Trends in Utilization of Palm Kernel Shells

The palm kernel shells used to be initially dumped in the open thereby impacting the environment negatively without any economic benefit. However, over time, palm oil mills in Southeast Asia and elsewhere realized their brilliant properties as a fuel and that they can easily replace coal as an industrial fuel for generating heat and steam.

palm-kernel-shell-uses

Palm kernel shells is an abundant biomass resource in Southeast Asia

Major Applications

Nowadays, the primary use of palm kernel shells is as a boiler fuel supplementing the fibre which is used as primary fuel. In recent years kernel shells are extensively sold as alternative fuel around the world. Besides selling shells in bulk, there are companies that produce fuel briquettes from shells which may include partial carbonisation of the material to improve the combustion characteristics.

Palm kernel shells have a high dry matter content (>80% dry matter). Therefore the shells are generally considered a good fuel for the boilers as it generates low ash amounts and the low K and Cl content will lead to less ash agglomeration. These properties are also ideal for production of biomass for export.

As a raw material for fuel briquettes, palm shells are reported to have the same calorific characteristics as coconut shells. The relatively smaller size makes it easier to carbonise for mass production, and its resulting palm shell charcoal can be pressed into a heat efficient biomass briquette.

Although the literature on using oil palm shells (and fibres) is not as extensive as EFB, common research directions of using shells, besides energy, are to use it as raw material for light-weight concrete, fillers, activated carbon, and other materials. However, none of the applications are currently done on a large-scale. Since shells are dry and suitable for thermal conversion, technologies that further improve the combustion characteristics and increase the energy density, such as torrefaction, could be relevant for oil palm shells.

Torrefaction is a pretreatment process which serves to improve the properties of biomass in relation to the thermochemical conversion technologies for more efficient energy generation. High lignin content for shells affects torrefaction characteristics positively (as the material is not easily degraded compared to EFB and fibres).

Furthermore, palm oil shells are studied as feedstock for fast pyrolysis. To what extent shells are a source of fermentable sugars is still not known, however the high lignin content in palm kernel shells indicates that shells are less suitable as raw material for fermentation.

Future Outlook

The leading palm oil producers in the world should consider limiting the export of palm kernel shells (PKS) to ensure supplies of the biomass material for renewable energy projects, in order to decrease dependency on fossil fuels. For example, many developers in Indonesia have expressed an interest in building palm kernel shell-fired power plants.

However, they have their concerns over supplies, as many producers prefer to sell their shells overseas currently. Many existing plants are facing problems on account of inconsistent fuel quality and increasing competition from overseas PKS buyers. PKS market is well-established in provinces like Sumatra and export volumes to Europe and North Asia as a primary fuel for biomass power plants is steadily increasing.

The creation of a biomass supply chain in palm oil producing countries may be instrumental in discouraging palm mills to sell their PKS stocks to brokers for export to foreign countries. Establishment of a biomass exchange in leading countries, like Indonesia, Malaysia and Nigeria, will also be a deciding factor in tapping the unharnessed potential of palm kernel shells as biomass resource.

Biomass Pyrolysis Process

Biomass pyrolysis is the thermal decomposition of biomass occurring in the absence of oxygen. It is the fundamental chemical reaction that is the precursor of both the combustion and gasification processes and occurs naturally in the first two seconds. The products of biomass pyrolysis include biochar, bio-oil and gases including methane, hydrogen, carbon monoxide, and carbon dioxide.

Pyrolysis

Depending on the thermal environment and the final temperature, pyrolysis will yield mainly biochar at low temperatures, less than 450 0C, when the heating rate is quite slow, and mainly gases at high temperatures, greater than 800 0C, with rapid heating rates. At an intermediate temperature and under relatively high heating rates, the main product is bio-oil.

Pyrolysis can be performed at relatively small scale and at remote locations which enhance energy density of the biomass resource and reduce transport and handling costs.  Pyrolysis offers a flexible and attractive way of converting solid biomass into an easily stored and transported liquid, which can be successfully used for the production of heat, power and chemicals.

A wide range of biomass feedstocks can be used in pyrolysis processes. The pyrolysis process is very dependent on the moisture content of the feedstock, which should be around 10%. At higher moisture contents, high levels of water are produced and at lower levels there is a risk that the process only produces dust instead of oil. High-moisture waste streams, such as sludge and meat processing wastes, require drying before subjecting to pyrolysis.

The efficiency and nature of the pyrolysis process is dependent on the particle size of feedstocks. Most of the pyrolysis technologies can only process small particles to a maximum of 2 mm keeping in view the need for rapid heat transfer through the particle. The demand for small particle size means that the feedstock has to be size-reduced before being used for pyrolysis.

Pyrolysis processes can be categorized as slow pyrolysis or fast pyrolysis. Fast pyrolysis is currently the most widely used pyrolysis system. Slow pyrolysis takes several hours to complete and results in biochar as the main product. On the other hand, fast pyrolysis yields 60% bio-oil and takes seconds for complete pyrolysis. In addition, it gives 20% biochar and 20% syngas.

Bio-oil

Bio-oil is a dark brown liquid and has a similar composition to biomass. It has a much higher density than woody materials which reduces storage and transport costs. Bio-oil is not suitable for direct use in standard internal combustion engines. Alternatively, the oil can be upgraded to either a special engine fuel or through gasification processes to a syngas and then biodiesel. Bio-oil is particularly attractive for co-firing because it can be more readily handled and burned than solid fuel and is cheaper to transport and store.

Bio-oil can offer major advantages over solid biomass ands gaification due to the ease of handling, storage and combustion in an existing power station when special start-up procedures are not necessary. In addition, bio-oil is also a vital source for a wide range of organic compounds and speciality chemicals.

The Pyrolysis of Scrap Tires

Pyrolysis of scrap tires offers an environmentally and economically attractive method for transforming waste tires into useful products, heat and electrical energy. Pyrolysis refers to the thermal decomposition of scrap tires either in the absence or lack of oxygen. The principal feedstocks for pyrolysis are pre-treated car, bus or truck tire chips. Scrap tires are an excellent fuel because of their high calorific value which is comparable to that of coal and crude oil. The heating value of an average size passenger tire is between 30 – 34MJ/kg.

scrap-tires-pyrolysis

Pyrolysis is the most recommended alternative for the thermochemical treatment of waste tires and extensively used for conversion of carbonaceous materials in Europe and the Asia-Pacific. Pyrolysis is a two-phase treatment which uses thermal decomposition to heat the rubber in the absence of oxygen to break it into its constituent parts, e.g., pyrolysis oil (or bio oil), synthetic gas and char. Cracking and post-cracking take place progressively as the material is heated to 450-500°C and above.

Process Description

The pyrolysis method for scrap tires recycling involves heating whole or halved or shredded tires in a reactor containing an oxygen free atmosphere and a heat source. In the reactor, the rubber is softened after which the rubber polymers disintegrate into smaller molecules which eventually vaporize and exit from the reactor. These vapors can be burned directly to produce power or condensed into an oily type liquid, called pyrolysis oil or bio oil.

Some molecules are too small to condense and remain as a gas which can be burned as fuel. The minerals that were part of the tire, about 40% by weight, are removed as a solid. When performed well a tire pyrolysis process is a very clean operation and has nearly no emissions or waste.

The heating rate of tire is an important parameter affecting the reaction time, product yield, product quality and energy requirement of the waste tire pyrolysis process. If the temperature is maintained at around 450oC the main product is liquid which could be a mixture of hydrocarbon depending on the initial composition of waste material. At temperature above 700oC, synthetic gas (also known as syngas), a mixture of hydrogen and carbon monoxide, becomes the primary product due to further cracking of the liquids.

Schematic for Pyrolysis of Scrap Tires

Schematic for Pyrolysis of Scrap Tires

The nature of the feedstock and process conditions defines the properties of the gas, liquid and solid products. For example, whole tires contain fibers and steel while shredded tires have most of the steel and sometimes most of the fiber removed.

Processes can be either batch or continuous. The energy required for thermal decomposition of the scrap tires can be in the form of directly-fired fuel, electrical induction and or by microwaves (like a microwave oven). A catalyst may also be required to accelerate the pyrolysis process.

Useful Products

The high acceptance of pyrolysis for the treatment of scrap tires is due to the fact that the derived oils and syngas can be used as biofuels or as feedstock for refining crude oil or chemical products. The pyrolysis oil (or bio oil) has higher calorific value, low ash, low residual carbon and low sulphur content.

The use of pyrolysis oil in cement kilns, paper mills, power plants, industrial furnaces, foundries and other industries is one of the best uses of scrap tires.  Pyrolysis of scrap tyres produces oil that can be used as liquid fuels for industrial furnaces, foundries and boilers in power plants due to their higher calorific value, low ash, residual carbon and sulphur content.

The solid residue, called char, contains carbon black, and inorganic matter. It contains carbon black and the mineral matter initially present in the tire. This solid char may be used as reinforcement in the rubber industry, as activated carbon or as smokeless fuel.

Recommended Reading: Environmental Impact of Tire Recycling