Tag Archives: Agricultural residues

A Glance at Biomass Resources

  By Salman Zafar | March 5, 2012 - 9:41 am | Agricultural Residues, biogas, Biomass Energy, Energy-from-Waste, Waste-to-energy
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Biomass is the material derived from plants that use sunlight to grow which include plant and animal material such as wood from forests, material left over from agricultural and forestry processes, and organic industrial, human and animal wastes. The energy contained in biomass originally came from the sun. Through photosynthesis carbon dioxide in the air is transformed into other carbon containing molecules (e.g. sugars, starches and cellulose) in plants. The chemical energy that is stored in plants and animals (animals eat plants or other animals) or in their waste is called bio-energy. Biomass comes from a variety of sources which include:

  • Wood from natural forests and woodlands
  • Forestry plantations
  • Forestry residues
  • Agricultural residues such as straw, stover, cane trash and green agricultural wastes
  • Agro-industrial wastes, such as sugarcane bagasse and rice husk
  • Animal wastes
  • Industrial wastes, such as black liquor from paper manufacturing
  • Sewage
  • Municipal solid wastes (MSW)
  • Food processing wastes

Biomass energy projects provide major business opportunities, environmental benefits, and rural development.  Feedstocks can be obtained from a wide array of sources without jeopardizing the food and feed supply, forests, and biodiversity in the world.

Agricultural Residues

Crop residues encompasses all agricultural wastes such as bagasse, straw, stem, stalk, leaves, husk, shell, peel, pulp, stubble, etc. Large quantities of crop residues are produced annually worldwide, and are vastly underutilised. Rice produces both straw and rice husks at the processing plant which can be conveniently and easily converted into energy. Significant quantities of biomass remain in the fields in the form of cob when maize is harvested which can be converted into energy. Sugar cane harvesting leads to harvest residues in the fields while processing produces fibrous bagasse, both of which are good sources of energy. Harvesting and processing of coconuts produces quantities of shell and fibre that can be utilized.

Current farming practice is usually to plough these residues back into the soil, or they are burnt, left to decompose, or grazed by cattle. These residues could be processed into liquid fuels or thermochemical processed to produce electricity and heat. Agricultural residues are characterized by seasonal availability and have characteristics that differ from other solid fuels such as wood, charcoal, char briquette. The main differences are the high content of volatile matter and lower density and burning time.

Animal Waste

There are a wide range of animal wastes that can be used as sources of biomass energy. The most common sources are animal and poultry manures. In the past this waste was recovered and sold as a fertilizer or simply spread onto agricultural land, but the introduction of tighter environmental controls on odour and water pollution means that some form of waste management is now required, which provides further incentives for waste-to-energy conversion.

The most attractive method of converting these waste materials to useful form is anaerobic digestion which gives biogas that can be used as a fuel for internal combustion engines, to generate electricity from small gas turbines, burnt directly for cooking, or for space and water heating.

Forestry Residues

Forestry residues are generated by operations such as thinning of plantations, clearing for logging roads, extracting stem-wood for pulp and timber, and natural attrition. Harvesting may occur as thinning in young stands, or cutting in older stands for timber or pulp that also yields tops and branches usable for biomass energy. Harvesting operations usually remove only 25 to 50 percent of the volume, leaving the residues available as biomass for energy.

Stands damaged by insects, disease or fire are additional sources of biomass. Forest residues normally have low density and fuel values that keep transport costs high, and so it is economical to reduce the biomass density in the forest itself.

Wood Wastes

Wood processing industries primarily include sawmilling, plywood, wood panel, furniture, building component, flooring, particle board, moulding, jointing and craft industries. Wood wastes generally are concentrated at the processing factories, e.g. plywood mills and sawmills. The amount of waste generated from wood processing industries varies from one type industry to another depending on the form of raw material and finished product.

Generally, the waste from wood industries such as saw millings and plywood, veneer and others are sawdust, off-cuts, trims and shavings. Sawdust arise from cutting, sizing, re-sawing, edging, while trims and shaving are the consequence of trimming and smoothing of wood. In general, processing of 1,000 kg of wood in the furniture industries will lead to waste generation of almost half (45 %), i.e. 450 kg of wood. Similarly, when processing 1,000 kg of wood in sawmill, the waste will amount to more than half (52 %), i.e. 520 kg wood.

Industrial Wastes

The food industry produces a large number of residues and by-products that can be used as biomass energy sources. These waste materials are generated from all sectors of the food industry with everything from meat production to confectionery producing waste that can be utilised as an energy source.

Solid wastes include peelings and scraps from fruit and vegetables, food that does not meet quality control standards, pulp and fibre from sugar and starch extraction, filter sludges and coffee grounds. These wastes are usually disposed of in landfill dumps.

Liquid wastes are generated by washing meat, fruit and vegetables, blanching fruit and vegetables, pre-cooking meats, poultry and fish, cleaning and processing operations as well as wine making.

These waste waters contain sugars, starches and other dissolved and solid organic matter. The potential exists for these industrial wastes to be anaerobically digested to produce biogas, or fermented to produce ethanol, and several commercial examples of waste-to-energy conversion already exist.

Pulp and paper industry is considered to be one of the highly polluting industries and consumes large amount of energy and water in various unit operations. The wastewater discharged by this industry is highly heterogeneous as it contains compounds from wood or other raw materials, processed chemicals as well as compound formed during processing.  Black liquor can be judiciously utilized for production of biogas using anaerobic UASB technology.

Municipal Solid Wastes and Sewage

Millions of tonnes of household waste are collected each year with the vast majority disposed of in open fields. The biomass resource in MSW comprises the putrescibles, paper and plastic and averages 80% of the total MSW collected. Municipal solid waste can be converted into energy by direct combustion, or by natural anaerobic digestion in the engineered landfill. At the landfill sites the gas produced by the natural decomposition of MSW (approximately 50% methane and 50% carbon dioxide) is collected from the stored material and scrubbed and cleaned before feeding into internal combustion engines or gas turbines to generate heat and power. The organic fraction of MSW can be anaerobically stabilized in a high-rate digester to obtain biogas for electricity or steam generation.

Sewage is a source of biomass energy that is very similar to the other animal wastes. Energy can be extracted from sewage using anaerobic digestion to produce biogas. The sewage sludge that remains can be incinerated or undergo pyrolysis to produce more biogas.

Defining Agricultural Residues

  By Salman Zafar | February 14, 2012 - 9:35 am | Agricultural Residues, Biomass Energy
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The term agricultural residue is used to describe all the organic materials which are produced as by-products from harvesting and processing of agricultural crops. These residues can be further categorized into primary residues and secondary residues. Agricultural residues, which are generated in the field at the time of harvest, are defined as primary or field based residues whereas those co-produced during processing are called secondary or processing based residues.

  • Primary residues – paddy straw, sugarcane top, maize stalks, coconut empty bunches and frond, palm oil frond and bunches;
  • Secondary residues – paddy husk, bagasse, maize cob, coconut shell, coconut husk, coir dust, saw dust, palm oil shell, fiber and empty bunches, wastewater, black liquor.

Agricultural residues are highly important sources of biomass fuels for both the domestic and industrial sectors. Availability of primary residues for energy application is usually low since collection is difficult and they have other uses as fertilizer, animal feed etc. However secondary residues are usually available in relatively large quantities at the processing site and may be used as captive energy source for the same processing plant involving minimal transportation and handling cost.

Crop residues encompasses all agricultural wastes such as straw, stem, stalk, leaves, husk, shell, peel, pulp, stubble, etc. which come from cereals (rice, wheat, maize or corn, sorghum, barley, millet), cotton, groundnut, jute, legumes (tomato, bean, soy) coffee, cacao, tea, fruits (banana, mango, coco, cashew) and palm oil.

Rice produces both straw and rice husks at the processing plant which can be conveniently and easily converted into energy. Significant quantities of biomass remain in the fields in the form of cob when maize is harvested which can be converted into energy. Sugar cane harvesting leads to harvest residues in the fields while processing produces fibrous bagasse, both of which are good sources of energy. Harvesting and processing of coconuts produces quantities of shell and fibre that can be utilised. Peanuts leave shells. All these materials can be converted into energy.

Anaerobic Digestion of Agricultural Residues

  By Salman Zafar | January 13, 2012 - 10:02 pm | Agricultural Residues, Anaerobic Digestion, biogas
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Agriculture

The main problem with anaerobic digestion of crop residues is that most of the agricultural residues are lignocellulosic with low nitrogen content. To improve the digestibility of crop residues, pre-treatment methods like size reduction, electron irradiation, heat treatment, enzymatic action etc are necessary. For optimizing the C/N ratio of agricultural residues, co-digestion with sewage sludge, animal manure or poultry litter is recommended.

Several organic wastes from plants and animals have been exploited for biogas production as reported in the literature. Plant materials include agricultural crops such as sugar cane, cassava, corn etc, agricultural residues like rice straw, cassava rhizome, corn cobs etc, wood and wood residues (saw dust, pulp wastes, and paper mill. Others include molasses and bagasse from sugar refineries, waste streams such as rice husk from rice mills and residues from palm oil extraction and municipal solid wastes, etc. However, plant materials such as crop residues are more difficult to digest than animal wastes (manures) because of difficulty in achieving hydrolysis of cellulosic and lignocellulosic constituents.

Crop residues can be digested either alone or in co-digestion with other materials, employing either wet or dry processes. In the agricultural sector one possible solution to processing crop biomass is co-digestion together with animal manures, the largest agricultural waste stream. In addition to the production of renewable energy, controlled anaerobic digestion of animal manures reduces emissions of greenhouse gases, nitrogen and odour from manure management, and intensifies the recycling of nutrients within agriculture.

In co-digestion of plant material and manures, manures provide buffering capacity and a wide range of nutrients, while the addition of plant material with high carbon content balances the carbon to nitrogen (C/N) ratio of the feedstock, thereby decreasing the risk of ammonia inhibition. The gas production per digester volume can be increased by operating the digesters at a higher solids concentration. Batch high solids reactors, characterized by lower investment costs than those of continuously fed processes, but with comparable operational costs, are currently applied in the agricultural sector to a limited extent.

Biomass Energy Scenario in Indonesia

  By Salman Zafar | October 31, 2011 - 10:15 am | Biomass Energy, Southeast Asia
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With Indonesia’s recovery from the Asian financial crisis of 1998, energy consumption has grown rapidly in past decade. The priority of the Indonesian energy policy is to reduce oil consumption and to use renewable energy. For power generation, it is important to increase electricity power in order to meet national demand and to change fossil fuel consumption by utilization of biomass wastes. The development of renewable energy is one of priority targets in Indonesia.

It is estimated that Indonesia produces 146.7 million tons of biomass per year, equivalent to about 470 GJ/y. The source of biomass energy is scattered all over the country, but the big potential in concentrated scale can be found in the Island of Kalimantan, Sumatera, Irian Jaya and Sulawesi. Studies estimate the electricity generation potential from the roughly 150 Mt of biomass residues produced per year to be about 50 GW or equivalent to roughly 470 GJ/year. These studies assume that the main source of biomass energy in Indonesia will be rice residues with a technical energy potential of 150 GJ/year. Other potential biomass sources are rubber wood residues (120 GJ/year), sugar mill residues (78 GJ/year), palm oil residues (67 GJ/year), and less than 20 GJ/year in total from plywood and veneer residues, logging residues, sawn timber residues, coconut residues, and other agricultural wastes.

Sustainable and renewable natural resources such as biomass can supply potential raw materials for energy conversion. In Indonesia, they comprise variable-sized wood from forests (i.e. natural forests, plantations and community forests that commonly produce small-diameter logs used as firewood by local people), woody residues from logging and wood industries, oil-palm shell waste from crude palm oil factories, coconut shell wastes from coconut plantations, as well as skimmed coconut oil and straw from rice cultivation.

The major crop residues to be considered for power generation in Indonesia are palm oil sugar processing and rice processing residues. Currently, 67 sugar mills are in operation in Indonesia and eight more are under construction or planned. The mills range in size of milling capacity from less than 1,000 tons of cane per day to 12,000 tons of cane per day. Current sugar processing in Indonesia produces 8 millions MT bagasse and 11.5 millions MT canes top and leaves. There are 39 palm oil plantations and mills currently operating in Indonesia, and at least eight new plantations are under construction. Most palm oil mills generate combined heat and power from fibres and shells, making the operations energy self –efficient. However, the use of palm oil residues can still be optimized in more energy efficient systems.

Other potential source of biomass energy can also come from municipal wastes. The quantity of city or municipal wastes in Indonesia is comparable with other big cities of the world. Most of these wastes are originated from household in the form of organic wastes from the kitchen. At present the wastes are either burned at each household or collected by the municipalities and later to be dumped into a designated dumping ground or landfill. Although the government is providing facilities to collect and clean all these wastes, however, due to the increasing number of populations coupled with inadequate number of waste treatment facilities in addition to inadequate amount of allocated budget for waste management, most of big cities in Indonesia had been suffering from the increasing problem of waste disposals.

The current pressure for cost savings and competitiveness in Indonesia’s most important biomass-based industries, along with the continually growing power demands of the country signal opportunities for increased exploitation of biomass wastes for power generation.

Production of Cellulosic Ethanol

  By Salman Zafar | September 10, 2011 - 7:51 am | Agricultural Residues, Bioethanol, Biofuels, Biomass Energy, Energy-from-Waste, Thermochemical Conversion, Waste-to-energy
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The production of biofuels from lignocellulosic feedstocks can be achieved through two very different processing routes. They are:

  • Biochemical – in which enzymes and other micro-organisms are used to convert cellulose and hemicellulose components of the feedstocks to sugars prior to their fermentation to produce ethanol;
  • Thermo-chemical – where pyrolysis/gasification technologies produce a synthesis gas (CO + H2) from which a wide range of long carbon chain biofuels, such as synthetic diesel or aviation fuel, can be reformed.

Lignocellulosic biomass consists mainly of lignin and the polysaccharides cellulose and hemicellulose. Compared with the production of ethanol from first-generation feedstocks, the use of lignocellulosic biomass is more complicated because the polysaccharides are more stable and the pentose sugars are not readily fermentable by Saccharomyces cerevisiae. In order to convert lignocellulosic biomass to biofuels the polysaccharides must first be hydrolysed, or broken down, into simple sugars using either acid or enzymes. Several biotechnology-based approaches are being used to overcome such problems, including the development of strains of Saccharomyces cerevisiae that can ferment pentose sugars, the use of alternative yeast species that naturally ferment pentose sugars, and the engineering of enzymes that are able to break down cellulose and hemicellulose into simple sugars.

Lignocellulosic processing pilot plants have been established in the EU, in Denmark, Spain and Sweden. The world’s largest demonstration facility of lignocellulose ethanol (from wheat, barley straw and corn stover), with a capacity of 2.5 Ml, was first established by Iogen Corporation in Ottawa, Canada. Many other processing facilities are now in operation or planning throughout the world.

Ethanol from lignocellulosic biomass is produced mainly via biochemical routes. The three major steps involved are pretreatment, enzymatic hydrolysis, and fermentation as shown in Figure. Biomass is pretreated to improve the accessibility of enzymes. After pretreatment, biomass undergoes enzymatic hydrolysis for conversion of polysaccharides into monomer sugars, such as glucose and xylose. Subsequently, sugars are fermented to ethanol by the use of different microorganisms.

Pretreated biomass can directly be converted to ethanol by using the process called simultaneous saccharification and cofermentation (SSCF).  Pretreatment is a critical step which enhances the enzymatic hydrolysis of biomass. Basically, it alters the physical and chemical properties of biomass and improves the enzyme access and effectiveness which may also lead to a change in crystallinity and degree of polymerization of cellulose. The internal surface area and pore volume of pretreated biomass are increased which facilitates substantial improvement in accessibility of enzymes. The process also helps in enhancing the rate and yield of monomeric sugars during enzymatic hydrolysis steps.

Pretreatment methods can be broadly classified into four groups – physical, chemical, physio-chemical and biological. Physical pretreatment processes employ the mechanical comminution or irradiation processes to change only the physical characteristics of biomass. The physio-chemical process utilizes steam or steam and gases, like SO2 and CO2. The chemical processes employs acids (H2SO4, HCl, organic acids etc) or alkalis (NaOH, Na2CO3, Ca(OH)2, NH3 etc). The acid treatment typically shows the selectivity towards hydrolyzing the hemicelluloses components, whereas alkalis have better selectivity for the lignin. The fractionation of biomass components after such processes help in improving the enzymes accessibility which is also important to the efficient utilization of enzymes.

Presently, a ton of dry biomass typically yields 60-70 gallons of bioethanol. The major cost components in bioethanol production from lignocellulosic biomass are the pretreatment and the enzymatic hydrolysis steps. In fact, these two process are someway interrelated too where an efficient pretreatment strategy can save substantial enzyme consumption. Pretreatment step can also affect the cost of other operations such as size reduction prior to pretreatment. Therefore, optimization of these two important steps, which collectively contributes about 70% of the total processing cost, are the major challenges in the commercialization of bioethanol from 2nd generation feedstock.

Biomass Energy Resources in Philippines

  By Salman Zafar | July 27, 2011 - 7:59 am | Biochar, Bioethanol, Biofuels, biogas, Biomass Energy, Clean Energy, Energy-from-Waste, Solid Waste Management, Waste-to-energy
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Like any developing country, the Philippines is facing a formidable challenge of fostering sustainable energy options to support the energy requirements of its economic and social development goals with minimal adverse effects on the environment. In the Philippines, renewable energy sources contribute 43 percent to the country’s primary energy mix, one of the highest in Southeast Asia. The Philippines has an existing capacity of 5,500 MW of renewable energy power. Out of which, 61 percent is hydropower while 37 percent is geothermal power. Biomass energy application accounts for around 15 percent of the primary energy use in the country. The resources available in the Philippines can generate biomass projects with a potential capacity of around 200 MW.

The country has abundant supplies of biomass resources, offering much potential for clean energy generation.  These include agricultural crop residues, forest residues, animal wastes, agro-industrial wastes, municipal solid wastes and aquatic biomass. The most common agricultural wastes are rice hull, bagasse, coconut shell/husk and coconut coir. The use of crop residues as biofuels is increasing in the Philippines as fossil fuel prices continue to rise. Rice hull is perhaps the most important, underdeveloped biomass resource that could be fully utilized in a sustainable manner.

The Philippines is mainly an agricultural country with a land area of 30 million hectares, 47 percent of which is agricultural. The total area devoted to agricultural crops is 13 million hectares distributed among food grains, food crops and non-food crops. Among the crops grown, rice, coconut and sugarcane are major contributors to biomass energy resources. The most common agricultural residues are rice husk, rice straw, coconut husk, coconut shell and bagasse. The country has good potential for biomass power plants as one-third of the country’s agricultural land produces rice, and consequently large volumes of rice straw and hulls are generated.

Major Issues in Biomass Energy Projects

  By Salman Zafar | March 27, 2011 - 11:00 pm | Agricultural Residues, Biochar, Biofuels, biogas, Biomass Energy, Waste-to-energy
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The issues enumerated below are not geography-specific and are usually a matter of concern for most of the biomass energy projects:

  1. Large Project Costs: In India, a 1 MW gasification plant usually costs about USD 1-1.5 million. A combustion-based 1 MW plant would need a little more expenditure, to the tune of USD 1-2 million. An anaerobic digestion-based plant of the same capacity, on the other hand, could range anywhere upwards USD 3 million. Such high capital costs prove to be a big hurdle for any entrepreneur or clean-tech enthusiast to come forward and invest into these technologies.
  2. Low Conversion Efficiencies: In general, efficiencies of combustion-based systems are in the range of 20-25% and gasification-based systems are considered even poorer, with their efficiencies being in the range of a measly10-15%. The biomass resources themselves are low in energy density, and such poor system efficiencies could add a double blow to the entire project.
  3. Dearth of Mature Technologies: Poor efficiencies call for a larger quantum of resources needed to generate a unit amount of energy. Owing to this reason, investors and project developers find it hard to go for such plants on a larger scale. Moreover, the availability of only a few reliable technology and operation & maintenance service providers makes these technologies further undesirable. Gasification technology is still limited to scales lesser than 1 MW in most parts of the world. Combustion-based systems have although gone upwards of 1 MW, a lot many are now facing hurdles because of factors like unreliable resource chain, grid availability, and many others.
  4. Lack of Funding Options: Financing agencies usually give a tough time to biomass project developers as compared to what it takes to invest in other renewable energy technologies.
  5. Non-Transparent Trade Markets: Usually, the biomass energy resources are obtained through forests, farms, industries, animal farms etc. There is no standard pricing mechanism for such resources and these usually vary from vendor to vendor, even with the same resource in consideration.
  6. High Risks / Low Pay-Backs: Biomass energy projects are not much sought-after owing to high project risks which could entail from failed crops, natural disasters, local disturbances, etc.
  7. Resource Price Escalation: Unrealistic fuel price escalation too is a major cause of worry for the plant owners. Usually, an escalation of 3-5% is considered while carrying out the project’s financial modelling. However, it has been observed that in some cases, the rise has been as staggering as 15-20% per annum, forcing the plants to shut down.

Contributed by Setu Goyal, TERI University (New Delhi) who can be reached at setu.goyal@gmail.com)