Tag Archives: gasification

Gasification of Municipal Wastes

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Gasification of municipal wastes involves the reaction of carbonaceous feedstock with an oxygen-containing reagent, usually oxygen, air, steam or carbon dioxide, generally at temperatures above 800°C. The process is largely exothermic but some heat may be required to initialise and sustain the gasification process.

utishinai-gasification-plant

The main product of the gasification process is syngas, which contains carbon monoxide, hydrogen and methane. Typically, the gas generated from gasification has a low heating value (LHV) of 3 – 6 MJ/Nm3.The other main product produced by gasification is a solid residue of non-combustible materials (ash) which contains a relatively low level of carbon.

Syngas can be used in a number of ways, including:

  • Syngas can be burned in a boiler to generate steam for power generation or industrial heating.
  • Syngas can be used as a fuel in a dedicated gas engine.
  • Syngas, after reforming, can be used in a gas turbine
  • Syngas can also be used as a chemical feedstock.

Gasification has been used worldwide on a commercial scale for several decades by the chemical, refining, fertilizer and electric power industries. MSW gasification plants are relatively small-scale, flexible to different inputs and modular development. The quantity of power produced per tonne of waste by gasification process is larger than when applying the incineration method.

The most important reason for the growing popularity of gasification of municipal solid wastes has been the increasing technical, environmental and public dissatisfaction with the performance of conventional incinerators.

Plasma Gasification

Plasma gasification uses extremely high temperatures in an oxygen-starved environment to completely decompose input waste material into very simple molecules in a process similar to pyrolysis. The heat source is a plasma discharge torch, a device that produces a very high temperature plasma gas. It is carried out under oxygen-starved conditions and the main products are vitrified slag, syngas and molten metal.

plasma-gasification

Vitrified slag may be used as an aggregate in construction; the syngas may be used in energy recovery systems or as a chemical feedstock; and the molten metal may have a commercial value depending on quality and market availability. The technology has been in use for steel-making and is used to melt ash to meet limits on dioxin/furan content. There are several commercial-scale plants already in operation in Japan for treating MSW and auto shredder residue.

Advantages of MSW Gasification

There are numerous MSW gasification facilities operating or under construction around the world. Gasification of solid wastes has several advantages over traditional combustion processes for MSW treatment. It takes place in a low oxygen environment that limits the formation of dioxins and of large quantities of SOx and NOx. Furthermore, it requires just a fraction of the stoichiometric amount of oxygen necessary for combustion. As a result, the volume of process gas is low, requiring smaller and less expensive gas cleaning equipment.

The lower gas volume also means a higher partial pressure of contaminants in the off-gas, which favours more complete adsorption and particulate capture. Finally, gasification generates a fuel gas that can be integrated with combined cycle turbines, reciprocating engines and, potentially, with fuel cells that convert fuel energy to electricity more efficiently than conventional steam boilers.

Disadvantages of Gasification

The gas resulting from gasification of municipal wastes contains various tars, particulates, halogens, heavy metals and alkaline compounds depending on the fuel composition and the particular gasification process. This can result in agglomeration in the gasification vessel, which can lead to clogging of fluidised beds and increased tar formation. In general, no slagging occurs with fuels having ash content below 5%. MSW has a relatively high ash content of 10-12%.

Utilization of Date Palm Biomass

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Date palm trees produce huge amount of agricultural wastes in the form of dry leaves, stems, pits, seeds etc. A typical date tree can generate as much as 20 kilograms of dry leaves per annum while date pits account for almost 10 percent of date fruits.

date-wastes

Date palm biomass is found in large quantities across the Middle East

Date palm is considered a renewable natural resource because it can be replaced in a relatively short period of time. It takes 4 to 8 years for date palms to bear fruit after planting, and 7 to 10 years to produce viable yields for commercial harvest. Usually date palm wastes are burned in farms or disposed in landfills which cause environmental pollution in dates-producing nations.

The major constituents of date palm biomass are cellulose, hemicelluloses and lignin. In addition, date palm has high volatile solids content and low moisture content. These factors make date palm residues an excellent biomass resource in date-palm producing nations.

Date palm biomass is an excellent resource for charcoal production in Middle East

A wide range of physico-chemical, thermal and biochemical technologies exists for sustainable utilization of date palm biomass. Apart from charcoal production and energy conversion (using technologies like combustion and gasification), below are few ways for utilization of date palm wastes:

Conversion into fuel pellets or briquettes

Biomass pellets are a popular type of alternative fuel (analogous to coal), generally made from wood wastes and agricultural biomass. The biomass pelletization process consists of multiple steps including pre-treatment, pelletization and post-treatment of biomass wastes. Biomass pellets can be used as a coal replacement in power plant, industries and other application.

Conversion into energy-rich products

Biomass pyrolysis is the thermal decomposition of date palm biomass occurring in the absence of oxygen. The products of biomass pyrolysis include biochar, bio-oil and gases including methane, hydrogen, carbon monoxide, and carbon dioxide.

Depending on the thermal environment and the final temperature, pyrolysis will yield mainly biochar at low temperatures, less than 450 0C, when the heating rate is quite slow, and mainly gases at high temperatures, greater than 800 0C, with rapid heating rates. At an intermediate temperature and under relatively high heating rates, the main product is bio-oil.

Bio-oil can be upgraded to either a special engine fuel or through gasification processes to a syngas which can then be processed into biofuels. Bio-oil is particularly attractive for co-firing because it can be more readily handled and burned than solid fuel and is cheaper to transport and store.

Conversion into biofertilizer

Composting is the most popular method for biological decomposition of organic wastes. Date palm waste has around 80% organic content which makes it very well-suited for the composting process. Commercial-scale composting of date palm wastes can be carried out by using the traditional windrow method or a more advanced method like vermicomposting.

Issues Confronting Biomass Energy Ventures

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Biomass resources can be transformed into clean energy and/or fuels by thermal and biochemical technologies. Besides recovery of substantial energy, these technologies can lead to a substantial reduction in the overall waste quantities requiring final disposal.

Biomass_Cogeneration

However, biomass energy projects worldwide are often hampered by a variety of techno-commercial issues. The issues enumerated below are not geography-specific and are usually a matter of concern for project developers, entrepreneurs and technology companies:

Large Project Costs

In India, a 1 MW gasification plant usually costs about USD 1-1.5 million. A combustion-based 1 MW plant would need a little more expenditure, to the tune of USD 1-2 million. An anaerobic digestion-based plant of the same capacity, on the other hand, could range anywhere upwards USD 3 million. Such high capital costs prove to be a big hurdle for any entrepreneur or renewable energy enthusiast to come forward and invest into these technologies.

Low Conversion Efficiencies

In general, efficiencies of combustion-based systems are in the range of 20-25% and gasification-based systems are considered even poorer, with their efficiencies being in the range of a measly 10-15%. The biomass resources themselves are low in energy density, and such poor system efficiencies could add a double blow to the entire project.

Dearth of Mature Technologies

Poor efficiencies call for a larger quantum of resources needed to generate a unit amount of energy. Owing to this reason, investors and project developers find it hard to go for such plants on a larger scale. Moreover, the availability of only a few reliable technology and operation & maintenance service providers makes these technologies further undesirable.

Gasification technology is still limited to scales lesser than 1 MW in most parts of the world. Combustion-based systems have although gone upwards of 1 MW, a lot many are now facing hurdles because of factors like unreliable resource chain, grid availability, and many others.

Lack of Funding Options

Financing agencies usually give a tough time to biomass project developers as compared to what it takes to invest in other renewable energy technologies.

Non-Transparent Trade Markets

Usually, the biomass energy resources are obtained through forests, farms, industries, animal farms etc. There is no standard pricing mechanism for such resources and these usually vary from vendor to vendor, even with the same resource in consideration.

High Risks / Low Pay-Backs

Biomass energy projects are not much sought-after owing to high project risks which could entail from failed crops, natural disasters, local disturbances, etc.

Resource Price Escalation

Unrealistic fuel price escalation too is a major cause of worry for the plant owners. Usually, an escalation of 3-5% is considered while carrying out the project’s financial modelling. However, it has been observed that in some cases, the rise has been as staggering as 15-20% per annum, forcing the plants to shut down.

Comparison of MSW-to-Energy Processes

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MSW-to-Energy is the use of thermochemical and biochemical technologies to recover energy, usually in the form of electricity, steam and other fuels, from urban wastes. The main categories of MSW-to-energy technologies are physical technologies, which process waste to make it more useful as fuel; thermal technologies, which can yield heat, fuel oil, or syngas from both organic and inorganic wastes; and biological technologies, in which bacterial fermentation is used to digest organic wastes to yield fuel. These new technologies can reduce the volume of the original waste by 90%, depending upon composition and use of outputs.

Components of MSW-to-Energy Systems

  1. Front-end MSW preprocessing
  2. Conversion unit (reactor or anaerobic digester)
  3. Gas cleanup and residue treatment plant
  4. Energy recovery plant (optional)
  5. Emissions clean up

Incineration

  • Combustion of raw MSW, moisture less than 50%
  • Sufficient amount of oxygen is required to fully oxidize the fuel
  • Combustion temperatures are in excess of 850oC
  • Waste is converted into CO2 and water concern about toxics (dioxin, furans)
  • Any non-combustible materials (inorganic such as metals, glass) remain as a solid, known as bottom ash (used as feedstock in cement and brick manufacturing)
  • Air pollution control system for fly ash, bottom ash, particulates etc.
  • Needs high calorific value waste to keep combustion process going, otherwise requires high energy for maintaining high temperatures

Anaerobic Digestion

  • Well-known biochemical technology for organic fraction of MSW and sewage sludge.
  • Biological conversion of biodegradable organic materials in the absence of oxygen at mesophilic or thermophilic temperatures.
  • Residue is stabilized organic matter that can be used as soil amendment
  • Digestion is used primarily to reduce quantity of sludge for disposal / reuse
  • Methane gas is generated which is used for heat and power generation.

Gasification

  • Can be seen as between pyrolysis and combustion (incineration) as it involves partial oxidation.
  • Exothermic process (some heat is required to initialize and sustain the gasification process).
  • Oxygen is added but at low amounts not sufficient for full oxidation and full combustion.
  • Temperatures are above 650oC
  • Main product is syngas, typically has net calorific value of 4 to 10 MJ/Nm3
  • Other product is solid residue of non-combustible materials (ash) which contains low level of carbon

Pyrolysis

  • Thermal degradation of organic materials through use of indirect, external source of heat
  • Temperatures between 300 to 850oC are maintained for several seconds in the absence of oxygen.
  • Product is char, oil and syngas composed primarily of O2, CO, CO2, CH4 and complex hydrocarbons.
  • Syngas can be utilized for energy production or proportions can be condensed to produce oils and waxes
  • Syngas typically has net calorific value (NCV) of 10 to 20 MJ/Nm

Plasma Gasification

  • Use of electricity passed through graphite or carbon electrodes, with steam and/or oxygen / air injection to produce electrically conducting gas (plasma)
  • Temperatures are above 3000oC
  • Organic materials are converted to syngas composed of H2, CO
  • Inorganic materials are converted to solid slag
  • Syngas can be utilized for energy production or proportions can be condensed to produce oils and waxes

MSW-to-energy technologies can address a host of environmental issues, such as land use and pollution from landfills, and increasing reliance on fossil fuels. In many countries, the availability of landfill capacity has been steadily decreasing due to regulatory, planning and environmental permitting constraints. As a result, new approaches to waste management are rapidly being written into public and institutional policies at local, regional and national levels.

Biomass Cogeneration Systems

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Biomass fuels are typically used most efficiently and beneficially when generating both power and heat through biomass cogeneration systems (also known as combined heat and power or CHP system). Biomass conversion technologies transform a variety of wastes into heat, electricity and biofuels by employing a host of strategies. Conversion routes are generally thermochemical or biochemical, but may also include chemical and physical.

The simplest way is to burn the biomass in a furnace, exploiting the heat generated to produce steam in a boiler, which is then used to drive a steam turbine. Advanced biomass conversion technologies include biomass integrated gasification combined cycle (BIGCC) systems, cofiring (with coal or gas), pyrolysis and second generation biofuels.

Biomass Cogeneration Systems

A typical biomass cogeneration (or biomass cogen) system provides:

  • Distributed generation of electrical and/or mechanical power.
  • Waste-heat recovery for heating, cooling, or process applications.
  • Seamless system integration for a variety of technologies, thermal applications, and fuel types into existing building infrastructure.

Biomass cogeneration systems consist of a number of individual components—prime mover (heat engine), generator, heat recovery, and electrical interconnection—configured into an integrated whole. The type of equipment that drives the overall system (i.e., the prime mover) typically identifies the CHP unit.

Prime Movers

Prime movers for biomass cogeneration units include reciprocating engines, combustion or gas turbines, steam turbines, microturbines, and fuel cells. These prime movers are capable of burning a variety of fuels, including natural gas, coal, oil, and alternative fuels to produce shaft power or mechanical energy.

Key Components

A biomass-fueled cogeneration facility is an integrated power system comprised of three major components:

  • Biomass receiving and feedstock preparation.
  • Energy conversion – Conversion of the biomass into steam for direct combustion systems or into biogas for the gasification systems.
  • Power and heat production – Conversion of the steam or syngas or biogas into electric power and process steam or hot water

Feedstock for Biomass Cogeneration Plants

The lowest cost forms of biomass for cogeneration plants are residues. Residues are the organic byproducts of food, fiber, and forest production, such as sawdust, rice husks, wheat straw, corn stalks, and sugarcane bagasse. Forest residues and wood wastes represent a large potential resource for energy production and include forest residues, forest thinnings, and primary mill residues.

combined-heat-and-power

Energy crops are perennial grasses and trees grown through traditional agricultural practices that are produced primarily to be used as feedstocks for energy generation, e.g. hybrid poplars, hybrid willows, and switchgrass. Animal manure can be digested anaerobically to produce biogas in large agricultural farms and dairies.

To turn a biomass resource into productive heat and/or electricity requires a number of steps and considerations, most notably evaluating the availability of suitable biomass resources; determining the economics of collection, storage, and transportation; and evaluating available technology options for converting biomass into useful heat or electricity.

Guide to Effective Waste Management

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The best way of dealing with waste, both economically and environmentally, is to avoid creating it in the first place. For effective waste management, waste minimization, reuse, recycle and energy recovery are more sustainable than conventional landfill or dumpsite disposal technique.

Olusosun is the largest dumpsite in Nigeria

Waste Minimization

Waste minimization is the process of reducing the amount of waste produced by a person or a society. Waste minimization is about the way in which the products and services we all rely on are designed, made, bought and sold, used, consumed and disposed of.

Waste Reuse

Reuse means using an item more than once. This includes conventional reuse where the item is used again for the same function and new-life reuse where it is used for a new function. For example, concrete is a type of construction waste which can be recycled and used as a base for roads; inert material may be used as a layer that covers the dumped waste on landfill at the end of the day.

Waste Recycling

Recycling of waste involves reprocessing the particular waste materials, including e-waste, so that it can be used as raw materials in another process. This is also known as material recovery. A well-known process for recycling waste is composting, where biodegradable wastes are biologically decomposed leading to the formation of nutrient-rich compost.

Waste-to-Energy

As far as waste-to-energy is concerned, major processes involved are mass-burn incineration, RDF incineration, anaerobic digestion, gasification and pyrolysis. Gasification and pyrolysis involves super-heating of municipal solid waste in an oxygen-controlled environment to avoid combustion. The primary differences among them relate to heat source, oxygen level, and temperature, from as low as about 300°C for pyrolysis to as high as 11 000°C for plasma gasification. The residual gases like carbon dioxide, hydrogen, methane etc are released after a sophisticated gas cleaning mechanism.

MSW incineration produce significant amounts of a waste called bottom ash, of which about 40% must be landfilled. The remaining 60% can be further treated to separate metals, which are sold, from inert materials, which are often used as road base.

The above mentioned techniques are trending in many countries and region. As of 2014, Tokyo (Japan) has nineteen advanced and sophisticated waste incinerator plants making it one of the cleanest cities. From the legislature standpoint, the country has implemented strict emission parameters in incinerator plants and waste transportation.

The European Union also has a similar legislature framework as they too faced similar challenges with regards to waste management. Some of these policies include – maximizing recycling and re-use, reducing landfill, ensuring the guidelines are followed by the member states.

Singapore has also turned to converting household waste into clean fuel, which both reduced the volume going into landfills and produced electricity. Now its four waste-to-energy plants account for almost 3% of the country’s electricity needs, and recycling rates are at an all-time high of 60%. By comparison, the U.S. sent 53% of its solid waste to landfills in 2013, recycled only 34% of waste and converted 13% into electricity, according to the US Environmental Protection Agency.

Trends in Waste Collection

Since the municipal solid waste can be a mixture of all possible wastes and not just ones belonging to the same category and recommended process, recent advances in physical processes, sensors, and actuators used as well as control and autonomy related issues in the area of automated sorting and recycling of source-separated municipal solid waste.

Automated vacuum waste collection systems that are located underground are also actively used in various parts of the world like Abu Dhabi, Barcelona, Leon, Mecca and New York etc. The utilization of the subsurface space can provide the setting for the development of infrastructure which is capable of addressing in a more efficient manner the limitations of existing waste management schemes.

AI-based waste management systems can help in route optimization and waste disposal

This technique also minimizes operational costs, noise and provides more flexibility. There are various new innovations like IoT-enabled garbage cans, electric garbage trucks, waste sorting robots, eco dumpster and mechanisms etc are also being developed and deployed at various sites.

Conclusion

Waste management is a huge and ever growing industry that has to be analyzed and updated at every point based on the new emergence of threats and technology. With government educating the normal people and creating awareness among different sector of the society, setting sufficient budgets and assisting companies and facilities for planning, research and waste management processes can help to relax the issues to an extent if not eradicating it completely. These actions not only help in protecting environment, but also help in employment generation and boosting up the economy.

Biomass Gasification Power Systems

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Biomass gasification power systems have followed two divergent pathways, which are a function of the scale of operations. At sizes much less than 1MW, the preferred technology combination today is a moving bed gasifier and ICE combination, while at scales much larger than 10 MW, the combination is of a fluidized bed gasifier and a gas turbine.

biomass-gasifier

Larger scale units than 25 MW would justify the use of a combined cycle, as is the practice with natural gas-fired gas turbine stations. In the future it is anticipated that extremely efficient gasification based power systems would be based on a combined cycle that incorporates a fuel cell, gas turbine  and possibly a Rankine bottoming cycle.

Integrated Gasification Combined Cycle

The most attractive means of utilising a biomass gasifier for power generation is to integrate the gasification process into a gas turbine combined cycle power plant. This will normally require a gasifier capable of producing a gas with heat content close to 19 MJ/Nm3. A close integration of the two parts of the plant can lead to significant efficiency gains.

The syngas from the gasifier must first be cleaned to remove impurities such as alkali metals that might damage the gas turbine. The clean gas is fed into the combustor of the gas turbine where it is burned, generating a flow of hot gas which drives the turbine, generating electricity.

Hot exhaust gases from the turbine are then utilised to generate steam in a heat recovery steam generator. The steam drives a steam turbine, producing more power. Low grade waste heat from the steam generator exhaust can be used within the plant, to dry the biomass fuel before it is fed into the gasifier or to preheat the fuel before entry into the gasifier reactor vessel.

Schematic of integrated biomass gasification combined cycle

The gas-fired combined cycle power plant has become one of the most popular configurations for power generation in regions of the world where natural gas is available. The integration of a combined cycle power plant with a coal gasifier is now considered a potentially attractive means of burning coal cleanly in the future.

Biomass Fuel Cell Power Plant

Another potential use for the combustible gas from a biomass gasification plant is as fuel for a fuel cell power plant. Modern high temperature fuel cells are capable of operating with hydrogen, methane and carbon monoxide. Thus product gas from a biomass gasifier could become a suitable fuel.

As with the integrated biomass gasification combined cycle plant, a fuel cell plant would offer high efficiency. A future high temperature fuel cell burning biomass might be able to achieve greater than 50% efficiency.