coconuts has the potential to produce electricity, heat, fiberboards, organic fertilizer, animal feeds, fuel additives for cleaner emissions, eco-friendly cutlery, health drinks, etc.

The coconut fruit yields 40 % coconut husks containing 30 % fiber, with dust making up the rest. The chemical composition of coconut husks consists of cellulose, lignin, pyroligneous acid, gas, charcoal, tar, tannin, and potassium. Coconut dust has high lignin and cellulose content. The materials contained in the casing of coco dusts and coconut fibers are resistant to bacteria and fungi.

Coconut biomass is available in the form of coconut husk and coconut shells. Coconut husk and shells are an attractive biomass fuel and are also a good source of charcoal. The major advantage of using coconut biomass as a fuel is that coconut is a permanent crop and available round the year so there is constant whole year supply. Activated carbon manufactured from coconut shell is considered extremely effective for the removal of impurities in wastewater treatment processes.

Coconut Shell

Coconut shell is an agricultural waste and is available in plentiful quantities throughout tropical countries worldwide. In many countries, coconut shell is subjected to open burning which contributes significantly to CO₂ and methane emissions.

Coconut shell is widely used for making charcoal. The traditional pit method of production has a charcoal yield of 25–30% of the dry weight of shells used. The charcoal produced by this method is of variable quality, and often contaminated with extraneous matter and soil. The smoke evolved from pit method is not only a nuisance but also a health hazard.

The coconut shell has a high calorific value of 20.8MJ/kg and can be used to produce steam, energy-rich gases, bio-oil, biochar etc. It is to be noted that coconut shell and coconut husk are solid fuels and have the peculiarities and problems inherent in this kind of fuel.

Coconut shell is more suitable for pyrolysis process as it contain lower ash content, high volatile matter content and available at a cheap cost. The higher fixed carbon content leads to the production to a high-quality solid residue which can be used as activated carbon in wastewater treatment. Coconut shell can be easily collected in places where coconut meat is traditionally used in food processing.

Coconut Husk

Coconut husk has high amount of lignin and cellulose, and that is why it has a high calorific value of 18.62MJ/kg. The chemical composition of coconut husks consists of cellulose, lignin, pyroligneous acid, gas, charcoal, tar, tannin, and potassium.

The predominant use of coconut husks is in direct combustion in order to make charcoal, otherwise husks are simply thrown away. Coconut husk can be transformed into a value-added fuel source which can replace wood and other traditional fuel sources. In terms of the availability and costs of coconut husks, they have good potential for use in power plants.

Utilization of Date Palm Biomass

By Salman Zafar | August 13, 2022 - 10:22 pm |August 13, 2022 Agriculture, Biomass Energy, Recycling, Waste Management

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Date palm trees produce huge amount of agricultural wastes in the form of dry leaves, stems, pits, seeds etc. A typical date tree can generate as much as 20 kilograms of dry leaves per annum while date pits account for almost 10 percent of date fruits.

Date palm biomass is found in large quantities across the Middle East

Date palm is considered a renewable natural resource because it can be replaced in a relatively short period of time. It takes 4 to 8 years for date palms to bear fruit after planting, and 7 to 10 years to produce viable yields for commercial harvest. Usually date palm wastes are burned in farms or disposed in landfills which cause environmental pollution in dates-producing nations.

The major constituents of date palm biomass are cellulose, hemicelluloses and lignin. In addition, date palm has high volatile solids content and low moisture content. These factors make date palm residues an excellent biomass resource in date-palm producing nations.

Date palm biomass is an excellent resource for charcoal production in Middle East

A wide range of physico-chemical, thermal and biochemical technologies exists for sustainable utilization of date palm biomass. Apart from charcoal production and energy conversion (using technologies like combustion and gasification), below are few ways for utilization of date palm wastes:

Conversion into fuel pellets or briquettes

Biomass pellets are a popular type of alternative fuel (analogous to coal), generally made from wood wastes and agricultural biomass. The biomass pelletization process consists of multiple steps including pre-treatment, pelletization and post-treatment of biomass wastes. Biomass pellets can be used as a coal replacement in power plant, industries and other application.

Conversion into energy-rich products

Biomass pyrolysis is the thermal decomposition of date palm biomass occurring in the absence of oxygen. The products of biomass pyrolysis include biochar, bio-oil and gases including methane, hydrogen, carbon monoxide, and carbon dioxide.

Depending on the thermal environment and the final temperature, pyrolysis will yield mainly biochar at low temperatures, less than 450 ⁰C, when the heating rate is quite slow, and mainly gases at high temperatures, greater than 800⁰C, with rapid heating rates. At an intermediate temperature and under relatively high heating rates, the main product is bio-oil.

Bio-oil can be upgraded to either a special engine fuel or through gasification processes to a syngas which can then be processed into biofuels. Bio-oil is particularly attractive for co-firing because it can be more readily handled and burned than solid fuel and is cheaper to transport and store.

Conversion into biofertilizer

Composting is the most popular method for biological decomposition of organic wastes. Date palm waste has around 80% organic content which makes it very well-suited for the composting process. Commercial-scale composting of date palm wastes can be carried out by using the traditional windrow method or a more advanced method like vermicomposting.

Comparison of MSW-to-Energy Processes

By Salman Zafar | June 7, 2022 - 4:39 pm |June 7, 2022 Renewable Energy, Waste Management, Waste-to-energy

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MSW-to-Energy is the use of thermochemical and biochemical technologies to recover energy, usually in the form of electricity, steam and other fuels, from urban wastes. The main categories of MSW-to-energy technologies are physical technologies, which process waste to make it more useful as fuel; thermal technologies, which can yield heat, fuel oil, or syngas from both organic and inorganic wastes; and biological technologies, in which bacterial fermentation is used to digest organic wastes to yield fuel. These new technologies can reduce the volume of the original waste by 90%, depending upon composition and use of outputs.

Components of MSW-to-Energy Systems

Front-end MSW preprocessing
Conversion unit (reactor or anaerobic digester)
Gas cleanup and residue treatment plant
Energy recovery plant (optional)
Emissions clean up

Incineration

Combustion of raw MSW, moisture less than 50%
Sufficient amount of oxygen is required to fully oxidize the fuel
Combustion temperatures are in excess of 850^oC
Waste is converted into CO2 and water concern about toxics (dioxin, furans)
Any non-combustible materials (inorganic such as metals, glass) remain as a solid, known as bottom ash (used as feedstock in cement and brick manufacturing)
Air pollution control system for fly ash, bottom ash, particulates etc.
Needs high calorific value waste to keep combustion process going, otherwise requires high energy for maintaining high temperatures

Anaerobic Digestion

Well-known biochemical technology for organic fraction of MSW and sewage sludge.
Biological conversion of biodegradable organic materials in the absence of oxygen at mesophilic or thermophilic temperatures.
Residue is stabilized organic matter that can be used as soil amendment
Digestion is used primarily to reduce quantity of sludge for disposal / reuse
Methane gas is generated which is used for heat and power generation.

Gasification

Can be seen as between pyrolysis and combustion (incineration) as it involves partial oxidation.
Exothermic process (some heat is required to initialize and sustain the gasification process).
Oxygen is added but at low amounts not sufficient for full oxidation and full combustion.
Temperatures are above 650^oC
Main product is syngas, typically has net calorific value of 4 to 10 MJ/Nm³
Other product is solid residue of non-combustible materials (ash) which contains low level of carbon

Thermal degradation of organic materials through use of indirect, external source of heat
Temperatures between 300 to 850^oC are maintained for several seconds in the absence of oxygen.
Product is char, oil and syngas composed primarily of O₂, CO, CO₂, CH₄ and complex hydrocarbons.
Syngas can be utilized for energy production or proportions can be condensed to produce oils and waxes
Syngas typically has net calorific value (NCV) of 10 to 20 MJ/Nm

Plasma Gasification

Use of electricity passed through graphite or carbon electrodes, with steam and/or oxygen / air injection to produce electrically conducting gas (plasma)
Temperatures are above 3000^oC
Organic materials are converted to syngas composed of H2, CO
Inorganic materials are converted to solid slag
Syngas can be utilized for energy production or proportions can be condensed to produce oils and waxes

MSW-to-energy technologies can address a host of environmental issues, such as land use and pollution from landfills, and increasing reliance on fossil fuels. In many countries, the availability of landfill capacity has been steadily decreasing due to regulatory, planning and environmental permitting constraints. As a result, new approaches to waste management are rapidly being written into public and institutional policies at local, regional and national levels.

Trends in Utilization of Palm Kernel Shells

By Salman Zafar | April 20, 2022 - 11:25 am |April 20, 2022 Agriculture, Biomass Energy, Renewable Energy

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The palm kernel shells used to be initially dumped in the open thereby impacting the environment negatively without any economic benefit. However, over time, palm oil mills in Southeast Asia and elsewhere realized their brilliant properties as a fuel and that they can easily replace coal as an industrial fuel for generating heat and steam.

Palm kernel shells is an abundant biomass resource in Southeast Asia

Major Applications

Nowadays, the primary use of palm kernel shells is as a boiler fuel supplementing the fibre which is used as primary fuel. In recent years kernel shells are extensively sold as alternative fuel around the world. Besides selling shells in bulk, there are companies that produce fuel briquettes from shells which may include partial carbonisation of the material to improve the combustion characteristics.

Palm kernel shells have a high dry matter content (>80% dry matter). Therefore the shells are generally considered a good fuel for the boilers as it generates low ash amounts and the low K and Cl content will lead to less ash agglomeration. These properties are also ideal for production of biomass for export.

As a raw material for fuel briquettes, palm shells are reported to have the same calorific characteristics as coconut shells. The relatively smaller size makes it easier to carbonise for mass production, and its resulting palm shell charcoal can be pressed into a heat efficient biomass briquette.

Although the literature on using oil palm shells (and fibres) is not as extensive as EFB, common research directions of using shells, besides energy, are to use it as raw material for light-weight concrete, fillers, activated carbon, and other materials. However, none of the applications are currently done on a large-scale. Since shells are dry and suitable for thermal conversion, technologies that further improve the combustion characteristics and increase the energy density, such as torrefaction, could be relevant for oil palm shells.

Torrefaction is a pretreatment process which serves to improve the properties of biomass in relation to the thermochemical conversion technologies for more efficient energy generation. High lignin content for shells affects torrefaction characteristics positively (as the material is not easily degraded compared to EFB and fibres).

Furthermore, palm oil shells are studied as feedstock for fast pyrolysis. To what extent shells are a source of fermentable sugars is still not known, however the high lignin content in palm kernel shells indicates that shells are less suitable as raw material for fermentation.

Future Outlook

The leading palm oil producers in the world should consider limiting the export of palm kernel shells (PKS) to ensure supplies of the biomass material for renewable energy projects, in order to decrease dependency on fossil fuels. For example, many developers in Indonesia have expressed an interest in building palm kernel shell-fired power plants.

However, they have their concerns over supplies, as many producers prefer to sell their shells overseas currently. Many existing plants are facing problems on account of inconsistent fuel quality and increasing competition from overseas PKS buyers. PKS market is well-established in provinces like Sumatra and export volumes to Europe and North Asia as a primary fuel for biomass power plants is steadily increasing.

The creation of a biomass supply chain in palm oil producing countries may be instrumental in discouraging palm mills to sell their PKS stocks to brokers for export to foreign countries. Establishment of a biomass exchange in leading countries, like Indonesia, Malaysia and Nigeria, will also be a deciding factor in tapping the unharnessed potential of palm kernel shells as biomass resource.

Biomass Pyrolysis Process

By Salman Zafar | April 10, 2022 - 10:43 am |April 10, 2022 Biofuels, Biomass Energy, Renewable Energy

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Biomass pyrolysis is the thermal decomposition of biomass occurring in the absence of oxygen. It is the fundamental chemical reaction that is the precursor of both the combustion and gasification processes and occurs naturally in the first two seconds. The products of biomass pyrolysis include biochar, bio-oil and gases including methane, hydrogen, carbon monoxide, and carbon dioxide.

Pyrolysis can be performed at relatively small scale and at remote locations which enhance energy density of the biomass resource and reduce transport and handling costs. Pyrolysis offers a flexible and attractive way of converting solid biomass into an easily stored and transported liquid, which can be successfully used for the production of heat, power and chemicals.

A wide range of biomass feedstocks can be used in pyrolysis processes. The pyrolysis process is very dependent on the moisture content of the feedstock, which should be around 10%. At higher moisture contents, high levels of water are produced and at lower levels there is a risk that the process only produces dust instead of oil. High-moisture waste streams, such as sludge and meat processing wastes, require drying before subjecting to pyrolysis.

The efficiency and nature of the pyrolysis process is dependent on the particle size of feedstocks. Most of the pyrolysis technologies can only process small particles to a maximum of 2 mm keeping in view the need for rapid heat transfer through the particle. The demand for small particle size means that the feedstock has to be size-reduced before being used for pyrolysis.

Pyrolysis processes can be categorized as slow pyrolysis or fast pyrolysis. Fast pyrolysis is currently the most widely used pyrolysis system. Slow pyrolysis takes several hours to complete and results in biochar as the main product. On the other hand, fast pyrolysis yields 60% bio-oil and takes seconds for complete pyrolysis. In addition, it gives 20% biochar and 20% syngas.

Bio-oil

Bio-oil is a dark brown liquid and has a similar composition to biomass. It has a much higher density than woody materials which reduces storage and transport costs. Bio-oil is not suitable for direct use in standard internal combustion engines. Alternatively, the oil can be upgraded to either a special engine fuel or through gasification processes to a syngas and then biodiesel. Bio-oil is particularly attractive for co-firing because it can be more readily handled and burned than solid fuel and is cheaper to transport and store.

Bio-oil can offer major advantages over solid biomass ands gaification due to the ease of handling, storage and combustion in an existing power station when special start-up procedures are not necessary. In addition, bio-oil is also a vital source for a wide range of organic compounds and speciality chemicals.

The Pyrolysis of Scrap Tires

By Salman Zafar | March 24, 2022 - 9:08 am |July 27, 2023 Biofuels, Waste Management, Waste-to-energy

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Pyrolysis of scrap tires offers an environmentally and economically attractive method for transforming waste tires into useful products, heat and electrical energy. Pyrolysis refers to the thermal decomposition of scrap tires either in the absence or lack of oxygen. The principal feedstocks for pyrolysis are pre-treated car, bus or truck tire chips. Scrap tires are an excellent fuel because of their high calorific value which is comparable to that of coal and crude oil. The heating value of an average size passenger tire is between 30 – 34MJ/kg.

Pyrolysis is the most recommended alternative for the thermochemical treatment of waste tires and extensively used for conversion of carbonaceous materials in Europe and the Asia-Pacific. Pyrolysis is a two-phase treatment which uses thermal decomposition to heat the rubber in the absence of oxygen to break it into its constituent parts, e.g., pyrolysis oil (or bio oil), synthetic gas and char. Cracking and post-cracking take place progressively as the material is heated to 450-500°C and above.

Process Description

The pyrolysis method for scrap tires recycling involves heating whole or halved or shredded tires in a reactor containing an oxygen free atmosphere and a heat source. In the reactor, the rubber is softened after which the rubber polymers disintegrate into smaller molecules which eventually vaporize and exit from the reactor. These vapors can be burned directly to produce power or condensed into an oily type liquid, called pyrolysis oil or bio oil.

Some molecules are too small to condense and remain as a gas which can be burned as fuel. The minerals that were part of the tire, about 40% by weight, are removed as a solid. When performed well a tire pyrolysis process is a very clean operation and has nearly no emissions or waste.

The heating rate of tire is an important parameter affecting the reaction time, product yield, product quality and energy requirement of the waste tire pyrolysis process. If the temperature is maintained at around 450^oC the main product is liquid which could be a mixture of hydrocarbon depending on the initial composition of waste material. At temperature above 700^oC, synthetic gas (also known as syngas), a mixture of hydrogen and carbon monoxide, becomes the primary product due to further cracking of the liquids.

Schematic for Pyrolysis of Scrap Tires

The nature of the feedstock and process conditions defines the properties of the gas, liquid and solid products. For example, whole tires contain fibers and steel while shredded tires have most of the steel and sometimes most of the fiber removed.

Processes can be either batch or continuous. The energy required for thermal decomposition of the scrap tires can be in the form of directly-fired fuel, electrical induction and or by microwaves (like a microwave oven). A catalyst may also be required to accelerate the pyrolysis process.

Useful Products

The high acceptance of pyrolysis for the treatment of scrap tires is due to the fact that the derived oils and syngas can be used as biofuels or as feedstock for refining crude oil or chemical products. The pyrolysis oil (or bio oil) has higher calorific value, low ash, low residual carbon and low sulphur content.

The use of pyrolysis oil in cement kilns, paper mills, power plants, industrial furnaces, foundries and other industries is one of the best uses of scrap tires. Pyrolysis of scrap tyres produces oil that can be used as liquid fuels for industrial furnaces, foundries and boilers in power plants due to their higher calorific value, low ash, residual carbon and sulphur content.

The solid residue, called char, contains carbon black, and inorganic matter. It contains carbon black and the mineral matter initially present in the tire. This solid char may be used as reinforcement in the rubber industry, as activated carbon or as smokeless fuel.

Recommended Reading: Environmental Impact of Tire Recycling

Torrified PKS: An Attractive Biomass Commodity in West Africa

By Eko Sb Setyawan | January 19, 2022 - 3:38 am |January 19, 2022 Biofuels, Biomass Energy, Industry, Waste-to-energy

Torrefaction of Biomass: An Overview

By Eko Sb Setyawan | January 15, 2022 - 3:06 am |January 18, 2022 Biofuels, Biomass Energy, Industry, Waste-to-energy

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To improve the quality of biomass, especially for cofiring purposes, biomass waste can be processed with torrefaction (also known as mild pyrolysis). With the torrefaction process, it becomes easier to make powder (high grindability) so that the desired particle size for cofiring of biomass is easier to obtain. Another advantage of the torrefaction process is that the caloric value of biomass increases by about 20%. Torrified biomass is essentially hydropobic which means ease in storage including outdoor storage. This condition also makes it easier to handle and use, in addition to reduction in transportation costs.

What is Torrefaction?

Torrefaction, which is currently being considered for effective biomass utilization, is also a form of pyrolysis. In this process (named for the French word for roasting), the biomass is heated to 230 to 300 °C without contact with oxygen. For comparison, pyrolysis of biomass is typically carried out in a relatively low temperature range of 300 to 650 °C compared to 800 to 1000 °C for gasification. Torrefaction is a relatively new process that heats the biomass in the absence of air to improve its usefulness as a fuel.

Torrefaction, a process different from carbonization, is a mild pyrolysis process carried out in a temperature range of 230 to 300 °C in the absence of oxygen. During this process the biomass dries and partially devolatilizes, decreasing its mass while largely preserving its energy content. The torrefaction process removes H2O and CO2 from the biomass. As a result, both the O/C and the H/C ratios of the biomass decrease.

Benefits of Biomass Torrefaction

Torrefaction of biomass improves its energy density, reduces its oxygen-to-carbon (O/C) ratio, and reduces its hygroscopic nature. Torrefaction also increases the relative carbon content of the biomass. The properties of a torrefied biomass depends on torrefaction temperature, time, and on the type of biomass feed.

Torrefaction also modifies the structure of the biomass, making it more friable or brittle. This is caused by the depolymerization of hemicellulose. As a result, the process of size reduction becomes easier, lowering its energy consumption and the cost of handling. This makes it easier to cofire biomass in a pulverized coal-fired boiler or gasify it in an entrained-flow reactor.

Another special feature of torrefaction is that it reduces the hygroscopic property of biomass; therefore, when torrefied biomass is stored, it absorbs less moisture than that absorbed by fresh biomass. For example, while raw bagasse absorbed 186% moisture when immersed in water for two hours, it absorbed only 7.6% moisture under this condition after torrefying the bagasse for 60 minutes at 250 °C (Pimchua et al., 2009). The reduced hygroscopic (or enhanced hydrophobic) nature of torrefied biomass mitigates one of the major shortcomings for energy use of biomass.

In biomass, hemicellulose is like the cement in reinforced concrete, and cellulose is like the steel rods. The strands of microfibrils (cellulose) are supported by the hemicellulose. Decomposition of hemicellulose during torrefaction is like the melting away of the cement from the reinforced concrete. Thus, the size reduction of biomass consumes less energy after torrefaction. During torrefaction the weight loss of biomass comes primarily from the decomposition of its hemicellulose constituents. Hemicellulose decomposes mostly within the temperature range 150 to 280 °C, which is the temperature window of torrefaction.

As we can see from figure above, the hemicellulose component undergoes the greatest amount of degradation within the 200 to 300 °C temperature window. Thus, hemicellulose decomposition is the primary mechanism of torrefaction. At lower temperatures (< 160 °C), as biomass dries it releases H2O and CO2. Water and carbon dioxide, which make no contribution to the energy in the product gas, constitute a dominant portion of the weight loss during torrefaction.

Above 180 °C, the reaction becomes exothermic, releasing gas with small heating values. The initial stage (< 250 °C) involves hemicellulose depolymerization, leading to an altered and rearranged polysugar structures. At higher temperatures (250–300 °C) these form chars, CO, CO2, and H2O. The hygroscopic property of biomass is partly lost in torrefaction because of the destruction of OH groups through dehydration, which prevents the formation of hydrogen bonds.