Energy Value of Agricultural Wastes

Large quantities of agricultural wastes, resulting from crop cultivation activities, are a promising source of energy supply for production, processing and domestic activities in the rural areas. The available agricultural residues are either being used inefficiently or burnt in the open to clear the fields for subsequent crop cultivation.

agricultural-wastes

On an average 1.5 tons of crop residue are generated for processing 1 ton of the main product. In addition, substantial quantities of secondary residues are produced in agro-industries processing farm produce such as paddy, sugarcane, coconut, fruits and vegetables.

Agricultural crop residues often have a disposal cost associated with them. Therefore, the “waste-to-energy” conversion processes for heat and power generation, and even in some cases for transport fuel production, can have good economic and market potential. They have value particularly in rural community applications, and are used widely in countries such as Sweden, Denmark, Netherlands, USA, Canada, Austria and Finland.

The energy density and physical properties of agricultural biomass wastes are critical factors for feedstock considerations and need to be understood in order to match a feedstock and processing technology.

There are six generic biomass processing technologies based on direct combustion (for power), anaerobic digestion (for methane-rich biogas), fermentation (of sugars for alcohols), oil exaction (for biodiesel), pyrolysis (for biochar, gas and oils) and gasification (for carbon monoxide and hydrogen-rich syngas). These technologies can then be followed by an array of secondary treatments (stabilization, dewatering, upgrading, refining) depending on specific final products.

It is well-known that power plants based on baled agricultural residues are efficient and cost-effective energy generators. Residues such as Rice Husks, Wheat Straw and Maize Cobs are already concentrated at a point where it is an easily exploitable source of energy, particularly if it can be utilized on-site to provide combined heat and power.

The selection of processing technologies needs to be aligned to the nature and structure of the biomass feedstock and the desired project outputs. It can be seen that direct combustion or gasification of biomass are appropriate when heat and power are required.

Anaerobic digestion, fermentation and oil extraction are suitable when specific biomass wastes are available that have easily extractable oils and sugars or high water contents. On the other hand, only thermal processing of biomass by pyrolysis can provide the platform for all of the above forms of product.

Many thermal processing technologies for agricultural wastes require the water content of biomass to be low (<15 per cent) for proper operation. For these technologies the energy cost of drying can represent a significant reduction in process efficiency.

Moisture content is of important interest since it corresponds to one of the main criteria for the selection of energy conversion process technology. Thermal conversion technology requires biomass fuels with low moisture content, while those with high moisture content are more appropriate for biological-based process such as fermentation or anaerobic digestion.

The ash content of biomass influences the expenses related to handling and processing to be included in the overall conversion cost. On the other hand, the chemical composition of ash is a determinant parameter in the consideration of a thermal conversion unit, since it gives rise to problems of slagging, fouling, sintering and corrosion.

Renewable Energy for Water Reuse

Water is essential to life, making it one of the most valuable resources on the planet. We drink it, use it to grow food and stay clean. However, water is of increasingly short supply and the Earth’s population only continues to expand. Many of the countries with the largest populations are also ones that use the most water. For instance, in the United States, the average person uses 110 gallons of water each day. Meanwhile, three-fourths of those living in Africa don’t have access to clean water.

To ensure we have enough water to survive — and share with those in need — the best approach is to conserve this resource and find sustainable ways of recycling it. Currently, conventional methods or water purification use about three percent of the world’s energy supply. This isn’t sustainable long-term and can have adverse effects on the environment.

Recently, however, major steps have been made to reduce both the collective water and carbon footprint. Now, there are multiple, sustainable ways to both save energy and reuse water.

Anaerobic Digestion

Anaerobic digestion — or AD — is the natural process in which microorganisms break down organic materials like industrial residuals, animal manure and sewage sludge. This process takes place in spaces where there is no oxygen, making it an ideal system for cleaning and reusing wastewater. This recycled water can provide nutrients for forest plantations and farmland alike.

For example, in Yucatan, Mexico, the successful implementation of AD systems has provided water to promote reforestation efforts. This system has also helped accelerate the search for a sustainable solution to water-sanitation issues in rural Latin American communities.

Additionally, AD also reduces adverse environmental impacts. As the system filters water, it creates two byproducts — biogas and sludge. The biogas can be used as energy to supply electricity or even fuel vehicles. And the sludge is used as fertilizers and bedding for livestock. In poor countries, like Peru, 14 percent of primary energy comes from biogas, providing heat for food preparation and electricity to homes that would not have access to it otherwise.

Vapor Compression Distillation

In this process, the vapor produced by evaporating water is compressed, increasing pressure and temperature. This vapor is then condensed to water for injection — highly purified water that can be used to make pharmaceutical-grade solutions.

Vapor compression distillation is incredibly sustainable because it can produce pure water on combustible fuel sources like cow dung — no chemicals, filters or electricity necessary. This makes it water accessible to even the most rural communities. The system only needs enough energy to start the first boil and a small amount to power the compressor. This energy can be easily supplied by a solar panel, producing roughly 30 liters of water an hour using no more energy than that of a handheld hairdryer.

Solar Distillation

Utilizing solar energy for water treatment may be one of the most sustainable solutions to the water crisis, without sacrificing the environment or non-renewable resources. Between 80 and 90 percent of all energy collected through commercial solar panels is wasted, shed into the atmosphere as heat. However, recent advancements in technology have allowed scientists to capture this heat and use it to generate clean, recycled water.

By integrating a solar PV panel-membrane distillation device behind solar panels, researchers were able to utilize heat to drive water distillation. This panel also increases solar to electricity efficiency. This device can even be used to desalinate seawater, providing a sustainable solution to generating freshwater from saltwater.

Environmental and Economic Benefits

Finding sustainable methods of recycling water is essential to reducing energy consumption and helping the planet, and all those dependent upon it, thrive. Using methods like anaerobic digestion and environmentally-friendly distillation processes can reduce toxic emissions and provide purified, recycled water to those who need it most.

Sustainable reuse of water can also benefit the economy. The financial costs of constructing and operating desalination and purification systems are often high compared to the above solutions. Furthermore, using recycled water that is of lower quality for agricultural and reforestation purposes saves money by reducing treatment requirements.

Comparison of MSW-to-Energy Processes

MSW-to-Energy is the use of thermochemical and biochemical technologies to recover energy, usually in the form of electricity, steam and other fuels, from urban wastes. The main categories of MSW-to-energy technologies are physical technologies, which process waste to make it more useful as fuel; thermal technologies, which can yield heat, fuel oil, or syngas from both organic and inorganic wastes; and biological technologies, in which bacterial fermentation is used to digest organic wastes to yield fuel. These new technologies can reduce the volume of the original waste by 90%, depending upon composition and use of outputs.

Components of MSW-to-Energy Systems

  1. Front-end MSW preprocessing
  2. Conversion unit (reactor or anaerobic digester)
  3. Gas cleanup and residue treatment plant
  4. Energy recovery plant (optional)
  5. Emissions clean up

Incineration

  • Combustion of raw MSW, moisture less than 50%
  • Sufficient amount of oxygen is required to fully oxidize the fuel
  • Combustion temperatures are in excess of 850oC
  • Waste is converted into CO2 and water concern about toxics (dioxin, furans)
  • Any non-combustible materials (inorganic such as metals, glass) remain as a solid, known as bottom ash (used as feedstock in cement and brick manufacturing)
  • Air pollution control system for fly ash, bottom ash, particulates etc.
  • Needs high calorific value waste to keep combustion process going, otherwise requires high energy for maintaining high temperatures

Anaerobic Digestion

  • Well-known biochemical technology for organic fraction of MSW and sewage sludge.
  • Biological conversion of biodegradable organic materials in the absence of oxygen at mesophilic or thermophilic temperatures.
  • Residue is stabilized organic matter that can be used as soil amendment
  • Digestion is used primarily to reduce quantity of sludge for disposal / reuse
  • Methane gas is generated which is used for heat and power generation.

Gasification

  • Can be seen as between pyrolysis and combustion (incineration) as it involves partial oxidation.
  • Exothermic process (some heat is required to initialize and sustain the gasification process).
  • Oxygen is added but at low amounts not sufficient for full oxidation and full combustion.
  • Temperatures are above 650oC
  • Main product is syngas, typically has net calorific value of 4 to 10 MJ/Nm3
  • Other product is solid residue of non-combustible materials (ash) which contains low level of carbon

Pyrolysis

  • Thermal degradation of organic materials through use of indirect, external source of heat
  • Temperatures between 300 to 850oC are maintained for several seconds in the absence of oxygen.
  • Product is char, oil and syngas composed primarily of O2, CO, CO2, CH4 and complex hydrocarbons.
  • Syngas can be utilized for energy production or proportions can be condensed to produce oils and waxes
  • Syngas typically has net calorific value (NCV) of 10 to 20 MJ/Nm

Plasma Gasification

  • Use of electricity passed through graphite or carbon electrodes, with steam and/or oxygen / air injection to produce electrically conducting gas (plasma)
  • Temperatures are above 3000oC
  • Organic materials are converted to syngas composed of H2, CO
  • Inorganic materials are converted to solid slag
  • Syngas can be utilized for energy production or proportions can be condensed to produce oils and waxes

MSW-to-energy technologies can address a host of environmental issues, such as land use and pollution from landfills, and increasing reliance on fossil fuels. In many countries, the availability of landfill capacity has been steadily decreasing due to regulatory, planning and environmental permitting constraints. As a result, new approaches to waste management are rapidly being written into public and institutional policies at local, regional and national levels.

Food Waste Management in UK

Food waste in the United Kingdom is a matter of serious environmental, economic and social concern that has been attracting widespread attention in recent years. According to ‘Feeding the 5K’ organisation, 13,000 slices of crusts are thrown away every day by a single sandwich factory. More recently, Tesco, one of the largest UK food retailers, has published its sustainability report admitting that the company generated 28,500 tonnes of food waste in the first six months of 2013. TESCO’s report also state that 47% of the bakery produced is wasted. In terms of GHG emissions, DEFRA estimated that food waste is associated with 20 Mt of CO2 equivalent/year, which is equivalent to 3% of the total annual GHG emissions.

Food-Waste-UK

Globally, 1.2 to 2 billion tonnes (30%-50%) of food produced is thrown away before it reaches a human stomach. Food waste, if conceived as a state, is responsible for 3.3 Bt-CO2 equivalent/year, which would make it the third biggest carbon emitter after China and USA.

What makes food waste an even more significant issue is the substantially high demand for food which is estimated to grow 70% by 2050 due to the dramatic increase of population which is expected to reach 9.5 billion by 2075. Therefore, there is an urgent need to address food waste as a globally challenging issue which should be considered and tackled by sustainable initiatives.

A War on Food Waste

The overarching consensus to tackle the food waste issue has led to the implementation of various policies. For instance, the European Landfill Directive (1999/31/EC) set targets to reduce organic waste disposed to landfill in 2020 to 35% of that disposed in 1995 (EC 1999). More recently, the European Parliament discussed a proposal to “apply radical measures” to halve food waste by 2025 and to designate the 2014 year as “the European Year Against Food Waste”. In the light of IMechE’s report (2013), the United Nations Environment Programme (UNEP) in cooperation with FAO has launched the Save Food Initiative in an attempt to reduce food waste generated in the global scale.

In the UK, WRAP declared a war on food waste by expanding its organic waste programme in 2008 which was primarily designed to “establish the most cost-effective and environmentally sustainable ways of diverting household food waste from landfill that leads to the production of a saleable product”. DEFRA has also identified food waste as a “priority waste stream” in order to achieve better waste management performance. In addition to governmental policies, various voluntary schemes have been introduced by local authorities such as Nottingham Declaration which aims to cut local CO2 emissions 60% by 2050.

Sustainable Food Waste Management

Engineering has introduced numerous technologies to deal with food waste. Many studies have been carried out to examine the environmental and socio-economic impacts of food waste management options. This article covers the two most preferable options; anaerobic digestion and composting.

In-vessel composting (IVC) is a well-established technology which is widely used to treat food waste aerobically and convert it into a valuable fertilizer. IVC is considered a sustainable option because it helps by reducing the amount of food waste landfilled. Hence, complying with the EU regulations, and producing a saleable product avoiding the use of natural resources.

IVC is considered an environmentally favourable technology compared with other conventional options (i.e. landfill and incineration). It contributes less than 0.06% to the national greenhouse gas inventories. However, considering its high energy-intensive collection activities, the overall environmental performance is “relatively poor”.

Anaerobic Digestion (AD) is a leading technology which has had a rapidly growing market over the last few years. AD is a biologically natural process in which micro-organisms anaerobically break down food waste and producing biogas which can be used for both Combined Heat & Power (CHP) and digestate that can be used as soil fertilizers or conditioners. AD has been considered as the “best option” for food waste treatment. Therefore, governmental and financial support has been given to expand AD in the UK.

AD is not only a food waste treatment technology, but also a renewable source of energy. For instance, It is expected that AD would help the UK to meet the target of supplying 15% of its energy from renewable sources by 2020. Furthermore, AD technology has the potential to boost the UK economy by providing 35,000 new jobs if the technology is adopted nationally to process food waste. This economic growth will significantly improve the quality of life among potential beneficiaries and thus all sustainability elements are considered.

Biomethane Utilization Pathways

Biogas can be used in raw (without removal of CO2) or in upgraded form. The main function of upgrading biogas is the removal of CO2 (to increase the energy content) and H2S (to reduce risk of corrosion). After upgrading, biogas becomes biomethane and possesses identical gas quality properties as  natural gas, and can thus be used as natural gas replacement. The main pathways for biomethane utilization are as follows:

  • Production of heat and/or steam
  • Electricity production / combined heat and power production (CHP)
  • Natural gas replacement (gas grid injection)
  • Compressed natural gas (CNG) & diesel replacement – (bio-CNG for transport fuel usage)
  • Liquid natural gas (LNG) replacement – (bio-LNG for transport fuel usage)

Prior to practically all utilization options, the biogas has to be dried (usually through application of a cooling/condensation step). Furthermore, elements such as hydrogen sulphide and other harmful trace elements must be removed (usually trough application of an activated carbon filter) to prevent adverse effects on downstream processing equipment (such as compressors, piping, boilers and CHP systems).

biomethane-transport

Although biogas is perfectly suitable to be utilized in boilers (as an environmental friendlier source for heat and steam production), this option is rather obsolete due to the abundance of alternative sources from solid waste origin.

Most Palm Oil Mills are already self-reliant with respect to heat and steam production due to the combustion of their solid waste streams (such as EFB and PKS). Consequently, conversion to electricity (by means of a CHP unit) or utilization as natural gas, CNG or LNG replacement, would be a more sensible solution.

The biogas masterplan as drafted by the Asia Pacific Biogas Alliance foresees a distribution in which 30% of the biomethane is used for power generation, 40% for grid injection and 30% as compressed/liquefied fuel for transportation purpose (Asian Pacific Biogas Alliance, 2015).

For each project, the most optimal option has to be evaluated on a case to case basis. Main decision-making factors will be local energy prices and requirements, available infrastructure (for gas and electricity), incentives and funding.

For the locations where local demand is exceeded, and no electricity or gas infrastructure is available within a reasonable distance (<5-10 km, due to investment cost and power loss), production of CNG could offer a good solution.

Moreover, during the utilization of biogas within a CHP unit only 40-50% of the energetic content of the gas is converted into electricity. The rest of the energy is transformed into heat. For those locations where an abundance of heat is available, such as Palm Oil Mills, this effectively means that 50-60% of the energetic content of the biogas is not utilized. Converting the biogas into biomethane (of gas grid or CNG quality) through upgrading, would facilitate the transportation and commercialisation of over 95%  of the energetic content of the biogas.

Within the CNG utilization route, the raw biogas will be upgraded to a methane content of >96%, compressed to 250 bar and stored in racks with gas bottles. The buffered gas (bottles) will be suitable for transportation by truck or ship. For transportation over large distances (>200km), it will be advised to further reduce the gas volume by converting the gas to LNG (trough liquefaction).

Overall the effects and benefits from anaerobic digestion of POME and utilization of biomethane can be summarized as follows:

  • Reduction of emissions i.e. GHG methane and CO2
  • Reduced land use for POME treatment
  • Enhanced self-sufficiency trough availability of on-site diesel replacement (CNG)
  • Expansion of economic activities/generation of additional revenues
    • Sales of surplus electricity (local or to the grid)
    • Sales of biomethane (injection into the natural gas grid)
    • Replacement of on-site diesel usage by CNG
    • Sales of bottled CNG
  • Reducing global and local environmental impact (through fuel replacement)
  • Reducing dependence on fossil fuel, and enhances fuel diversity and security of energy supply
  • Enhancement of local infrastructure and employment
    • Through electrical and gas supply
    • Through Fuel (CNG) supply

Co-Authors: H. Dekker and E.H.M. Dirkse (DMT Environmental Technology)

Note: This is the second article in the special series on ‘Sustainable Utilization of POME-based Biomethane’ by Langerak et al of DMT Environmental Technology (Holland). The first article can be viewed at this link

Anaerobic Digestion of Animal Manure

Animal manure is a valuable source of nutrients and renewable energy. However, most of the manure is collected in lagoons or left to decompose in the open which pose a significant environmental hazard. The air pollutants emitted from manure include methane, nitrous oxide, ammonia, hydrogen sulfide, volatile organic compounds and particulate matter, which can cause serious environmental concerns and health problems. In the past, livestock waste was recovered and sold as a fertilizer or simply spread onto agricultural land. The introduction of tighter environmental controls on odour and water pollution means that some form of waste management is necessary, which provides further incentives for biomass-to-energy conversion.

Anaerobic digestion is a unique treatment solution for animal manure as it can  deliver  positive  benefits  related  to  multiple  issues,  including  renewable  energy,  water pollution, and air emissions. Anaerobic digestion of animal manure is gaining popularity as a means to protect the environment and to recycle materials efficiently into the farming systems. Waste-to-Energy (WTE) plants, based on anaerobic digestion of cow manure, are highly efficient in harnessing the untapped renewable energy potential of organic waste by converting the biodegradable fraction of the waste into high calorific gases.

The establishment of anaerobic digestion systems for livestock manure stabilization and energy production has accelerated substantially in the past several years. There are thousands of digesters operating at commercial livestock facilities in Europe, United States,  Asia and elsewhere. which are generating clean energy and fuel. Many of the projects that generate electricity also capture waste heat for various in-house requirements.

Important Factors

The main factors that influence biogas production from livestock manure are pH and temperature of the feedstock. It is well established that a biogas plant works optimally at neutral pH level and mesophilic temperature of around 35o C. Carbon-nitrogen ratio of the feed material is also an important factor and should be in the range of 20:1 to 30:1. Animal manure has a carbon – nitrogen ratio of 25:1 and is considered ideal for maximum gas production. Solid concentration in the feed material is also crucial to ensure sufficient gas production, as well as easy mixing and handling. Hydraulic retention time (HRT) is the most important factor in determining the volume of the digester which in turn determines the cost of the plant; the larger the retention period, higher the construction cost.

Process Description

The fresh animal manure is stored in a collection tank before its processing to the homogenization tank which is equipped with a mixer to facilitate homogenization of the waste stream. The uniformly mixed waste is passed through a macerator to obtain uniform particle size of 5-10 mm and pumped into suitable-capacity anaerobic digesters where stabilization of organic waste takes place.

In anaerobic digestion, organic material is converted to biogas by a series of bacteria groups into methane and carbon dioxide. The majority of commercially operating digesters are plug flow and complete-mix reactors operating at mesophilic temperatures. The type of digester used varies with the consistency and solids content of the feedstock, with capital investment factors and with the primary purpose of digestion.

Biogas contain significant amount of hydrogen sulfide (H2S) gas which needs to be stripped off due to its highly corrosive nature. The removal of H2S takes place in a biological desulphurization unit in which a limited quantity of air is added to biogas in the presence of specialized aerobic bacteria which oxidizes H2S into elemental sulfur. Biogas can be used as domestic cooking, industrial heating, combined heat and power (CHP) generation as well as a vehicle fuel. The digested substrate is passed through screw presses for dewatering and then subjected to solar drying and conditioning to give high-quality organic fertilizer.

Renewable Energy from Food Residuals

Food residuals are an untapped renewable energy source that mostly ends up rotting in landfills, thereby releasing greenhouse gases into the atmosphere. Food residuals are difficult to treat or recycle since it contains high levels of sodium salt and moisture, and is mixed with other waste during collection. Major generators of food wastes include hotels, restaurants, supermarkets, residential blocks, cafeterias, airline caterers, food processing industries, etc.

In United States, food scraps is the third largest waste stream after paper and yard waste. Around 12.7 percent of the total municipal solid waste (MSW) generated in the year 2008 was food scraps that amounted to about 32 million tons. According to EPA, about 31 million tons of food waste was thrown away into landfills or incinerators in 2008. As far as United Kingdom is concerned, households throw away 8.3 million tons of food each year. These statistics are an indication of tremendous amount of food waste generated all over the world.

The proportion of food residuals in municipal waste stream is gradually increasing and hence a proper food waste management strategy needs to be devised to ensure its eco-friendly and sustainable disposal. Currently, only about 3 percent of food waste is recycled throughout U.S., mainly through composting. Composting provides an alternative to landfill disposal of food waste, however it requires large areas of land, produces volatile organic compounds and consumes energy. Consequently, there is an urgent need to explore better recycling alternatives.

Anaerobic digestion has been successfully used in several European and Asian countries to stabilize food wastes, and to provide beneficial end-products. Sweden, Austria, Denmark, Germany and England have led the way in developing new advanced biogas technologies and setting up new projects for conversion of food waste into energy.

Anaerobic Digestion of Food Waste

Anaerobic digestion is the most important method for the treatment of organic waste, such as food residuals, because of its techno-economic viability and environmental sustainability. The use of anaerobic digestion technology generates biogas and preserves the nutrients which are recycled back to the agricultural land in the form of slurry or solid fertilizer.

The relevance of biogas technology lies in the fact that it makes the best possible use of various organic wastes as a renewable source of clean energy. A biogas plant is a decentralized energy system, which can lead to self-sufficiency in heat and power needs, and at the same time reduces environmental pollution. Thus, anaerobic digestion of food waste can lead to climate change mitigation, economic benefits and landfill diversion opportunities.

Of the different types of organic wastes available, food waste holds the highest potential in terms of economic exploitation as it contains high amount of carbon and can be efficiently converted into biogas and organic fertilizer. Food waste can either be used as a single substrate in a biogas plant, or can be co-digested with organic wastes like cow manure, poultry litter, sewage, crop residues, slaughterhouse wastes, etc.

A Typical Energy Conversion Plant

The feedstock for the food waste-to-energy plant includes leftover food, vegetable refuse, stale cooked and uncooked food, meat, teabags, napkins, extracted tea powder, milk products, etc. Raw waste is shredded to reduce to its particle size to less than 12 mm. The primary aim of shredding is to produce a uniform feed and reduce plant “down-time” due to pipe blockages by large food particles. It also improves mechanical action and digestibility and enables easy removal of any plastic bags or cling-film from waste.

Fresh waste and re-circulated digestate (or digested food waste) are mixed in a mixing tank. The digestate is added to adjust the solids content of the incoming waste stream from 20 to 25 percent (in the incoming waste) to the desired solids content of the waste stream entering the digestion system (10 to 12 percent total solids). The homogenized waste stream is pumped into the feeding tank, from which the anaerobic digestion system is continuously fed. Feeding tank also acts as a pre-digester and subjected to heat at 55º to 60º C to eliminate pathogens and to facilitate the growth of thermophilic microbes for faster degradation of waste.

From the predigestor tank, the slurry enters the main digester where it undergoes anaerobic degradation by a consortium of Archaebacteria belonging to Methanococcus group. The anaerobic digester is a CSTR reactor having average retention time of 15 to 20 days. The digester is operated in the mesophilic temperature range (33º to 38°C), with heating carried out within the digester. Food waste is highly biodegradable and has much higher volatile solids destruction rate (86 to 90 percent) than biosolids or livestock manure. As per conservative estimates, each ton of food waste produces 150 to 200 m3 of biogas, depending on reactor design, process conditions, waste composition, etc.

Biogas contains significant amount of hydrogen sulfide (H2S) gas that needs to be stripped off due to its corrosive nature. The removal of H2S takes place in a biological desulphurization unit in which a limited quantity of air is added to biogas in the presence of specialized aerobic bacteria that oxidizes H2S into elemental sulfur. The biogas produced as a result of anaerobic digestion of waste is sent to a gas holder for temporary storage. Biogas is eventually used in a combined heat and power (CHP) unit for its conversion into thermal and electrical energy in a co­generation power station of suitable capacity. The exhaust gases from the CHP unit are used for meeting process heat requirements.

The digested substrate leaving the reactor is rich in nutrients like nitrogen, potassium and phosphorus which are beneficial for plants as well as soil. The digested slurry is dewatered in a series of screw presses to remove the moisture from slurry. Solar drying and additives are used to enhance the market value and handling characteristics of the fertilizer.

Diverting Food from Landfills

Food residuals are one of the single largest constituents of municipal solid waste stream. Diversion of food waste from landfills can provide significant contribution towards climate change mitigation, apart from generating revenues and creating employment opportunities. Rising energy prices and increasing environmental pollution makes it more important to harness renewable energy from food scraps.

Anaerobic digestion technology is widely available worldwide and successful projects are already in place in several European as well as Asian countries that makes it imperative on waste generators and environmental agencies to root for a sustainable food waste management system.

Biogas from Crop Wastes: European Perspectives

Most, if not all of Europe has a suitable climate for biogas production. The specific type of system depends on the regional climate. Regions with harsher winters may rely more on animal waste and other readily available materials compared to warmer climates, which may have access to more crop waste or organic material.

Regardless of suitability, European opinions vary on the most ethical and appropriate materials to use for biogas production. Multiple proponents argue biogas production should be limited to waste materials derived from crops and animals, while others claim crops should be grown with the intention of being used for biogas production.

Biogas Production From Crops

Europeans in favor of biogas production from crops argue the crops improve the quality of the soil. Additionally, they point to the fact that biogas is a renewable energy resource compared to fossil fuels. Crops can be rotated in fields and grown year after year as a sustainable source of fuel.

Extra crops can also improve air quality. Plants respire carbon dioxide and can help reduce harmful greenhouse gasses in the air which contribute to global climate change.

Biogas crops can also improve water quality because of plant absorption. Crops grown in otherwise open fields reduce the volume of water runoff which makes it to lakes, streams and rivers. The flow of water and harmful pollutants is impeded by the plants and eventually absorbed into the soil, where it is purified.

Urban residents can also contribute to biogas production by growing rooftop or vertical gardens in their homes. Waste from tomatoes, beans and other vegetables is an excellent source of biogas material. Residents will benefit from improved air quality and improved water quality as well by reducing runoff.

Proponents of biogas production from crops aren’t against using organic waste material for biogas production in addition to crop material. They believe crops offer another means of using more sustainable energy resources.

Biogas Production From Waste Materials Only

Opponents to growing crops for biogas argue the crops used for biogas production degrade soil quality, making it less efficient for growing crops for human consumption. They also argue the overall emissions from biogas production from crops will be higher compared to fossil fuels.

Growing crops can be a labor-intensive process. Land must be cleared, fertilized and then seeded. While crops are growing, pesticides and additional fertilizers may be used to promote crop growth and decrease losses from pests. Excess chemicals can run off of fields and degrade the water quality of streams, lakes and rivers and kill off marine life.

Once crops reach maturity, they must be harvested and processed to be used for biogas material. Biogas is less efficient compared to fossil fuels, which means it requires more material to yield the same amount of energy. Opponents argue that when the entire supply chain is evaluated, biogas from crops creates higher rates of emissions and is more harmful to the environment.

Agricultural residues, such as rice straw, are an important carbon source for anaerobic digestion

The supply chain for biogas from agricultural waste materials is more efficient compared to crop materials. Regardless of whether or not the organic waste is reused, it must be disposed of appropriately to prevent any detrimental environmental impacts. When the waste material is then used for biogas production, it creates an economical means of generating useful electricity from material which would otherwise be disposed of.

Rural farms which are further away from the electric grid can create their own sources of energy through biogas production from waste material as well. The cost of the energy will be less expensive and more eco-friendly as it doesn’t have the associated transportation costs.

Although perspectives differ on the type of materials which should be used for biogas production, both sides agree biogas offers an environmentally friendly and sustainable alternative to using fossil fuels.

Miscanthus: Reducing the Establishment Costs

Miscanthus-Elephant-GrassMiscanthus has been lauded as a dynamic high potential biomass crop for some time now due to its high yields, low input requirements and perennial nature. Miscanthus is commonly used as a biomass fuel to produce heat and electricity through combustion, but studies have found that miscanthus can produce similar biogas yields to maize when harvested at certain times of the year.  Miscanthus is a C4 grass closely related to maize and sugarcane, it can grow to heights of three metres in a single growing season.

High Establishment Costs

However, high establishment costs have impeded the popularity of the crop. High establishment costs of miscanthus are as a result of the sterile nature of the crop, which means that miscanthus cannot be propagated from seed and instead must be propagated from vegetative material. The vegetative material commonly used is taken from the root structure known as rhizomes; rhizome harvesting is a laborious process and when combined with low multiplication rates, results in a high cost for miscanthus rhizomes. The current figure based on Irish figures is €1,900 ha for rhizomes.

Promising Breakthrough

Research conducted in Teagasc Oak Park Carlow Ireland, suggests that there may be a cost effective of method of propagating miscanthus by using the stem as the vegetative material rather than having to dig up expensive rhizomes. The system has been proven in a field setting over two growing seasons and plants have been shown to be perennial.

A prototype planter suitable for commercial up scaling has been developed to sow stem segments of miscanthus. Initial costs are predicted at €130 ha for plant material. The image below shows the initial stem that was planted in a field setting and the shoots, roots, and rhizome developed by the stem at the end of the first growing season.

miscanthus-stem

Feedstock for AD Plants

Switching from maize to miscanthus as a feedstock for anaerobic digestion plants would increase profitability and boost the GHG abatement credentials of the systems. Miscanthus is a perennial crop which would provide a harvest every year once established for 20 years in a row without having to be replanted compared to maize which is replanted every year. This would provide an obvious economic saving as well as allowing carbon sequestration in the undisturbed soil.

There would be further GHG savings from the reduced diesel consumption required for the single planting as opposed to carrying out heavy seedbed cultivation each year for maize. Miscanthus harvested as an AD feedstock would also alleviate soil compaction problems associated with maize production through an earlier harvest in more favourable conditions.

Future Perspectives

Miscanthus is a nutrient efficient crop due to nutrient cycling. With the onset of senescence nutrients in the stem are transferred back to the rhizome and over-wintered for the following year’s growth. However the optimum date to harvest biomass to produce biogas is before senescence. This would mean that a significant proportion of the plants nutrient stores would be removed which would need to be replaced. Fertiliser in the form of digestate generated from a biogas plant could be land spread to bridge nutrient deficiencies. However additional more readily available chemical N fertiliser may have to be applied.

Some work at Oak Park on September harvested miscanthus crops has seen significant responses from a range of N application rates. With dwindling subsidies to support anaerobic digestion finding a low cost perennial high yielding feedstock could be key to ensuring economic viability.

Description of a Biogas Power Plant

A biogas plant is a decentralized energy system, which can lead to self-sufficiency in heat and power needs, and at the same time reduces environmental pollution. The components of a modern biogas (or anaerobic digestion) plant include: manure collection, anaerobic digester, effluent treatment, biogas storage, and biogas use/electricity generating equipment.

Working of a Biogas Plant

The fresh animal manure is stored in a collection tank before its processing to the homogenization tank which is equipped with a mixer to facilitate homogenization of the waste stream. The uniformly mixed waste is passed through a macerator to obtain uniform particle size of 5-10 mm and pumped into suitable-capacity anaerobic digesters where stabilization of organic waste takes place.

In anaerobic digestion, organic material is converted to biogas by a series of bacteria groups into methane and carbon dioxide. The majority of commercially operating digesters are plug flow and complete-mix reactors operating at mesophilic temperatures. The type of digester used varies with the consistency and solids content of the feedstock, with capital investment factors and with the primary purpose of digestion.

Biogas Cleanup

Biogas contain significant amount of hydrogen sulfide (H2S) gas which needs to be stripped off due to its highly corrosive nature. The removal of H2S takes place in a biological desulphurization unit in which a limited quantity of air is added to biogas in the presence of specialized aerobic bacteria which oxidizes H2S into elemental sulfur.

Utilization of Biogas

Biogas is dried and vented into a CHP unit to a generator to produce electricity and heat. The size of the CHP system depends on the amount of biogas produced daily.

Treatment of Digestate

The digested substrate is passed through screw presses for dewatering and then subjected to solar drying and conditioning to give high-quality organic fertilizer.  The press water is treated in an effluent treatment plant based on activated sludge process which consists of an aeration tank and a secondary clarifier. The treated wastewater is recycled to meet in-house plant requirements.

Monitoring of Environmental Parameters

A chemical laboratory is necessary to continuously monitor important environmental parameters such as BOD, COD, VFA, pH, ammonia, C:N ratio at different locations for efficient and proper functioning of the process.

Control System

The continuous monitoring of the biogas plant is achieved by using a remote control system such as Supervisory Control and Data Acquisition (SCADA) system. This remote system facilitates immediate feedback and adjustment, which can result in energy savings.