Trends in Utilization of Biogas

The valuable component of biogas is methane (CH4) which typically makes up 60%, with the balance being carbon dioxide (CO2) and small percentages of other gases. The proportion of methane depends on the feedstock and the efficiency of the process, with the range for methane content being 40% to 70%. Biogas is saturated and contains H2S, and the simplest use is in a boiler to produce hot water or steam.

The most common use is where the biogas fuels an internal combustion gas engine in a Combined Heat and Power (CHP) unit to produce electricity and heat. In Sweden the compressed gas is used as a vehicle fuel and there are a number of biogas filling stations for cars and buses. The gas can also be upgraded and used in gas supply networks. The use of biogas in solid oxide fuel cells is also being researched.

Biogas can be combusted directly to produce heat. In this case, there is no need to scrub the hydrogen sulphide in the biogas. Usually the process utilize dual-fuel burner and the conversion efficiency is 80 to 90%. The main components of the system are anaerobic digester, biogas holder, pressure switch, booster fan, solenoid valve, dual fuel burner and combustion air blower.

The most common method for utilization of biogas in developing countries is for cooking and lighting. Conventional gas burners and gas lamps can easily be adjusted to biogas by changing the air to gas ratio. In more industrialized countries boilers are present only in a small number of plants where biogas is used as fuel only without additional CHP. In a number of industrial applications biogas is used for steam production.

Burning biogas in a boiler is an established and reliable technology. Low demands are set on the biogas quality for this application. Pressure usually has to be around 8 to 25 mbar. Furthermore it is recommended to reduce the level of hydrogen sulphide to below 1 000 ppm, this allows to maintain the dew point around 150 ┬░C.

CHP Applications

Biogas is the ideal fuel for generation of electric power or combined heat and power. A number of different technologies are available and applied. The most common technology for power generation is internal combustion. Engines are available in sizes from a few kilowatts up to several megawatts. Gas engines can either be SI-engines (spark ignition) or dual fuel engines. Dual fuel engines with injection of diesel (10% and up) or sometimes plant oil are very popular in smaller scales because they have good electric efficiencies up to guaranteed 43%.

The biogas pressure is turbo-charged and after-cooled and has a high compression ratio in the gas engines. The cooling tower provides cooling water for the gas engines. The main component of the system required for utilizing the technology are anaerobic digester, moisture remover, flame arrester, waste gas burner, scrubber, compressor, storage, receiver, regulator, pressure switch and switch board.

Gas turbines are an established technology in sizes above 500 kW. In recent years also small scale engines, so called micro-turbines in the range of 25 to 100kW have been successfully introduced in biogas applications. They have efficiencies comparable to small SI-engines with low emissions and allow recovery of low pressure steam which is interesting for industrial applications. Micro turbines are small, high-speed, integrated power plants that include a turbine, compressor, generator and power electronics to produce power.

New Trends

The benefit of the anaerobic treatment will depend on the improvement of the process regarding a higher biogas yield per m3 of biomass and an increase in the degree of degradation. Furthermore, the benefit of the process can be multiplied by the conversion of the effluent from the process into a valuable product. In order to improve the economical benefit of biogas production, the future trend will go to integrated concepts of different conversion processes, where biogas production will still be a significant part. In a so-called biorefinery concept, close to 100% of the biomass is converted into energy or valuable by-products, making the whole concept more economically profitable and increasing the value in terms of sustainability.

Typical layout of a modern biogas facility

One example of such biorefinery concept is the Danish Bioethanol Concept that combines the production of bioethanol from lignocellulosic biomass with biogas production of the residue stream. Another example is the combination of biogas production from manure with manure separation into a liquid and a solid fraction for separation of nutrients. One of the most promising concepts is the treatment of the liquid fraction on the farm-site in a UASB reactor while the solid fraction is transported to the centralized biogas plant where wet-oxidation can be implemented to increase the biogas yield of the fiber fraction. Integration of the wet oxidation pre-treatment of the solid fraction leads to a high degradation efficiency of the lignocellulosic solid fraction.

Summary of Biomass Combustion Technologies

Direct combustion is the best established and most commonly used technology for converting biomass to heat. During combustion, biomass fuel is burnt in excess air to produce heat. The first stage of combustion involves the evolution of combustible vapours from the biomass, which burn as flames. The residual material, in the form of charcoal, is burnt in a forced air supply to give more heat. The hot combustion gases are sometimes used directly for product drying, but more usually they are passed through a heat exchanger to produce hot air, hot water or steam.

The combustion efficiency depends primarily on good contact between the oxygen in the air and the biomass fuel. The main products of efficient biomass combustion are carbon dioxide and water vapor, however tars, smoke and alkaline ash particles are also emitted. Minimization of these emissions and accommodation of their possible effects are important concerns in the design of environmentally acceptable biomass combustion systems.

Biomass combustion systems, based on a range of furnace designs, can be very efficient at producing hot gases, hot air, hot water or steam, typically recovering 65-90% of the energy contained in the fuel. Lower efficiencies are generally associated with wetter fuels. To cope with a diversity of fuel characteristics and combustion requirements, a number of designs of combustion furnaces or combustors are routinely utilized around the world

Underfeed Stokers

Biomass is fed into the combustion zone from underneath a firing grate. These stoker designs are only suitable for small scale systems up to a nominal boiler capacity of 6 MWth and for biomass fuels with low ash content, such as wood chips and sawdust. High ash content fuels such as bark, straw and cereals need more efficient ash removal systems. Sintered or molten ash particles covering the upper surface of the fuel bed can cause problems in underfeed stokers due to unstable combustion conditions when the fuel and the air are breaking through the ash covered surface.

Grate Stokers

The most common type of biomass boiler is based on a grate to support a bed of fuel and to mix a controlled amount of combustion air, which often enters from beneath the grate. Biomass fuel is added at one end of the grate and is burned in a fuel bed which moves progressively down the grate, either via gravity or with mechanical assistance, to an ash removal system at the other end. In more sophisticated designs this allows the overall combustion process to be separated into its three main activities:

  • Initial fuel drying
  • Ignition and combustion of volatile constituents
  • Burning out of the char.

Grate stokers are well proven and reliable and can tolerate wide variations in fuel quality (i.e. variations in moisture content and particle size) as well as fuels with high ash content. They are also controllable and efficient.

Fluidized Bed Boilers

The basis for a fluidized bed combustion system is a bed of an inert mineral such as sand or limestone through which air is blown from below. The air is pumped through the bed in sufficient volume and at a high enough pressure to entrain the small particles of the bed material so that they behave much like a fluid.

The combustion chamber of a fluidized bed plant is shaped so that above a certain height the air velocity drops below that necessary to entrain the particles. This helps retain the bulk of the entrained bed material towards the bottom of the chamber. Once the bed becomes hot, combustible material introduced into it will burn, generating heat as in a more conventional furnace. The proportion of combustible material such as biomass within the bed is normally only around 5%. The primary driving force for development of fluidized bed combustion is reduced SO2 and NOx emissions from coal combustion.

Bubbling fluidized bed (BFB) combustors are of interest for plants with a nominal boiler capacity greater than 10 MWth. Circulating fluidized bed (CFB) combustors are more suitable for plants larger than 30 MWth. The minimum plant size below which CFB and BFB technologies are not economically competitive is considered to be around 5-10 MWe.