Tag Archives: Polymer

Everything You Need to Know About Carbon Black

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Carbon Black is a commercial form of solid carbon that is manufactured in highly controlled processes to produce specifically engineered aggregates of carbon particles that vary in particle size, aggregate size, shape, porosity and surface chemistry. Carbon Black typically contains more than 95 % pure carbon with minimal quantities of oxygen, hydrogen and nitrogen.

In the manufacturing process, Carbon Black particles range from 10 nm to approximately 500 nm in size. These fuse into chain-like aggregates, which define the structure of individual Carbon Black grades.

What is Carbon Black

Carbon Black is used in a diverse group of materials in order to enhance their physical, electrical and optical properties. Its largest volume use is as a reinforcement and performance additive in rubber products.

In rubber compounding, natural and synthetic elastomers are blended with Carbon Black, elemental sulphur, processing oils and various organic processing chemicals, and then heated to produce a wide range of vulcanized rubber products. In these applications, Carbon Black provides reinforcement and improves resilience, tear-strength, conductivity and other physical properties.

Carbon Black is the most widely used and cost effective rubber reinforcing agent (typically called Rubber Carbon Black) in tire components (such as treads, sidewalls and inner liners), in mechanical rubber goods (“MRG”), including industrial rubber goods, membrane roofing, automotive rubber parts (such as sealing systems, hoses and anti-vibration parts) and in general rubber goods (such as hoses, belts, gaskets and seals).

Applications of Carbon Black

Besides rubber reinforcement, Carbon Black is used as black pigment and as an additive to enhance material performance, including conductivity, viscosity, static charge control and UV protection. This type of Carbon Black (typically called Specialty Carbon Black) is used in a variety of applications in the coatings, polymers and printing industries, as well as in various other special applications.

Actually, after oil removal and ash removal processing from tire pyrolysis, we can get high-purity commercial carbon black, which can be used to make color masterbatch, color paste, oil ink and as addictive in plastic and rubber products. Besides, after activation treatment, the carbon black will become good materials to produce activated carbon.

In the coatings industry, treated fine particle Carbon Black is the key to deep jet black paints. The automotive industry requires the highest black intensity of black pigments and a bluish undertones.

Carbon Black has got a wide array of applications in different industries

Small particle size Carbon Blacks fulfill these requirements. Coarser Carbon Blacks, which offer a more brownish undertone, are commonly used for tinting and are indispensable for obtaining a desired grey shade or color hue.

In the polymer industry, fine particle Carbon Black is used to obtain a deep jet black color. A major attribute of Carbon Black is its ability to absorb detrimental UV light and convert it into heat, thereby making polymers, such as polypropylene and polyethylene, more resistant to degradation by UV radiation from sunlight. Specialty Carbon Black is also used in polymer insulation for wires and cables. Specialty Carbon Black also improves the insulation properties of polystyrene, which is widely used in construction.

In the printing industry, Carbon Black is not only used as pigment but also to achieve the required viscosity for optimum print quality. Post-treating Carbon Black permits effective use of binding agents in ink for optimum system properties. New Specialty Carbon Blacks are being developed on an ongoing basis and contribute to the pace of innovation in non-impact printing.

Dyne Testing and its Usefulness

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Dyne Testing is a technology, a method to measure surface wettability. The low surface wettability of polymer-based substrates is the sign of poor adhesion of inks, glues and coatings. Thus, to obtain the optimum amount of adhesive it is necessary to increase the surface energy of the substrate which can be done by surface treatment with either Corona or Plasma. It will result in good wetting of the material over the surface of the substrate and hence, it improves adhesion.

For the optimum adhesion, while printing, gluing, or coating the various substrates, it is necessary to obtain high surface energy which can be obtained by Dyne Testing Markers. The fluid that is present in the Dyne Testing markers is based on ISO 8296 method for measuring the surface energy of polythene film.

When the Dyne Testing Pens are being applied to the surface, the liquid will form a continues film or will form a small trail of droplets. If it is being stretched as a film for at least 3 seconds, the substrate will have a minimum surface energy of that ink value which will be expressed in mN/m (Dynes).

The exact surface energy (Dyne level) can be determined by applying a range of increasing or decreasing values of Dyne test pens thereby taking the steps to improve its condition.

The Dyne Test Pen may lose its accuracy for which there are 3 reasons:

  1. It could get contaminated with the foreign substance
  2. It could evaporate quicker than it is expected to be
  3. And the third reason is ageing, during which chemical reactions take place among the constituents.

The experts have also faced the problem with the ageing of Dyne Testing Equipment. If their hue or color density are almost past their expiration date, it is advisable to replace them as stated by experts. The lower Dyne value states that the value stated on the bottle does not match true surface tension. You must be sure that retains the substrate used for the measurements are to be kept well sealed, free from contamination, and stored under laboratory conditions.

The ideal Dyne Testing Pen should be:

  • easy to handle,
  • perfect for the quick spot checks on the production floor,
  • very easy to read,
  • no subjectivity for this type of test,
  • no wiping off necessary,
  • lasting display of result, and
  • very striking coloring.

Conclusion

The Dyne Testing Kit is based on valve tip applicator and not the magic marker type. The quick test 38 pen is our most popular product amongst all and it is available in a bright red ink. This is the quick test pen which serves to check the surface treatment of all plastic substrates.

It has a shown an effect onto the material such that a stroke of the pens leaves a full line on the material if the material’s surface energy is below 38 Dynes/cm. Also, as mentioned above if the materials surface energy is below 38 Dynes/cm, the fluid will form small drops on the surface. The fluid applied to the surface will dry within seconds; it does not need to be wiped off anymore.

Applications of Epoxy Resin in Clean Energy Sector

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Epoxy resin is a kind of reactive prepolymer and polymer that contains epoxide groups. It is important to note that epoxy resin is different from other polyester resins in terms of curing. Unlike other resins, instead of using a catalyst as a curing agent, it is cured by an agent known as the hardener. It possesses many desirable properties such as high tensile strength, high adhesive strength, high corrosion resistance, and excellent moisture & chemical resistance. It is also resistant to fatigue, has a long shelf life, and has good electrical and insulating properties. The ability of epoxy resins to be used in various combinations and reinforcements makes it the foundation of a plethora of industries, including clean energy systems.

Applications of Epoxy Resins

Because of the versatile properties of epoxy resins, it is used widely in adhesives, potting, encapsulating electronics, and printed circuit boards. It is also used in the form of matrices for composites in the aerospace industries. Epoxy composite laminates are commonly used for repairing both composite as well as steel structures in marine applications.

Due to its high reactivity, epoxy resin is preferred in repairing boats that have been damaged by impact. Its low shrinking properties and ease of fabrication make it well suited for many tooling applications such as metal-shaping molds, vacuum-forming molds, jigs, patterns etc.

Use of Epoxy Resins in Clean Energy

A variety of industries have been actively trying to find a path that’s moving towards a society that puts less load on the the environment and also contributes towards reducing the carbon footprint. The accelerated use of epoxy resins in generating renewable energy has lead to a rise in its production demand. This is why the epoxy resin market is projected to witness a high demand and growth rate by 2022. Here are some of the sectors contributing to the production of clean energy and how they utilize epoxy resin for their functioning:

  • Solar Energy

The harnessing of solar energy dates back to 700 B.C, when people used a magnifying glass to focus the sun’s rays to produce fire. Today solar power is a vigorously developing energy source around the globe. It not only caters to the rising energy requirements but also the need to protect the environment from the exploitation of exhaustible energy resources.

A piece of average solar equipment endures intense environmental conditions such as scorching heat, UV radiations, bitter cold,  pouring rain, hail, storms, and turbulent winds. To withstand such conditions, the sealing and mounting application of epoxy resins increase the environmental tolerance of the solar equipment.

With their high mechanical strength, impressive dimensional stability and excellent adhesion properties, they are used to protect the solar panels from a wide range of temperatures. Epoxies are cheap, less labor-intensive and easy to apply.

  • Wind Energy

The global wind industry has quickly emerged as one of the largest sources of renewable energy around the world. The wind energy in the U.S. alone grew by 9% in 2017 and today is the largest source for generating clean energy in the country. With such a tremendous demand for wind power, the need for fabricating bigger and better wind turbine blades is also rising. The industry is in a dearth of long-lasting blades, that endure the harsh climatic conditions and wear tear and are able to collect more wind energy at a time.

Sealing and mounting application of epoxy resins increase the environmental tolerance of the solar equipment

Epoxy thermosets are used for making the blades more durable because of their high tensile strength and high creep resistance. Mixing of epoxy resins with various toughening agents and using them on the blades have shown positive results towards making the blades corrosion resistant and fatigue-proof.

  • Hydropower

Hydropower is an essential source of renewable and clean energy. As the hydropower industry is developing rapidly, the solution for protecting the hydropower concrete surfaces against low temperatures and lashing water flow has also been looked into.

As a solution to this issue, epoxy mortar, a mixture of epoxy resins, binder, solvent, mineral fillers, and some additives has proven to be the most effective material used for surface protection. Owing to the properties like non-permeability, adhesive strength, anti-erosive nature, and non-abrasiveness, epoxy mortar paste has been used as a repairing paste in the hydropower industry.

Over the last few decades, epoxy resins have contributed immensely in the maintenance and protection of clean energy sources, helping them to become more efficient and productive.

Final Thoughts

While many argue that factors like a relatively high cost when compared to petroleum-based resins and conventional cement-mortar alternatives has affected the epoxy resin market growth, the fact remains that epoxy resin never fails to deliver top-notch and unmatchable results in the areas of application.