Properties and Uses of POME

Palm Oil processing gives rise to highly polluting wastewater, known as Palm Oil Mill Effluent (POME), which is often discarded in disposal ponds, resulting in the leaching of contaminants that pollute the groundwater and soil, and in the release of methane gas into the atmosphere. POME is an oily wastewater generated by palm oil processing mills and consists of various suspended components. This liquid waste combined with the wastes from steriliser condensate and cooling water is called palm oil mill effluent.

POME

On average, for each ton of FFB (fresh fruit bunches) processed, a standard palm oil mill generate about 1 tonne of liquid waste with biochemical oxygen demand 27 kg, chemical oxygen demand 62 kg, suspended solids (SS) 35 kg and oil and grease 6 kg. POME has a very high BOD and COD, which is 100 times more than the municipal sewage.

POME is a non-toxic waste, as no chemical is added during the oil extraction process, but will pose environmental issues due to large oxygen depleting capability in aquatic system due to organic and nutrient contents. The high organic matter is due to the presence of different sugars such as arabinose, xylose, glucose, galactose and manose. The suspended solids in the POME are mainly oil-bearing cellulosic materials from the fruits. Since the POME is non-toxic as no chemical is added in the oil extraction process, it is a good source of nutrients for microorganisms.

Biogas Potential of POME

POME is always regarded as a highly polluting wastewater generated from palm oil mills. However, reutilization of POME to generate renewable energies in commercial scale has great potential. Anaerobic digestion is widely adopted in the industry as a primary treatment for POME. Biogas is produced in the process in the amount of 20 mper ton FFB. This effluent could be used for biogas production through anaerobic digestion. At many palm oil mills this process is already in place to meet water quality standards for industrial effluent. The gas, however, is flared off.

Palm oil mills, being one of the largest industries in Malaysia and Indonesia, effluents from these mills can be anaerobically converted into biogas which in turn can be used to generate power through CHP systems such as gas turbines or gas-fired engines. A cost effective way to recover biogas from POME is to replace the existing ponding/lagoon system with a closed digester system which can be achieved by installing floating plastic membranes on the open ponds.

As per conservative estimates, potential POME produced from all Palm Oil Mills in Indonesia and Malaysia is more than 50 million m3 each year which is equivalent to power generation capacity of more than 800 GW.

New Trends

Recovery of organic-based product is a new approach in managing POME which is aimed at getting by-products such as volatile fatty acid, biogas and poly-hydroxyalkanoates to promote sustainability of the palm oil industry.  It is envisaged that POME can be sustainably reused as a fermentation substrate in production of various metabolites through biotechnological advances. In addition, POME consists of high organic acids and is suitable to be used as a carbon source.

POME has emerged as an alternative option as a chemical remediation to grow microalgae for biomass production and simultaneously act as part of wastewater treatment process. POME contains hemicelluloses and lignocelluloses material (complex carbohydrate polymers) which result in high COD value (15,000–100,000 mg/L).

POME-Biogas

Utilizing POME as nutrients source to culture microalgae is not a new scenario, especially in Malaysia. Most palm oil millers favor the culture of microalgae as a tertiary treatment before POME is discharged due to practically low cost and high efficiency. Therefore, most of the nutrients such as nitrate and ortho-phosphate that are not removed during anaerobic digestion will be further treated in a microalgae pond. Consequently, the cultured microalgae will be used as a diet supplement for live feed culture.

In recent years, POME is also gaining prominence as a feedstock for biodiesel production, especially in the European Union. The use of POME as a feedstock in biodiesel plants requires that the plant has an esterification unit in the back-end to prepare the feedstock and to breakdown the FFA. In recent years, biomethane production from POME is also getting traction in Indonesia and Malaysia.

The Energy Potential of Palm Kernel Shells

The Palm Oil industry in Southeast Asia and Africa generates large quantity of biomass wastes whose disposal is a challenging task. Palm kernel shells (or PKS) are the shell fractions left after the nut has been removed after crushing in the Palm Oil mill. Kernel shells are a fibrous material and can be easily handled in bulk directly from the product line to the end use. Large and small shell fractions are mixed with dust-like fractions and small fibres. Moisture content in kernel shells is low compared to other biomass residues with different sources suggesting values between 11% and 13%.

palm-kernel-shells

Palm kernel shells contain residues of Palm Oil, which accounts for its slightly higher heating value than average lignocellulosic biomass. Compared to other residues from the industry, it is a good quality biomass fuel with uniform size distribution, easy handling, easy crushing, and limited biological activity due to low moisture content. PKS can be readily co-fired with coal in grate fired -and fluidized bed boilers as well as cement kilns in order to diversify the fuel mix.

The primary use of palm kernel shells is as a boiler fuel supplementing the fibre which is used as primary fuel. In recent years kernel shells are sold as alternative fuel around the world. Besides selling shells in bulk, there are companies that produce fuel briquettes from shells which may include partial carbonisation of the material to improve the combustion characteristics.

As a raw material for fuel briquettes, palm shells are reported to have the same calorific characteristics as coconut shells. The relatively smaller size makes it easier to carbonise for mass production, and its resulting palm shell charcoal can be pressed into a heat efficient biomass briquette.

Palm kernel shells have been traditionally used as solid fuels for steam boilers in palm oil mills across Southeast Asia. The steam generated is used to run turbines for electricity production. These two solid fuels alone are able to generate more than enough energy to meet the energy demands of a palm oil mill. Most palm oil mills in the region are self-sufficient in terms of energy by making use of kernel shells and mesocarp fibers in cogeneration.

In recent years, the demand for palm kernel shells has increased considerably in Europe, Asia-Pacific, China etc. resulting in price close to that of coal. Nowadays, cement industries and power producers are increasingly using palm kernel shells to replace coal. In grate-fired boiler systems, fluidized-bed boiler systems and cement kilns, palm kernel shells are an excellent fuel.

Cofiring of PKS yields added value for power plants and cement kilns, because the fuel significantly reduces carbon emissions – this added value can be expressed in the form of renewable energy certificates, carbon credits, etc. However, there is a great scope for introduction of high-efficiency cogeneration systems in the industry which will result in substantial supply of excess power to the public grid and supply of surplus PKS to other nations. Palm kernel shell is already extensively in demand domestically by local industries for meeting process heating requirements, thus creating supply shortages in the market.

Palm oil mills around the world may seize an opportunity to supply electricity for its surrounding plantation areas using palm kernel shells, empty fruit branches and palm oil mill effluent which have not been fully exploited yet. This new business will be beneficial for all parties, increase the profitability and sustainability for palm oil industry, reduce greenhouse gas emissions and increase the electrification ratio in surrounding plantation regions.

Palm Kernel Shells as Biomass Resource

Biomass residue from palm oil industry are attractive renewable energy fuel in Southeast Asia. The abundance of these biomass resources is increasing with the fast development of palm oil industry in Malaysia, Indonesia and Thailand. In the Palm Oil value chain there is an overall surplus of by-products and the utilisation rate of these by-products is low.

Palm kernel shells (or PKS) are the shell fractions left after the nut has been removed after crushing in the palm oil mill. Palm kernel shells are a fibrous material and can be easily handled in bulk directly from the product line to the end use. Large and small shell fractions are mixed with dust-like fractions and small fibres.

Moisture content in kernel shells is low compared to other biomass residues with different sources suggesting values between 11% and 13%. Palm kernel shells contain residues of Palm Oil, which accounts for its slightly higher heating value than average lignocellulosic biomass. Compared to other residues from the industry, palm kernel shells are a good quality biomass fuel with uniform size distribution, easy handling, easy crushing, and limited biological activity due to low moisture content.

Press fibre and kernel shell generated by the palm oil mills are traditionally used as solid fuels for steam boilers. The steam generated is used to run turbines for electricity production. These two solid fuels alone are able to generate more than enough energy to meet the energy demands of a palm oil mill.

Most palm oil mills in the region are self-sufficient in terms of energy by making use of kernel shells and mesocarp fibers in cogeneration. The demand for palm kernel shells has increased considerably in Malaysia, Indonesia and Thailand resulting in price close to that of coal. Nowadays, cement industries are using palm kernel shells to replace coal mainly because of CDM benefits.

PKS has also emerged as a hot biomass commodity in the Asia-Pacific region, especially in South Korea and Japan, where PKS is being used to power huge biomass power plants. PKS is also getting traction in Europe as an attractive alternative fuel.

The problems associated with the burning of these solid fuels are the emissions of dark smoke and the carry-over of partially carbonized fibrous particulates due to incomplete combustion of the fuels can be tackled by commercially-proven technologies in the form of high-pressure boilers.

Dual-fired boilers capable of burning either diesel oil or natural gas are the most suitable for burning palm Oil waste since they could also facilitate the use of POME-derived biogas as a supplementary fuel. However, there is a great scope for introduction of high-efficiency CHP systems in the industry which will result in substantial supply of excess power to the public grid.

Agricultural Biomass in Malaysia

Malaysia is located in a region where biomass productivity is high which means that the country can capitalize on this renewable energy resource to supplements limited petroleum and coal reserves. Malaysia, as a major player in the palm oil and sago starch industries, produces a substantial amount of agricultural biomass waste which present a great opportunity for harnessing biomass energy in an eco-friendly and commercially-viable manner.

Peninsular Malaysia generates large amounts of wood and’ agricultural residues, the bulk of which are not being currently utilised for any further downstream operations. The major agricultural crops grown in Malaysia are rubber (39.67%), oil palm (34.56%), cocoa (6.75%), rice (12.68%) and coconut (6.34%). Out of the total quantity of residues generated, only 27.0% is used either as fuel for the kiln drying of timber, for the manufacture of bricks, the curing of tobacco leaves, the drying rubber-sheets and for the manufacture of products such as particleboard and fibreboard. The rest has to be disposed of by burning.

Palm Oil Industry

Oil palm is one of the world’s most important fruit crops. Malaysia is one of the largest producers and exporter of palm oil in the world, accounting for 30% of the world’s traded edible oils and fats supply. Palm oil industries in Malaysia have good potential for high pressure modern power plants and the annual power generation potential is about 8,000 GWh. Malaysia produced more than 20 million tonnes of palm oil in 2012 over 5 million hectares of land.

The palm oil industry is a significant branch in Malaysian agriculture. Almost 70% of the volume from the processing of fresh fruit bunch is removed as biomass waste in the form of empty fruit bunches (EFBs), fibers and shells, as well as liquid effluent. Fibres and shells are traditionally used as fuels to generate power and steam. Palm oil mill effluent, commonly known as POME, are sometimes converted into biogas that can be used in gas-fired gensets.

Sugar Industry

The cultivation of sugarcane in Malaysia is surprisingly small. Production is concentrated in the Northwest extremity of peninsular Malaysia in the states of Perlis and Kedah. This area has a distinct dry season needed for cost-efficient sugarcane production. Plantings in the states of Perak and Negri Sembilan were unsuccessful due to high unit costs as producing conditions were less suitable.

The lack of growth in cane areas largely reflects the higher remuneration received by farmers for other crops, especially oil palm. Over the past 20 years while the sugarcane area has remained at around 20000 hectares, that planted to oil palm has expanded from 600 000 hectares to 5 million hectares.

Other leading crops in terms of planted areas are rubber with 2.8 million hectares, rice with 670 000 hectares and cocoa with 380 000 hectares. Malaysia, the world’s third largest rubber producer, accounted for 1 million tons of natural rubber production in 2012. Like oil palm industry, the rubber industry produces a variety of biomass wastes whose energy potential is largely untapped until now.

Bioenergy in Southeast Asia: Perspectives

Southeast Asia, with its abundant bioenergy resources, holds a strategic position in the global biomass energy atlas. There is immense biomass energy potential in Southeast Asian countries due to plentiful supply of diverse forms of biomass wastes, such as agricultural residues, woody biomass, animal wastes, municipal solid waste, etc. The rapid economic growth and industrialization in the region has accelerated the drive to implement the latest waste-to-energy technologies to tap the unharnessed potential of biomass resources.

Southeast_asia

Southeast Asia is a big producer of agricultural and wood products which, when processed in industries, produces large amounts of biomass residues. According to conservative estimates, the amount of biomass residues generated from sugar, rice and palm oil mills is more than 200-230 million tons per year which corresponds to cogeneration potential of 16-19 GW.

Rice mills in the region produce 38 million tonnes of rice husk as solid residue which is a good fuel for producing heat and power. Sugar industry is an integral part of the industrial scenario in Southeast Asia accounting for 7% of sugar production worldwide. Sugar mills in Thailand, Indonesia, Philippines and Vietnam generate 34 million tonnes of bagasse every year.  Malaysia, Indonesia and Thailand account for 90% of global palm oil production leading to the generation of 27 million tonnes of waste per annum in the form of empty fruit bunches (EFBs), fibers and shells, as well as liquid effluent.

Woody biomass is a good energy resource due to presence of large number of forests in Southeast Asia. Apart from natural forests, non-industrial plantations of different types (e.g. coconut, rubber and oil palm plantations, fruit orchards, and trees in homesteads and gardens) have gained recognition as important sources of biomass. In addition, the presence of a large number of wood processing industries also generates significant quantity of wood wastes. The annual production of wood wastes in the region is estimated to be more than 30 million m3.

The prospects of biogas power generation are also high in the region, thanks to presence of well-established food-processing and dairy industries. Another important biomass resource is contributed by municipal solid wastes in heavily populated urban areas.  In addition, there are increasing efforts both commercially and promoted by governments to develop biomass energy systems for efficient biofuel production, e.g. bio-diesel from palm oil.

Biomass resources, particularly residues from forests, wood processing, agricultural crops and agro-processing, are under-utilised in Southeast Asian countries. There is an urgent need to utilize biomass wastes for commercial electricity and heat production to cater to the needs of the industries as well as urban and rural communities.

Southeast Asian countries are yet to make optimum use of the additional power generation potential from biomass waste resources which could help them to partially overcome the long-term problem of energy supply. Technologies for biomass utilization which are at present widely used in Southeast counties need to be improved towards best practice by making use of the latest trends in the biomass energy sector.

Bioenergy Developments in Malaysia

Malaysia is blessed with abundant renewable sources of energy, especially biomass and solar. Under the Eighth Malaysian Plan, renewable energy was added in the energy mix to unveil a Five-Fuel Strategy to achieve 5 percent contribution by 2005.

Among the various sources of renewable energy, bioenergy seems to be the most promising option for Malaysia. The National Biofuel Policy, launched in 2006 encourages the use of environmentally friendly, sustainable and viable sources of biomass energy. Under the Five Fuel Policy, the government of Malaysia has identified biomass as one of the potential renewable energy.

Malaysia produces atleast 168 million tonnes of biomass, including timber and oil palm waste, rice husks, coconut trunk fibres, municipal waste and sugar cane waste annually. Being a major agricultural commodity producer in the region Malaysia is well positioned amongst the ASEAN countries to promote the use of biomass as a renewable energy source.

Malaysia has been one of the world’s largest producers and exporters of palm oil for the last forty years. The Palm Oil industry, besides producing Crude Palm Oil (CPO) and Palm Kernel Oil, produces Palm Shell, Press Fibre, Empty Fruit Bunches (EFB), Palm Oil Mill Effluent (POME), Palm Trunk (during replanting) and Palm Fronds (during pruning).

Malaysia has approximately 4 million hectares of land under oil palm plantation. Over 75% of total area planted is located in just four states, Sabah, Johor, Pahang and Sarawak, each of which has over half a million hectares under cultivation. The total amount of processed FFB (Fresh Fruit Bunches) was estimated to be 75 million tons while the total amount of EFB produced was estimated to be 16.6 million tons. Around 58 million tons of POME is produced in Malaysia annually, which has the potential to produce an estimated 15 billion m3 of biogas can be produced each year.

Malaysia is the world’s second largest producer of crude palm oil. Almost 70% of the volume from the processing of fresh fruit bunch is removed as wastes in the form of empty fruit bunches, palm kernel shells, palm oil mill effluent etc. With more than 451 mills in Malaysia, this palm oil industry generate around 100 million dry tonnes of biomass. Malaysia has more than 2400 MW of biomass and 410 MW of biogas potential, out of which only a fraction has been harnessed until now.

Rice husk is another important agricultural biomass resource in Malaysia with good potential for power cogeneration. An example of its attractive energy potential is biomass power plant in the state of Perlis which uses rice husk as the main source of fuel and generates 10 MW power to meet the requirements of 30,000 households. The US$15 million project has been undertaken by Bio-Renewable Power Sdn Bhd in collaboration with the Perlis state government, while technology provider is Finland’s Foster Wheeler Energia Oy.

Under the EC-ASEAN Cogeneration Program, there are three ongoing Full Scale Demonstration Projects (FSDPs) – Titi Serong, Sungai Dingin Palm Oil Mill and TSH Bioenergy – to promote biomass energy systems in Malaysia. The 1.5MW Titi Serong power plant, located at Parit Buntar (Perak), is based on rice husk while the 2MW Sungai Dingin Palm Oil Mill project make use of palm kernel shell and fibre to generate steam and electricity. The 14MW TSH Bioenergy Sdn Bhd, located at Tawau (Sabah), is the biggest biomass power plant in Malaysia and utilizes empty fruit bunches, palm oil fibre and palm kernel shell as fuel resources.