Biomethane Utilization Pathways

biomethane-transportBiogas can be used in raw (without removal of CO2) or in upgraded form. The main function of upgrading biogas is the removal of CO2 (to increase the energy content) and H2S (to reduce risk of corrosion). After upgrading, biogas possesses identical gas quality properties as  natural gas, and can thus be used as natural gas replacement. The main pathways for biomethane utilization are as follows:

  • Production of heat and/or steam
  • Electricity production / combined heat and power production (CHP)
  • Natural gas replacement (gas grid injection)
  • Compressed natural gas (CNG) & diesel replacement – (bio-CNG for transport fuel usage)
  • Liquid natural gas (LNG) replacement – (bio-LNG for transport fuel usage)

Prior to practically all utilization options, the biogas has to be dried (usually through application of a cooling/condensation step). Furthermore, elements such as hydrogen sulphide and other harmful trace elements must be removed (usually trough application of an activated carbon filter) to prevent adverse effects on downstream processing equipment (such as compressors, piping, boilers and CHP systems).

Although biogas is perfectly suitable to be utilized in boilers (as an environmental friendlier source for heat and steam production), this option is rather obsolete due to the abundance of alternative sources from solid waste origin.

Most Palm Oil Mills are already self-reliant with respect to heat and steam production due to the combustion of their solid waste streams (such as EFB and PKS). Consequently, conversion to electricity (by means of a CHP unit) or utilization as natural gas, CNG or LNG replacement, would be a more sensible solution.

The biogas masterplan as drafted by the Asia Pacific Biogas Alliance foresees a distribution in which 30% of the biomethane is used for power generation, 40% for grid injection and 30% as compressed/liquefied fuel for transportation purpose (Asian Pacific Biogas Alliance, 2015).

For each project, the most optimal option has to be evaluated on a case to case basis. Main decision-making factors will be local energy prices and requirements, available infrastructure (for gas and electricity), incentives and funding.

For the locations where local demand is exceeded, and no electricity or gas infrastructure is available within a reasonable distance (<5-10 km, due to investment cost and power loss), production of CNG could offer a good solution.

Moreover, during the utilization of biogas within a CHP unit only 40-50% of the energetic content of the gas is converted into electricity. The rest of the energy is transformed into heat. For those locations where an abundance of heat is available, such as Palm Oil Mills, this effectively means that 50-60% of the energetic content of the biogas is not utilized. Converting the biogas into biomethane (of gas grid or CNG quality) through upgrading, would facilitate the transportation and commercialisation of over 95%  of the energetic content of the biogas.

Within the CNG utilization route, the raw biogas will be upgraded to a methane content of >96%, compressed to 250 bar and stored in racks with gas bottles. The buffered gas (bottles) will be suitable for transportation by truck or ship. For transportation over large distances (>200km), it will be advised to further reduce the gas volume by converting the gas to LNG (trough liquefaction).

Overall the effects and benefits from anaerobic digestion of POME and utilization of biomethane can be summarized as follows:

  • Reduction of emissions i.e. GHG methane and CO2
  • Reduced land use for POME treatment
  • Enhanced self-sufficiency trough availability of on-site diesel replacement (CNG)
  • Expansion of economic activities/generation of additional revenues
    • Sales of surplus electricity (local or to the grid)
    • Sales of biomethane (injection into the natural gas grid)
    • Replacement of on-site diesel usage by CNG
    • Sales of bottled CNG
  • Reducing global and local environmental impact (through fuel replacement)
  • Reducing dependence on fossil fuel, and enhances fuel diversity and security of energy supply
  • Enhancement of local infrastructure and employment
    • Through electrical and gas supply
    • Through Fuel (CNG) supply

Co-Authors: H. Dekker and E.H.M. Dirkse (DMT Environmental Technology)

Note: This is the second article in the special series on ‘Sustainable Utilization of POME-based Biomethane’ by Langerak et al of DMT Environmental Technology (Holland). The first article can be viewed at this link

POME as a Source of Biomethane

POME-BiogasDuring the production of crude palm oil, large amount of waste and by-products are generated. The solid waste streams consist of empty fruit bunch (EFB), mesocarp fruit fibers (MF) and palm kernel shells (PKS). Reuse of these waste streams in applications for heat, steam, compost and to lesser extent power generation are practised widely across Southeast Asia. POME or Palm Oil Mill Effluent is an underutilized liquid waste stream from palm oil mills which is generated during the palm oil extraction/decanting process and often seen as a serious environmental issue but it is a very good source for biomethane production. Therefore, discharge of POME is subject to increasingly stringent regulations in many palm oil-producing nations.

Anaerobic Digestion of POME

POME is an attractive feedstock for biomethane production and is abundantly available in all palm oil mills. Hence, it ensures continuous supply of substrates at no or low cost for biogas production, positioning it as a great potential source for biomethane production. (Chin May Ji, 2013).

POME is a colloidal suspension containing 95-96% water, 0.6-0.7% oil and 4-5% total solids, which include 2-4% suspended solids. Biological Oxygen Demand (BOD) generally ranges between 25,000 and 65,714 mg/L, Chemical Oxygen Demand (COD) ranges between 44,300 and 102,696 mg/L.

Most palm oil mills and refineries have their own treatment systems for POME, which is easily amenable to biodegradation due to its high organic content. The treatment system usually consists of anaerobic and aerobic ponds. (Sulaiman, 2013).

Open pond systems are still commonly applied. Although relatively cheap to install, these system often fail to meet discharge requirements (due to lack of operational control, long retention time, silting and short circuiting issues).

Moreover, the biogas produced during the anaerobic decomposition of POME in open pond systems is not recovered for utilization. The produced gas dissipates into the atmosphere where it causes adverse environment effects (due to the fact that CH4 is a twenty times stronger greenhouse gas then CO2 (Chin May Ji, 2013).

Biogas capture from POME can be carried out using a number of various technologies ranging in cost and complexity. The closed-tank anaerobic digester system with continuous stirred-tank reactor (CSTR), the methane fermentation system employing special microorganisms and the reversible flow anaerobic baffled reactor (RABR) system are among the technologies offered by technology providers. (Malaysian Palm Oil Board, 2015).

Biogas production largely depends on the method deployed for biomass conversion and capture of the biogas, and can, therefore, approximately range from 5.8 to 12.75 kg of CH4 per cubic meter of POME. Application of enclosed anaerobic digestion will significantly increase the quality of the effluent/ discharge stream as well as the biogas composition, as mentioned in table below.

 Table: Performance comparison between open and closed digester systems

Parameters Open digester system Closed anaerobic digester
COD removal efficiency (%) 81% 97%
HRT (days) 20 10
Methane utilization Released to atmosphere Recoverable
Methane yield (kg CH4/kg COD removed) 0.11 0.2
Methane content (%) 36 55
Solid discharge (g/L) 20 8

*This table has been reproduced from (Alawi Sulaiman, 2007)

A closed anaerobic system is capable of producing and collecting consistently high quality of methane rich biogas from POME. Typical raw biogas composition will be: 50-60 % CH4, 40-50 % CO2, saturated with water and with trace amounts of contaminants (H2S, NH3, volatiles, etc.).

Biomethane Potential in Southeast Asia

The amount of biomethane (defined as methane produced from biomass, with properties close to natural gas) that can be potentially produced from POME (within the Southeast Asian region) exceeds 2.25 billion cubic meter of biomethane (on a yearly basis).

Especially Indonesia and Malaysia, as key producers within the palm oil industry, could generate significant quantities of biomethane. An impression of the biomethane potential of these countries including other feedstock sources is being highlighted below (VIV Asia, 2015).

Indonesia (4.35 billion m3 of biomethane):

  • 25 billion m3 of biomethane from Palm Oil Mill Effluent (POME).
  • 2 billion m3 of bio-methane from Sewage Treatment Plant (STP).
  • 9 billion m3 of bio-methane from Municipal Solid Waste (MSW).

Malaysia (3 billion m3 of biomethane):

  • 1 billion m3 of biomethane from Palm Oil Mill Effluent (POME).
  • 2 billion m3 of biomethane from Sewage Treatment Plant (STP).
  • 8 billion m3 of biomethane from Municipal Solid Waste (MSW).

The Asian Pacific Biogas Alliance estimates that the potential of conversion of biomass to biomethane is sufficient to replace 25 percent of the natural gas demand by renewable biogas (Asian Pacific Biogas Alliance, 2015).

To sum up, due to the high fraction of organic materials, POME has a large energetic potential. By unlocking the energetic potential of these streams through conversion/ digesting and capture of biomethane, plant owners have the opportunity to combine waste management with a profitable business model.

Co-Authors: H. Dekker and E.H.M. Dirkse (DMT Environmental Technology)

References

Alawi Sulaiman, Z. B. (2007). Biomethane production from pal oil mill effluent (POME) in a semi-commercial closed anaerobic digester. Seminar on Sustainable Palm Biomass initiatives. Japan Society on Promotion of Science (JSPS).

Asia Biogas Group. (2015, 08 15). Retrieved from Asia Biogas : http://www.asiabiogas.com

Asian Pacific Biogas Alliance. (2015). Biogas Opportunities in South East Asia. Asian Pacific Biogas Alliance/ICESN.

Chin May Ji, P. P. (2013). Biogas from palm oil mill effluent (POME): Opportunities and challenges from Malysia’s perspective. Renewable and Sustainable Energy Reviews , 717-726.

Malaysian Palm Oil Board. (2015, 08 26). Biogas capture and CMD project implementation for palm oil mills. Retrieved from Official Portal Of Malaysian Palm Oild Board:

Sulaiman, N. A. (2013). The Oil Palm Wastes in Malaysia. In M. D. Matovic, “Biomass Now – Sustainable Growth and Use”. InTech.

VIV Asia. (2015, 08 26). The international platform from feed to food in Asia. Retrieved from http://www.vivasia.nl

Note: This is the first article in the special series on ‘Sustainable Utilization of POME-based Biomethane’ by Langerak et al of DMT Environmental Technology (Holland)

Biomass Wastes from Palm Oil Mills

The Palm Oil industry generates large quantity of wastes whose disposal is a challenging task. In the Palm Oil mill, fresh fruit bunches are sterilized after which the oil fruits can be removed from the branches. The empty fruit bunches (are left as residues, and the fruits are pressed in oil mills. The Palm Oil fruits are then pressed, and the kernel is separated from the press cake (mesocarp fibers). The palm kernels are then crushed and the kernels then transported and pressed in separate mills.

In a typical Palm Oil plantation, almost 70% of the fresh fruit bunches are turned into wastes in the form of empty fruit bunches, fibers and shells, as well as liquid effluent. These by-products can be converted to value-added products or energy to generate additional profit for the Palm Oil Industry.

Palm Kernel Shells (PKS)

Palm kernel shells (or PKS) are the shell fractions left after the nut has been removed after crushing in the Palm Oil mill. Kernel shells are a fibrous material and can be easily handled in bulk directly from the product line to the end use. Large and small shell fractions are mixed with dust-like fractions and small fibres.

Moisture content in kernel shells is low compared to other biomass residues with different sources suggesting values between 11% and 13%. Palm kernel shells contain residues of Palm Oil, which accounts for its slightly higher heating value than average lignocellulosic biomass. Compared to other residues from the industry, it is a good quality biomass fuel with uniform size distribution, easy handling, easy crushing, and limited biological activity due to low moisture content.

Press fibre and shell generated by the Palm Oil mills are traditionally used as solid fuels for steam boilers. The steam generated is used to run turbines for electricity production. These two solid fuels alone are able to generate more than enough energy to meet the energy demands of a Palm Oil mill.

Empty Fruit Bunches (EFBs)

In a typical Palm Oil mill, empty fruit bunches are abundantly available as fibrous material of purely biological origin. EFB contains neither chemical nor mineral additives, and depending on proper handling operations at the mill, it is free from foreign elements such as gravel, nails, wood residues, waste etc. However, it is saturated with water due to the biological growth combined with the steam sterilization at the mill. Since the moisture content in EFB is around 67%, pre-processing is necessary before EFB can be considered as a good fuel.

In contrast to shells and fibers, empty fruit bunches are usually burnt causing air pollution or returned to the plantations as mulch. Empty fruit bunches can be conveniently collected and are available for exploitation in all Palm Oil mills. Since shells and fibres are easy-to-handle, high quality fuels compared to EFB, it will be advantageous to utilize EFB for on-site energy demand while making shells and fibres available for off-site utilization which may bring more revenues as compared to burning on-site.

Palm Oil Mill Effluent (POME)

Palm Oil processing also gives rise to highly polluting waste-water, known as Palm Oil Mill Effluent, which is often discarded in disposal ponds, resulting in the leaching of contaminants that pollute the groundwater and soil, and in the release of methane gas into the atmosphere. POME could be used for biogas production through anaerobic digestion. At many Palm-oil mills this process is already in place to meet water quality standards for industrial effluent. The gas, however, is flared off.

In a conventional Palm Oil mill, 600-700 kg of POME is generated for every ton of processed FFB. Anaerobic digestion is widely adopted in the industry as a primary treatment for POME. Liquid effluents from palm oil mills can be anaerobically converted into biogas which in turn can be used to generate power through gas turbines or gas-fired engines.

Conclusions

Most of the Biomass residues from Palm Oil Mills are either burnt in the open or disposed off in waste ponds. The Palm Oil industry, therefore, contributes significantly to global climate change by emitting carbon dioxide and methane. Like sugar mills, Palm Oil mills have traditionally been designed to cover their own energy needs (process heat and electricity) by utilizing low pressure boilers and back pressure turbo-generators. Efficient energy conversion technologies, especially thermal systems for crop residues, that can utilize all Palm Oil residues, including EFBs, are currently available.

In the Palm Oil value chain there is an overall surplus of by-products and their utilization rate is negligible, especially in the case of POME and EFBs. For other mill by-products the efficiency of the application can be increased. Presently, shells and fibers are used for in-house energy generation in mills but empty fruit bunches is either used for mulching or dumped recklessly. Palm Oil industry has the potential of generating large amounts of electricity for captive consumption as well as export of surplus power to the public grid.