Anaerobic digestion is the natural biological process which stabilizes organic waste in the absence of air and transforms it into biofertilizer and biogas. Almost any organic material can be processed with anaerobic digestion.
Anaerobic digestion is particularly suited to wet organic material and is commonly used for effluent and sewage treatment. This includes biodegradable waste materials such as waste paper, grass clippings, leftover food, sewage and animal waste. Large quantity of waste, in both solid and liquid forms, is generated by the industrial sector like breweries, sugar mills, distilleries, food-processing industries, tanneries, and paper and pulp industries. Poultry waste has the highest per ton energy potential of electricity per ton but livestock have the greatest potential for energy generation in the agricultural sector.
Organic fraction of MSW (OFMSW)
Grass clippings/garden waste
Institutional wastes etc.
Pulp and paper
Slaughterhouse/rendering plant etc.
Anaerobic digestion is particularly suited to wet organic material and is commonly used for effluent and sewage treatment. Almost any organic material can be processed with anaerobic digestion process. This includes biodegradable waste materials such as waste paper, grass clippings, leftover food, sewage and animal waste. The exception to this is woody wastes that are largely unaffected by digestion as most anaerobic microorganisms are unable to degrade lignin.
Anaerobic digesters can also be fed with specially grown energy crops such as silage for dedicated biogas production. A wide range of crops, especially C-4 plants, demonstrate good biogas potentials. Corn is one of the most popular co-substrate in Germany while Sudan grass is grown as an energy crop for co-digestion in Austria. Crops like maize, sunflower, grass, beets etc., are finding increasing use in agricultural digesters as co-substrates as well as single substrate.
A wide range of organic substances are anaerobically easily degradable without major pretreatment. Among these are leachates, slops, sludges, oils, fats or whey. Some wastes can form inhibiting metabolites (e.g.NH3) during anaerobic digestion which require higher dilutions with substrates like manure or sewage sludge. A number of other waste materials often require pre-treatment steps (e.g. source separated municipal organic waste, food residuals, expired food, market wastes and crop residues).
Biogas, sometimes called renewable natural gas, could be part of the solution for providing people in rural areas with reliable, clean and cheap energy. In fact, it could provide various benefits beyond clean fuel as well, including improved sanitation, health and environmental sustainability.
Using manure for energy might seem unappealing, but you don’t burn the organic matter directly. Instead, you burn the methane gas it produces, which is odorless and clean burning.
Biogas Prospects in Rural Areas
Biogas finds wide application in all parts of the world, but it could be especially useful to developing countries, especially in rural areas. People that live in these places likely already use a form of biomass energy — burning wood. Using wood fires for heat, light and cooking releases large amounts of greenhouse gases into the atmosphere.
The smoke they release also has harmful health impacts, particularly when used indoors. You also need a lot to burn a lot of wood when it’s your primary energy source. Collecting this wood is a time-consuming and sometimes difficult as well as dangerous task.
Many of these same communities that rely on wood fires, however, also have an abundant supply of another fuel source. They just need the tools to capture and use it. Many of these have a lot of dung from livestock and lack sanitation equipment. This lack of sanitation creates health hazards.
Turning that waste into biogas could solve both the energy problem and the sanitation problem. Creating a biogas system for a rural home is much simpler than building other types of systems. It requires an airtight pit lined and covered with concrete and a way to feed waste from animals and latrines into the pit. Because the pit is sealed, the waste will decompose quickly, releasing methane.
This methane flows through a PCV pipe to the home where you can turn it on and light on when you need to use it. This system also produces manure that is free of pathogens, which farmers can use as fertilizer.
A similar but larger setup can provide similar benefits for urban areas in developing countries and elsewhere.
Benefits of Biogas
Anaerobic digestion systems are beneficial to developing countries because they are low-cost compared to other technologies, low-tech, low-maintenance and safe. They provide reliable fuel as well as improved public health and sanitation. Also, they save people the labor of collecting large amounts of firewood, freeing them up to do other activities. Thus, biomass-based energy systems can help in rural development.
Biogas also has environmental benefits. It reduces the need to burn wood fires, which helps to slow deforestation and eliminates the emissions those fires would have produced. On average, a single home biogas system can replace approximately 4.5 tons of firewood annually and eliminate the associated four tons of annual greenhouse gas emissions, according to the World Wildlife Fund.
Biogas is also a clean, renewable energy source and reduces the need for fossil fuels. Chemically, biogas is the same as natural gas. Biogas, however, is a renewable fuel source, while natural gas is a fossil fuel. The methane in organic wastes would release into the atmosphere through natural processes if left alone, while the greenhouse gases in natural gas would stay trapped underground. Using biogas as a fuel source reduces the amount of methane released by matter decomposing out in the open.
What Can We Do?
Although biogas systems cost less than some other technologies, affording them is often still a challenge for low-income families in developing countries, especially in villages. Many of these families need financial and technical assistance to build them. Both governments and non-governmental organizations can step in to help in this area.
Once people do have biogas systems in place though, with minimal maintenance of the system, they can live healthier, more comfortable lives, while also reducing their impacts on the environment.
The waste management hierarchy suggests that reduce, reuse and recycling should always be given preference in a typical waste management system. However, these options cannot be applied uniformly for all kinds of wastes. For examples, food waste is quite difficult to deal with using the conventional 3R strategy.
Of the different types of organic wastes available, food waste holds the highest potential in terms of economic exploitation as it contains high amount of carbon and can be efficiently converted into biogas and organic fertilizer.
There are numerous places which are the sources of large amounts of food waste and hence a proper food waste management strategy needs to be devised for them to make sure that either they are disposed off in a safe manner or utilized efficiently. These places include hotels, restaurants, malls, residential societies, college/school/office canteens, religious mass cooking places, communal kitchens, airline caterers, food and meat processing industries and vegetable markets which generate food residuals of considerable quantum on a daily basis.
The anaerobic digestion technology is highly apt in dealing with the chronic problem of food waste management in urban societies. Although the technology is commercially viable in the longer run, the high initial capital cost is a major hurdle towards its proliferation.
The onus is on the governments to create awareness and promote such technologies in a sustainable manner. At the same time, entrepreneurs, non-governmental organizations and environmental agencies should also take inspiration from successful food waste-to-energy projects in Western countries and try to set up such facilities in cities and towns.
Essentially a process operating by living organisms, the biogas industry is a natural target for synthetic biology. Synthetic biology combines biology and engineering to design and construct biological devices. Contrary to traditional genetic engineering that only alters an already existing DNA sequence, synthetic biology allows us to build entirely new sequences of DNA and put them to work in cells. This allows us to build novel biological devices that would never exist in nature.
Constructions and operations of devices that do not exist in nature, such as tools, vehicles, computers and the internet, have crafted modern civilization. Now, it is synthetic biology that is challenging nature’s limitations and advancing civilization to a higher level.
Generating biogas via anaerobic digestion of biomass and organic waste is one of the few proven, cost-effective, scalable biomass energy strategies. Biogas consists of mainly methane and carbon dioxide, and combustion of methane with air generates energy which can be used for many purposes such as cooking, heating, producing electricity and vehicle fuel. As a result, countless biogas plants are operating around the globe helping to clean up waste and generate energy. With more plants being built, they come in all sizes ranging from household to factory scales.
Anaerobic digestion is a process where extremely complex microbial communities degrade organic matter, such as sugars, fats and proteins, resulting in biogas as the primary end-product. Such inherent complexity makes this process very difficult to optimize. Mechanical engineers have made tremendous progress to optimize this process, but in many places it still requires government subsidies to be profitable.
Synthetic Biology and Biogas Industry
Essentially a process operating by living organisms, the biogas industry is a natural target for synthetic biology. In terms of their genetic content, organisms are classified into three natural groups, Archaea, Bacteria and Eukarya. Most microbes are Archaea and Bacteria, while humans are Eukarya.
In an anaerobic digester, many different types of Bacteria convert the complex organic matter in waste or biomass to hydrogen gas, carbon dioxide, formate and acetate. A unique group of methanogenic Archaea then produces the invaluable part of biogas, methane, by eating hydrogen and carbon dioxide, formate or acetate.
One can imagine creating a super microbe to convert the complex organic matter directly into biogas, thus making anaerobic digestion faster, more efficient and easier-to-manipulate. Making a synthetic microbial community by reprogramming key microbes may also help them work together when a tough job (i.e., eating extremely complex waste) needs to be done.
Among numerous microbes in anaerobic digester, methanogenic Archaea are one of a few microbial groups that have been extensively studied, and a number of genetic tools are available for engineering via synthetic biology. Therefore, scientists have begun to reprogram methanogenic archaea, allowing them to eat organic matter such as sugars and directly produce methane. If they succeed, they may engineer a super microbe that never existed in nature and revolutionize the biogas industry by making anaerobic digestion much simpler and more efficient.
There is also the possibility of more applications downstream. For instance, upgrading biogas by removal of carbon dioxide improves its combustibility. A super microbe could be made to upgrade biogas using hydrogen gas or even electricity to form more methane from carbon dioxide.
Conceptualized super cell that converts idealized organic matter (2CH2O) directly into biogas.
However promising, grand challenges remain when it comes to applying synthetic biology to the biogas industry. About 10,000 moving parts are needed to make an automobile, millions of parts for an airplane, and all the parts are standardized.
Similar to those engineering sectors, synthetic biology also needs many standardized genetic parts and modules to be able to create biological devices that can really revolutionize an industry. Sophisticated genetic tools are needed as well to assemble these parts and put them to work. However, few such parts, modules and tools are at disposal for engineering microbes in an anaerobic digester.
Take methanogenic Archaea for example, only three parts are available in the iGEM registry, the world largest collection of biological parts for synthetic biology. Another challenge is an apparent neglect of synthetic biology by the biogas industry. Symposiums bringing professionals from biogas industry and synthetic biology together for discussions are rare, as are major investments for promoting synthetic biology.
As a result, few research groups are developing synthetic tools and parts for the biogas industry. For example, the aforementioned three iGEM parts were all contributed by only one group, the UGA-iGEM team at the University of Georgia.
Synthetic biology is developing faster than ever, and its cost continues to fall. Thanks to prompt actions of many industrial pioneers in embracing and supporting synthetic biology, it is already starting to revolutionize a few fields.
Synthetic biology also holds great potentials to revolutionize the biogas industry. To achieve this goal, joint efforts between the biogas industry and academia must be made. The former side needs to understand what synthetic biology can achieve, while the latter side should identify which parts of the process in the biogas industry can be re-designed and optimized by synthetic biology.
Once the two sides start to work together, novel synthetic parts and tools are bound to be invented, and they will make anaerobic digestion a better process for the biogas industry.
The Middle East region offers tremendous renewable energy potential in the form of solar, wind and bioenergy which has remained unexplored to a great extent. The major biomass producing Middle East countries are Egypt, Algeria, Yemen, Iraq, Syria and Jordan. Traditionally, biomass energy has been widely used in rural areas for domestic purposes in the Middle East. Since most of the region is arid/semi-arid, the biomass energy potential is mainly contributed by municipal solid wastes, agricultural residues and agro-industrial wastes.
Municipal solid wastes represent the best bioenergy resource in the Middle East. The high rate of population growth, urbanization and economic expansion in the region is not only accelerating consumption rates but also accelerating the generation of municipal waste. Bahrain, Saudi Arabia, UAE, Qatar and Kuwait rank in the top-ten worldwide in terms of per capita solid waste generation. The gross urban waste generation quantity from Middle East countries is estimated at more than 150 million tons annually.
In Middle East countries, huge quantity of sewage sludge is produced on daily basis which presents a serious problem due to its high treatment costs and risk to environment and human health. On an average, the rate of wastewater generation is 80-200 litres per person each day and sewage output is rising by 25 percent every year. According to estimates from the Drainage and Irrigation Department of Dubai Municipality, sewage generation in the Dubai increased from 50,000 m3 per day in 1981 to 400,000 m3 per day in 2006.
The food processing industry in Middle East produces a large number of organic residues and by-products that can be used as source of bioenergy. In recent decades, the fast-growing food and beverage processing industry has remarkably increased in importance in major countries of the Middle East.
Since the early 1990s, the increased agricultural output stimulated an increase in fruit and vegetable canning as well as juice, beverage, and oil processing in countries like Egypt, Syria, Lebanon and Saudi Arabia. There are many technologically-advanced dairy products, bakery and oil processing plants in the region.
Date palm biomass is found in large quantities across the Middle East
Agriculture plays an important role in the economies of most of the countries in the Middle East. The contribution of the agricultural sector to the overall economy varies significantly among countries in the region, ranging, for example, from about 3.2 percent in Saudi Arabia to 13.4 percent in Egypt. Cotton, dates, olives, wheat are some of the prominent crops in the Middle East
Large quantities of crop residues are produced annually in the region, and are vastly underutilised. Current farming practice is usually to plough these residues back into the soil, or they are burnt, left to decompose, or grazed by cattle. These residues could be processed into liquid fuels or thermochemically processed to produce electricity and heat in rural areas.
Energy crops, such as Jatropha, can be successfully grown in arid regions for biodiesel production. Infact, Jatropha is already grown at limited scale in some Middle East countries and tremendous potential exists for its commercial exploitation.
The Middle Eastern countries have strong animal population. The livestock sector, in particular sheep, goats and camels, plays an important role in the national economy of the Middle East countries. Many millions of live ruminants are imported into the Middle Eastern countries each year from around the world. In addition, the region has witnessed very rapid growth in the poultry sector. The biogas potential of animal manure can be harnessed both at small- and community-scale.
Vermicomposting is a type of composting in which certain species of earthworms are used to enhance the process of organic waste conversion and produce a better end-product. It is a mesophilic process utilizing microorganisms and worms. Earthworms feeds the organic waste materials and passes it through their digestive system and gives out in a granular form (cocoons) which is known as vermicompost.
Simply speaking, vermicompost is earthworm excrement, called castings, which can improve biological, chemical, and physical properties of the soil. The chemical secretions in the earthworm’s digestive tract help break down soil and organic matter, so the castings contain more nutrients that are immediately available to plants.
Earthworms consume organic wastes and reduce the volume by 40–60 percent. Each earthworm weighs about 0.5 to 0.6 gram, eats waste equivalent to its body weight and produces cast equivalent to about 50 percent of the waste it consumes in a day. The moisture content of castings ranges between 32 and 66 percent and the pH is around 7. The level of nutrients in compost depends upon the source of the raw material and the species of earthworm.
Types of Earthworms
There are nearly 3600 types of earthworms which are divided into burrowing and non-burrowing types. Red earthworm species, like Eiseniafoetida,and are most efficient in compost making. The non-burrowing earthworms eat 10 percent soil and 90 percent organic waste materials; these convert the organic waste into vermicompost faster than the burrowing earthworms.
They can tolerate temperatures ranging from 0 to 40°C but the regeneration capacity is more at 25 to 30°C and 40–45 percent moisture level in the pile. The burrowing types of earthworms come onto the soil surface only at night. These make holes in the soil up to a depth of 3.5 m and produce 5.6 kg casts by ingesting 90 percent soil and 10 percent organic waste.
Types of Vermicomposting
The types of vermicomposting depend upon the amount of production and composting structures. Small-scale vermicomposting is done to meet personal requirements and farmers/gardeners can harvest 5-10 tons of vermicompost annually.
On the other hand, large-scale vermicomposting is done at commercial scale by recycling large quantities of organic waste in modern facilities with the production of more than hundreds of tons annually.
Benefits of Vermicompost
The worm castings contain higher percentage of both macro and micronutrients than the garden compost. Apart from other nutrients, a fine worm cast is rich in NPK which are in readily available form and are released within a month of application. Vermicompost enhances plant growth, suppresses disease in plants, increases porosity and microbial activity in soil, and improves water retention and aeration.
Vermicompost also benefits the environment by reducing the need for chemical fertilizers and decreasing the amount of waste going to landfills. Vermicompost production is trending up worldwide and it is finding increasing use especially in Western countries, Asia-Pacific and Southeast Asia.
A relatively new product from vermicomposting is vermicompost tea which is a liquid produced by extracting organic matter, microorganisms, and nutrients from vermicompost. Unlike vermicompost and compost, this tea may be applied directly to plant foliage, reportedly to enhance disease suppression. Vermicompost tea also may be applied to the soil as a supplement between compost applications to increase biological activity.
Vermicompost may be sold in bulk or bagged with a variety of compost and soil blends. Markets include home improvement centers, nurseries, landscape contractors, greenhouses, garden supply stores, grocery chains, flower shops, discount houses, indoor gardens, and the general public.
Biomass is a key renewable energy resource that includes plant and animal material, such as wood from forests, material left over from agricultural and forestry processes, and organic industrial, human and animal wastes. The energy contained in biomass originally came from the sun. Through photosynthesis carbon dioxide in the air is transformed into other carbon containing molecules (e.g. sugars, starches and cellulose) in plants. The chemical energy that is stored in plants and animals (animals eat plants or other animals) or in their waste is called biomass energy or bioenergy
What is Biomass
Biomass comes from a variety of sources which include:
Wood from natural forests and woodlands
Agricultural residues such as straw, stover, cane trash and green agricultural wastes
Crop residues encompasses all agricultural wastes such as bagasse, straw, stem, stalk, leaves, husk, shell, peel, pulp, stubble, etc. Large quantities of crop residues are produced annually worldwide, and are vastly underutilised. Rice produces both straw and rice husks at the processing plant which can be conveniently and easily converted into energy.
Significant quantities of biomass remain in the fields in the form of cob when maize is harvested which can be converted into energy. Sugar cane harvesting leads to harvest residues in the fields while processing produces fibrous bagasse, both of which are good sources of energy. Harvesting and processing of coconuts produces quantities of shell and fibre that can be utilized.
Current farming practice is usually to plough these residues back into the soil, or they are burnt, left to decompose, or grazed by cattle. These residues could be processed into liquid fuels or thermochemically processed to produce electricity and heat. Agricultural residues are characterized by seasonal availability and have characteristics that differ from other solid fuels such as wood, charcoal, char briquette. The main differences are the high content of volatile matter and lower density and burning time.
There are a wide range of animal wastes that can be used as sources of biomass energy. The most common sources are animal and poultry manure. In the past this waste was recovered and sold as a fertilizer or simply spread onto agricultural land, but the introduction of tighter environmental controls on odour and water pollution means that some form of waste management is now required, which provides further incentives for waste-to-energy conversion.
The most attractive method of converting these organic waste materials to useful form is anaerobic digestion which gives biogas that can be used as a fuel for internal combustion engines, to generate electricity from small gas turbines, burnt directly for cooking, or for space and water heating.
Forestry residues are generated by operations such as thinning of plantations, clearing for logging roads, extracting stem-wood for pulp and timber, and natural attrition. Harvesting may occur as thinning in young stands, or cutting in older stands for timber or pulp that also yields tops and branches usable for biomass energy. Harvesting operations usually remove only 25 to 50 percent of the volume, leaving the residues available as biomass for energy.
Stands damaged by insects, disease or fire are additional sources of biomass. Forest residues normally have low density and fuel values that keep transport costs high, and so it is economical to reduce the biomass density in the forest itself.
Wood processing industries primarily include sawmilling, plywood, wood panel, furniture, building component, flooring, particle board, moulding, jointing and craft industries. Wood wastes generally are concentrated at the processing factories, e.g. plywood mills and sawmills. The amount of waste generated from wood processing industries varies from one type industry to another depending on the form of raw material and finished product.
Generally, the waste from wood industries such as saw millings and plywood, veneer and others are sawdust, off-cuts, trims and shavings. Sawdust arise from cutting, sizing, re-sawing, edging, while trims and shaving are the consequence of trimming and smoothing of wood. In general, processing of 1,000 kg of wood in the furniture industries will lead to waste generation of almost half (45 %), i.e. 450 kg of wood. Similarly, when processing 1,000 kg of wood in sawmill, the waste will amount to more than half (52 %), i.e. 520 kg wood.
The food industry produces a large number of residues and by-products that can be used as biomass energy sources. These waste materials are generated from all sectors of the food industry with everything from meat production to confectionery producing waste that can be utilised as an energy source.
Solid wastes include peelings and scraps from fruit and vegetables, food that does not meet quality control standards, pulp and fibre from sugar and starch extraction, filter sludges and coffee grounds. These wastes are usually disposed of in landfill dumps.
Liquid wastes are generated by washing meat, fruit and vegetables, blanching fruit and vegetables, pre-cooking meats, poultry and fish, cleaning and processing operations as well as wine making.
These waste waters contain sugars, starches and other dissolved and solid organic matter. The potential exists for these industrial wastes to be anaerobically digested to produce biogas, or fermented to produce ethanol, and several commercial examples of waste-to-energy conversion already exist.
Pulp and paper industry is considered to be one of the highly polluting industries and consumes large amount of energy and water in various unit operations. The wastewater discharged by this industry is highly heterogeneous as it contains compounds from wood or other raw materials, processed chemicals as well as compound formed during processing. Black liquor can be judiciously utilized for production of biogas using anaerobic UASB technology.
Municipal Solid Wastes and Sewage
Millions of tonnes of household waste are collected each year with the vast majority disposed of in open fields. The biomass resource in MSW comprises the putrescibles, paper and plastic and averages 80% of the total MSW collected. Municipal solid waste can be converted into energy by direct combustion, or by natural anaerobic digestion in the engineered landfill.
At the landfill sites, the gas produced, known as landfill gas or LFG, by the natural decomposition of MSW (approximately 50% methane and 50% carbon dioxide) is collected from the stored material and scrubbed and cleaned before feeding into internal combustion engines or gas turbines to generate heat and power. The organic fraction of MSW can be anaerobically stabilized in a high-rate digester to obtain biogas for electricity or steam generation.
Sewage is a source of biomass energy that is very similar to the other animal wastes. Energy can be extracted from sewage using anaerobic digestion to produce biogas. The sewage sludge that remains can be incinerated or undergo pyrolysis to produce more biogas.
Biomass pyrolysis is the thermal decomposition of biomass occurring in the absence of oxygen. It is the fundamental chemical reaction that is the precursor of both the combustion and gasification processes and occurs naturally in the first two seconds. The products of biomass pyrolysis include biochar, bio-oil and gases including methane, hydrogen, carbon monoxide, and carbon dioxide.
The pyrolysis process consists of both simultaneous and successive reactions when organic material is heated in a non-reactive atmosphere. Thermal decomposition of organic components in biomass starts at 350 °C–550 °C and goes up to 700 °C–800 °C in the absence of air/oxygen. The long chains of carbon, hydrogen and oxygen compounds in biomass break down into smaller molecules in the form of gases, condensable vapours (tars and oils) and solid charcoal under pyrolysis conditions. Rate and extent of decomposition of each of these components depends on the process parameters of the reactor temperature, biomass heating rate, pressure, reactor configuration, feedstock etc
Depending on the thermal environment and the final temperature, pyrolysis will yield mainly biochar at low temperatures, less than 450 0C, when the heating rate is quite slow, and mainly gases at high temperatures, greater than 800 0C, with rapid heating rates. At an intermediate temperature and under relatively high heating rates, the main product is bio-oil.
Slow and Fast Pyrolysis
Pyrolysisprocesses can be categorized as slow or fast. Slow pyrolysis takes several hours to complete and results in biochar as the main product. On the other hand, fast pyrolysis yields 60% bio-oil and takes seconds for complete pyrolysis. In addition, it gives 20% biochar and 20% syngas. Fast pyrolysis is currently the most widely used pyrolysis system.
The essential features of a fast pyrolysis process are:
Very high heating and heat transfer rates, which require a finely ground feed.
Carefully controlled reaction temperature of around 500oC in the vapour phase
Residence time of pyrolysis vapours in the reactor less than 1 sec
Quenching (rapid cooling) of the pyrolysis vapours to give the bio-oil product.
Advantages of Biomass Pyrolysis
Pyrolysis can be performed at relatively small scale and at remote locations which enhance energy density of the biomass resource and reduce transport and handling costs. Heat transfer is a critical area in pyrolysis as the pyrolysis process is endothermic and sufficient heat transfer surface has to be provided to meet process heat needs. Biomass pyrolysis offers a flexible and attractive way of converting organic matter into energy products which can be successfully used for the production of heat, power and chemicals.
A wide range of biomass feedstocks can be used in pyrolysis processes. The pyrolysis process is very dependent on the moisture content of the feedstock, which should be around 10%. At higher moisture contents, high levels of water are produced and at lower levels there is a risk that the process only produces dust instead of oil. High-moisture waste streams, such as sludge and meat processing wastes, require drying before subjecting to pyrolysis.
Furthermore, the bio-char produced can be used on the farm as an excellent soil amender as it is highly absorbent and therefore increases the soil’s ability to retain water, nutrients and agricultural chemicals, preventing water contamination and soil erosion. Soil application of bio-char may enhance both soil quality and be an effective means of sequestering large amounts of carbon, thereby helping to mitigate global climate change through carbon sequestration. Use of bio-char as a soil amendment will offset many of the problems associated with removing crop residues from the land.
Biomass pyrolysis has been garnering much attention due to its high efficiency and good environmental performance characteristics. It also provides an opportunity for the processing of agricultural residues, wood wastes and municipal solid waste into clean energy. In addition, biochar sequestration could make a big difference in the fossil fuel emissions worldwide and act as a major player in the global carbon market with its robust, clean and simple production technology.
Animal manure is a valuable source of nutrients and renewable energy. However, most of the manure is collected in lagoons or left to decompose in the open which pose a significant environmental hazard. The air pollutants emitted from manure include methane, nitrous oxide, ammonia, hydrogen sulfide, volatile organic compounds and particulate matter, which can cause serious environmental concerns and health problems. In the past, livestock waste was recovered and sold as a fertilizer or simply spread onto agricultural land. The introduction of tighter environmental controls on odour and water pollution means that some form of waste management is necessary, which provides further incentives for biomass-to-energy conversion.
Anaerobic digestion is a unique treatment solution for animal manure as it can deliver positive benefits related to multiple issues, including renewable energy, water pollution, and air emissions. Anaerobic digestion of animal manure is gaining popularity as a means to protect the environment and to recycle materials efficiently into the farming systems. Waste-to-Energy (WTE) plants, based on anaerobic digestion of cow manure, are highly efficient in harnessing the untapped renewable energy potential of organic waste by converting the biodegradable fraction of the waste into high calorific gases.
The establishment of anaerobic digestion systems for livestock manure stabilization and energy production has accelerated substantially in the past several years. There are thousands of digesters operating at commercial livestock facilities in Europe, United States, Asia and elsewhere. which are generating clean energy and fuel. Many of the projects that generate electricity also capture waste heat for various in-house requirements.
The main factors that influence biogas production from livestock manure are pH and temperature of the feedstock. It is well established that a biogas plant works optimally at neutral pH level and mesophilic temperature of around 35o C. Carbon-nitrogen ratio of the feed material is also an important factor and should be in the range of 20:1 to 30:1. Animal manure has a carbon – nitrogen ratio of 25:1 and is considered ideal for maximum gas production. Solid concentration in the feed material is also crucial to ensure sufficient gas production, as well as easy mixing and handling. Hydraulic retention time (HRT) is the most important factor in determining the volume of the digester which in turn determines the cost of the plant; the larger the retention period, higher the construction cost.
The fresh animal manure is stored in a collection tank before its processing to the homogenization tank which is equipped with a mixer to facilitate homogenization of the waste stream. The uniformly mixed waste is passed through a macerator to obtain uniform particle size of 5-10 mm and pumped into suitable-capacity anaerobic digesters where stabilization of organic waste takes place.
In anaerobic digestion, organic material is converted to biogas by a series of bacteria groups into methane and carbon dioxide. The majority of commercially operating digesters are plug flow and complete-mix reactors operating at mesophilic temperatures. The type of digester used varies with the consistency and solids content of the feedstock, with capital investment factors and with the primary purpose of digestion.
Biogas contain significant amount of hydrogen sulfide (H2S) gas which needs to be stripped off due to its highly corrosive nature. The removal of H2S takes place in a biological desulphurization unit in which a limited quantity of air is added to biogas in the presence of specialized aerobic bacteria which oxidizes H2S into elemental sulfur. Biogas can be used as domestic cooking, industrial heating, combined heat and power (CHP) generation as well as a vehicle fuel. The digested substrate is passed through screw presses for dewatering and then subjected to solar drying and conditioning to give high-quality organic fertilizer.
Biochemical conversion of biomass involves use of bacteria, microorganisms and enzymes to breakdown biomass into gaseous or liquid fuels, such as biogas or bioethanol. The most popular biochemical technologies are anaerobic digestion (or biomethanation) and fermentation. Anaerobic digestion is a series of chemical reactions during which organic material is decomposed through the metabolic pathways of naturally occurring microorganisms in an oxygen depleted environment. Biomass wastes can also yield liquid fuels, such as cellulosic ethanol, which can be used to replace petroleum-based fuels.
Anaerobic digestion is the natural biological process which stabilizes organic waste in the absence of air and transforms it into biofertilizer and biogas. Anaerobic digestion is a reliable technology for the treatment of wet, organic waste. Organic waste from various sources is biochemically degraded in highly controlled, oxygen-free conditions circumstances resulting in the production of biogas which can be used to produce both electricity and heat. Biomass conversion technologies are slowing being built for home boilers.
Almost any organic material can be processed with anaerobic digestion. This includes biodegradable waste materials such as municipal solid waste, animal manure, poultry litter, food wastes, sewage and industrial wastes.
An anaerobic digestion plant produces two outputs, biogas and digestate, both can be further processed or utilized to produce secondary outputs. Biogas can be used for producing electricity and heat, as a natural gas substitute and also a transportation fuel. A combined heat and power plant system (CHP) not only generates power but also produces heat for in-house requirements to maintain desired temperature level in the digester during cold season. In Sweden, the compressed biogas is used as a transportation fuel for cars and buses. Biogas can also be upgraded and used in gas supply networks.
Working of Anaerobic Digestion Process
Digestate can be further processed to produce liquor and a fibrous material. The fiber, which can be processed into compost, is a bulky material with low levels of nutrients and can be used as a soil conditioner or a low level fertilizer. A high proportion of the nutrients remain in the liquor, which can be used as a liquid fertilizer. Many companies are use R&D tax credits to carry out these initiatives.
A variety of fuels can be produced from waste resources including liquid fuels, such as ethanol, methanol, biodiesel, Fischer-Tropsch diesel, and gaseous fuels, such as hydrogen and methane. The resource base for biofuel production is composed of a wide variety of forestry and agricultural resources, industrial processing residues, and municipal solid and urban wood residues. Globally, biofuels are most commonly used to power vehicles, heat homes, and for cooking, apart from powering home boilers.
The largest potential feedstock for ethanol is lignocellulosic biomass wastes, which includes materials such as agricultural residues (corn stover, crop straws and bagasse), herbaceous crops (alfalfa, switchgrass), short rotation woody crops, forestry residues, waste paper and other wastes (municipal and industrial). Bioethanol production from these feedstocks could be an attractive alternative for disposal of these residues. Importantly, lignocellulosic feedstocks do not interfere with food security.
Ethanol from lignocellulosic biomass is produced mainly via biochemical routes. The three major steps involved are pretreatment, enzymatic hydrolysis, and fermentation. Biomass is pretreated to improve the accessibility of enzymes. After pretreatment, biomass undergoes enzymatic hydrolysis for conversion of polysaccharides into monomer sugars, such as glucose and xylose. Subsequently, sugars are fermented to ethanol by the use of different microorganisms.
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